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Lithiophilic Li-Si alloy-solid electrolyte interface enabled by high-concentration dual salt-reinforced quasi-solid-state electrolyte

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Journal of Energy Chemistry 2024年第8期95卷 216-230,I0005页

作者： Yuanxing Zhang Ling Zhang Zhiguang Zhao Yuxiang Zhang Jingwen Cui Chengcai Liu Daobin Mu Yuefeng Su Borong Wu Feng Wu School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081China Chongqing innovation center Beijing Institute of TechnologyChongqing 401120China collaborative innovation center of electric vehicles in Beijing Beijing 100081China

Solid polymer electrolytes(SPEs)are urgently required to achieve practical solid-state lithium metal batteries(LMBs)and lithium-ion batteries(LIBs),Herein,we proposed a mechanism for modulating interfacial conduction and anode interfaces in high-concentration SPEs by *** electrolyte exhibits superior ionic conductivity and remarkable interface compatibility with salt-rich clusters:(1)polymer-plastic crystal electrolyte(P-PCE,TPU-SN matrix)dissociates ion pairs to facilitate Li+transport in the electrolyte and regulates Li^(+)diffusion in the *** crosslinking structure of the matrix compensates for the loss of mechanical strength at high-salt concentrations;(2)dual-anion TFSI^(-)_(n)-DFBOP^(-)_(m)in the Li^(+)solvation sheath facilitates facile Li^(+)desolvation and formation of salt-rich clusters and is conducive to the formation of Li conductive segments of TPU-SN matrix;(3)theoretical calculations indicate that the decomposition products of LiDFBOP form SEI with lower binding energy with LiF in the SN system,thereby enhancing the interfacial electrochemical redox kinetics of SPE and creating a solid interface SEI layer rich in *** a result,the optimized electrolyte exhibits an excellent ionic conductivity of9.31×10^(-4)S cm^(-1)at 30℃and a broadened electrochemical stability up to 4.73 *** designed electrolyte effectively prevents the formation of Li dendrites in Li symmetric cells for over 6500 h at0.1 mA cm^(-2).The specific Li-Si alloy-solid state half-cell capacity shows 711.6 mAh g^(-1)after 60 cycles at 0.3 A g^(-1).Excellent rate performance and cycling stability are achieved for these solid-state batteries with Li-Si alloy anodes and NCM 811 *** 811‖Prelithiated silicon-based anode solid-state cell delivers a discharge capacity of 195.55 mAh g^(-1)and a capacity retention of 97.8%after 120 *** 811‖Li solid-state cell also delivers capacity retention of 84.2%after 450 cycles.

关键词： Prelithiation Li-Si alloy anode Solid-state electrolyte SEI layer

Insight into the capacity degradation and structural evolution of single-crystal Ni-rich cathodes

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Journal of Energy Chemistry 2024年第8期95卷 68-76,I0003页

作者： Xiaodong Zhang Jiao Lin Ersha Fan Qingrong Huang Su Ma Renjie Chen Feng Wu Li Li Beijing Key Laboratory of Environmental Science and Engineering School of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China Advanced Technology Research Institute Beijing Institute of TechnologyJinan 250300ShandongChina collaborative innovation center of electric vehicles in Beijing Beijing 100081China

Single-crystal Ni-rich cathodes are a promising candidate for high-energy lithium-ion batteries due to their higher structural and cycling stability than polycrystalline ***,the phase evolution and capacity degradation of these single-crystal cathodes during continuous lithation/delithation cycling remains *** the mapping relationship between the macroscopic electrochemical properties and the material physicochemical properties is ***,we investigate the correlation between the physical-chemical characteristics,phase transition,and capacity decay using capacity differential curve feature identification and in-situ X-ray spectroscopic *** systematically clarify the dominant mechanism of phase evolution in aging *** high cut-off voltages can mitigate the slow kinetic and electrochemical properties of single-crystal *** also find that second-order differential capacity discharge characteristic curves can be used to identify the crystal structure disorder of Ni-rich *** findings constitute a step forward in elucidating the correlation between the electrochemical extrinsic properties and the physicochemical intrinsic properties and provide new perspectives for failure analysis of layered electrode materials.

