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ChemPhysMater 2024年第2期3卷 194-203页

作者： Jingjing Ru Fan Zeng Bing Zhao Chenqing Ye Tonghui Zhong Feiyun Guo Jianzhong Chen College of chemistry and Materials Fujian Province University Key Laboratory of Green Energy and Environment CatalysisNingde Normal UniversityNingde 352100China School of Environment and Resources School of Carbon Neutral and Modern IndustryFujian Normal UniversityFuzhou 350007China College of Information and Mechanical&Electrical Engineering Ningde Normal UniversityNingde 352100China College of chemistry Fuzhou UniversityFuzhou 350108China

A set of novel red phosphors Li_(8)CaLa_(2)Ta_(2)O_(13):Eu^(3+)(LCLTO:xEu^(3+))were successfully prepared using a solid-state reaction method.The properties of the prepared samples,including phase purity,elemental composition,and morphology,were systematically investigated using X-ray diffraction,scanning electron microscopy,and diffuse reflectance spectroscopy analyses.The 610 nm maximum emission peak is attributed to the^(5)D_(0)→^(7)F_(2)transition of Eu^(3+)ion under 394 nm irradiation.Among all the LCLTO:xEu^(3+)phosphors,LCLTO:0.6Eu^(3+)showed the strongest emission intensity because of the concentration quenching effect of the electric dipole-dipole in-teraction among the Eu^(3+)ions,which was also demonstrated by the decay curves.Remarkably,the emission intensity of the optimal LCLTO:0.6Eu^(3+)phosphor,which exhibited a high internal quantum efficiency of 49.30%and excellent color purity of 96.79%,was approximately 2.29 times higher than that of commercial Y203:Eu^(3+)red phosphors.The thermal stability of the LCLTO:0.6Eu^(3+)sample with good color stability was meticulously inves-tigated.The fabricated white-light-emitting diode(WLED)exhibited a superior color-rendering index of Ra=82 and chromaticity coordinates of(0.3260,0.3639),suggesting that LCLTO:0.6Eu^(3+)has potential applicability in developing efficient and high-quality WLEDs.Moreover,the prepared LCLTO:0.6Eu^(3+)/PDMS composite film demonstrated exceptional flexural resistance and chemical stability,indicating considerable promise for practical anti-counterfeitingapplications.

关键词： Phosphor Tantalate Luminescence LED device

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Small-sized Ni-Co/Mo_(2)C/Co_(6)Mo_(6)C_(2)@C for efficient alkaline and acidic hydrogen evolution reaction by an anchoring calcination strategy

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Frontiers of Chemical Science and Engineering 2024年第5期18卷 95-103页

作者： Jianxia Gu Ying Zhu Haiyan Zheng Chunyi Sun Zhongmin Su department of chemistry Xinzhou Normal UniversityXinzhou 034000China School of chemistry Northeast Normal UniversityChangchun 130024China

A novel,cheap and highly efficient Ni-Co/Mo_(2)C/Co_(6)Mo_(6)C_(2)@C nanocomposite has been successfully constructed through simple one-step carbonization method in a nitrogen atmosphere.Polyethyleneimine in the precursor can effectively anchor molybdenum-based Keggin-type polyoxometallate and NiCo-layered double hydroxide through electrostatic and coordination interactions,which avoids the aggregation of catalyst particles during the pyrolysis process.After optimization,the obtained Ni-Co/Mo_(2)C/Co_(6)Mo_(6)C_(2)@C possesses small size(3-8 nm),large specific surface area and hierarchical pore structure.More importantly,Ni-Co/Mo_(2)C/Co_(6)Mo_(6)C_(2)@C presents remarkable hydrogen evolution reaction activity with low overpotentials in 0.5 mol·L^(-1)H_(2)SO_(4)(102.3 mV)and 1 mol·L^(-1)KOH(95 mV)to afford the current density of 10 mA·cm^(-2),as well as small Tafel slopes of 82.49 and 99.92 mV·dec^(-1),respectively.Simultaneously,this catalyst also shows outstanding stability for 12 h without a significant change in current density.The excellent catalytic performance of Ni-Co/Mo_(2)C/Co_(6)Mo_(6)C_(2)@C can put down to the synergistic effect between multiple components and the small size of the catalyst.This work provides unique insights into the preparation of efficient transition metal-based catalysts for HER.

