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Thermally cross-linkable hole-transport materials enable solution-processed blue OLED with LT95 over 150 h

science China materials 2024年第9期67卷 2767-2777页

作者： Xinkang Zhang Hao Yan Xiaopeng Zhang Hong Meng school of Advanced materials Peking University Shenzhen Graduate SchoolShenzhen518055China

The solution-processed method for organic light-emitting diodes(OLEDs)offers the benefits of cost-effectiveness and enhanced material *** the multilayer architecture of solution-processed OLEDs(SOLEDs),the role of hole-transport materials(HTMs)is pivotal for cascade hole ***,commercial HTMs such as poly-(9,9-dioctylfluorene-alt-N-(4-sec-butylphenyl)-diphenylamine)(TFB)are hampered by incompatible energy levels and redissolution with overlayer solvent,prompting the exploration of cross-linkable HTMs(X-HTMs)for better *** this study,we have developed two novel small-molecule X-HTMs,N^(1),N^(1)′-((perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(N^(4),N^(4)-diphenyl-N^(1)-(4-vinylphenyl)benzene-1,4-diamine)(FTPA-V)and N,N′-((perfluoropropane-2,2-diyl)bis-(4,1-phenylene))bis(9-phenyl-N-(4-vinylphenyl)-9H-carbazol-3-amine)(FPCz-V),which incorporate thermally cross-linkable vinyl groups and electron-rich trifluoromethyl *** X-HTMs enhance interfacial contact through superior film formation and solvent resistance,along with optimal energy *** application of X-HTMs significantly enhances the efficiencies and longevities of blue,green,and red ***,blue SOLED incorporating FPCz-V exhibits unprecedented lifetime(LT95)extending to over 150 h,setting a new record for blue *** electrochemistry stability,high bond dissociation energy,and triplet energy levels of X-HTMs can effectively minimize exciton annihilation and prolong the *** findings underscore the potential of X-HTM optimization to propel the development of stable solution-processed luminescent technologies.

关键词： solution-processed OLED cross-linkable HTMs solvent resistance bond dissociation energy exciton-polaron annihilation

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Efficient flexible perovskite solar cells and modules using a stable SnO_(2)-nanocrystal isopropanol dispersion

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Nano Research 2024年第4期17卷 2704-2711页

作者： Zhiwei Su Jing Li Ruixuan Jiang Shujie Zhang Chengkai Jin Feng Ye Bingcan Ke Mengjun Zhou Jinhui Tong Hyesung Park Fuzhi Huang Yi-Bing Cheng Tongle Bu State Key Laboratory of Advanced Technology for materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China school of Material science and Engineering Wuhan University of TechnologyWuhan 430070China Department of materials science and Engineering Graduate School of Semiconductor Materials and Devices EngineeringGraduate School of Carbon NeutralityLow Dimensional Carbon Materials CenterUlsan National Institute of Science and TechnologyUlsan 44919Republic of Korea Xianhu Laboratory of the Advanced Energy science and Technology Guangdong Laboratory Foshan 528200China

The outstanding advantages of lightweight and flexibility enable flexible perovskite solar cells(PSCs)to have great application potential in mobile energy *** to the low cost,low-temperature processibility,and high electron mobility,SnO_(2) nanocrystals have been widely employed as the electron transport layer in flexible *** prepare high-quality SnO_(2) layers,a monodispersed nanocrystal solution is normally ***,the SnO_(2) nanocrystals can easily aggregate,especially after long periods of ***,we develop a green and cost-effective strategy for the synthesis of high-quality SnO_(2) nanocrystals at low temperatures by introducing small molecules of glycerol,obtaining a stable and well-dispersed SnO_(2)-nanocrystal isopropanol dispersion *** to the enhanced dispersity and super wettability of this alcohol-based SnO_(2)-nanocrystal solution,large-area smooth and dense SnO_(2) films are easily deposited on the plastic conductive ***,this contributes to effective charge transfer and suppressed non-radiative recombination at the interface between the SnO_(2) and perovskite *** a result,a greatly enhanced power conversion efficiency(PCE)of 21.8%from 19.2%is achieved for small-area flexible PSCs.A large-area 5 cm×5 cm flexible perovskite solar mini-module with a champion PCE of 16.5%and good stability is also demonstrated via this glycerol-modified SnO_(2)-nanocrystal isopropanol dispersion approach.

