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Particuology 2024年第3期86卷 205-210页

作者： Chenjing Liang Lingling Shi Zhengguo Chen Lan Zhou Zhaoxia Zhang Guoqing Zhang School of Materials science and Engineering Zhejiang Sci-tech UniversityHangzhouChina College of textile science and Engineering Zhejiang Sci-tech UniversityHangzhouChina Zhejiang Provincial innovation center of Advanced textile technology ShaoxingChina

The aim of this work is to develop a venlafaxine hydrochloride sustained release system based on hollow mesoporous silica microspheres(HMSMs).HMSMs were innovatively prepared with tetraethyl silicate(TEOS)as the precursor and volatile n-heptane as a soft *** obtained HMSMs show a well-defined hollow structure with an average size of 967 nm and pore volume of 0.85 cm^(3)/g,implying it is a potential drug ***,venlafaxine hydrochloride(VF)was absorbed in the HMSMs with a content of 37.67% or *** sustained release effect is further measured by the dissolution in-strument at 37℃ and 50 rpm in ultrapure *** results showed that the HMSMs/VF system shows good sustained release properties compared with sustained release tablets with hydroxypropyl meth-ylcellulose as the main *** HMSMs sustained release system appears to be a promising candidate for a sustained drug release.

关键词： Hollowmesoporous silica microspheres(HMSMs) Venlafaxine hydrochloride Drug loading Sustained release

Polyetherketoneketone/carbon fiber composites with an amorphous interface prepared by solution impregnation

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新型炭材料（中英文） 2024年第4期39卷 692-702页

作者： ZHANG Feng LI Bo-lan JIAO Meng-xiao LI Yan-bo WANG Xin YANG Yu YANG Yu-qiu ZHANG Xiao-hua MOE Key Laboratory of textile science&technology College of TextilesInnovation Center for Textile Science and TechnologyDonghua UniversityShanghai 201620China Key Laboratory of Carbon Materials National Engineering Laboratory for Carbon Fiber TechnologyInstitute of Coal ChemistryChinese Academy of SciencesTaiyuan 030001China

Interfacial adhesion between carbon fibers(CF)and polyetherketoneketone(PEKK)is a key factor that affects the mechanical performances of their *** is therefore of great importance to impregnate the CF bundles with PEKK as effi-ciently as *** report that PEKK with a good dispersion in a mixed solution of 4-chlorophenol and 1,2-dichloroethane can be introduced onto CF surfaces by solution impregnation and curing at 280,320,340 and 360℃.The excellent wettability or infiltra-tion of the PEKK solution guarantees a full covering and its tight binding to CFs,making it possible to evaluate the interfacial shear strength(IFSS)with the microdroplet *** interior of the CF bundles is completely and uniformly filled with PEKK by solu-tion impregnation,leading to a high interlaminar shear strength(ILSS).The maximum IFSS and ILSS reached 107.8 and 99.3 MPa,*** superior shear properties are ascribed to the formation of amorphous PEKK in the small spaces between CFs.

关键词： Polyetherketoneketone Carbon fiber Wettability Amorphous adhesion Interfacial strength

Atomically dispersed Ni electrocatalyst for superior urea-assisted water splitting

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Journal of Energy Chemistry 2024年第3期90卷 1-6,I0002页

作者： Fang Luo Shuyuan Pan Yuhua Xie Chen Li Yingjie Yu Zehui Yang College of Materials science and Engineering State Key Laboratory of New Textile Materials&Advanced Processing TechnologyWuhan Textile UniversityWuhan 430200China Hubei Hydrogen Energy technology innovation center Faculty of Materials Science and ChemistryChina University of GeosciencesWuhan 430074HubeiChina

Urea oxidation reaction(UOR) has been selected as substitution for oxygen evolution reaction ascribing to its low thermodynamic voltage as well as utilization of nickel as ***,we report the formation of nickel single atoms(Ni-SAs) as exceptional bifunctional electrocatalyst toward UOR and hydrogen evolution reaction(HER) in urea-assisted water *** UOR catalysis,Ni-SAs perform a superior catalytic performance than Ni-NP/NC and Pt/C ascribing to the formation of HOO-Ni-N_(4) structure evidenced by in-situ Raman spectroscopy,corresponding to a boosted mass activity by 175-fold at 1.4 V *** than Ni-NP/***,Ni-SAs requires only 450 mV overpotential to obtain HER current density of 500 mA cm^(-2).136 mA cm^(-2) is achieved in urea-assisted water splitting at1.7 V for Ni-SAs,boosted by 5.7 times than Pt/C-IrO_(2) driven water splitting.