关键词： polyoxometallates layered double hydroxide transition metal-based electrocatalysts hydrogen evolution reaction

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Rare earth fluorescent nanoprobes with minimal side effects enable tumor microenvironment activation for chemotherapy

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Journal of Rare Earths 2024年第2期42卷 256-262,I0001页

作者： Tianqi Cao Yuxin Liu Qi Jia Xiaolu Wang Shouqiang Zhang Jing Zhou department of chemistry Capital Normal UniversityBeijing100048China

Chemotherapy,the use of antitumor drugs to kill cancer cells,is currently one of the most effective treatments for cancer.However,serious toxic side effects caused by long-term drug accumulation can cause significant damage to the body,which limits the clinical application of antitumor drugs.In this study,a novel RENPs@DOX-Fe nanoprobe(NP) was constructed by coating the surface of rare earth nanomaterials(NaLuF_(4):Yb,Er) with a complex formed by doxorubicin(DOX) and iron ion(Ⅲ).Due to the low toxicity of anthracycline-metal complexes,the damage to normal cells is reduced.The unique acidic microenvironment in tumor cells facilitates the decomposition and gradual release of DOX from the DOX-Fe complex.In addition,the DOX-Fe complex can convert near-infrared(NIR) light into heat energy,which promotes the decomposition of the complex,further enhancing the release of DOX in the tumor environment.The change of ratio fluorescence of rare earth nanomaterials at 660 and 1550 nm after DOX release enables visual monitoring of drug release,which can potentially improve the chemotherapeutic effect.In vitro experiments established that RENPs@DOX-Fe NPs with NIR illumination had good therapeutic efficacy in tumors.This work provides new insights into designing tumor microenvironment-responsive nanoprobes for chemotherapy with minimal side effects.

关键词： Rare earth nanoprobes Fluorescence Ratiometric imaging DOX Chemotherapy

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Research on Interpolation Method for Missing Electricity Consumption Data

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Computers, Materials & Continua 2024年第2期78卷 2575-2591页

作者： Junde Chen Jiajia Yuan Weirong Chen Adnan Zeb Md Suzauddola Yaser A.Nanehkaran department of Electronic Commerce Xiangtan UniversityXiangtan411105China School of Information Engineering Yancheng Teachers UniversityYancheng224000China department of Information and Electrical Engineering Ningde Normal UniversityNingde352100China College of Engineering Southern University of Science and TechnologyShenzhen518005China School of Informatics Xiamen UniversityXiamen361005China

Missing value is one of the main factors that cause dirty data.Without high-quality data,there will be no reliable analysis results and precise decision-making.Therefore,the data warehouse needs to integrate high-quality data consistently.In the power system,the electricity consumption data of some large users cannot be normally collected resulting in missing data,which affects the calculation of power supply and eventually leads to a large error in the daily power line loss rate.For the problem of missing electricity consumption data,this study proposes a group method of data handling(GMDH)based data interpolation method in distribution power networks and applies it in the analysis of actually collected electricity data.First,the dependent and independent variables are defined from the original data,and the upper and lower limits of missing values are determined according to prior knowledge or existing data information.All missing data are randomly interpolated within the upper and lower limits.Then,the GMDH network is established to obtain the optimal complexity model,which is used to predict the missing data to replace the last imputed electricity consumption data.At last,this process is implemented iteratively until the missing values do not change.Under a relatively small noise level(α=0.25),the proposed approach achieves a maximum error of no more than 0.605%.Experimental findings demonstrate the efficacy and feasibility of the proposed approach,which realizes the transformation from incomplete data to complete data.Also,this proposed data interpolation approach provides a strong basis for the electricity theft diagnosis and metering fault analysis of electricity enterprises.

关键词： Data interpolation GMDH electricity consumption data distribution system

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The etching strategy of zinc anode to enable high performance zinc-ion batteries

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Journal of Energy chemistry 2024年第1期88卷 125-143,I0004页

作者： Xueqing Fu Gaopeng Li Xinlu Wang Jinxian Wang Wensheng Yu Xiangting Dong Dongtao Liu School of chemistry and Environmental Engineering Changchun University of Science and TechnologyChangchun 130022JilinChina department of chemistry Northeast Normal UniversityChangchun 130024JilinChina

Zinc-ion batteries(ZIBs)are considered to be one of the most promising candidates to replace lithium-ion batteries(LIBs)due to the high theoretical capacity,low cost and intrinsic safety.However,zinc dendrites,hydrogen evolution reaction,surface passivation and other side reactions will inevitably occur during the charging and discharging process of Zn anode,which will seriously affect the cycle stability of the battery and hinder its practical application.The etching strategy of Zn anode has attracted wide attention because of its simple operation and broad commercial prospects,and the etched Zn anode can effectively improve its electrochemical performance.However,there is no comprehensive review of the etching strategy of Zn anode.This review first summarizes the challenges faced by Zn anode,then puts forward the etching mechanisms and properties of acid,salt and other etchants.Finally,based on the above discussion,the challenges and opportunities of Zn anode etching strategy are proposed.

