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Dynamic emission characteristics and control strategies of air pollutants from motor vehicles in downtown beijing,China

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Journal of Environmental Sciences 2024年第2期136卷 637-646页

作者： Yan Shen Tongran Wu Aiping Lian Jie Gao Fei Peng Guohua Song Xuefang Wu Yangyang Cui Xinyu Liu Yunfei Wan Jing Yan Yifeng Xue National Engineering Research Center of Urban Environmental Pollution Control Beijing Municipal Research Institute of Eco-Environmental ProtectionBeijing 100037China beijing Municipal Ecology and Environment Bureau Beijing 100048China beijing Jiaotong University Beijing 100091China

This study combined the real-time monitoring and investigation of traffic flows to comprehensively analyze the road traffic flow and vehicle structure in downtown beijing.A dynamic emission inventory of motor vehicle air pollutants in downtown beijing in 2021 was established,and the impact of these emissions on air quality was simulated and quantified,and different emission reduction control scenarios were proposed to evaluate their environmental improvement effects and explore measures to mitigate the impact of pollution *** results show that the high traffic flow and the structure of the motor vehicle emissions in downtown beijing are the main causes of severe motor vehicle *** data shows that traffic flow in central beijing is dominated by small passenger vehicles,while the vehicle mix is better than in other regions,with 72.0%of vehicles meeting"National V"or higher emission ***,to achieve higher air quality goals,further reducing vehicle emissions is *** on dynamic traffic flow,the average daily emissions of nitrogen oxides(NOX),particulate matters(PM_(2.5))and volatile organic compounds(VOC)from motor vehicles in central beijing are 17.7 tons,0.6 tons and 14.0 tons,respectively,accounting for 23.0%of the city’s average daily motor vehicle *** a zero-emission zone for motor vehicles were implemented in central beijing,the annual average emission level of pollutants will be reduced by 10.4%to 21.0%.The designation of ultra-low emission zones for motor vehicles could be effective in improving the air quality in the center of beijing.

关键词： Motor vehicle Air pollutant Emission characteristics Control strategy beijing

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Doping engineering of iron oxide nanoparticles towards high performance and biocompatible T_(1)-weighted MRI contrast agents

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Rare Metals 2024年第1期43卷 298-308页

作者： Xue Xu Ping-Li Dong Yu-Yun Chai Run Yang Zhen-Hui Ma Chi-Chong Lu Department of Chemistry College of Chemistry and Materials EngineeringBeijing Technology and Business UniversityBeijing 100048China Department of Physics Beijing Technology and Business UniversityBeijing 100048China

Extremely small-sized iron oxide nanoparticles(IONPs) are of great interest in magnetic resonance imaging(MRI) due to their biosafety as an alternative to clinical gadolinium(Ⅲ) complexes-based contrast *** when the particle size is less than 10 nm,it has strong diffusion ability and deep penetration distance in tumor *** doping can significantly enhance the T_(1)contrast effect of nanoparticles by regulating the surface exposed ***,the nucleation and growth processes of multi-component synthesis systems are complex and difficult to be accurately controlled,leading to great challenges in the synthesis of ultra-small-sized nanoparticles with different components and ***,extremely smallsized superparamagnetic gadolinium-doped iron oxide nanoparticles(GdIONPs,Gd_(x)Fe_(3-x)O_(4) NPs) with adjustable doping amount and controllable size in the range of 3.5-7.5 nm were synthesized by thermal ***,as-synthesized GdIONPs were surface modified with a highly water-soluble and biocompatible carboxyl-polyethylene glycol-phosphoric acid ligand with high binding ***_(0.65)Fe_(2.35)O_(4) NPs exhibited very high r_(1) relaxivity of 10.6 mmol^(-1)·L·s^(-1) in terms of all metal concentrations and 49.0 mmol^(-1)·L·s^(-1) in terms of gadolinium alone,respectively,3 and 14 times higher than clinical T_(1) contrast agents(Gd-DTPA).GdIONPs can continuously obtain high resolution images of blood vessels,and can be used as an efficient and multifunctional contrast agent for MR T_(1)*** stable and efficient doping strategy provides an easy and effective method to individually optimize the magnetic properties of complex oxides and their relaxation effects for a variety of biomedical applications.

