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Tunable luminescence of Bi^(3+)/Eu^(3+)-doped SiO_(2)-Al_(2)O_(3)-MCO_(3)(M=Ca,Sr,Ba) glasses for WLED

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Journal of Rare Earths 2024年第9期42卷 1652-1657,I0001页

作者： Falin Zhang Xiaoying Liang Rongfei Wei Hai Guo Fangfang Hu department of Physics Zhejiang Normal UniversityJinhua321004China

In this work,a group of Bi^(3+)/Eu^(3+)-doped SiO2-Al_(2)O_(3)-MCO_(3)(M=Ca,Sr,Ba) glasses were fabricated through melt-quenching *** structure and photoluminescence characters were studied via Xray diffraction(XRD),UV-Vis transmission spectra(TRS),excitation spectra,emission spectra and decay *** XRD results show that no nano-crystal phase forms in glass matrix with different doping concentrations of Bi^(3+)and Eu^(3+)*** regulating optical alkalinity value,the intensity of Bi^(3+)ions increases and the peak position shifts to red *** Bi^(3+)/Eu^(3+) co-doped glasses show a blue-white-yellow-red luminescence by changing concentration of Eu^(3+) *** transfer efficiency from Bi^(3+) to Eu^(3+) can reach as high as 10.54%.At 423 K, the emission intensity of 55SiO_(2)-10Al_(2)O_(3)-35BaO-0.25Bi_(2)O_(3)(GBE0.5) is 31.1% of that at 308 ***,the activation energy of the glass matrix is 0.251 *** results suggest that these Bi^(3+)/Eu^(3+) co-doped glass samples possess potential application in LED field.

关键词： Bi^(3+) Eu^(3+) Glass White light-emitting diode Energy transfer Rare earths

A dual-mode optical thermometer based on dual-excitation Bi^(3+),Sm^(3+)co-doped Y_(4)GeO_(8) phosphors

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Journal of Rare Earths 2024年第8期42卷 1437-1446,I0002页

作者： Danyu Zhang Yuxuan Luo Junyu Chen Lianjie Li Hai Guo department of Physics Zhejiang Normal UniversityJinhua321004China

Dual-excitation and dual-emission Y_(4)GeO_(8):Bi^(3+),Sm^(3+)phosphors were manufactured by traditional solidphase sintering *** X-ray diffraction,morphology,photoluminescence,energy transfer process and temperature sensing properties of Y_(4)GeO_(8):Bi^(3+),Sm^(3+)samples were comprehensively *** Y4GeO_(8):Bi^(3+),Sm^(3+)phosphors exhibit characteristic emissions of Bi^(3+)(^(3)P_(1)→^(1)S_(0)) and Sm^(3+)(^(4)G_(5/2)→^(6)H)under both 290 and 347 nm *** fluorescence intensity ratio and Commission International de L'Eclairage coordinates modes,Y_(4)GeO_(8):Bi^(3+),Sm^(3+)samples present excellent temperature measurement *** maximum relative sensitivity(S_(r-max)) values of the former are 1.55%/K(460 K,290 nm excitation) and 0.82%/K(506 K,347 nm excitation).The S_(r-max)(x) values of the latter are 0.21 %/K(437 K,290 nm excitation) and 0.15%/K(513 K,347 nm excitation).These results illustrate that Y_(4)GeO_(8):Bi^(3+),Sm^(3+)phospho rs can be used as a candidate material for a dual-mode optical thermometer under dual-excitation.

关键词： Dual-mode optical thermometer Luminescent properties Y_(4)GeO_(8):Bi^(3+) Sm^(3+)phosphors Rare earths

Dynamical nonlinear excitations induced by interaction quench in a two-dimensional box-trapped Bose-Einstein condensate

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Chinese Physics B 2024年第2期33卷 209-215页

作者：牛真霞高超 department of Physics Zhejiang Normal UniversityJinhua 321004China Key Laboratory of Optical Information Detection and Display Technology of zhejiang Zhejiang Normal UniversityJinhua 321004China

