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Electrocatalytic cleavage of a lignin β-O-4 model compound and coupling with nitrogen-containing aromatics using Prussian blue analogue-derived nickel–cobalt spinel

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Journal of Energy Chemistry 2025年第1期100卷 628-636页

作者： Yi Qi Xueying Chen Bowen Liu Xuliang Lin Xueqing Qiu Yanlin Qin Guangdong Provincial Key Laboratory of plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center Guangdong Basic Research Center of Excellence for Ecological Security and Green development Guangdong University of Technology

Electrochemical conversion of lignin for the production of high-value heterocyclic aromatic compounds has great *** demonstrate the targeted synthesis and cation modulation of NiCo2O4spinel nanoboxes,synthesized via cation exchange and calcination *** catalysts exhibit excellent efficacy in the electrocatalytic conversion of lignin model compounds,specifically 2-phenoxy-1-phenylethanol,into nitrogen-containing aromatics,achieving high conversion rates and *** catalysts were synthesized via a cation exchange and calcination oxidation process,using Prussian blue nanocubes as *** porous architecture and polymetallic composition of the NiCo2O4spinel demonstrated superior performance in electrocatalytic oxidative coupling,achieving a 99.2 wt%conversion rate of the 2-phenoxy-1-phenylethanol with selectivities of 37.5 wt%for quinoline derivatives and 31.5 wt%for *** innovations include the development of a sustainable one-pot synthesis method for quinoline derivatives,the elucidation of a multistage reaction pathway involving CAO bond cleavage,hydroxyaldol condensation,and CAN bond formation,and a deeper mechanistic understanding derived from DFT *** work establishes a new strategy for lignin valorization,offering a sustainable route to produce high-value nitrogen-containing aromatics from renewable biomass under mild conditions,without the need for additional reagents.

关键词： Spinel Biomass valorization Electrocatalysis Lignin oxidation Coupling

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How dopamine tunes parvalbumin interneurons in the hippocampus:new experimental observations in Alzheimer's disease

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Neural Regeneration Research 2025年第5期20卷 1405-1406页

作者： Livia La Barbera Paraskevi Krashia Annalisa Nobili Department of Medicine and Surgery UniversitàCampus Bio-Medico di RomaViaÁlvaro del PortilloRomeItaly Department of experimental Neurosciences IRCCS Santa Lucia FoundationVia del Fosso di FioranoRomeItaly Department of Science and Technology for Sustainable development and One Health UniversitàCampus Bio-Medico di RomaViaÁlvaro del PortilloRomeItaly

Despite decades of dedicated resea rch,Alzheimer's disease (AD) is an age-related and progressive neurodegenerative disorder for which the mechanisms of onset are sti unc *** is cha racterized by featured histological alterations including amyloid-beta (AB) plaque deposition,accumulation of neurofibrillary to ngles of hyperphosphorylated-tau,and neuronal loss,accompanied by progressive cognitive decline and behavioral changes.

关键词： Alzheimer alterations dopamine

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Unraveling the origins of PGY-sRNA-6,BZL-sRNA-20,and XKC-sRNA-h3

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Science China Life Sciences 2025年

作者： Shanfa Lu State Key Laboratory for Quality Ensurance and Sustainable Use of Dao-di Herbs Institute of Medicinal Plant DevelopmentChinese Academy of Medical Sciences&Peking Union Medical College Engineering Research Center of Chinese Medicine Resource Ministry of Education

Dear Editor,The regulatory role of herbal sRNAs in humans and animals is an interesting research ***,current evidence is insufficient to conclude that herbal sRNAs are novel precision medicines.I previously showed that HJT-sRNA-m1-HJT-sRNA-m8,identified as herbal sRNAs previously (Du et al.,2019),may be derived from humans and/or animals(Lu,2023).To minimize errors during herbal sRNA analysis,I provided a list of matters needing special attention and proposed problem-solving solutions for researchers working on sRNA cross-kingdom regulation (Lu,2023).