关键词： Iron oxide nanoparticles Small size Magnetic resonance imaging Substitutional doping Gd dopant

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Rare earth fluorescent nanoprobes with minimal side effects enable tumor microenvironment activation for chemotherapy

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Journal of Rare Earths 2024年第2期42卷 256-262,I0001页

作者： Tianqi Cao Yuxin Liu Qi Jia Xiaolu Wang Shouqiang Zhang Jing Zhou Department of Chemistry Capital Normal UniversityBeijing100048China

Chemotherapy,the use of antitumor drugs to kill cancer cells,is currently one of the most effective treatments for ***,serious toxic side effects caused by long-term drug accumulation can cause significant damage to the body,which limits the clinical application of antitumor *** this study,a novel RENPs@DOX-Fe nanoprobe(NP) was constructed by coating the surface of rare earth nanomaterials(NaLuF_(4):Yb,Er) with a complex formed by doxorubicin(DOX) and iron ion(Ⅲ).Due to the low toxicity of anthracycline-metal complexes,the damage to normal cells is *** unique acidic microenvironment in tumor cells facilitates the decomposition and gradual release of DOX from the DOX-Fe *** addition,the DOX-Fe complex can convert near-infrared(NIR) light into heat energy,which promotes the decomposition of the complex,further enhancing the release of DOX in the tumor *** change of ratio fluorescence of rare earth nanomaterials at 660 and 1550 nm after DOX release enables visual monitoring of drug release,which can potentially improve the chemotherapeutic *** vitro experiments established that RENPs@DOX-Fe NPs with NIR illumination had good therapeutic efficacy in *** work provides new insights into designing tumor microenvironment-responsive nanoprobes for chemotherapy with minimal side effects.

关键词： Rare earth nanoprobes Fluorescence Ratiometric imaging DOX Chemotherapy

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Facile synthesis of a tumor microenvironment-responsive nanomaterial with metallic polyphenol-encapsulated for enhanced synergistic therapy

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Journal of Rare Earths 2024年第10期42卷 1895-1902页

作者： Kaige Yu Nuo Kou Shouqiang Zhang Tianqi Cao Hanqing Wu Jing Zhou Department of Chemistry Capital Normal UniversityBejing100048China College of Teacher Education Capital Normal University Beijing100048China

The tumor microenvironment(TME)differs from normal tissue cells in its physiological and biochemical *** construction of TME-responsive nanoplatforms requires a tedious preparation process and complex multicomponent *** this work,Er@EGCG-Cu,a TME-responsive nanoplatform,was simply and rapidly synthesized by combining rare earth-doped nanomaterials(NaLuF_(4):Yb,Er)with EGCG-Cu which is based on the ability of metal ions to coordinate with polyphenols to form a metal-phenolic network(MPN)*** MPN structure is then destroyed under an acidic TME,releasing the chemotherapy(CT)drug EGCG,which can cause apoptosis,Cu_(x)S_(y)is generated by combining Cu^(2+)with H_2S overexpressed in human colorectal cancer cells and can be used for photothermal therapy(PTT).Cell experiments show that laser irradiation improves the CT/PTT synergistic effect of Er@*** study has significance for the construction of TME-responsive nanomedicines with simple and rapid preparation for synergistic therapy.

