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Plasma induced grain boundaries to boost electrochemical reduction of CO_(2)to formate

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Journal of Energy Chemistry 2024年第8期95卷 636-643,I0014页

作者： Guan Wang Shengtao Zhong Xiaoqian Xiong Jing Li Fangyuan Wang Li Huo Daoxiong Wu Xingqi Han Zhitong Wang Qi Chen Xinlong Tian Peilin Deng School of marine Science and engineering State Key Laboratory of Marine Resource Utilization in South China SeaHainan UniversityHaikou 570228HainanChina

Bismuth-based catalysts are highly promising for the electrochemical carbon dioxide reduction reaction(eCO_(2)RR)to formate ***,achieving high activity and selectivity towards formate and ensuring long-term stability remains *** work reports the oxygen plasma inducing strategy to construct the abundant grain boundaries of Bi/BiO_x on ultrathin two-dimensional Bi *** oxygen plasma-treated Bi nanosheet(OP-Bi)exhibits over 90%Faradaic efficiency(FE)for formate at a wide potential range from-0.5 to-1.1 V,and maintains a great stability catalytic performance without significant decay over 30 h in flow ***,membrane electrode assembly(MEA)device with OPBi as catalyst sustains the robust current density of 100 mA cm^(-2)over 50 h,maintaining a formate FE above 90%.In addition,rechargeable Zn-CO_(2)battery presents the peak power density of1.22 mW cm^(-2)with OP-Bi as bifunctional *** mechanism experiments demonstrate that the high-density grain boundaries of OP-Bi provide more exposed active sites,faster electron transfer capacity,and the stronger intrinsic activity of Bi *** situ spectroscopy and theo retical calculations further elucidate that the unsaturated Bi coordination atoms between the grain boundaries can effectively activate CO_(2)molecules through elongating the C-O bond,and reducing the formation energy barrier of the key intermediate(^(*)OCOH),thereby enhancing the catalytic performance of eCO_(2)RR to formate product.

关键词： CO_(2)electroreduction Bi nanosheet Grain boundary Unsaturation Bi atoms MEA device

Selective immobilization of Pb(Ⅱ)by biogenic whewellite and its mechanism

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Journal of Environmental Sciences 2024年第3期137卷 664-676页

作者： Xingxing Wang Kaiyan Ren Kairui Jiao Wenjun Nie Xiaochi An Bin Lian College of Life Sciences College of Marine Science and EngineeringNanjing Normal UniversityNanjing 210023China

The development of bio-adsorbents with highly selective immobilization properties for specific heavy metals is a great challenge,but has important application *** whewellite(BW)with high selectivity for Pb(Ⅱ)was synthesized by mineral microbial *** selective immobilization properties and mechanism of BW for Pb(Ⅱ)were analyzed by combining mineral characterization technology and batch adsorption research *** results indicated that BW can efficiently and selectively immobilize Pb(Ⅱ)in single or composite heavy metal adsorption solutions,and the immobilized Pb(Ⅱ)is difficult to *** undergoes monolayer adsorption on Pb(Ⅱ),Qmax≈1073.17 mg/*** immobilization of Pb(Ⅱ)by BW is a physico-chemical adsorption process with spontaneous heat absorption and an accompanying increase in *** addition,the sequestration of Pb(Ⅱ)by BW remains around 756.99 mg/g even at p H=*** excellent selective immobilization properties of BW for Pb(Ⅱ)are closely related to its smaller Ksp,electrostatic repulsion effect,organic-inorganic composite structure,acid resistance and the formation of Pb(Ⅱ)*** study provides beneficial information about the recycling of lead in acidic lead-containing wastewater and composite heavy metal contaminated water bodies.

关键词： Aspergillus niger Biogenic whewellite Pb(Ⅱ) Selective adsorption Immobilization mechanism

Synergistic effect of adsorption and photocatalytic degradation of oilfield-produced water by electrospun photocatalytic fibers of Polystyrene/Nanorod-Graphitic carbon nitride

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Journal of Environmental Sciences 2024年第7期141卷 287-303页

作者： Parisa Azmoon Mehrdad Farhadian Alireza Pendashteh Amir H.Navarchian Department of Chemical engineering Faculty of EngineeringUniversity of IsfahanIsfahanIran Department of Chemical engineering Faculty of EngineeringUniversity of GuilanRashtIran Department of Water and Environmental engineering Caspian Sea Basin Research CenterUniversity of GuilanRashtIran

Graphitic carbon nitride with nanorod structure(Nr-GCN)was synthesized using melamine as a precursor without any other reagents by hydrothermal pretreatment ***,FTIR,SEM,N_(2)adsorption-desorption from BET,UV-Vis DRS spectroscopy,and photoluminescence were used to characterize the prepared ***,the photoelectrochemical behavior of nanoparticles was studied by photocurrent transient response and cyclic voltammetry ***(PS)fibrous mat was fabricated by electrospinning technique and used as a support for the stabilization of the *** performance of the synthesized nanoparticles and photocatalytic fibers(PS/Nr-GCN)was evaluated in oilfield-produced water treatment under visible light *** this process,oil contaminants were adsorbed by hydrophobic polystyrene fibers and simultaneously degraded by *** removal efficiency of chemical oxygen demand(COD)has been obtained 96.6%and 98.4%by Nr-GCN and PS/Nr-GCN,respectively,at the optimum conditions of pH4,photocatalyst dosage 0.5 g/L,COD initial concentration 550 mg/L,and illumination time 150 *** gas chromatography-mass spectroscopy analysis results showed 99.3%removal of total petroleum hydrocarbons using photocatalytic fibers of PS/*** results demonstrated that the GCN has outstanding features like controllable morphology,visible-light-driven,and showing high potential in oily wastewater ***,the synergistic effect of adsorption and photocatalytic degradation is an effective technique in oilfield-produced water treatment.