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Calibration of a γ-Re_θ transition model and its validation in low-speed flows with high-order numerical method

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Chinese Journal of Aeronautics 2015年第3期28卷 704-711页

作者： Wang Yuntao Zhang Yulun Li Song Meng Dehong computational Aerodynamics Institute China Aerodynamics Research and Development Center

Abstract Based on the Reynolds-averaged Navier--Stokes （RANS） equations and structured grid technology, the calibration and validation of Y-Reo transition model is preformed with fifth-order weighted compact nonlinear scheme （WCNS）, and the purpose of the present work is to improve the numerical accuracy for aerodynamic characteristics simulation of low-speed flow with transition model on the basis of high-order numerical method study. Firstly, the empirical correlation functions involved in the Y-Reo transition model are modified and calibrated with experimental data of turbulent flat plates. Then, the grid convergence is studied on NLR-7301 two-element airfoil with the modified empirical correlation. At last, the modified empirical correlation is validated with NLR-7301 two-element airfoil and high-lift trapezoidal wing from transition location, velocity pro- file in boundary layer, surface pressure coefficient and aerodynamic characteristics. The numerical results illustrate that the numerical accuracy of transition length and skin friction behind transition location are improved with modified empirical correlation function, and obviously increases the numerical accuracy of aerodynamic characteristics prediction for typical transport configurations in low-speed range.

关键词： Aerodynamic characteristicsFinite difference scheme High-order method Laminar to turbulenttransition RANS

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Deciphering fungal metabolon coupling tandem inverse-electrondemand Diels-Alder reaction and semipinacol rearrangement for the biosynthesis of spiro polycyclic alkaloids

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Science China Chemistry 2025年第01期 288-296页

作者： Shuai Liu Wen-Qiang Xu Ying-Tong Di Man-Cheng Tang Ding-Kang Chen Ming-Ming Cao Yao-Wen Chang Hong-Yu Tang Chun-Mao Yuan Jun-Bo Yang Zhi-Li Zuo Han Guo Zi-Fei Xu Ying Zeng Yun-Dong Wu Xiao-Jiang Hao Key Laboratory of Phytochemistry and Natural Medicines (Chinese Academy of Sciences) Kunming Institute of Botany Chinese Academy of Sciences University of Chinese Academy of Sciences Lab of computational Chemistry and Drug Design State Key Laboratory of Chemical Oncogenomics Peking University Shenzhen Graduate School Shenzhen Bay Laboratory State Key Laboratory of Microbial Metabolism School of Life Sciences & Biotechnology Shanghai Jiao Tong University State Key Laboratory of Functions and Applications of Medicinal plants Guizhou Medical University Molecular Biology experimental Center Germplasm Bank of Wild Species in Southwest China Kunming Institute of Botany Chinese Academy of Sciences Yunnan Key Laboratory for Wild plant Resources Kunming Institute of Botany Chinese Academy of Sciences Research Unit of Chemical Biology of Natural Anti-Virus Products Chinese Academy of Medical Sciences

In the intricate process of natural product biosynthesis, a metabolon can enhance metabolic flux by associating sequential enzymes. A fungal metabolon, comprising of flavin-dependent monooxygenase Spe F and P450 monooxygenase Spe G, is identified in the biosynthesis of spiro polycyclic alkaloids(+)-notoamide B and its diastereomer(+)-versicolamide B. Using notoamide E as a substance, Spe F/Spe G metabolon can control the stereoselectivity of its 2,3-epoxidation, followed by hydrogen atom ion at C-17 to generate reactive epoxide tau-m A with dienyl iminium unit. Subsequently,(+)-notoamide B and(+)-versicolamide B are produced via tandem nonenzymatic inverse-electron-demand Diels-Alder reaction and semipinacol rearrangement. This provides the first example of metabolon in the biosynthesis of spiro-prenylated indole alkaloids.