关键词： Zinc-ion batteries Zn anode Etching 3D structures Dendrite-free

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Electrode particulate materials for advanced rechargeable batteries:A review

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Particuology 2024年第3期86卷 160-181页

作者： Mingyang Ma Miao Du Yan Liu Hongyan Lü Jialin Yang Zelin Hao Jinzhi Guo Xinglong Wu MOE Key Laboratory for UV Light-Emitting Materials and Technology Northeast Normal UniversityChangchunJilin130024China department of chemistry Northeast Normal UniversityChangchunJilin130024China

The demand for large-scale energy storage is increasing due to the decreasing non-renewable resources and deteriorating environmental pollution.Developing rechargeable batteries with high energy density and long cycle performance is an ideal choice to meet the demand of energy storage system.The development of excellent electrode particles is of great significance in the commercialization of nextgeneration batteries.The ideal electrode particles should balance raw material reserves,electrochemical performance,price and environmental protection.Among them,the development of electrode particulate materials with excellent electrochemical properties is the top priority at present.In this review,the typical researches of electrode materials are summarized in terms of crystal structure,morphology,pore structure,surface and interface regulation.Firstly,the structural characteristics and improvement methods of transition metal oxides,polyanionic compounds,Prussian blue and their analogues are introduced.Then,the different effects of particulate morphology,pore,surface and interface structure on the performance of electrode materials are discussed.For designing high-performance electrode materials,preparation route should be set according to the particle properties of the materials and the synergistic effect of various optimization methods should be adopted.At the same time,in addition to the electrode materials,other components of the rechargeable batteries,such as current collector,separator and electrolytes,should be optimized to improve the overall performance of the batteries.This review would provide important guiding principle for designing high-performance electrode particulate materials.

关键词： Particulate properties Electrode materials Rechargeable batteries

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Ternary-phase layered cathodes toward ultra-stable and highrate sodium ion storage

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Rare Metals 2024年第4期43卷 1589-1598页

作者： Wen-Ji Yin Pei-Dan Su Qi Lu Xiao-Qiong Li Ji-Ming Peng Teng-Fei Zhou Ge-Meng Liang Yu-Liang Cao Hong-Qiang Wang Qing-Yu Li Si-Jiang Hu Guangxi Key Laboratory of Low Carbon Energy Materials School of Chemistry and Pharmaceutical SciencesGuangxi Normal University Institutes of Physical Science and Information Technology Anhui University department of chemistry and Pharmaceutical Sciences Guilin Normal College College of chemistry and Chemical Engineering Huanggang Normal University School of Chemical Engineering and Advanced Materials The University of Adelaide Engineering Research Center of Organosilicon Compounds and Materials of Ministry of Education College of Chemistry and Molecular SciencesWuhan University

With the shortage of lithium resources,sodiumion batteries（SIBs） are considered one of the most promising candidates for lithium-ion batteries.P2-type and O3-type layered oxides are one of the few cathodes that can access high energy density.However,they usually exhibit structural change,capacity decay,and slow Na ion kinetic.Herein,we present layered ternary-phase cathodes with P2,P3 and O3 phases by a lattice doping strategy,which is demonstrated by X-ray diffraction（XRD） refinement.Combining the characteristics of P2,P3 and O3 phases,the layered composites show performance improvement during long-term battery cycling.In particular,Na0.7Li0.1Co0.3-Fe0.3Mn0.3O2（NLCFM） delivers a reversible capacity of120.1 mAh·g-1at 0.1C(1.0C=175 mA·g-1) with a superior capacity retention of 72.5% after 1000 cycles at10.0C.This work offers insights into the development of advanced cathode materials for SIBs.

关键词： Sodium-ion battery Cathode material Layered oxides Lattice doping Mixed phase

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Differential bonding behaviors of sodium/potassium-ion storage in sawdust waste carbon derivatives

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Chinese Chemical Letters 2024年第4期35卷 496-501页

作者： Jun-Ming Cao Kai-Yang Zhang Jia-Lin Yang Zhen-Yi Gu Xing-Long Wu MOE Key Laboratory for UV Light-Emitting Materials and Technology Northeast Normal UniversityChangchun 130024China department of chemistry Northeast Normal UniversityChangchun 130024China

Sodium-ion batteries(SIBs) and potassium-ion batteries(PIBs) are the most promising alternatives to lithium-ion batteries, and thus have drawn intensive research attention. Porous carbon materials from different precursors have been widely used as anode materials owing to their compatible storage effectiveness of both larger radii sodium and potassium ions. However, the differential bonding behaviors of Na and K ions with porous carbon-based anode are the significant one worth investigating, which could provide a clean picture of alkali ions storage mechanism. Therefore, in this work, we prepare a porous carbon network derived from sawdust(SDC) wastes, to further analyze the differences on sodium and potassium ions storage behaviors in terms of bond-forming process. It is found that, as-prepared SDC anodes could deliver stable sodium and potassium storage capacities, however, there are notable distinctions in terms of electrochemical behaviors and diffusion processes. By virtue of ex-situ XRD and Raman spectroscopy, the phase transition reaction of potassium ions could be well-observed, and the results shows that the multiple intercalated compounds was formed in SDC network during ions insertion, further resulting in slower diffusion kinetics and larger resistance compared to non-bonded process of sodium ions storage. This study provides more insights into the differences between sodium and potassium ions storage, as well as the energy storage mechanism of porous carbon as anodes for secondary batteries.