关键词： Tumor microenvironment Metal-polyphenol networks Synergistic therapy Rare earths Nanomaterials

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Distributed Heterogeneous Multi-Agent Optimization with Stochastic Sub-Gradient

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Journal of Systems Science & Complexity 2024年第4期37卷 1470-1487页

作者： HU Haokun MO Lipo CAO Xianbing School of Mathematics and Statistics Central South UniversityChangsha 410083China School of Mathematics and Statistics Beijing Technology and Business UniversityBeijing 100048China Research Centre for Agri-Product Quality Traceability Beijing Technology and Business UniversityBeijing 100048China School of Computer and Artificial Intelligence Beijing Technology and Business UniversityBeijing 100048China China Food Flavor and Nutrition Health Innovation Center Beijing Technology and Business UniversityBeijing 100048China

This paper studies the optimization problem of heterogeneous networks under a timevarying *** agent only accesses to one local objective function,which is *** improved algorithm with noisy measurement of local objective functions' sub-gradients and additive noises among information exchanging between each pair of agents is designed to minimize the sum of objective functions of all *** weaken the effect of these noises,two step sizes are introduced in the control *** graph theory,stochastic analysis and martingale convergence theory,it is proved that if the sub-gradients are uniformly bounded,the sequence of digraphs is balanced and the union graph of all digraphs is joint strongly connected,then the designed control protocol can force all agents to find the global optimal point almost *** last,the authors give some numerical examples to verify the effectiveness of the stochastic sub-gradient algorithms.

关键词： Communication noises distributed stochastic optimization heterogeneous networks subgradient measurement noises

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Distributed Region Tracking and Perimeter Surveillance for Second-Order Multi-Agent Systems in Star-Shaped Sets

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Journal of Systems Science & Complexity 2024年第5期37卷 1995-2020页

作者： SHANG Juan MO Lipo MI Rongxin CAO Xianbing School of Mathematics and Statistics Beijing Technology and Business UniversityBeijing 100048China The Department of Foundation Shijiazhuang Institute of Railway TechnologyShijiazhuang 050041China School of Computer and Artificial Intelligence Beijing Technology and Business UniversityBeijing 100048China Research Centre for Agri-Product Quality Traceability Beijing Technology and Business UniversityBeijing 100048China Coordination Center of China National Computer Network Emergency Response Technical TeamBeijing 100029China

This paper investigates region tracking and perimeter surveillance of second-order multiagent systems,where all agents move within a star-shaped ***,by coordination transformations,the region tracking problem is converted from the star-shaped sets to a circular *** authors employ communication and collaboration to complete region tracking and perimeter surveillance tasks,and then revert back to the star-shaped set by using inverse ***,the authors propose a distributed control strategy based on attractive and interaction potential functions,under which all agents can quickly track a given circular region and move around the ***,the authors validate the effectiveness and performance advantages of the proposed method through simulation experiments.

关键词： Distributed control multi-agent systems star-shaped sets target tracking

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Functional properties of defatted chickpea flour heat-induced gels

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International Journal of Agricultural and Biological Engineering 2024年第2期17卷 280-286页

作者： Chonghao Bi Aoxue Qie Tong Zhou Yi Liu Bin Tian School of Artificial Intelligence Beijing Technology and Business UniversityBeijing 100048China

Defatted chickpea flour(DCF),which is a by-product of chickpea oil extraction industry,is rich in nutrients that are beneficial to human *** this study,the effects of temperature and DCF variation on the rheological properties,water holding capacity,freeze-thaw stability and microstructure of DCF heat induced gels were *** results showed that the viscoelasticity,frequency dependence,and resistance strength of heat induced gels increased significantly with the increase of temperature and DCF *** degree of denaturation and water retention of heat induced gels increased significantly with increased variables within the temperature and variation windows of 75℃ to 95℃ and 13%to 21%.The CLSM results revealed that variations of both temperature and DCF variation could cause the proteins in the heat induced gels to aggregate gradually and to form protein *** temperature or variation exceeded certain value(85℃ or 17%),the protein aggregations broke up and the protein clusters became smaller and more ***,the heat induced gels presented better water holding capacity,viscoelasticity,structural stability and gel property at a temperature of 95℃ or a DCF variation of 21%within the present experimental range.

