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Crystal structure and luminescence dynamics of highly pure LiM(PO_(3))_(3):Eu^(3+)(M=Sr,Ca) red phosphors for white light emitting diodes

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Journal of Rare Earths 2024年第8期42卷 1470-1478,I0002页

作者： Payal Khajuria M.Manhas A.K.Bedyal Ankush Vij H.C.Swart Vinay Kumar Department of Physics and Astronomical Sciences Central University of JammuRahy-Suchani.Samba1143J&KIndia Department of Physics School of SciencesCluster University of JammuCanal RoadJammu180001India Department of Physics University of Petroleum and Energy StudiesDehradunUttarakhand248007India Department of Physics University of the Free StateP.O.Box 339BloemfonteinZA 9300South Africa

Highly pure red phosphors LiM(PO_(3))_(3):Eu^(3+)(M=Sr,Ca) doped with Eu^(3+)(1 mol%) were synthesized via solution combustion method and their crystal structure and luminescence dynamics were studied to explore its suitability in white light emitting *** Rietveld refinement analysis of the powder Xray diffraction patterns reveals that the phosphors belong to the pure triclinic phase of LiSr(PO_(3))_(3) and LiCa(PO_(3)) with space group P-1(2).The scanning electron microscopy images showed the agglomerated *** photoluminescence emission spectra under 393 nm show an orange band at 594 nm and a red band at 613 nm ascribed to ^(5)D_(0)→^(7)F_(1).^(5)D_(0)→^(7)F_(2) transitions of Eu^(3+)ion in both the ***,the spectroscopic properties such as luminescence behaviour,and Stark splitting were used to examine the symmetry of Eu^(3+)ions in LiM(PO_(3))_(3):Es^(3+)(M=Sr,Ca) phosphors in terms of distortion induced upon *** Stark splitting shows that the actual site symmetry for Eu^(3+)ion was estimated to be D_(2) type for both *** photometric properties of LiCa(PO_(3))_(3):Eu^(3+)such as Commission International de l'Eclairage coordinates(x=0.64,y=0.36) near to the standard one(red),high color purity(95%) and higher brightness reveal that the phosphor has the capability of acting as a red component in n-UV white light emitting diodes.

关键词： Photoluminescence Phosphate WLEDs Stark splitting Rare earths

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Retinoscopes:Past and present

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World Journal of Methodology 2024年第3期14卷 126-140页

作者： Mutali Musa Ehimare Enaholo Babatunde Ismail Bale Carlo Salati Leopoldo Spadea Marco Zeppieri Department of Optometry University of BeninBenin 300283Nigeria Department of Ophthalmology Africa Eye Laser CentreBenin 300105Nigeria Department of Ophthalmology Centre for Sight AfricaNkpor 434101Nigeria Department of Ophthalmology University Hospital of UdineUdine 33100Italy Eye Clinic Policlinico Umberto I"Sapienza"University of RomeRome 00142Italy

BACKGROUND Retinoscopy is arguably the most important method in the eye clinic for diagnosing and managing refractive *** of retinoscopy include its noninvasive nature,ability to assess patients of all ages,and usefulness in patients with limited cooperation or communication *** To discuss the history of retinoscopes and examine current literature on the *** A search was conducted on the PubMed and with the reference citation analysis(https://***)database using the term"Retinoscopy,"with a range restricted to the last 10 years(2013-2023).The search string algorithm was:"Retinoscopy"(MeSH Terms)OR"Retinoscopy"(All Fields)OR"Retinoscopes"(All Fields)AND[(All Fields)AND 2013:2023(pdat)].RESULTS This systematic review included a total of 286 *** reviewed iterations of the retinoscope into autorefractors,infrared photo retinoscope,television retinoscopy,and the Wifi enabled digital *** The retinoscope has evolved significantly since its discovery,with a significant improvement in its diagnostic *** it has advantages such as non-invasiveness and broad applicability,limitations exist,and the need for skilled interpretation *** ongoing research,including the integration of artificial intelligence,retinoscopy is expected to continue advancing and playing a vital role in eye care.

