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Fe-Induced Electronic Transfer and Structural Evolution of Lotus Pod-Like CoNiFePx@P,N-C Heterostructure for Sustainable Oxygen Evolution

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Energy & Environmental materials 2024年第3期7卷 186-193页

作者： Xiaojun Zeng Qingqing Zhang Chulong Jin Hui Huang Yanfeng Gao Advanced Ceramic materials research institute School of Materials Science and EngineeringJingdezhen Ceramic University Singapore institute of Technology School of materials Science and Engineering Shanghai University

Transition metal phosphides with metallic properties are a promising candidate for electrocatalytic water oxidation,and developing highly active and stable metal phosphide-based oxygen evolution reaction catalysts is still ***,we present a facile ion exchange and phosphating processes to transform intestine-like CoNiPx@P,N-C into lotus pod-like CoNiFePx@P,N-C heterostructure in which numerous P,N-codoped carboncoated CoNiFePxnanoparticles tightly anchors on the 2D carbon ***,the as-prepared CoNiFePx@P,N-C enables a core-shell structure,high specific surface area,and hierarchical pore structure,which present abundant heterointerfaces and fully exposed active ***,the incorporation of Fe can also induce electron transfer in CoNiPx@P,IM-C,thereby promoting the oxygen evolution ***,CoNiFePx@P,IM-C delivers a low overpotential of 278 mV （vs RHE） at a current density of10 mA cm-1and inherits excellent long-term stability with no observable current density decay after 30 h of chronoamperometry *** work not only highlights heteroatom induction to tune the electronic structure but also provides a facile approach for developing advanced and stable oxygen evolution reaction electrocatalysts with abundant heterointerfaces.

关键词： electronic transfer Fe exchange multi-metal phosphides OER electrocatalysts structural evolution

Thermal stability improvement and microstructure optimization of high cobalt content Nd-Fe-B magnets via terbium grain boundary diffusion

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Journal of Rare Earths 2024年第8期42卷 1531-1538,I0004页

作者： Jiyuan Xu Ruiyang Meng Jing Liu Jiateng Zhang Rui Han Yikun Fang Shengzhi Dong Wei Li Division of Functional materials research Central Iron and Steel Research InstituteBeijing100081China

The substitution of Fe by Co in the 2:14:1 phase is an effective method to increase the Curie temperature and enhance the thermal stability of the Nd-Fe-B ***,the accumulation of Co ele ment at the grain boundaries(GBs) changes the GBs from nonmagnetic to ferromagnetic and causes the thinlayer GBs to become rare,In this paper,the method of diffusing Tb element was chosen to improve the microstructure and temperature stability of high-Co *** original sintered Nd_(28.5)Dy_(3)-CO_(x)e_(bal)M_(0.6)B_(i)(x=0,6 wt%,12 wt%;M = Cu,Al,Zr) magnets with different Co contents were diffused with Tb by grain boundary diffusion(GBD).After GBD,high-Co magnets exhibit more continuously distributed thin-layer GBs,and their thermal stability is significantly *** high-Co magnets(x=6 wt%),the absolute value of the temperature coefficient of coercivity decreases from 0.603%/K to0.508%/K in the temperature range of 293-413 K,that of remanence decreases from 0.099%/K to 0.091%/K,and the coercivity increases from 18.44 to 25.04 *** electron microscopy(TEM)characterization reveals that there are both the 1:2 phase and the amorphous phase in the high-Co magnet before and after GBD,EDS elemental analysis shows that Tb element is more likely to preferentially replace the rare earth elements in the 2:14:1 main phase than in the 1:2 phase and the amorphous *** concentration of Tb at the edge of the main phase is much higher than that in the 1:2phase and amorphous phase,which is beneficial to the improvement of the *** preferential replacement of Tb elements at the edge of the 2:14:1 phase and thin-layer GBs with a more continuous distribution are synergistically responsible for improving the thermal stability of high-Co *** study indicates that GBD is an effective method to improve the microstructure and thermal stability of high-Co magnets.