关键词： defatted chickpea flour rheological property freeze-thaw stability water holding capacity microstructure

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Enhancing comprehension of water vapor on adsorption performance of VOC on porous carbon materials and its application challenge

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Frontiers of Environmental Science & Engineering 2024年第9期18卷 51-66页

作者： Xiaolong Yao Kuan Wan Wenxin Yu Zheng Liu School of Ecology and Environment Beijing Technology and Business UniversityBeijing 100048China State Environmental Protection Key Laboratory of Food Chain Pollution Control Beijing Technology and Business UniversityBeijing 100048China School of Resources Environment and MaterialsGuangxi UniversityNanning 530004China

Volatile organic compounds(VOC)have been proven to cause considerable harm to both the ecological environment and human *** VOC emissions are primarily generated by the industrial *** utilization of porous carbon as an adsorbent has emerged as an effective method for the efficient removal of VOC from industrial ***,during the actual production processes,VOC exhaust gases are often mixed with water vapor,which poses challenges for adsorption *** review provides a comprehensive overview of the remarkable advancements in various carbon materials in terms of their ability to adsorb both VOC and water ***,it systematically summarizes the influence of surface groups on adsorbents and the molecular properties of VOC on their adsorption by carbon ***,this review introduces the mechanism underlying adsorption-adsorbent interactions and discusses the construction of models for adsorbing water vapor and *** challenges associated with the application of carbon materials for VOC adsorption in humid environments are also *** review aims to offer theoretical and technical guidance for the effective purification of moist VOC waste gases emitted from industrial sources,thereby achieving precise control of VOC emissions.

关键词： Adsorption Water vapor Carbon-based adsorbents Surface functional groups VOC properties

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Atmospheric Particulate Matter 2.5(PM_(2.5))Induces Cell Damage and Pruritus in Human Skin

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Biomedical and Environmental Sciences 2024年第2期37卷 216-220页

作者： HE Qiao XUE Wan Ting LI Li YI Fan LING Xiao GUO Miao Miao College of Chemistry and Materials Engineering Beijing Technology and Business UniversityBeijing 100048China China Light Industry Cosmetics Key Laboratory Beijing Technology and Business UniversityBeijing 100048China beijing Lan Divine Technology Co.LTD Beijing 100872China

With the accelerated rate of urbanization in recent years,air pollution has become an environmental problem that requires urgent resolution,almost all of the world’s population exposed to pollution on a daily *** the... 详细信息

关键词： pollution Skin Human

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Numerical manifold method for steady-state nonlinear heat conduction using Kirchhoff transformation

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Science China(Technological Sciences) 2024年第4期67卷 992-1006页

作者： ZHANG LiMei KONG Heng ZHENG Hong Key Laboratory of Urban Security and Disaster Engineering Ministry of EducationBeijing University of TechnologyBeijing 100124China beijing Municipal Construction Co. Ltd.Beijing 100048China

The numerical manifold method(NMM)introduces the mathematical and physical cover to solve both continuum and discontinuum problems in a unified *** this study,the NMM for solving steady-state nonlinear heat conduction problems is presented,and heat conduction problems consider both convection and radiation boundary ***,the nonlinear governing equation of thermal conductivity,which is dependent on temperature,is transformed into the Laplace equation by introducing the Kirchhoff *** transformation reserves linearity of both the Dirichlet and the Neumann boundary conditions,but the Robin and radiation boundary conditions remain ***,the NMM is employed to solve the Laplace equation using a simple iteration procedure because the nonlinearity focuses on parts of the problem domain ***,the temperature field is retrieved through the inverse Kirchhoff *** examples are analyzed,demonstrating the advantages of the Kirchhoff transformation over the direct solution of nonlinear equations using the NewtonRaphson *** study provides a new method for calculating nonlinear heat conduction.

关键词： numerical manifold method nonlinear heat conduction temperature-dependent thermal conductivity Kirchhoff transformation convection and radiation boundary conditions

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