关键词： Retinoscopy Autorefractor Refractive errors Ophthalmology Optics Artificial intelligence

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CFD investigation of structural effects of internal gas intake on powder conveying performance in fuel supply systems for aerospace engines

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Particuology 2024年第9期92卷 140-154页

作者： Guanlong Ren Haijun Sun Fangjun Chen Wen Shen Yunzhen Cai Yihua Xu Henrik Ström Bilainu Oboirien Qingang Xiong School of Aircraft Engineering Nanchang Hangkong UniversityNanchang330063China Engineering Research Center of Aero-engine Technology for General Aviation Ministry of EducationNanchang330063China State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhou510640China Department of Mechanics and Maritime Sciences Chalmers University of TechnologyGöteborg41296Sweden Department of Chemical Engineering University of JohannesburgJohannesburg17011South Africa

Optimal design of gas intake in powder fuel supply systems is crucial for performance of aerospace *** is little research on the impact of intake structure on powder conveying *** novel internal intakes were proposed,which are spherical,cube-shaped,and *** validation,CFD simulations demonstrate that fluctuation of mass flow rate of powders in the dome-shaped intake is reduced by about 73.3%compared with the annular external *** trends of phase velocities are similar for the spherical and cube-shaped intakes,while those are similar for the annular external and dome-shaped internal *** of area of gas zone for the annular external and spherical internal intakes is larger than that for the cube-shaped and dome-shaped internal *** and relative pressure drop in the fluidization chamber have a stable stage,and fluctuation of relative pressure drop is small when dome-shaped internal intake is used.

关键词： Powder supply system Intake structure Dense gas-solid flow Two-fluid model Powder fluidization Pressure drop

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Herpes simplex keratitis:A brief clinical overview

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World Journal of Virology 2024年第1期13卷 5-32页

作者： Mutali Musa Ehimare Enaholo Gladness Aluyi-Osa George Nnamdi Atuanya Leopoldo Spadea Carlo Salati Marco Zeppieri Department of Optometry University of BeninBenin 300283Nigeria Department of Ophthalmology Africa Eye Laser CentreKm 7Benin 300105Nigeria Department of Ophthalmology Centre for Sight AfricaNkpor 434101Nigeria Eye Clinic Policlinico Umberto I"Sapienza"University of RomeRome 00142Italy of Ophthalmology University Hospital of UdineUdine 33100Italy

The aim of our minireview is to provide a brief overview of the diagnosis,clinical aspects,treatment options,management,and current literature available regarding herpes simplex keratitis(HSK).This type of corneal viral infection is caused by the herpes simplex virus(HSV),which can affect several tissues,including the *** significant aspect of HSK is its potential to cause recurrent episodes of inflammation and damage to the *** the initial infection,the HSV can establish a latent infection in the trigeminal ganglion,a nerve cluster near the *** virus may remain dormant for extended *** reactivation of the virus can occur,leading to recurrent episodes of *** triggering reactivation include stress,illness,immunosuppression,or *** episodes can manifest in different clinical patterns,ranging from mild epithelial involvement to more severe stromal or endothelial *** severity and frequency of recurrences vary among *** cases of HSK,especially those involving the stroma and leading to scarring,can result in vision impairment or even blindness in extreme *** cornea's clarity is crucial for good vision,and scarring can compromise this,potentially leading to visual *** management of HSK involves not only treating acute episodes but also implementing long-term strategies to prevent recurrences and attempt repairs of corneal nerve endings via *** medications,such as oral Acyclovir or topical Ganciclovir,may be prescribed for *** immune response to the virus can contribute to corneal ***,caused by the body's attempt to control the infection,may inadvertently harm the corneal *** should be informed about triggers and advised on measures to minimize the risk of *** summary,the recurrent nature of HSK underscores the importance of both acute and long-term management strategies to preserve corneal health and maintai

关键词： Herpes simplex virus Herpes simplex keratitis Acyclovir Neurotization Reactivation

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Anisotropic quintessence compact star in f(T)gravity with Tolman–Kuchowicz metric potentials

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Communications in Theoretical Physics 2024年第1期76卷 61-75页