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Machine learning empowers efficient design of ternary organic solar cells with PM6 donor

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Journal of Energy Chemistry 2025年第1期 337-347页

作者： Kiran A.Nirmal Tukaram D.Dongale Santosh S.Sutar Atul C.Khot Tae Geun Kim School of Electrical Engineering Korea University computational Electronics and Nanoscience Research Laboratory School of Nanoscience and Biotechnology Shivaji University Yashwantrao Chavan School of Rural development Shivaji University

Organic solar cells(OSCs) hold great potential as a photovoltaic technology for practical ***, the traditional experimental trial-and-error method for designing and engineering OSCs can be complex, expensive, and time-consuming. Machine learning(ML) techniques enable the proficient extraction of information from datasets, allowing the development of realistic models that are capable of predicting the efficacy of materials with commendable accuracy. The PM6 donor has great potential for high-performance OSCs. However, it is crucial for the rational design of a ternary blend to accurately forecast the power conversion efficiency(PCE) of ternary OSCs(TOSCs) based on a PM6 ***, we collected the device parameters of PM6-based TOSCs and evaluated the feature importance of their molecule descriptors to develop predictive models. In this study, we used five different ML algorithms for analysis and prediction. For the analysis, the classification and regression tree provided different rules, heuristics, and patterns from the heterogeneous dataset. The random forest algorithm outperforms other prediction ML algorithms in predicting the output performance of PM6-based TOSCs. Finally, we validated the ML outcomes by fabricating PM6-based TOSCs. Our study presents a rapid strategy for assessing a high PCE while elucidating the substantial influence of diverse descriptors.

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Programmed cell death in seeds of angiosperms

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Journal of Integrative plant Biology 2015年第12期57卷 996-1002页

作者： María Paula López-Fernández Sara Maldonado Laboratory of plant development Department of Biodiversity and Experimental Biology Faculty of Exact and Natural Sciences University of Buenos Aires National Research Council of Argentine (CONICET)

During the diversification of angiosperms, seeds have evolved structuralp chemical, molecular and physiolog- ically developing changes that specially affect the nucellus and endosperm. All through seed evolution, programmed celldeath （PCD） has played a fundamental role. However, examples of PCD during seed development are limited. The present review examines PCD in integuments, nucellus, suspensor and endosperm in those representative examples of seeds studied to date.

关键词： Caspases endosperm KDEL-CysEP metacaspases nucellus nucleases programmed cell death perisperm ricinosomes

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Differential leaf flooding resilience in Arabidopsis thaliana is controlled by ethylene signalingactivated and age-dependent phosphorylation of ORESARA1

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plant Communications 2024年第6期5卷 73-88页

作者： Tom Rankenberg Hans van Veen Mastoureh Sedaghatmehr Che-Yang Liao Muthanna Biddanda Devaiah Evelien AStouten Salma Balazadeh Rashmi Sasidharan plant Stress Resilience Utrecht UniversityPadualaan 83584 CH Utrechtthe Netherlands Evolutionary plant-Ecophysiology Groningen Institute for Evolutionary LIfe SciencesNijenborgh 79747 AG Groningenthe Netherlands Max Planck Institute of Molecular plant Physiology Am Muhlenberg 114476 PotsdamGermany experimental and computational plant development Utrecht UniversityPadualaan 83584 CH Utrechtthe Netherlands Leiden University Leidenthe Netherlands

The phytohormone ethylene is a major regulator of plant adaptive responses to *** flooded plant tissues,ethylene quickly increases to high concentrations owing to its low solubility and diffusion rates in *** accumulation in submerged plant tissues makes it a reliable cue for triggering flood acclimation responses,including metabolic adjustments to cope with flood-induced ***,persistent ethylene accumulation also accelerates leaf ***-induced senescence hampers photosynthetic capacity and stress *** submerged Arabidopsis,senescence follows a strict age-dependent pattern starting with the older *** mechanisms underlying ethylene-mediated senescence have been uncovered,it is unclear how submerged plants avoid indiscriminate breakdown of leaves despite high systemic ethylene *** demonstrate that although submergence triggers leaf-age-independent activation of ethylene signaling viaEIN3 in Arabidopsis,senescence is initiated only inold ***3 stabilization also leads to overall transcript and protein accumulation of the senescence-promoting transcription factor ORESARA1(ORE1)in both old and young leaves during ***,leaf-age-dependent senescence can be explained by ORE1 protein activation via phosphorylation specifically in old leaves,independent of the previously identifiedage-dependentcontrol of ORE1 viami R164.A systematic analysis of the roles of the majorflooding stresscuesand signalingpathways shows that only the combination of ethylene and darkness is sufficientto mimic submergence-induced senescence involving ORE1 accumulation and ***,most of ten associated with flooding stress in plants,appears to have no role in these *** results reveal a mechanism by which plants regulate the speed and pattern of senescence during environmental stresses such as ***-dependent ORE1 activity ensures that older,expendable leaves are dismantled firs

