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Maximizing biomass utilization: An integrated strategy for coproducing multiple chemicals

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Journal of Energy Chemistry 2025年第1期100卷 180-191页

作者： Byeongchan Ahn Sua Jo Jonggeol Na J.Jay Liu Young-Ju Kim Wangyun Won department of Chemical and Biological Engineering Korea University department of Chemical Engineering (Integrated process) Kyung Hee University department of Chemical Engineering and Materials Science Ewha Womans University department of Chemical Engineering Pukyong National University Resources Engineering plant Research department Korea Institute of Geoscience and Mineral Resources

Lignocellulosic biomass is one of the viable solutions to alleviate the global warming. However, the limited utilization of biomass majorly focused on cellulose and hemicellulose restricts the economic and environmental feasibilities. To cope with this issue, we proposed an integrated process of co-producing 1,6-hexanediol（1,6-HDO） with tetrahydrofuran and adipic acid from biomass, referred to as Strategy A. To compare the impacts of lignin upgrading and feedstock, Strategy B, which co-produces tetrahydrofuran alone, and Strategy C, which is the traditional route to produce 1,6-HDO from fossil fuels, were used. Heat networks are also designed to reduce operating costs and indirect carbon emissions due to energy consumption, saving 87% and 83% of the heat and cooling requirements, respectively, in Strategy A. The market competitiveness of Strategy A was evaluated by determining the minimum selling price through techno-economic analysis, and sustainability was thoroughly investigated by quantifying the environmental impacts through both midpoint and endpoint life-cycle assessments（LCAs）.Strategy A was found to be the most favorable both economically（USRDSCHARDOLLAR3,402/ton） and environmentally（-26.9 kg CO2eq.）. This indicates that lignin valorization is not only economically but also environmentally preferred. Finally, changes in economic and environmental feasibilities depending on economic, process, and environmental parameters were investigated using sensitivity and uncertainty analyses. The results of these analyses provide valuable insight into bio-based chemical production.

关键词： Biorefinery Carbon mitigation Climate change Global warming Lignin utilization Bioeconomy

Biotechnological approaches in glucosinolate production

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Journal of Integrative plant Biology 2018年第12期60卷 1231-1248页

作者： Annette Petersen Cuiwei Wang Christoph Crocoll Barbara Ann Halkier DynaMo Center Copenhagen Plant Science Centre Department of Plant and Environmental Sciences University of Copenhagen

Glucosinolates(GLSs) are sulfur-rich, amino acid-derived defense compounds characteristic of the Brassicales order. In the past, GLSs were mostly known as anti-nutritional factors in fodder, biopesticides in agriculture, and flavors in condiments such as mustard. However, in recent times, GLSs have received increased attention as promoters of human *** has spurred intensive research towards generating rich sources of health-promoting GLSs. We provide a comprehensive overview of the biotechnologica approaches applied to reach this goal. This includes optimization of GLS production and composition in native, GLS-producing plants, including hairy root and cell cultures thereof, as well as synthetic biology approaches in heterologous hosts, such as tobacco and the microbial organisms Escherichia coli and Saccharomyces cerevisiae. The progress using these different approaches is discussed.

关键词： GLS Biotechnological approaches in glucosinolate production

Chemical composition and Zn bioavailability of the soil solution extracted from Zn amended variable charge soils

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Journal of environmental sciences 2010年第9期22卷 1398-1406页

作者： Mariavittoria Zampella Paola Adamo department of Soil Plant Environmental and Animal Production Sciences University of Naples Federico II

A study on variable charge soils （volcanic Italian and podzolic Scottish soils） was performed to investigate the influence of soil properties on the chemical composition of soil solution. Zinc speciation, bioavallability and toxicity in the soil solution were examined. The soils were spiked with increasing amounts of Zn （0, 100, 200, 400 and 1000 mg/kg） and the soil solutions were extracted using rhizon soil moisture samplers. The pH, total organic carbon （TOC）, base cations, anions, total Zn and free Zn^2＋ in soil solution were analysed. A rapid bioassay with the luminescent bacterium Escherichia coli HB 101 pUCD607 was performed to assess Zn toxicity. The influence of soil type and Zn treatments on the chemical composition of soil solution and on Zn toxicity was considered and discussed. Different trends of total and free Zn concentrations, base cations desorption and luminescence of E. coli HB 101 pUCD607 were observed. The soil solution extracted from the volcanic soils had very low total and free Zn concentrations and showed specific Zn^2＋/Ca^2＋ exchange. The soil solution from the podzolic soil had much higher total and free Zn concentrations and showed no evidence of specific Zn^2＋/Ca^2＋ exchange. In comparison with the subalkaline volcanic soils, the acidic podzol showed enhanced levels of toxic free Zn^2＋ and consequently stronger effects on E. coli viability.