关键词： Graphitic carbon nitride(GCN) Nanorod structure Polystyrene fibrous mat Photocatalytic fibers Oilfield-produced water(OPW)

Deep eutectic solvents:Green multi-task agents for sustainable super green hydrogen technologies

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Journal of Energy Chemistry 2024年第5期92卷 357-382页

作者： Raiyan Al-Farsi Maan Hayyan Renewable Energy engineering Program Faculty of Engineering and TechnologyMuscat UniversityMuscat 130Oman Chemical engineering Program Faculty of Engineering and TechnologyMuscat UniversityMuscat 130Oman

While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is currently believed to be a reliable solution for global warming and the pollution challenges arising from fossil fuels, making it the resilient fuel of the future. However, the sustainability of green hydrogen technologies is yet to be achieved. In this context, generation of green hydrogen with the aid of deep eutectic solvents(DESs) as green mixtures has been demonstrated as a promising research area. This systematic review article covers green hydrogen generation through water splitting and biomass fermentation when DESs are utilized within the generation process. It also discusses the incorporation of DESs in fuel cell technologies. DESs can play a variety of roles such as solvent, electrolyte, or precursor;colloidal suspension and reaction medium;galvanic replacement, shape-controlling, decoration, or extractive agent;finally oxidant. These roles are relevant to several methods of green hydrogen generation, including electrocatalysis, photocatalysis, and fermentation. As such, it is of utmost importance to screen potential DES formulations and determine how they can function in and contribute throughout the green hydrogen mobility stages. The realization of super green hydrogen generation stands out as a pivotal milestone in our journey towards achieving a more sustainable form of development;DESs have great potential in making this milestone achievable. Overall, incorporating DESs in hydrogen generation constitutes a promising research area and offers potential scalability for green hydrogen production, storage,transport, and utilization.

关键词： Watersplitting Biohydrogen Super green hydrogen Electrocatalysis Photocatalysis Fuel cell Power-to-X

Performance Assessment of a Real PV System Connected to a Low-Voltage Grid

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Energy engineering 2024年第1期121卷 13-26页

作者： Gaber Magdy Mostafa Metwally Adel A.Elbaset Esam Zaki Electrical engineering Department Faculty of Energy EngineeringAswan UniversityAswanEgypt `2faculty of engineering King Salman International UniversityEl-Tor46511Egypt Electrical engineering Department Faculty of EngineeringMinia UniversityMiniaEgypt Department of Electromechanics engineering Faculty of EngineeringHeliopolis UniversityCairoEgypt Computer Department Faculty of EngineeringModern Academy of Engineering&TechnologyCairoEgypt

The generation of photovoltaic(PV)solar energy is increasing continuously because it is renewable,unlimited,and clean *** the past,generation systems depended on non-renewable sources such as oil,coal,and ***,this paper assesses the performance of a 51 kW PV solar power plant connected to a low-voltage grid to feed an administrative building in the 6th of October City,*** performance analysis of the considered grid-connected PV system is carried out using power system simulator for engineering(PSS/E)*** the PSS/E program,monitors and uses the power analyzer that displays the parameters and measures some parameters such as current,voltage,total power,power factor,frequency,and current and voltage harmonics,the used inverter from the type of grid inverter for the considered *** results conclude that when the maximum solar radiation is reached,the maximum current can be obtained from the solar panels,thus obtaining the maximum power and power *** total voltage harmonic distortion,a current harmonic distortion within permissible limits using active harmonic distortion because this type is fast in processing up to 300 *** connection between solar stations and the national grid makes the system more efficient.

关键词： Low-voltage grid photovoltaic(PV)system total harmonic distortion grid-connected PV system

Genuine entanglement under squeezed generalized amplitude damping channels with memory

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Chinese Physics B 2024年第2期33卷 158-163页

作者： Mazhar Ali Department of Electrical engineering Faculty of EngineeringIslamic University MadinahMadinah 107Saudi Arabia

We study genuine entanglement among three qubits undergoing a noisy process that includes dissipation, squeezing,and decoherence. We obtain a general solution and analyze the asymptotic quantum states. We find that most of these asymptotic states can be genuinely entangled depending upon the parameters of the channel, memory parameter, and the parameters of the initial states. We study Greenberger–Horne–Zeilinger(GHZ) states and W states, mixed with white noise,and determine the conditions for them to be genuinely entangled at infinity. We find that for these mixtures, it is possible to start with a bi-separable state(with a specific mixture of white noise) and end with genuine entangled states. However, the memory parameter μ must be very high. We find that in contrast to the two-qubit case, none of the three-qubit asymptotic states for n → ∞ are genuinely entangled.