关键词： tin oxide isopropanol dispersion colloid stability flexible perovskite solar cells

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Two-stage aging treatment to accelerate aging kinetics without impairing strength in B_4C/7A04Al composite

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science China(Technological sciences) 2024年第8期67卷 2485-2492页

作者： CHEN YunTao MA GuoNan ZHU ShiZe WANG Dong XIAO BoLv MA ZongYi Shi-Changxu Innovation Center for Advanced materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China school of materials science and Engineering University of Science and Technology of ChinaShenyang 110016China Centre of excellence for Advanced materials Dongguan 523808China

Aging treatments are the key process to obtain satisfactory strength for 7xxxAl alloys and their composites. However, traditional single-stage(SS) aging is time-consuming to reach a peak strength condition. In this study, an efficient 120℃ + 160℃ two-stage(TS) aging treatment was proposed on a B_4C/7A04Al composite fabricated via powder metallurgy(PM) technology, which could acquire similar peak-aging strength but only took about 15% of the time compared to traditional 120℃ SS aging. The evolution of precipitation during the TS aging was investigated, as well as those of the 7A04Al alloys for comparison. In the second stage aging process, the higher aging temperature accelerated the nucleation of η′ phases inside the grains and thus increased the density of precipitates. Moreover, the short aging time limited the coarsening of precipitates and the broadening of precipitatefree zones. The above factors were beneficial for quickly obtaining satisfactory precipitation strengthening effects. The B_4C/7A04Al composite exhibited slower aging kinetics than the 7A04Al alloy in the TS aging. Mg elements consumption by the chemical reaction between B impurities introduced by B_4C particles and the Al matrix was considered to potentially retard the aging kinetics of the B_4C/7A04Al composite. Nevertheless, the precipitation sequence was not affected.

关键词： aluminum matrix composites aging treatment powder metallurgy mechanical properties precipitation

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Field induced Chern insulating states in twisted monolayer–bilayer graphene

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Chinese Physics B 2024年第6期33卷 69-73页

作者：王政文韩英卓 Kenji Watanabe Takashi Taniguchi 姜宇航毛金海 school of Physical science and CAS Center for excellence in Topological Quantum Computation University of Chinese Academy of SciencesBeijing 100049China College of materials science and Optoelectronic Technology Center of Materials Science and Optoelectronics EngineeringUniversity of Chinese Academy of SciencesBeijing 100049China Advanced materials Laboratory National Institute for Materials ScienceTsukuba 305-0044Japan

Unraveling the mechanism underlying topological phases, notably the Chern insulators(Ch Is) in strong correlated systems at the microscopy scale, has captivated significant research interest. Nonetheless, Ch Is harboring topological information have not always manifested themselves, owing to the constraints imposed by displacement fields in certain experimental configurations. In this study, we employ density-tuned scanning tunneling microscopy(DT-STM) to investigate the Ch Is in twisted monolayer–bilayer graphene(t MBG). At zero magnetic field, we observe correlated metallic *** under a magnetic field, a metal–insulator transition happens and an integer Ch I is formed emanating from the filling index s = 3 with a Chern number C = 1. Our results underscore the pivotal role of magnetic fields as a powerful probe for elucidating topological phases in twisted Van der Waals heterostructures.