关键词： Urea oxidation reaction Hydrogen evolution reaction Nickel single atoms Water splitting

Sequence-Controlled Synthesis of Alternating Poly(ester amide)s using Water as Control Agent in One-Pot

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Chinese Journal of Polymer science 2024年第8期42卷 1015-1020页

作者： Tao Liu Fang-Fang Niu Kan Cheng Yu-Min Xia Bo-Mou Ma Xue-Li Wang Jian-Yong Yu and Yong He State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringDonghua UniversityShanghai 201620China innovation center for textile science and technology Donghua UniversityShanghai 201620China

Poly(ester amide)s(PEAs)attract much attention as a new kind of biodegradable ***,the synthesis of PEAs with sequence-regulated chain structures is still complicated due to the multistep polymerization,high monomer purity,as well as the usage of organic solvents,which greatly inhibits its development and ***,a one-pot strategy without solvent was developed to synthesize the alternating PEA fromα,ω-amino alcohol and dicarboxylic acid by sequential polycondensation,where water was used as the controlling agent for amidation and ***,the amidation and esterification were controlled to proceed in turn by adding or removing water,realizing the one-pot preparation of alternating *** resultant PEA is characterized by^1H-and^(13)C-NMR,and its chain structure is confirmed to be highly quasi-alternating similar to alternating PEAs prepared by classical methods The evaluations from DSC and DMA demonstrate that the properties of quasi-alternating PEA(T_(m)=102℃,ΔH_(m)=30J·g^(-1))are far superior to those of random PEA(T_(m)=72℃,ΔH_(m)<1 J·g^(-1)).

关键词： Biodegradable macromolecules Polymer architectures Sequence-controlled synthesis One-pot polymerization

Symmetrization of quasi-regular patterns with periodic tilting of regular polygons

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Computational Visual Media 2024年第3期10卷 559-576页

作者： Zhengzheng Yin Yao Jin Zhijian Fang Yun Zhang Huaxiong Zhang Jiu Zhou Lili He School of Computer science and technology Zhejiang Sci-Tech UniversityHangzhou 310018China Zhejiang Provincial innovation center of Advanced textile technology Shaoxing 312000China School of Media Engineering Communication University of ZhejiangHangzhou 310018China

Computer-generated aesthetic patterns arewidely used as design materials in various ﬁelds. Themost common methods use fractals or dynamicalsystems as basic tools to create various patterns. Toenhance aesthetics and controllability, some researchershave introduced symmetric layouts along with thesetools. One popular strategy employs dynamical systemscompatible with symmetries that construct functionswith the desired symmetries. However, these aretypically conﬁned to simple planar symmetries. Theother generates symmetrical patterns under theconstraints of tilings. Although it is slightly moreﬂexible, it is restricted to small ranges of tilingsand lacks textural variations. Thus, we proposed anew approach for generating aesthetic patterns bysymmetrizing quasi-regular patterns using general kuniformtilings. We adopted a uniﬁed strategy toconstruct invariant mappings for k-uniform tilings thatcan eliminate texture seams across the tiling ***, we constructed three types of symmetriesassociated with the patterns: dihedral, rotational, andreﬂection symmetries. The proposed method can beeasily implemented using GPU shaders and is highlyefficient and suitable for complicated tiling with regularpolygons. Experiments demonstrated the advantages of our method over state-of-the-art methods in terms ofﬂexibility in controlling the generation of patterns withvarious parameters as well as the diversity of texturesand styles.

关键词： quasi-regular patterns(QRP) k-uniform tilings invariant mappings symmetry aesthetic patterns

Study on preparation,characterization and application of mixed-colorants thermochromic microcapsules

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Particuology 2024年第5期88卷 89-97页

作者： Lan Zhou Jingpeng Ye Qinze Cai Guojin Liu Mehran Dadgar Guocheng Zhu Guoqing Zhang College of textile science and Engineering (International Institute of Silk) Zhejiang Sci-Tech UniversityHangzhou310018China School of Materials science& Engineering Zhejiang Sci-Tech UniversityHangzhou310018China Department of textile University of NeyshaburAdib BoulevardKhorasan Razavi ProvinceIran Zhejiang Charming Dyeing and Finishing Co. LtdJiaxing314500China Zhejiang Provincial innovation center of Advanced textile technology Shaoxing312000China