关键词： Porous carbon Sodium-ion storage Potassium-ion storage Bonding behaviors Batteries

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A highly reduced Mo_(74) polyoxometalate featuring high proton conductivity accessed by building block strategy

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Science China chemistry 2024年第3期67卷 862-868页

作者： Shi-Yi Liu Xue-Xin Li Wei-Chao Chen Kui-Zhan Shao Xin-Long Wang Chao Qin Zhong-Min Su Key Laboratory of Polyoxometalate and Reticular Material chemistry of Ministry of Education Department of ChemistryNortheast Normal UniversityChangchun 130024China State Key Laboratory of Supramolecular Structure and Materials Institute of Theoretical ChemistryCollege of ChemistryJilin UniversityChangchun 130021China

Highly reduced polyoxometalates(POMs) are predicted to be used as rather high energy density materials;however,it still suffers from the limited cluster species and reduction ratio.Here we demonstrate that it is possible to employ the building block strategy to generate a highly reduced polyoxomolybdate(C_(2)H_(8)N)_(14)(NH_(4))_(4)H_(14)[Mo_(48)-ⅤMo_(26)ⅥO_(202)(OH)_(12)(SO_(4))_(6)]·46H_(2)O(Mo_(74)).The fundamental Mo-based{Mo_x}(x=4,5,and 6) building blocks,which are templated by tetra-coordinated anions{MoO_(4)}or{SO_(4)},not only lay foundation for the formation of Mo_(74) featuring an unprecedented reduction ratio of 65%,but also give rise to SBBs-mediated(secondary building blocks) supramolecular dense packing interactions among the isolated Mo_(74) clusters that are favorable for proton conduction.Remarkably,high proton conductivity(2.04×10^(-2)S cm^(-1)) had been realized at 50℃ and 90% relative humidity,revealing one of the well-known POMs-based crystalline proton conducting materials.This result highlights that this building block approach possesses great potential in producing highly reduced POM systems that can achieve controllable reduced ratio and desirable properties.

关键词： polyoxometalate building block molybdenum highly reduced state proton conduction

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Selective synthesis of the B_(11)H_(14)^(-) and B_(12)H_(12)^(2-) borane derivatives and the general mechanisms of the B-H bond condensation

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Science China chemistry 2024年第3期67卷 876-881页

作者： Yi Jing Xinghua Wang Hui Han Xin-Ran Liu Xing-Chao Yu Xi-Meng Chen Donghui Wei Lai-Sheng Wang Xuenian Chen College of chemistry Green Catalysis CenterZhengzhou UniversityZhengzhou 450001China School of chemistry and Chemical Engineering Henan Key Laboratory of Boron Chemistry and Advanced Energy MaterialsHenan Normal UniversityXinxiang 453007China department of chemistry Brown UniversityProvidenceRI 02912USA

Polyhedral boranes are a class of well-known boron molecular clusters with unique physical and chemical properties,and great efforts have been made in the past decades to find more effective synthetic methods.However,the established synthetic methods suffer from low efficiency and low selectivity because the mechanism of the B-H bond condensation reaction,critical for the synthesis of the polyhedral boranes,is not well understood.Here we report highly selective and efficient synthetic methods of the salts of the tetradecahydridoundecaborate(1-)(B_(11)H^(-)_(14)) and dodecahydrido-dodecaborates(2-)(B_(12)H_(12)^(2-)) anions by employing commercially available and inexpensive starting materials.Both theoretical and experimental investigations are carried out to elucidate the reaction mechanisms.We have found that the nature of the B-H bond condensation is the dihydrogen bonding interaction in which the positively charged hydrogens(bridged hydrogens) play a crucial role.The current study has not only led to more effective and selective synthetic methods for B_(11)H^(-)_(14) and B_(12)H_(12)^(2-) but also unveiled the nature of the B-H bond condensation and the general formation mechanisms of polyhedral boranes.This finding will facilitate the development of more effective synthetic methods for polyhedral boranes and spur their wide application.

关键词： Boranes polyhedral boranes dihydrogen bond nucleophilicity

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