关键词： Single-crystal cathodes Capacity decay Phase transition Differential capacity analysis

Risk assessment of oil and gas investment environment in countries along the Belt and Road Initiative

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Petroleum Science 2024年第2期21卷 1429-1443页

作者： Bao-Jun Tang Chang-Jing Ji Yu-Xian Zheng Kang-Ning Liu Yi-Fei Ma Jun-Yu Chen center for Energy and Environmental Policy Research Beijing Institute of TechnologyBeijing100081China School of Management and Economics Beijing Institute of TechnologyBeijing100081China collaborative innovation center of electric vehicles in Beijing BeijingChina Sustainable Development Research Institute for Economy and Society of Beijing BeijingChina Institute of Carbon Neutrality ShanghaiTech UniversityShanghai201210China

With the implementation of the Belt and Road Initiative, China is deepening its cooperation in oil and gas resources with countries along the Initiative. In order to better mitigate risks and enhance the safety of investments, it is of significant importance to research the oil and gas investment environment in these countries for China's overseas investment macro-layout. This paper proposes an indicator system including 27 indicators from 6 dimensions. On this basis, game theory models combined with global entropy method and analytic hierarchy process are applied to determine the combined weights, and the TOPSIS-GRA model is utilized to assess the risks of oil and gas investment in 76 countries along the Initiative from 2014 to 2021. Finally, the GM(1,1) model is employed to predict risk values for 2022-2025. In conclusion, oil and gas resources and political factors have the greatest impact on investment environment risk, and 12 countries with greater investment potential are selected through cluster analysis in conjunction with the predicted results. The research findings may provide scientific decisionmaking recommendations for the Chinese government and oil enterprises to strengthen oil and gas investment cooperation with countries along the Belt and Road Initiative.

关键词： Belt and Road Initiative Oil and Gas Investment Risk assessment

Water-facilitated targeted repair of degraded cathodes for sustainable lithium-ion batteries

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SusMat 2024年第2期4卷 28-40页

作者： Jiao Lin Xiaodong Zhang Zhujie Li Ersha Fan Xiaowei Lv Renjie Chen Feng Wu Li Li Beijing Key Laboratory of Environmental Science and Engineering School of Materials Science and EngineeringBeijing Institute of TechnologyBeijingChina collaborative innovation center of electric vehicles in Beijing No.5 South Zhongguancun StreetBeijingChina Advanced Technology Research Institute Beijing Institute of TechnologyJinanChina

Directly repairing end-of-life lithium-ion battery cathodes poses significant chal-lenges due to the diverse compositions of the ***,we propose a water-facilitated targeted repair strategy applicable to various end-of-life batches and *** process involves initiating structural repair and reconstruct-ing particle morphology in degraded LiMn_(2)O_(4)(LMO)through an additional thermal drive post-ambient water remanganization,achieving elemental *** to solid-phase repair,the resulting LMO material exhibits superior electrochemical and kinetic *** theoretical analysis highlights the impact of Mn defects on the structural stability and electron transfer rate of degraded *** propensity of Mn ions to diffuse within the Mn layer,specifically occupying the Mn 16d site instead of the Li 8a site,theoretically sup-ports the feasibility of ambient water ***,this method proves effective in the relithiation of degraded layered cathode materials,yielding single *** combining low energy consumption,environmental friendli-ness,and recyclability,our study proposes a sustainable approach to utilizing spent *** strategy holds the potential to enable the industrial direct repair of deteriorated cathode materials.

关键词： direct repair lithium-ion batteries water-facilitated

Online Monitoring Method for Junction Temperature of SiC MOSFETs based on Temperature Sensitive electrical Parameter

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CSEE Journal of Power and Energy Systems 2024年第4期10卷 1799-1807页

作者： Han Cao Puqi Ning Yunhao Huang Xuhui Wen Wuhan Second Ship Design and Research Institute Wuhan 430205China Key Laboratory of Power Electronics and electric Drive Institute of Electrical EngineeringChinese Academy of SciencesBeijing 100190China Institute of electrical Engineering Chinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China collaborative innovation center of electric vehicles in Beijing Beijing 100081China

Compared to Si devices,the junction temperature of SiC devices is more critical due to the reliability concern introduced by immature packaging technology applied to new *** paper proposes a practical SiC MOSFET junction temperature monitoring method based on the on-state voltage$\\boldsymbol{V}_{\\mathbf{ds}(\\mathbf{on})}$*** Section II of the paper,the temperature sensitivity of the on-state voltage$\\boldsymbol{V}_{\\mathbf{ds}(\\mathbf{on})}$is *** hardware of the measurement system is set up in Section III,which consists of an On-state Voltage Measurement Circuit(OVMC),the sampling and isolation ***,a calibration method based on the self-heating of the SiC MOSFET chip is presented in Section *** the final Section,the junction temperature is monitored synchronously according to the calibration *** proposed method is applied to a Buck converter and verified by both an Infrared Radiation(IR)camera and a Finite Element Analysis(FEA)tool.