关键词： genuine entanglement squeezed thermal baths multipartite states

Performance of pulsed plasma thruster at low discharge energy

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Plasma Science and Technology 2024年第4期26卷 122-132页

作者：李鸿俊林泽豪胡浩俊吴文东陈爱虹杜德扬 Department of Physics Faculty of ScienceUniversity of MalayaKuala Lumpur 50603Malaysia faculty of engineering The University of Nottingham Malaysia CampusSemenyih 43500Malaysia faculty of engineering Multimedia UniversityCyberjaya 63100Malaysia

As the size of satellites scales down, low-power and compact propulsion systems such as the pulsed plasma thruster(PPT) are needed for stabilizing these miniature satellites in orbit. Most PPT systems are operated at 2 J or more of discharge energy. In this work, the performance of a PPT with a side-fed, tongue-flared electrode configuration operated within a lower discharge energy range of 0.5-2.5 J has been investigated. Ablation and charring of the polytetrafluoroethylene propellant surface were analyzed through field-effect scanning electron microscopy imaging and energy-dispersive X-ray spectroscopy. When the discharge energy fell below 2 J, inconsistencies occurred in the specific impulse and the thrust efficiency due to the measurement of the low mass bit. At energy ≥2 J, the performance parameters are compared with other PPT systems of similar configuration and discussed in depth.

关键词： pulsed plasma thruster low discharge energy performance parameters

Applying the Protective Mn-Co-La_(2)O_(3)Coating on Crofer 22 APU Ferritic Stainless Steel Used as Solid Oxide Fuel Cell Interconnects

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Acta Metallurgica Sinica(English Letters) 2024年第5期37卷 872-888页

作者： Farhad Mohsenifar Hadi Ebrahimifar Ahmad Irannejad Department of Materials engineering and Metallurgy Faculty of EngineeringShahid Bahonar University of KermanKermanIran Mechanical engineering Department Faculty of EngineeringHigher Education Complex of Bam76615-314BamIran Department of Materials engineering Faculty of Mechanical and Materials EngineeringGraduate University of Advanced TechnologyKerman ***Iran

This research studies the effect of Mn-Co-La_(2)O_(3) coating synthesized by the electrodeposition method on the oxidation resistance and electrical conductivity of the Crofer 22 APU stainless steel interconnect plates in solid oxide fuel *** test samples were characterized by a field emission scanning electron microscope(FESEM)equipped with energy dispersive spectroscopy(EDS),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS).The oxidation kinetics of the coated and uncoated samples were studied by tracking their weight changes over time at 800°C,showing that the oxidation mechanism for all samples follows the parabolic *** oxidation rate constant(k_(p))values of the coated sample compared with that of the uncoated one indicated a reduction in the oxidation rate of the steel substrate in the presence of the Mn-Co-La_(2)O_(3) *** examination of the cross-section of different samples after the isothermal oxidation for 500 h at 800°C exhibited that applying the composite coating leads to a decrease in the thickness of the chromia layer formed on the steel ***,under these conditions,the area-specific resistance(ASR)of the coated sample(13.11 mΩcm^(2))is significantly lower than that of the uncoated one(41.45 mΩcm^(2)).

关键词： Area specific resistance Oxidation Fuel cell Composite coating

Frequency-dependent viscoelasticity effects on the wave attenuation performance of multi-layered periodic foundations

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Applied Mathematics and Mechanics(English Edition) 2024年第3期45卷 407-424页

作者： M.SAFI M.VAKILIFARD M.J.MAHMOODI faculty of Civil Water&Environmental EngineeringShahid Beheshti UniversityTehran ***Iran faculty of Mechanical and Energy engineering Shahid Beheshti UniversityTehran ***Iran

In this paper,layered periodic foundations(LPFs)are numerically examined for their responses to longitudinal and transverse modes in the time and frequency *** different unit-cells,i.e.,2-layer,4-layer,and 6-layer unit-cells,comprising concrete/rubber,concrete/rubber/steel/rubber,and concrete/rubber/steel/rubber/lead/rubber materials,respectively,are taken into ***,the viscoelasticity behavior of the rubber is modeled with two factors,i.e.,a frequency-independent(FI)loss factor and a linear frequency-dependent(FD)loss *** the extraction of the complex dispersion curves and the identification of the band gaps(BGs),the simulations of wave transmission in the time and frequency domains are performed using the COMSOL *** parametric studies evaluate the effects of the rubber viscoelasticity models on the dispersion curves and the wave transmission for the longitudinal and transverse *** results show that considering the rubber viscoelasticity enhances the wave attenuation ***,the transverse-mode damping is more sensitive to the viscoelasticity model than its longitudinal *** 6-layer unit-cell LPF exhibits the lowest BG,ranging from 4.8 Hz to 6.5 Hz.

关键词： layered metamaterial periodic foundation complex dispersion curve wave transmission diagram