关键词： rhizosamplers chemical speciation fractionation ecotoxicological test

Behavioral interactions between a coexisting rodent Micaelamys namaquensis and macroscelid Elephantulus myurus

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Current Zoology 2010年第4期56卷 395-400页

作者： Jennifer LANCASTER Neville PILLAY School of Animal Plant and Environmental Sciences University of the Witwatersrand

A number of mechanisms are known to influence coexistence in small mammal communities. However, the role ofbehavioral interactions in promoting species coexistence is under-represented in the literature. We studied the behavioral interactionsof two coexisting small mammals, the Namaqua rock mouse Micaelamys namaquensis (Rodentia) and the Rock sengi Elephantulusmyurus (Macroscelidae), which have high dietary and microhabitat overlap. Using wild-caught individuals, intra- andinterspecific dyadic encounters were staged in tanks on a neutral rocky outcrop. Interspecific dyads displayed significantly moreactive avoidance behavior. There was no support for the prediction that the larger, more specialist species, E. myurus, is behaviorallydominant over M. namaquensis. Intraspecific encounters of E. myurus showed significantly more passive avoidance andamicable behavior, whereas the behavior of M. namaquensis did not differ between intra- and inter-specific encounters, both ofwhich were characterized by low levels of aggression and amicability. Thus, due to the lack of aggression, direct competition appearsweak and instead mutual avoidance may reduce or minimize interspecific interactions, potentially promoting coexistence.

关键词： Avoidance Coexistence Elephantulus myurus Intraspecific behavior Interspecific behavior Micaelamys namaquensis

Limnological instrumentation in the middle of the 19^(th) century:the first temperature and density profiles measured in the Dead Sea

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Chinese Journal of Oceanology and Limnology 2015年第6期33卷 1496-1504页

作者： Aharon OREN department of plant and environmental sciences Alexander Silberman Institute of Life SciencesHebrew University of Jerusalem

The first modem survey of the Dead Sea was performed by the Geological Survey of Israel in 1959-1960, and the report published remains the baseline study for our understanding of the physical and chemical properties of the lake. At the time the Dead Sea was a meromictic lake with a strong salinity gradient separating the deep waters （〉40 m depth） from the less saline surface waters. A few results of analyses of deeper water samples collected in the 1930s were reported, but overall we have very little information about the structure of the lake＇s water column before the 1959-1960 survey. However, it is little known that data on the physical and the chemical structure of the Dead Sea water column were obtained already in the middle of the 19~ century, and the information collected then is highly relevant for the reconstruction of the limnological properties of the lake in earlier times. The expedition of Lieutenant William Lynch （U.S. Navy） in 1848 reported the presence of a temperature minimum at a depth of-18 m, and also retrieved a water sample collected close to the bottom for chemical analysis. In 1864, the French Dead Sea exploration by the Duc de Luynes and his crew yielded detailed density and salinity profiles for a number of sampling stations. The results of these pioneering studies are discussed here, as well as the sampling equipment and measuring instruments used by the 1848 and the 1864 expeditions.

关键词： Dead Sea stratification research history sampling equipment self-registering thermometer

＂La Vie en Rose＂： Biosynthesis, Sources, and Applications of Betalain Pigments

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Molecular plant 2018年第1期11卷 7-22页

作者： Guy Polturak Asaph Aharoni department of plant and environmental sciences Weizmann Institute of Science Rehovot 76100 Israel

Betalains are tyrosine-derived red-violet and yellow pigments found exclusively in plants of the Caryophyllales order, which have drawn both scientific and economic interest. Nevertheless, research into betalain chemistry, biochemistry, and function has been limited as comparison with other major classes of plant pigments such as anthocyanins and carotenoids. The core biosynthetic pathway of this pigment class has only been fully elucidated in the past few years, opening up the possibility for betalain pigment engineering in plants and microbes. In this review, we discuss betalain metabolism in light of recent advances in the field, with a current survey of characterized genes and enzymes that take part in be- talain biosynthesis, catabolism, and transcriptional regulation, and an outlook of what is yet to be discovered. A broad view of currently used and potential new sources for betalains, including utilization of natural sources or metabolic engineering, is provided together with a summary of potential applications of beta- lains in research and commercial use.

关键词： betalain biosynthesis plant pigment secondary metabolism metabolic engineering plant biotechnology

Interaction effect of nitrogen form and planting density on plant growth and nutrient uptake in maize seedlings

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Journal of Integrative Agriculture 2019年第5期18卷 1120-1129页

作者： WANG Peng WANG Zhang-kui SUN Xi-chao MU Xiao-huan CHEN Huan CHEN Fan-jun Yuan Li-xing MI Guo-hua department of plant Nutrition College of Resources and Environmental SciencesChina Agricultural University