关键词： Chern insulators strong correlation effects two-dimensional van der Waals heterostructure density-tuned scanning tunneling microscopy(DT-STM)

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Multiple-dimensioned defect engineering for graphite felt electrode of vanadium redox flow battery

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Carbon Energy 2024年第2期6卷 143-153页

作者： Yingqiao Jiang Yinhui Wang Gang Cheng Yuehua Li Lei Dai Jing Zhu Wei Meng Jingyu Xi Ling Wang Zhangxing He school of Chemical Engineering North China University of Science and TechnologyTangshanChina Tsinghua Shenzhen International graduate school Institute of Materials ResearchTsinghua UniversityShenzhenChina

The scarcity of wettability,insufficient active sites,and low surface area of graphite felt(GF)have long been suppressing the performance of vanadium redox flow batteries(VRFBs).Herein,an ultra-homogeneous multipledimensioned defect,including nano-scale etching and atomic-scale N,O codoping,was used to modify GF by the molten salt ***_(4)Cl and KClO_(3) were added simultaneously to the system to obtain porous N/O co-doped electrode(GF/ON),where KClO_(3) was used to ultra-homogeneously etch,and O-functionalize electrode,and NH4Cl was used as N dopant,***/ON presents better electrochemical catalysis for VO_(2)+/VO_(2)+ and V3+/V2+ reactions than only O-functionalized electrodes(GF/O)and *** enhanced electrochemical properties are attributed to an increase in active sites,surface area,and wettability,as well as the synergistic effect of N and O,which is also supported by the density functional theory ***,the cell using GF/ON shows higher discharge capacity,energy efficiency,and stability for cycling performance than the pristine cell at 140 mA cm^(−2) for 200 ***,the energy efficiency of the modified cell is increased by 9.7% from 55.2% for the pristine cell at 260 mA cm^(−2).Such an ultra-homogeneous etching with N and O co-doping through“boiling”molten salt medium provides an effective and practical application potential way to prepare superior electrodes for VRFB.

关键词： graphite felt molten salt N O co-doping ultra-homogeneous etching vanadium redox flow battery

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Design strategies for rechargeable aqueous metal-ion batteries

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science China Chemistry 2024年第1期67卷 165-190页

作者： Yang Li Xin Zhao Yifu Gao Yichen Ding Zhichun Si Liubing Dong Dong Zhou Feiyu Kang Tsinghua Shenzhen International graduate school Tsinghua UniversityShenzhen 518055China College of Chemistry and materials science Jinan UniversityGuangzhou 511443China

Rechargeable aqueous metal-ion batteries(AMBs)have attracted extensive scientific and commercial interest due to their potential for cost-effective,highly safe,and scalable stationary energy ***,their limited output voltage,inadequate energy density,and poor reversibility of ambiguous electrode reactions in aqueous electrolytes strongly limit their practical *** review aims to elucidate the challenges of existing AMBs from the material design to whole device *** summarize the emerging electrochemistry,fundamental properties,and key issues in interfacial behaviors of various classes of prevailing AMBs,including aqueous alkali metal-ion batteries and multivalent-ion batteries,and present an appraisal of recent advances for addressing the performance ***,the progress of zinc-ion batteries is highlighted to provide a ubiquitous guideline for their commercialization in the grid-scale energy ***,we figure out the dominating general challenges for achieving high-performance AMBs,laying out a perspective for future breakthroughs.

关键词： aqueous metal-ion batteries aqueous alkali metal-ion batteries zinc-ion batteries interfacial behavior stationary energy storage

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Deep-learning enabled atomic insights into the phase transitions and nanodomain topology of lead-free(K,Na)NbO_(3) ferroelectrics

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science China materials 2024年第9期67卷 3029-3038页

作者： Xu Zhang Bei Li Ji Zou Hanxing Liu Ben Xu Kai Liu school of materials science and Engineering Research Center for Materials Genome EngineeringWuhan University of TechnologyWuhan430070China State Key Laboratory of Advanced Technology for materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China International school of materials science and Engineering Wuhan University of TechnologyWuhan430070China graduate school China Academy of Engineering PhysicsBeijing100193China