关键词： Junction temperature Silicon Carbide(SiC)MOSFET TSEP

Amphipathic Phenylalanine-Induced Nucleophilic-Hydrophobic Interface Toward Highly Reversible Zn Anode

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Nano-Micro Letters 2024年第9期16卷 95-109页

作者： Anbin Zhou Huirong Wang Fengling Zhang Xin Hu Zhihang Song Yi Chen Yongxin Huang Yanhua Cui Yixiu Cui Li Li Feng Wu Renjie Chen Beijing Key Laboratory of Environmental Science and Engineering School of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081People’s Republic of China Advanced Technology Research Institute Beijing Institute of TechnologyJinan 250300People’s Republic of China collaborative innovation center of electric vehicles in Beijing Beijing 100081People’s Republic of China Institute of Electronic Engineering China Academy of Engineering PhysicsMianyang 621900People’s Republic of China

Aqueous Zn^(2+)-ion batteries(AZIBs),recognized for their high security,reliability,and cost efficiency,have garnered considerable ***,the prevalent issues of dendrite growth and parasitic reactions at the Zn electrode interface significantly impede their practical *** this study,we introduced a ubiquitous biomolecule of phenylalanine(Phe)into the electrolyte as a multifunctional additive to improve the reversibility of the Zn *** its exceptional nucleophilic characteristics,Phe molecules tend to coordinate with Zn^(2+)ions for optimizing the solvation ***,the distinctive lipophilicity of aromatic amino acids empowers Phe with a higher adsorption energy,enabling the construction of a multifunctional protective *** hydrophobic benzene ring ligands act as cleaners for repelling H_(2)O molecules,while the hydrophilic hydroxyl and carboxyl groups attract Zn^(2+)ions for homogenizing Zn^(2+)***,the preferential reduction of Phe molecules prior to H_(2)O facilitates the in situ formation of an organic-inorganic hybrid solid electrolyte interphase,enhancing the interfacial stability of the Zn ***,Zn||Zn cells display improved reversibility,achieving an extended cycle life of 5250 ***,Zn||LMO full cells exhibit enhanced cyclability of retaining 77.3%capacity after 300 cycles,demonstrating substantial potential in advancing the commercialization of AZIBs.

关键词： Zn anode Phenylalanine Adsorption energy Solvation sheath

Analysis and Optimization of Transient Mode Switching Behavior for Power Split Hybrid electric Vehicle with Clutch Collaboration

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Automotive innovation 2024年第1期7卷 150-165页

作者： Dehua Shi Sheng Liu Yujie Shen Shaohua Wang Chaochun Yuan Long Chen Automotive Engineering Research Institute Jiangsu UniversityZhenjiang 212013China Jiangsu Province Engineering Research center of electric Drive System and Intelligent Control for Alternative vehicles Zhenjiang 212013China

The power split hybrid electric vehicle(HEV)adopts a power coupling configuration featuring dual planetary gearsets and multiple clutches,enabling diverse operational modes through clutch engagement and *** multi-clutch configuration usually involves the collaboration of two clutches during the transient mode switching process,thereby substantially elevating control *** study focuses on power split HEVs that integrate multi-clutch mechanisms and investigates how different clutch collaboration manners impact the characteristics of transient mode *** powertrain model for the power-split HEV is established utilizing matrix-based *** the formulation of clutch torque curves and clutch collaboration models,this research systematically explores the effects of clutch engagement timing and the duration of clutch slipping state on transient mode switching *** upon this analysis,an optimization problem for control parameters pertaining to the two collaborative clutches is *** simulated annealing algorithm is employed to optimize these control *** results demonstrate that the clutch collaboration manners have a great influence on the transient mode switching *** with the pre-calibrated benchmark and the optimal solution derived by the genetic algorithm,the maximal longitudinal jerk and clutch slipping work during the transient mode switching process is reduced obviously with the optimal control parameters derived by the simulated annealing *** study provides valuable insights for the dynamic coordinated control of the power-split HEVs featuring complex clutch collaboration mechanisms.