关键词： Nd-Fe-B magnets Coercivity Grain boundary diffusion Thermal stability Micro structure Rare earths

Pr-Tb synergistic strengthening on coercivity of Nd-Ce-Fe-B magnets grain boundary diffused with Pr-Tb-Al-Ga alloys

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Journal of Rare Earths 2024年第9期42卷 1704-1709,I0003页

作者： Ruifang Song Hang Zhao Haibo Feng institute of Functional materials Central Iron&Steel Research InstituteBeijing100081China

Sintered Nd-Ce-Fe-B magnets were grain boundary diffused(GBDed) with Pr_(x)Tb_(80-x)Al_(10)Ga_(10)(at%)(x=0,20,40,60,80) *** effect of Pr/Tb content in diffusion source on magnetic properties,microstructure and elements distribution of GBDed magnets was *** Pr is used to substitute for 75% Tb in diffusion source,Tb consumption per unit coercivity improvement of GBDed magnet reduces by 77%,compared with the Tb_(80)Al_(10)Ga_(10) diffused *** element diffuses into magnets and then forms Tb-rich shell with high magneto-crystalline anisotropy field surrounding main phase grains,resulting in substantial coercivity *** with low melting point diffuses deeply along liquid grain boundary phase during GBD *** can eliminate some sharp defects of main phase grains and make grain boundaries smooth,which provides diffusion channels for further diffusion of Tb ***,there are more diffusion channels for Tb and less Tb enriched at surface region,making Tb diffuse more deeply and improving Tb utilization *** method significantly improves the coercivity,and realizes the green,efficient and high-quality utilization of heavy rare earth(HRE)elements.

关键词： Grain boundary diffusion Rare earths Microstructure Synergistic strengthening

On-Chip Micro Temperature Controllers Based on Freestanding Thermoelectric Nano Films for Low-Power Electronics

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Nano-Micro Letters 2024年第7期16卷 98-108页

作者： Qun Jin Tianxiao Guo Nicolas Perez Nianjun Yang Xin Jiang Kornelius Nielsch Heiko Reith institute for Metallic materials Leibniz Institute for Solid State and Materials Research01069 DresdenGermany institute of materials Engineering University of Siegen57076 SiegenGermany institute of Applied Physics Technical University of Dresden01069 DresdenGermany institute of materials Science Technical University of Dresden01069 DresdenGermany

Multidimensional integration and multifunctional com-ponent assembly have been greatly explored in recent years to extend Moore’s Law of modern ***,this inevitably exac-erbates the inhomogeneity of temperature distribution in microsystems,making precise temperature control for electronic components extremely ***,we report an on-chip micro temperature controller including a pair of thermoelectric legs with a total area of 50×50μm^(2),which are fabricated from dense and flat freestanding Bi2Te3-based ther-moelectric nano films deposited on a newly developed nano graphene oxide membrane *** tunable equivalent thermal resistance is controlled by electrical currents to achieve energy-efficient temperature control for low-power electronics.A large cooling temperature difference of 44.5 K at 380 K is achieved with a power consumption of only 445μW,resulting in an ultrahigh temperature control capability over 100 K mW^(-1).Moreover,an ultra-fast cooling rate exceeding 2000 K s^(-1) and excellent reliability of up to 1 million cycles are *** proposed on-chip temperature controller is expected to enable further miniaturization and multifunctional integration on a single chip for microelectronics.