Lead-free K_(x)Na_(1-x)NbO_(3)(KNN)perovskites have garnered increasing attention due to their exceptional ferropiezoelectric properties,which are effectively tuned via polymorphic structures and domain ***,atomic insights into the underlying nanomechanisms governing the ferroelectricity of KNNs amidst varying factors such as composition,phase,and domain are still ***,we perform molecular dynamics simulations of phase transitions and domain dynamics for KNNs with various K/Na ratios(x=0.25∼1.0)by using ab-initio accuracy deep learning potential(DP).As a demonstration of its transferability,the newly developed DP model shows quantum accuracy in terms of the equation of states,elastic constants,and phonon dispersion relations for various KNbO_(3)and K_(0.5)Na_(0.5)NbO_(3).Furthermore,intricate temperature-dependent phase transitions and domain formation of KNNs are extensively and quantitatively *** indicate that for KNNs with compositions x ranging from 0.25 to 1.0,the paraelectric-to-ferroelectric phase transition of KNNs is driven primarily by the order-disorder effect,while the displacive effect is dominant in the subsequent ferroelectric phase ***,flux-closure or herringbone-like nanodomain patterns arranged with 90°domain walls formed close to the experimental *** analyses reveal that favorable 90°domain wall formation becomes more challenging with increasing Na content due to distinct oxygen octahedron distortion arising from the different ionic radii of K/Na *** is envisioned that the combination of unified DP and atomistic simulations will help offer a robust solution for more accurate and efficient in silico explorations of complex structural,thermodynamic,and ferroelectric properties for relevant energy storage and conversion materials.

关键词： KNN molecular dynamics deep potential phase transitions domain dynamics

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Design of advanced porous silver powder with high-sintering activity to improve silicon solar cells

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Nano Research 2024年第4期17卷 3189-3197页

作者： Yongsheng Li Ziwei Chen Rui Zhou Wenguang Zhao Mu Li Jun Chen Zhongyuan Huang Jian Liu Yuhang Li Maolin Yang Minghan Yu Dong Zhou Yuan Lin Feng Pan school of Advanced materials Peking UniversityShenzhen Graduate SchoolShenzhen 518055China Institute of Advanced science Facilities Shenzhen 518107China Institute of Zhejiang University-Quzhou Quzhou 324000China Key Laboratory of Photochemistry Institute of ChemistryChinese Academy of SciencesBeijing 100190China Institute of materials Research(IMR) Tsinghua UniversityTsinghua Shenzhen International Graduate SchoolShenzhen 518055China school of materials science and Engineering Harbin Institute of Technology(Shenzhen)Shenzhen 518055China

Silver(Ag)paste is widely used in semiconductor metallization,especially in silicon solar *** powder is the material with the highest proportion in Ag *** morphology and structure of Ag powder are crucial which determine its characteristics,especially for the sintering *** this work,a simple method was developed to synthesize a type of microcrystalline spherical Ag particles(SP-A)with internal pores and the structural changes and sintering behavior were thoroughly studied by combining ultra-small-angle X-ray scattering(USAXS),small-angle X-ray scattering(SAXS),in-situ heating X-ray diffraction(XRD),focused ion beam(FIB),and thermal analysis *** to the unique internal pores,the grain size of SP-A is smaller,and the coefficient of thermal expansion(CTE)is higher than that of traditional solid Ag *** a result,the sintering activity of SP-A is excellent,which can form a denser sintered body and form silver nanoparticles at the Ag–Si interface to improve silver silicon *** silicon solar cell built with SP-A obtained a low series resistance(Rs)and a high photoelectric conversion efficiency(PCE)of 19.26%.These fill a gap in Ag particle structure research,which is significant for the development of high-performance electronic Ag particles and efficient semiconductor devices.

关键词： silver particles small angle X-ray scattering(SAXS) pore size distribution in-situ heating X-ray diffraction(XRD) sintering silicon solar cells

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Fe-Induced Electronic Transfer and Structural Evolution of Lotus Pod-Like CoNiFePx@P,N-C Heterostructure for Sustainable Oxygen Evolution

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Energy & Environmental materials 2024年第3期7卷 186-193页

作者： Xiaojun Zeng Qingqing Zhang Chulong Jin Hui Huang Yanfeng Gao Advanced Ceramic materials Research Institute School of Materials Science and EngineeringJingdezhen Ceramic University Singapore Institute of Technology school of materials science and Engineering Shanghai University