High planting density is essential to increasing maize grain ***,single plants suffer from insufficient light under high planting ***(NH_4^+)assimilation consumes less energy converted from radiation than nitrateIt is hypothesized that a mixed NO_3~–/NH_4^+supply is more important to improving plant growth and population productivity under high *** planting *** plants were grown under hydroponic conditions at two planting densities(low density:only).A significant interaction effect was found between planting density and N form on plant *** to nitrate only,75/25NO_3~–/NH_4^+increased per-plant biomass by 44%under low density,but by 81%under high *** with 75/25NO_3~–/NH_4^+increased plant ATP,photosynthetic rate,and carbon amount per plant by 31,7,and 44%under low density,respectively,but by 51,23,and 95%under high ***,carbon level per plant under 75/25NO_3~–/NH_4^+was improved,which increased leaf area,specific leaf weight and total root length,especially for high planting density,increased by 57,17 and 63%,***,under low density,75/25NO_3~–/NH_4^+increased nitrogen uptake rate,while under high density,75/25NO_3~–/NH_4^+increased nitrogen,phosphorus,copper and iron uptake *** increasing energy use efficiency,an optimum NO_3~–/NH_4^+ratio can improve plant growth and nutrient uptake efficiency,especially under high planting *** summary,an appropriate supply of NH_4^+in addition to nitrate can greatly improve plant growth and promote population productivity of maize under high planting density,and therefore a mixed N form is recommended for high-yielding maize management in the field.

关键词： maize planting density NO3^-/NH4^+ ratio carbon nutrient uptake root morphology

Solid Waste Management:A MADM Approach Using Fuzzy Parameterized Possibility Single-Valued Neutrosophic Hypersoft Expert Settings

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Computer Modeling in Engineering & sciences 2025年第1期142卷 531-553页

作者： Tmader Alballa Muhammad Ihsan Atiqe Ur Rahman Noorah Ayed Alsorayea Hamiden Abd El-Wahed Khalifa department of Mathematics College of SciencesPrincess Nourah bint Abdulrahman UniversityRiyadh11671Saudi Arabia 2 department of Mathematics University of Management and TechnologyLahore54000Pakistan department of Mathematics College of ScienceQassim UniversityBuraydah51452Saudi Arabia

The dramatic rise in the number of people living in cities has made many environmental and social problems *** search for a productive method for disposing of solid waste is the most notable of these *** scholars have referred to it as a fuzzy multi-attribute or multi-criteria decision-making problem using various fuzzy set-like approaches because of the inclusion of criteria and anticipated *** goal of the current study is to use an innovative methodology to address the expected uncertainties in the problem of solid waste site *** characteristics(or sub-attributes)that decision-makers select and the degree of approximation they accept for various options can both be indicators of these *** tackle these problems,a novel mathematical structure known as the fuzzy parameterized possibility single valued neutrosophic hypersoft expert set(ρˆ-set),which is initially described,is integrated with a modified version of Sanchez’s *** this,an intelligent algorithm is *** steps of the suggested algorithm are explained with an example that explains *** compatibility of solid waste management sites and systems is discussed,and rankings are established along with detailed justifications for their *** study’s strengths lie in its application of fuzzy parameterization and possibility grading to effectively handle the uncertainties embodied in the parameters’nature and alternative approximations,*** uses specific mathematical formulations to compute the fuzzy parameterized degrees and possibility grades that are missing from the prior *** is simpler for the decisionmakers to look at each option separately because the decision is *** the computed results,it is discovered that they are consistent and dependable because of their preferred properties.

关键词： Hypersoft expert set Sanchez’s method decision making optimization solid waste management possibility grade fuzzy parameterization

Soil application of Beauveria bassiana GHA against apple sawfly, Hoplocampa testudinea （Hymenoptera： Tenthredinidae）： Field mortality and fungal persistence

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Insect Science 2016年第6期23卷 854-868页

作者： Weronika Swiergiel Nicolai V. Meyling Mario Porcel Birgitta Ramert department of plant Protection Biology Unit of Integrated Plant Protection Swedish University of Agricultural Sciences (SLU) AlnarpSweden department of plant and environmental sciences University of Copenhagen Copenhagen Denmark

Low impact alternatives to synthetic insecticides for the control of apple sawfly （Hoplocampa testudinea Klug） are scarce encumbering pest management in organic apple orchards. We investigated the soil persistence and field efficacy of the entomopathogenic fungus Beauveria bassiana （Balsamo） Vuillemin （BotaniGard） against apple sawfly under common organic orchard practices. We also assessed the efficacy of B. bassiana GHA and Metarhiziurn brunneum Petch （indigenous strain） against sawfly in the laboratory. Larvae treated with either fungus in the laboratory died faster than control larvae and displayed 49.4%-68.4% mycosis. In the field, B. bassiana density remained high in the week after application, during larval descent to the soil. Fungal density decreased to 25% at 49 d after application and to 0.4% after 55 weeks. Molecular markers revealed that the majority of fungal isolates recovered comprised the applied B. bassiana strain GHA. Larvae pupating in soil cages in the orchard for 49 d displayed 17% mycosis. The high efficacy under laboratory conditions was not seen in the field. B. bassiana application resulted in densities above the upper natural background level during the growing season, but reversion to background levels occurred within a year. It remains to be investigated whether this has a detrimental effect on nontarget organisms. Additional work is needed to bridge the knowledge gap between laboratory and field efficacy in orchards.

关键词： biological control crop protection entomopathogenic fungi integrated pest management Metarhizium organic orchard