作者： Piyali Bhar Farook Rahaman Shyam Das Somi Aktar Abdelghani Errehymy Department of Mathematics Government General Degree College SingurHooghlyWest Bengal 712409India Department of Mathematics Jadavpur UniversityKolkata 700032West BengalIndia Department of Physics Malda College MaldaWest Bengal 732101India Astrophysics Research Centre School of MathematicsStatistics and Computer ScienceUniversity of KwaZulu-NatalPrivate Bag X54001Durban 4000South Africa

To obtain analytically relativistic quintessence anisotropic spherical solutions in the f(T)paradigm is the primary objective of this *** do this,the pressure anisotropy condition is imposed,and we employ a metric potential of the Tolman–Kuchowicz(TK)*** also suppose that our current model incorporates a quintessence field characterized by a parameterωq,in addition to the anisotropic matter *** the presence of the parameterα,the field equations are modified by the choice of the f(T)*** f(T)gravity parameterαadds new components to the basic physical characteristics,such as density,pressure,subliminal sound velocity,surface redshift,etc,of the present *** selecting the compact star Her X-1 and varyingαfrom 0.5 to 2.5,we examined all the physical characteristics of the model parameter of the *** graphical process demonstrates that a more compact item is produced with greater values ofα.The hydrostatic equilibrium condition of the model is discussed,as well as the mass-radius relationship for our current model is obtained.

关键词： quintessence star f(T)gravity stability condition

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Multi-Elemental Analysis and 2D Image Mapping within Roots, Leaves and Seeds from O. glaberrima Rice Plants Using Micro-PIXE Technique

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World Journal of Nuclear Science and Technology 2024年第2期14卷 97-106页

作者： Alassane Traore Anna Ndiaye Christopher Bongani Mtshali Manneh Baboucarr Jean Paul Latyr Faye Daouda Mbodj Kandiaba Traore Tapha Gueye Ababacar Sadikhe Ndao Département de Physique Faculté des Sciences et Techniques Université Cheikh Anta Diop Dakar Senegal Département de Chimie Faculté des Sciences et Techniques Université Cheikh Anta Diop Dakar Senegal Tandetron Laboratory IBA Group iThemba LABS Cape Town South Africa africa Rice Center St. Louis Senegal

Understanding metal accumulation at organ level in roots, leaves and seeds in O. glaberrima (OG) is crucial for improving physiological and metabolic aspects in growing Asian and african rice in salted areas. The micro-analytical imaging techniques are required to reveal its accumulation and distribution within plant tissues. PIXE studies have been performed to determine different elements in rice plants. The existing microbeam analytical technique at the iThemba LABS will be applied for the 2D image mapping of fresh rice tissues to perform a concentration of low atomic mass elements (such as Al, Si, P, S, Cl, Ca, Ti, Mn, Fe, Cu, Br, Zn and K) with detection limits of typically 1-10 μg/g. Comparison of the distribution of the elements between leaves, root and seed samples using uptake and distribution of elements in particular environmental conditions with potential amount of salt in water have been performed. We are also expecting to indicate metal exclusion as salt tolerance strategies from leaves, root, and seed compartments using matrix correlation between samples and between elements on rice species.

关键词： PIXE 2D Mapping Rice Concentration Elemental Analysis

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Determination and Quantification of Proximate and Mineral Composition for 20 Improved Sorghum Varieties Grown in Machache, Lesotho

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Food and Nutrition Sciences 2024年第8期15卷 744-758页

作者： Malefane Ts’ephe Puleng Letuma Karabelo Khomongata Fisseha Itanna Mamoipone Sebitia Monica Lephole Pitso Masupha Department of Crop Science Faculty of Agriculture National University of Lesotho Maseru Lesotho Department of Soil Science and Natural Resource Management Faculty of Agriculture National University of Lesotho Maseru Lesotho School of Interdisciplinary Research and Graduate Studies (SIRGS) University of South Africa (UNISA) Pretoria South Africa Department of Agricultural Research (DAR) Ministry of Agriculture Food Security and Nutrition Maseru Lesotho