关键词： Power split hybrid electric vehicle Transient mode switching Clutch collaboration Simulated annealing Powertrain model

Spin‑controlled topological phase transition in non‑Euclidean space

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Frontiers of Optoelectronics 2024年第1期17卷 67-76页

作者： Zhuochen Du Jinze Gao Qiuchen Yan Cuicui Lu Xiaoyong Hu Qihuang Gong State Key Laboratory for Mesoscopic Physics and Department of Physics Collaborative Innovation Center of Quantum Matter and Frontiers Science Center for Nano‑OptoelectronicsBeijing Academy of Quantum Information SciencesPeking UniversityBeijing 100871China Key Laboratory of Advanced Optoelectronic Quantum Architecture and Measurements of Ministry of Education Beijing Key Laboratory of Nanophotonics and Ultrafine Optoelectronic SystemsSchool of PhysicsBeijing Institute of TechnologyBeijing 100081China Peking University Yangtze Delta Institute of Optoelectronics Nantong 226010China collaborative innovation center of Extreme Optics Shanxi UniversityTaiyuan 030006China Hefei National Laboratory Hefei 230088China

Modulation of topological phase transition has been pursued by researchers in both condensed matter and optics research fields,and has been realized in Euclidean systems,such as topological photonic crystals,topological metamaterials,and coupled resonator ***,the spin-controlled topological phase transition in non-Euclidean space has not yet been ***,we propose a non-Euclidean configuration based on Mobius rings,and we demonstrate the spin-controlled transition between the topological edge state and the bulk *** Mobius ring,which is designed to have an 8πperiod,has a square cross section at the twist beginning and the length/width evolves adiabatically along the loop,accompanied by conversion from transverse electric to transverse magnetic modes resulting from the spin-locked *** 8πperiod Mobius rings are used to construct Su–Schrieffer–Heeger configuration,and the configuration can support the topological edge states excited by circularly polarized light,and meanwhile a transition from the topological edge state to the bulk state can be realized by controlling circular *** addition,the spin-controlled topological phase transition in non-Euclidean space is feasible for both Hermitian and non-Hermitian cases in 2D *** work provides a new degree of polarization to control topological photonic states based on the spin of Mobius rings and opens a way to tune the topological phase in non-Euclidean space.

关键词： Topological phase transition Non-Euclidean space Möbius ring Spin-locked effect

Interface engineering via temperature-dependent self-transformation on SnS2/SnS for enhanced piezocatalysis

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Chinese Journal of Catalysis 2024年第9期64卷 166-179页

作者： Wenrou Tian Jun Han Najun Li Dongyun Chen Qingfeng Xu Hua Li Jianmei Lu College of Chemistry Chemical Engineering and Materials ScienceCollaborative Innovation Center of Suzhou Nano Science and TechnologySoochow UniversitySuzhou 215123JiangsuChina

Heterojunction has been widely used in vibration-driven piezocatalysis for enhanced charges separation,while the weak interfaces seriously affect the efficiency during mechanical deformations due to prepared by traditional step-by-step ***,the intimate contact interfaces with shared S atoms are ingeniously constructed in SnS_(2)/SnS anchored on porous carbon by effective interface engineering,which is in-situ derived from temperature-dependent self-transformation of SnS_(2).Benefiting from intimate contact interfaces,the piezoelectricity is remarkably improved due to the larger interfacial dipole moment caused by uneven distribution of ***,vibration-induced piezoelectric polarization field strengthens the interfacial electric field to further promote the separation and migration of *** dynamic charges then transfer in porous carbon with high conductivity and adsorption for significantly improved piezocatalytic *** degradation efficiency of bisphenol A(BPA)is 6.3 times higher than SnS_(2) and H2 evolution rate is increased by 3.8 *** with SnS_(2)/SnS prepared by two-step solvothermal method,the degradation efficiency of BPA and H2 evolution activity are increased by 3 and 2 times,*** provides a theoretical guidance for developing various multiphase structural piezocatalyst with strong interface interactions to improve the piezocatalytic efficiency.

关键词： Piezocatalysis Self-transformation Phase junction Interfacial field Polarized field