Manipulating nonlinear excitations,including solitons and vortices,is an essential topic in quantum many-body physics.A new progress in this direction is a protocol proposed in[***.2043256(2020)]to produce dark solitons in a one-dimensional atomic Bose–Einstein condensate(BEC)by quenching inter-atomic *** by this work,we generalize the protocol to a two-dimensional BEC and investigate the generic scenario of its post-quench *** an isotropic disk trap with a hard-wall boundary,we find that successive inward-moving ring dark solitons(RDSs)can be induced from the edge,and the number of RDSs can be controlled by tuning the ratio of the after-and before-quench interaction strength across different critical *** role of the quench played on the profiles of the density,phase,and sound velocity is also *** to the snake instability,the RDSs then become vortex–antivortex pairs with peculiar dynamics managed by the initial density and the after-quench *** tuning the geometry of the box traps,demonstrated as polygonal ones,more subtle dynamics of solitons and vortices are *** proposed protocol and the discovered rich dynamical effects on nonlinear excitations can be realized in near future cold-atom experiments.

关键词： Bose-Einstein condensate quench interaction soliton vortex

Boosted sustained-release with iron-based MOF-derived mesoporouscarbon-spheres as a nitroimidazole drugs carrier

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Particuology 2024年第3期86卷 269-280页

作者： Danping Wu Jiaying Zou Junyi Chen Yan Li Na Ma Wei Dai College of Chemistry and Materials Science Zhejiang Normal UniversityJinhua321004China College of Life Sciences Zhejiang Normal UniversityJinhua321004China College of Geography and Environmental Sciences Zhejiang Normal UniversityJinhua321004China

Metal-organic framework(MoF)with a buildable internal structure has aroused great interest focus as self-sacrificing precursors of porous carbon(PC).However,as a drug carrier,the MOF-derived PC developed thus far are generally composed of irregular powder shape due to their crystalline nature,which consequently causing the cerebral infarction,cerebral thrombosis,and other blood *** this article,we propose a novel approach to constructing amorphous carbon microspheres(AcMs)by dis-torting the topological network through hydrothermal treatment precursors of MIL-101(Fe).Then,a distinctive MIL-101(Fe)-derived spherical porous carbons(MSPC)is achieved through high temperature calcination toward *** of the glucose initial concentration and hydrothermal treatment time on the sphericity of the as-prepared mesoporous MsPC were investigated in *** the loading capacities and sustained-release performances of nitroimidazole drugs over MsPC through simulation internal environment of human body at different pH values was systematically *** nitro-imidazole drugs loading rate and release time of MsPC are 10% and 17 h under preferred ***,the MSPC exhibited very low toxicity on Hela cells and 293T cells at the concentrations tested(10-800μg mL^(-1)).This study,therefore,supports the potential of the mesoporous carbon spheres as a carrierfor nitroimidazole drug delivery.

关键词： Ornidazole Metronidazole Carbon spheres Sustained-release performance Biocompatibility

The quasi-Gramian solution of a non-commutative extension of the higher-order nonlinear Schr?dinger equation

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Communications in Theoretical Physics 2024年第3期76卷 51-61页

作者： H W A Riaz J Lin department of Physics Zhejiang Normal UniversityJinhua 321004China

The nonlinear Schr?dinger(NLS)equation,which incorporates higher-order dispersive terms,is widely employed in the theoretical analysis of various physical *** this study,we explore the non-commutative extension of the higher-order NLS *** treat real or complex-valued functions,such as g_(1)=g_(1)(x,t)and g_(2)=g_(2)(x,t)as non-commutative,and employ the Lax pair associated with the evolution equation,as in the commutation *** derive the quasi-Gramian solution of the system by employing a binary Darboux *** soliton solutions are presented explicitly within the framework of *** visually understand the dynamics and solutions in the given example,we also provide simulations illustrating the associated ***,the solution can be used to study the stability of plane waves and to understand the generation of periodic patterns within the context of modulational instability.

关键词： integrable systems Darboux transformation solitons

Two Applications of the ■■-Hodge Theory

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Chinese Annals of mathematics,Series B 2024年第1期45卷 137-150页

作者： Dingchang WEI Shengmao ZHU Center of Mathematical Sciences Zhejiang UniversityHangzhou 310027China department of mathematics Zhejiang Normal UniversityJinhua 321004ZhejiangChina

Using Hodge theory and Banach fixed point theorem,Liu and Zhu developed a global method to deal with various problems in deformation *** this note,the authors generalize Liu-Zhu's method to treat two deformation problems for non-Kahler *** apply the ■■-Hodge theory to construct a deformation formula for(p,q)-forms of compact complex manifold under deformations,which can be used to study the Hodge number of complex manifold under *** the second part of this note,by using the ■■-Hodge theory,they provide a simple proof of the unobstructed deformation theorem for the non-Kahler Calabi-Yau ■■-manifolds.