Transition metal phosphides with metallic properties are a promising candidate for electrocatalytic water oxidation,and developing highly active and stable metal phosphide-based oxygen evolution reaction catalysts is still ***,we present a facile ion exchange and phosphating processes to transform intestine-like CoNiPx@P,N-C into lotus pod-like CoNiFePx@P,N-C heterostructure in which numerous P,N-codoped carboncoated CoNiFePxnanoparticles tightly anchors on the 2D carbon ***,the as-prepared CoNiFePx@P,N-C enables a core-shell structure,high specific surface area,and hierarchical pore structure,which present abundant heterointerfaces and fully exposed active ***,the incorporation of Fe can also induce electron transfer in CoNiPx@P,IM-C,thereby promoting the oxygen evolution ***,CoNiFePx@P,IM-C delivers a low overpotential of 278 mV （vs RHE） at a current density of10 mA cm-1and inherits excellent long-term stability with no observable current density decay after 30 h of chronoamperometry *** work not only highlights heteroatom induction to tune the electronic structure but also provides a facile approach for developing advanced and stable oxygen evolution reaction electrocatalysts with abundant heterointerfaces.

关键词： electronic transfer Fe exchange multi-metal phosphides OER electrocatalysts structural evolution

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Lithium Ion Transport Environment by Molecular Vibrations in Ion-Conducting Glasses

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Energy & Environmental materials 2024年第3期7卷 137-146页

作者： Hiroki Yamada Koji Ohara Satoshi Hiroi Atsushi Sakuda Kazutaka lkeda Takahiro Ohkubo Kengo Nakada Hirofumi Tsukasaki Hiroshi Nakajimai Laszlo Temleitner Laszlo Pusztai Shunsuke Ariga Aoto Matsuo Jiong Ding Takumi Nakano Takuya Kimura Ryo Kobayashi Takeshi Usuki Shuta Tahara Koji Amezawa Yoshitaka Tateyama Shigeo Mori Akitoshi Hayashi Diffraction and Scattering Division Japan Synchrotron Radiation Research Institute((JASRI) Faculty of materials for Energy Shimane University Department of Applied Chemistry Graduate School of EngineeringOsaka Metropolitan University Institute of materials Structure science High Energy Accelerator Research Organization (KEK) graduate school of Engineering Chiba University Department of materials science Graduate School of EngineeringOsaka Metropolitan University Wigner Research Centre for Physics International Research Organisation of Advanced science and Technology (IROAST) Kumamoto University Department of Applied Physics Nagoya Institute of Technology Faculty of science Yamagata University Faculty of science University of the Ryukyus Institute of Multidisciplinary Research for Advanced materials Tohoku University Center for Green Research on Energy and Environmental materials (GREEN) and International Center for materials Nanoarchitectonics (MANA) National Institute for Materials Science(NIMS)

Controlling Li ion transport in glasses at atomic and molecular levels is key to realizing all-solid-state batteries,a promising technology for electric *** this context,Li3PS4glass,a promising solid electrolyte candidate,exhibits dynamic coupling between the Li+cation mobility and the PS43-anion libration,which is commonly referred to as the paddlewheel *** addition,it exhibits a concerted cation diffusion effect （i.e.,a cation-cation interaction）,which is regarded as the essence of high Li ion ***,the correlation between the Li+ions within the glass structure can only be vaguely determined,due to the limited experimental information that can be ***,this study reports that the Li ions present in glasses can be classified by evaluating their valence oscillations via Bader analysis to topologically analyze the chemical *** is found that three types of Li ions are present in Li3PS4glass,and that the more mobile Li ions （i.e.,the Li3-type ions） exhibit a characteristic correlation at relatively long distances of 4.0-5.0?.Furthermore,reverse Monte Carlo simulations combined with deep learning potentials that reproduce X-ray,neutron,and electron diffraction pair distribution functions showed an increase in the number of Li3-type ions for partially crystallized glass structures with improved Li ion transport *** results show order within the disorder of the Li ion distribution in the glass by a topological analysis of their ***,considering the molecular vibrations in the glass during the evaluation of the Li ion valences is expected to lead to the development of new solid electrolytes.

关键词： electrolytes ionic conductors modeling molecular dynamics

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