Twenty varieties of improved sorghum were grown in Machache at the Department of Agricultural Research station, located (29˚22'60"S and 27˚52'0"E) in the central foothills of Lesotho in Maseru district. The varieties were planted in a randomized complete block design. At maturity, they were harvested, dried, threshed, milled and analyzed in the crop science laboratory at the National University of Lesotho. The proximate and mineral contents were analyzed from samples in a completely randomized design with three replicates. The proximate composition parameters measured were crude proteins, crude fiber, crude fat, moisture content, and carbohydrates. The minerals analyzed were, phosphorus, sodium, calcium, magnesium, potassium, copper, zinc, iron, and magnesium. The results showed the nutritional contents ranging from (4.7% - 16.16%), (0.35% - 2.10%), (1.25% - 4.00%), (71.60% - 84.06%), (5.53% - 10.18%), for protein, fat, fiber and carbohydrate, and moisture content, respectively. Mineral content ranged from (1342.96 - 3500.34 mg/kg), (25.97 - 185.25 mg/kg), (50.71 - 511.71 mg/kg), (29.35 - 4542.13 mg/kg), (577.19 - 3041.52 mg/kg), (0.25 - 4.07 mg/kg), (1.96 - 18.61 mg/kg), (67.14 - 122.96 mg/kg), (4.73 - 11.39 mg/kg) for phosphorus, sodium, calcium, magnesium, potassium, copper, zinc, iron, and manganese respectively. The following varieties were found to have the highest and appreciable amounts of nutrients and minerals that are crucial in the country diet;protein content was KARI Mtama 1, zinc, IESX 16 2533-SB-SSI-19, and iron IESX 16 2535-SB-SSI-34.

关键词： Varieties Sorghum Proximate Mineral

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Machine Learning and Statistical Analysis in Groundwater Monitoring for Total Dissolved Solids Assessment in Winkler County, Texas

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Journal of Geoscience and Environment Protection 2024年第6期12卷 1-29页

作者： Azuka I. Udeh Osayamen J. Imarhiagbe Erepamo J. Omietimi Abdulqudus O. Mohammed Oluwatomilola Andre-Obayanju Department of Geoscience University of Texas Permian Basin Odessa USA Department of Geology University of Pretoria Pretoria South Africa Department of Geology University of Benin Benin Nigeria

This research aims to develop reliable models using machine learning algorithms to precisely predict Total Dissolved Solids (TDS) in wells of the Permian basin, Winkler County, Texas. The data for this contribution was obtained from the Texas Water Development Board website (TWDB). Five hundred and ninety-three samples were obtained from two hundred and ninety-eight wells in the study area. The wells were drilled at different county locations into five aquifers, including Pecos Valley, Dockum, Capitan Reef, Edward Trinity, and Rustler aquifers. A total of fourteen different water quality parameters were used, and they include Potential hydrogen (pH), Sodium, Chloride, Magnesium, Fluoride, TDS, Specific Conductance, Nitrate, Total Hardness, Calcium, Temperature, Well Depth, Sulphate, and Bicarbonates. Four machine learning regression algorithms were developed to get a good model to help predict TDS in this area: Decision Tree regression, Linear regression, Support Vector Regression, and K-nearest neighbor. The study showed that the Decision Tree produced the best model with attributes like the coefficient of determination R2 = 1.00 and 0.96 for the training and testing, respectively. It also produced the lowest score of mean absolute error MAE = 0.00 and 0.04 for training and testing, respectively. This study will reduce the cost of obtaining different water quality parameters in TDS determination by leveraging machine learning to use only the parameters contributing to TDS, thereby helping researchers obtain only the parameters necessary for TDS prediction. It will also help the authorities enact policies that will improve the water quality in areas where drinking water availability is a challenge by providing important information for monitoring and assessing groundwater quality.