关键词： Complex structures Deformations (p,q)-Forms Non-Kahler Calabi-Yaumanifolds

Cholesterol-induced deformation of the gramicidin A channel inhibiting potassium ion binding and transport

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Chinese Physics B 2024年第5期33卷 696-702页

作者：肖盼曹宇朱瑾梁清 Center for Statistical and Theoretical Condensed Matter Physics & department of Physics Zhejiang Normal UniversityJinhua 321004China zhejiang Institute of Photoelectronics & zhejiang Institute for Advanced Light Source Zhejiang Normal UniversityJinhua 321004China

Gramicidin A(gA)is a kind of antibiotic peptide produced by bacillus brevis and it can dimerize across lipid bilayers to form a monovalent cation *** this work,we investigate the impact of cholesterol in the lipid bilayer on the binding of potassium ions with the gA channel and the transport of the ions across the *** results indicate that cholesterol can significantly influence the conformational stability of the gA channel and cause the channel deformation which inhibits the potassium ion binding with the channel and transport across the *** work provides some molecular insights into understanding of influence of lipids on the activity of gA channel in both model membranes and plasma membranes of intact cells.

关键词： gramicidin A lipid bilayer molecular dynamics interaction

Some properties of Melnikov functions near a cuspidal loop

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Science china mathematics 2024年第4期67卷 767-786页

作者： Junmin Yang Maoan Han School of Mathematical Sciences Hebei Normal UniversityShijiazhuang 050024China department of mathematics Zhejiang Normal UniversityJinhua 321004China

In this paper,we consider the first-order Melnikov functions and limit cycle bifurcations of a nearHamiltonian system near a cuspidal *** establishing relations between the coefficients in the expansions of the two Melnikov functions,we give a general method to obtain the number of limit cycles near the cuspidal *** an application,we consider a kind of Liénard systems and obtain a new estimation on the lower bound of the maximum number of limit cycles.

关键词： Melnikov function nilpotent cusp limit cycle bifurcation

Effects of zeolite imidazole frameworks on rice seedlings (Oryza sativa L.): Phytotoxicity, transformation, and bioaccumulation

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Journal of Environmental Sciences 2024年第10期144卷 15-25页

作者： Chaofa Chen Yongqi Yao Chenghua Xing Yunyu Guo Luyi Cai Jianfang Yan Xi-Lin Wu Miaozhen Cai College of Geography and Environmental Science Zhejiang Normal UniversityJinhuaZhejiang 321004China College of Agriculture Jinhua PolytechnicJinhuaZhejiang 321007China

Zeolite imidazole frameworks(ZIFs),a class of the metal organic framework,have been extensively studied in environmental ***,their environmental fate and potential ecological impact on plants remain ***,we investigated the phytotoxicity,transformation,and bioaccumulation processes of two typical ZIFs(ZIF-8 and ZIF-67)in rice(Oryza sativa L.)under hydroponic ***-8 and ZIF-67 in the concentration of 50 mg/L decreased root and shoot dry weight maximally by 55.2%and 27.5%,53.5%and 37.5%,*** scanning electron microscopy(SEM)imaging combined with X-ray diffraction(XRD)patterns revealed that ZIFs on the root surface gradually collapsed and transformed into nanosheets with increasing cultivation *** fluorescein isothiocyanate(FITC)labeled ZIFs were applied to trace the uptake and translocation of ZIFs in *** results demonstrated that the transformed ZIFs were mainly distributed in the intercellular spaces of rice root,while they cannot be transported to culms and *** so,the Co and Zn contents of rice roots and shoots in the ZIFs treated groups were increased by 1145%and 1259%,145%and 259%,respectively,compared with the control *** findings suggested that the phytotoxicity of ZIFs are primarily attributed to the transformed ZIFs and to a less extent,the metal ions and their ligands,and they were internalized by rice root and increased the Co and Zn contents of *** study reported the transformation of ZIFs and their biological effectiveness in rice,highlighting the potential environmental hazards and risks of ZIFs to crop plants.

关键词： Zeolitic imidazolate frameworks (ZIFs) Rice(Oryza sativa L.) Phytotoxicity Transformed ZIFs ZIFs bioaccumulation