In order to expand the color-change range and make the discoloration temperature suitable for the daily textiles,a new formulation of mixed-colorants thermochromic core material is designed,in which crystal violet lactone(CVL)is the basic color former,bisphenol A(BPA)is the developer,especially the solvent-based dye and dodecyl dedecanoate are used as the extended dye and the solvent,*** electron microscope(SEM),differential scanning calorimeter(DSC)and thermogravimetric analyzer(TGA)were applied to study the morphology,encapsulation rate,non-isothermal crystallization behavior and thermal stability of the mixed-colorant thermochromic microcapsules(MCTMs)prepared by in-situ *** results show that MCTMs have good sphericity,uniform particle size,good thermal stability and the encapsulation rate can reach 86.73%.Under the non-isothermal conditions,the encapsulation of formaldehyde-melamine resin wall material can slightly reduce the crystallization rate of the solvent,but does not affect the relative crystallinity,thermal properties and discoloration sensitivity of the core *** the variety of ambient temperatures in the range of 20–35℃,the printed cotton fabrics with MCTMs could change color reversibly between different tones with good reliability and durability,and exhibit more gorgeous colors than the common thermochromic materials.

关键词： Thermochromic microcapsule Color-change range Phase-change material Crystallization behavior

Towards catalytic reactions of Cu single-atom catalysts:Recent progress and future perspective

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Chinese Chemical Letters 2024年第2期35卷 197-207页

作者： Yitao Zhao Lei Tao Jiangsu Province Engineering Research center of Special Functional textile Materials Changzhou Vocational Institute of Textile and GarmentChangzhou 213164China Jiangsu Key Laboratory of Advanced Catalytic Materials and technology Advanced Catalysis and Green Manufacturing Collaborative Innovation CenterSchool of Petrochemical EngineeringChangzhou UniversityChangzhou 213164China

One of the urgent and challenging topics in diversified sustainable energy conversion is the development of high-performance,low-cost,and well durable *** single-atom catalysts(SACs)have become promising catalysts for diversified sustainable energy conversion due to their capability to maximize the utilization efficiency,acquire modulated electronic structure and optimized binding strength with *** this review,we have provided an interview of the recent progress achieved in the field of electrocatalysis,photocatalysis,and heterogeneous reaction based on Cu *** by this review,we have summarized some advanced synthetic strategies for the construction of Cu ***,the performance-improving strategies are discussed in terms of the coordination environments of the reaction center,reaction mechanism and selectivity,based on free energy diagram and electron structure ***,the remaining issues,challenges,and opportunities of Cu SACs are also provided,affording a perspective for future *** review not only offers us a deep understanding on the catalytic mechanism of Cu SACs for energy conversion,but also encourages more endeavors in prompting their practical application.

关键词： Cu SACs Energy conversion Catalysis Coordination environment

Morphological Evolution of Self-Assembled Sodium Dodecyl Sulfate/Dodecyltrimethylammonium Bromide@Epoxy-β-Cyclodextrin Supramolecular Aggregates Induced by Temperature

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Journal of Renewable Materials 2024年第4期12卷 629-641页

作者： Qingran Meng Wenwen Xu Zuobing Xiao Qinfei Ke Xingran Kou Key Laboratory of textile science&technology Ministry of EducationCollege of TextilesDonghua UniversityShanghai201620China Collaborative innovation center of Fragrance Flavor and Cosmetics School of Perfume and Aroma Technology(Shanghai Research Institute of Fragrance&Flavour Industry)Shanghai Institute of TechnologyShanghaiChina

Bio-based cyclodextrins(CDs)are a common research object in supramolecular *** special cavity structure of CDs can form supramolecular self-assemblies such as vesicles and microcrystals through weak interaction with guest *** different forms of supramolecular self-assemblies can be transformed into each other under certain *** regulation of supramolecular self-assembly is not only helpful to understand the self-assembly principle,but also beneficial to its *** the present study,the self-assembly behavior of epoxy-β-cyclodextrin(EP-β-CD)and mixed anionic and cationic surfactant system(sodium dodecyl sulfate/dodecyltrimethylammonium bromide,SDS/DTAB)in aqueous solution was *** and particle size characterization found that the SDS/DTAB@EP-β-CD complex,as the basic building unit,self-assembled into worm-like micelles at lower temperatures and vesicles at higher *** magnetic resonance(NMR)and Fourier transform infrared spectroscopy(FT-IR)analysis revealed that the driving force for the formation of vesicles and worm-like micelles was the hydrogen bonds between EP-β-CD molecules,while water molecules played an important role in promoting vesicle formation between SDS/DTAB@EP-β-CD ***,the mechanism of the morphologic transformation of SDS/DTAB@EP-β-CD supramolecular aggregates induced by temperature was elucidated by exploring the self-assembly process,which may provide an excellent basis for the development of delivery carriers.

