Selective immobilization of Pb(Ⅱ)by biogenic whewellite and its mechanism
作者机构:College of Life SciencesCollege of Marine Science and EngineeringNanjing Normal UniversityNanjing 210023China
出 版 物:《Journal of Environmental Sciences》 (环境科学学报(英文版))
年 卷 期:2024年第137卷第3期
页 面:664-676页
核心收录:
学科分类:083002[工学-环境工程] 0830[工学-环境科学与工程(可授工学、理学、农学学位)] 08[工学]
基 金:supported by the Interdisciplinary Project of the Nanjing Normal University (No.164320H1847) the National Natural Science Foundation of China (No.41772360)
主 题:Aspergillus niger Biogenic whewellite Pb(Ⅱ) Selective adsorption Immobilization mechanism
摘 要:The development of bio-adsorbents with highly selective immobilization properties for specific heavy metals is a great challenge,but has important application *** whewellite(BW)with high selectivity for Pb(Ⅱ)was synthesized by mineral microbial *** selective immobilization properties and mechanism of BW for Pb(Ⅱ)were analyzed by combining mineral characterization technology and batch adsorption research *** results indicated that BW can efficiently and selectively immobilize Pb(Ⅱ)in single or composite heavy metal adsorption solutions,and the immobilized Pb(Ⅱ)is difficult to *** undergoes monolayer adsorption on Pb(Ⅱ),Qmax≈1073.17 mg/*** immobilization of Pb(Ⅱ)by BW is a physico-chemical adsorption process with spontaneous heat absorption and an accompanying increase in *** addition,the sequestration of Pb(Ⅱ)by BW remains around 756.99 mg/g even at p H=*** excellent selective immobilization properties of BW for Pb(Ⅱ)are closely related to its smaller Ksp,electrostatic repulsion effect,organic-inorganic composite structure,acid resistance and the formation of Pb(Ⅱ)*** study provides beneficial information about the recycling of lead in acidic lead-containing wastewater and composite heavy metal contaminated water bodies.