关键词： ﬂooding abiotic stress hypoxia senescence ethylene

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Right Lateral Shear and Rotation in the Northeast of the Arabian-Iranian Collision Zone

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Journal of Earth Science 2018年第3期29卷 616-628页

作者： Arash Barjasteh Deputy for Dam and Power plant development Khuzestan Water and Power Authority

Accommodation of continental convergence by crustal thickening and lateral transport is mainly featured as strike-slip faulting along the trends roughly orthogonai to the orientation of plate convergence. This style of faulting will affect seismicity of the involving areas which can be proved in low seismic zones by determining regional stress pattern using numerical methods. Accordingly, the stress distribution and deformation pattern of the South Sanandaj-Sirjan zone in the northeastern part of the Iranian-Arabian collision zone is investigated here using a three dimen-sional mechanical model. The modeled area is bounded between the Zagros thrust fault on the west and Dehshir-Baft fault in the east. The model is composed of three layers： the upper two layers represent the upper brittle and lower ductile crust of the collided continent and the lowest layer represents the lithospheric mantle. The upper crust behaves as an elastic material while the lower crust is considered as a non-Newtonian viscous fluid layer. The lithospheric mantle is taken as a low-viscosity material which is not allowed to move in any direction relative to the overlying layers. The Zagros thrust fault was treated with two different dip values saying 90° and 45° but Dehshir-Baft fault was modeled as a vertical fault and allowed to have a dextral movement regarding to the existing evidence. The driving mechanism applied to the western side of the model was chosen considering two different approaches including a kinematic approach （the Arabian-Eurasian convergence velocity; 35 mm/yr） and a dynamic approach （an external boundary force equal to 3.55E＋17 N）. The resulted stress field indicates an orogen-parallel component of right lateral shear along the Zagros fault implying a rotational deformation pattern within the modeled region that suggests a stress partitioning in the study area. The pattern also indicates a stress accumulation towards the south which could be a reason for the regional seis

关键词： Zagros thrust fault Sanandaj-Sirjan belt numerical modeling shear zone Eghlid-Deh Bid.

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Maximizing biomass utilization: An integrated strategy for coproducing multiple chemicals

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Journal of Energy Chemistry 2025年第1期100卷 180-191页

作者： Byeongchan Ahn Sua Jo Jonggeol Na J.Jay Liu Young-Ju Kim Wangyun Won Department of Chemical and Biological Engineering Korea University Department of Chemical Engineering (Integrated process) Kyung Hee University Department of Chemical Engineering and Materials Science Ewha Womans University Department of Chemical Engineering Pukyong National University Resources Engineering plant Research Department Korea Institute of Geoscience and Mineral Resources

Lignocellulosic biomass is one of the viable solutions to alleviate the global warming. However, the limited utilization of biomass majorly focused on cellulose and hemicellulose restricts the economic and environmental feasibilities. To cope with this issue, we proposed an integrated process of co-producing 1,6-hexanediol（1,6-HDO） with tetrahydrofuran and adipic acid from biomass, referred to as Strategy A. To compare the impacts of lignin upgrading and feedstock, Strategy B, which co-produces tetrahydrofuran alone, and Strategy C, which is the traditional route to produce 1,6-HDO from fossil fuels, were used. Heat networks are also designed to reduce operating costs and indirect carbon emissions due to energy consumption, saving 87% and 83% of the heat and cooling requirements, respectively, in Strategy A. The market competitiveness of Strategy A was evaluated by determining the minimum selling price through techno-economic analysis, and sustainability was thoroughly investigated by quantifying the environmental impacts through both midpoint and endpoint life-cycle assessments（LCAs）.Strategy A was found to be the most favorable both economically（USRDSCHARDOLLAR3,402/ton） and environmentally（-26.9 kg CO2eq.）. This indicates that lignin valorization is not only economically but also environmentally preferred. Finally, changes in economic and environmental feasibilities depending on economic, process, and environmental parameters were investigated using sensitivity and uncertainty analyses. The results of these analyses provide valuable insight into bio-based chemical production.

关键词： Carbon capture and utilization

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