关键词： Epoxy-β-cyclodextrin SDS/DTAB self-assembly temperature morphological evolution

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多功能热电织物用于可穿戴无线传感系统

Engineering 2024年第4期35卷 158-167页

作者： Xinyang He Jiaxin Cai Mingyuan Liu Xuepeng Ni Wendi Liu Hanyu Guo Jianyong Yu Liming Wang Xiaohong Qin Key Laboratory of textile science&technology Ministry of EducationCollege of TextilesDonghua UniversityShanghai 201620China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringDonghua UniversityShanghai 201620China innovation center for textile science and technology Donghua UniversityShanghai 201620China

Flexible thermoelectric materials play an important role in smart wearables,such as wearable power generation,self-powered sensing,and personal thermal ***,with the rapid development of Internet of Things(IoT)and artificial intelligence(AI),higher standards for comfort,multifunctionality,and sustainable operation of wearable electronics have been proposed,and it remains challenging to meet all the requirements of currently reported thermoelectric ***,we present a multifunctional,wearable,and wireless sensing system based on a thermoelectric knitted fabric with over 600 mm·s^(-1)air permeability and a stretchability of 120%.The device coupled with a wireless transmission system realizes self-powered monitoring of human respiration through an mobile phone application(APP).Furthermore,an integrated thermoelectric system was designed to combine photothermal conversion and passive radiative cooling,enabling the characteristics of being powered by solar-driven in-plane temperature differences and monitoring outdoor sunlight intensity through the ***,we decoupled the complex signals of resistance and thermal voltage during deformation under solar irradiation based on the anisotropy of the knitted fabrics to enable the device to monitor and optimize the outdoor physical activity of the athlete via the *** novel thermoelectric fabricbased wearable and wireless sensing platform has promising applications in next-generation smart textiles.

关键词： Thermoelectric fabrics Wearable device Wireless Multifunctional sensing system Outdoor wearable signal monitoring

Advanced preparation and application of bimetallic materials in lithium-sulfur batteries:A review

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Journal of Energy Chemistry 2024年第1期88卷 469-512,I0011页

作者： Yongbing Jin Nanping Deng Yanan Li Hao Wang Meiling Zhang Weimin Kang Bowen Cheng State Key Laboratory of Separation Membranes and Membrane Processes/National center for International Joint Research on Separation Membranes School of Textile Science and EngineeringTiangong UniversityTianjin 300387China

Lithium-sulfur(Li-S)batteries are considered highly promising as next-generation energy storage systems due to high theoretical capacity(2600 Wh kg^(-1))and energy density(1675 mA h g^(-1))as well as the abundant natural reserves,low cost of elemental sulfur,and environmentally friendly ***,several challenges impede its commercialization including low conductivity of sulfur itself,the severe“shuttle effect”caused by lithium polysulfides(LiPSs)during charge–discharge processes,volume expansion effects and sluggish reaction *** a solution,polar metal particles and their compounds have been introduced as the main hosts for sulfur cathode due to their robust catalytic activity and adsorption capability,effectively suppressing the“shuttle effect”of Li *** alloys and their compounds with multi-functional properties exhibit remarkable electrochemical performance more readily when compared to single-metal ***-designed bimetallic materials demonstrate larger specific surface areas and richer active sites,enabling simultaneous high adsorption capability and strong catalytic *** synergistic effect of the“adsorption-catalysis”sites accelerates the adsorptiondiffusion-conversion process of Li PSs,ultimately achieving a long-lasting Li-S ***,the latest progress and performance of bimetallic materials in cathodes,separators,and interlayers of Li-S batteries are systematically ***,the principles and challenges of Li-S batteries are briefly ***,various mechanisms for suppressing“shuttle effects”of Li PSs are emphasized at the ***,the performance parameters of various bimetallic materials are comprehensively summarized,and some improvement strategies are proposed based on these ***,the future prospects of bimetallic materials are discussed,with the hope of providing profound insights for the rational design and manufacturing of high-performance bimetallic materia

关键词： Bimetallic materials Lithium-sulfur batteries Effectively suppress shuttle effect of LiPSs Significantly improve reaction kinetics Exceptionally long lifespan