关键词： Machine Learning Regression Aquifers Winkler County Sinkholes

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Urbanization does not increase“object curiosity”in vervet monkeys,but semi-urban individuals selectively explore food-related anthropogenic items

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Current Zoology 2024年第3期70卷 383-393页

作者： Lindsey Ellington Stephanie Mercier Alba Motes-Rodrigo Erica van de Waal Sofa Forss Behavioural&Physiological Ecology University of GroningenP.O.Box 111039700 CCGroningenThe Netherlands Department of Ecology and Evolution University of LausanneBiophore-CH-1015LausanneSwitzerland Department of Evolutionary Biology and Environmental Studies University of ZurichWinterthurerstrasse 190CH-8057ZurichSwitzerland School of Life Sciences University of KwaZulu-NatalPrivate Bag X01Scottsville3209South Africa

Urban environments expose animals to abundant anthropogenic materials and foods that facilitate foraging innovations in species with oppor-tunistic diets and high behavioral *** and exploration tendency are believed to be important behavioral traits for animals thriving in urban *** monkeys(Chlorocebus pygerythrus)are one of few primate species that have successfully adapted to urban environments,thus making them an ideal species to study these *** a within-species cross-habitat approach,we compared neophilia and exploration of novel objects(jointly referred to as"object curiosity")between semi-urban,wild,and captive monkeys to shed light on the cognitive traits facilitating urban *** measure"object curiosity:"we exposed monkeys to various types of novel stimuli and compared their approaches and explorative *** results revealed differences in the number of approaches and explorative behavior toward novel stimuli between the habitat types *** vervet monkeys were significantly more explorative than both semi-urban and wild troops,sug-gesting that positive experiences with humans and lack of predation,rather than exposure to human materials per se,influence object *** habitats,juvenile males were the most explorative age-sex *** is likely due to males being the dispersing sex and juveniles being more motivated to learn about their ***,we found that items potentially associated with human food,elicited stronger explorative responses in semi-urban monkeys than non-food related objects,suggesting that their motivation to explore might be driven by"anthrophilia'that is,their experience of rewarding foraging on similar anthropogenic food *** conclude that varying levels of exposure to humans,predation and pre-exposure to human food packaging explain variation in"object curiosity"in our sample of vervet monkeys.

关键词： animal urbanization neophilia novelty response object curiosity vervet monkeys

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Biorenewable materials for water remediation: The central role of cellulose in achieving sustainability

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Journal of Bioresources and Bioproducts 2024年第3期9卷 253-282页

作者： Kirti Mishra Samarjeet Singh Siwal Thandiwe Sithole Nirankar Singh Phil Hart Vijay Kumar Thakur Department of Chemistry M.M.Engineering CollegeMaharishi Markandeshwar(Deemed to be University)Haryana 133207India Department of Chemical Engineering University of JohannesburgDoornfontein 2088South Africa Biorefining and Advanced Materials Research Center Scotland’s Rural CollegeEdinburgh EH93JGUnited Kingdom Renewable and Sustainable Energy Research Centre Technology Innovation InstituteAbu Dhabi 9639United Arab Emirates School of Engineering University of Petroleum&Energy StudiesDehradun 248007India

As the population increases and manufacturing grows,greenhouse gas and other harmful emissions *** with chemicals such as dyes,pesticides,pharmaceuticals,oil,heavy metals or radionuclides,wastewater purification has become an urgent *** technologies exist that can remove these contaminants from wastewater sources,but they often demand high energy and/or high cost,and in some cases produce contaminant laden sludge that requires safe *** need for methods which are less capital intensive,less operationally costly and more environmentally friendly is ***-based materials have emerged as promising candidates for wastewater treatment due to their renewability,low cost,biodegradability,hydrophilicity,and antimicrobial *** this review article,we focussed on developing sustainable and biodegradable cellulose-based materials for wastewater *** article deals with cellulose-based materials’scope and their conversion into valuable products like hydrogel,aerogel,cellulose composites,and *** cellulose-based materials have no harmful environmental impact and are *** modified cellulose-based materials applying as membrane,adsorbent,sorbent,and beads to purify the wastewater were ***,the challenges and future prospects of cellulose-based materials for wastewater treatment were considered,emphasizing their potential to be sustainable and eco-friendly alternatives to traditional materials used in wastewater treatment.

关键词： Cellulose Wastewater treatment Hydrogel Nanocrystal Cellulose membrane

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