关键词： Temperature control Low-power electronics On-chip micro temperature controller Freestanding thermoelectric nano films Temperature-sensitive components

Electrochemically Deposited CZTSSe Thin Films for Monolithic Perovskite Tandem Solar Cells with Efficiencies Over 17%

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Energy & Environmental materials 2024年第1期7卷 151-156页

作者： Sun Kyung Hwang Ik Jae Park Se Won Seo Jae Hyun Park So Jeong Park Jin Young Kim Department of materials Science and Engineering Seoul National University Department of Applied Physics Sookmyung Women’s University research institute of Advanced materials and Systems Sookmyung Women’s University research institute of Advanced materials (RIAM) Seoul National University

In spite of the high potential economic feasibility of the tandem solar cells consisting of the halide perovskite and the kesterite Cu2ZnSn（S,Se）4（CZTSSe）,they have rarely been demonstrated due to the difficulty i... 详细信息

关键词： CZTSSe monolithic tandem solar cells perovskite solution process surface roughness control

Porously Reduced 2-Dimensional Bi2O2CO3 Petals for Strain-Mediated Electrochemical CO2 Reduction to HCOOH

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Energy & Environmental materials 2024年第1期7卷 219-225页

作者： Won Seok Cho Dae Myung Hong Wan Jae Dong Tae Hyung Lee Chul Jong Yoo Donghwa Lee Ho Won Jang Jong-Lam Lee Department of materials Science and Engineering Pohang University of Science and Technology (POSTECH) Department of materials Science and Engineering Research Institute of Advanced Materials Seoul National University

Here we introduce bismuth-based catalysts for the efficient electrochemical reduction of CO2to formic acid（HCOOH）,which are composed of petalshaped Bi2O2CO3（BOC） that spontaneously formed from Bi thin film in aqueous carbonate solution at room *** the electrochemical reduction process,the BOC petals transform to reduced BOC（R-BOC）consisting of individual BOC and Bi domains.

关键词： bismuth carbon dioxide reduction formic acid heterointerfaces strain

Theoretical Design of Defects as a Driving Force for Ion Transport in Li3OBr Solid Electrolyte

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Energy & Environmental materials 2024年第3期7卷 147-157页

作者： Xingyun Luo Yanlu Li Xian Zhao State Key Lab of Crystal materials and institute of Crystal materials Shandong University Center for Optics research and Engineering Shandong University

Due to ever-increasing concerns about safety issues in using Li ionic batteries,solid electrolytes have extensively *** Li-rich antiperovskite Li3OBr has been considered as a promising solid electrolyte candidate,but it still suffers challenges to achieve a high ionic conductivity owing to the high intrinsic symmetry of the crystal ***,we presented a design strategy that introduces various point defects and grain boundaries to break the high lattice symmetry of Li3OBr crystal,and their effect and microscopic mechanism of promoting the migration of Li-ion were explored *** has been found that Liiare the dominant defects responsible for the fast Li-ion diffusion in bulk Li3OBr and its surface,but they are easily trapped by the grain boundaries,leading to the annihilating of the Frenkel defect pair V'Li+Li,and thus limits the V'Lidiffusion at the grain *** VBrdefect near the grain boundaries can effectively drive V'Liacross the grain boundary,thereby converting the carrier of Li+migration from Li,in the bulk and surface to V'Liat the grain boundary,and thus improving the ionic conductivity in the whole Li3OBr *** work provides a comprehensive insight into the Li+transport and conduction mechanism in the Li3OBr *** opens a new way of improving the conductivity for all-solid-state Li electrolyte material through the defect design.

关键词： defects density functional theory ionic migration solid electrolyte

Microstructure and properties of coarse-grained WC-10Co cemented carbides with different carbon contents during heat treatments

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Rare Metals 2024年第4期43卷 1786-1792页

作者： Yuan-Feng Xie Xing-Cheng Xie Zhong-Wu Li Rui-Jun Cao Zhong-Kun Lin Qing Li Chen-Guang Lin Powder Metallurgy and Special materials research Department General Research Institute for Nonferrous MetalsBeijing100088China

The effects of cryogenic treatment(CT)and tempering-cryogenic treatment(TCT)on the microstructure and properties of coarse-grained WC-10Co cemented carbides with different carbon contents were *** binder phase,WC mean grain sizes,W solubility in the binder,relative magnetic s aturation,densities,hardness,wear resistance and second phase precipitation of cemented carbides with different heat treatments were *** results show that there are significant changes of microstructure and properties in the samples with CT and TCT,especially due to the precipitation of metastable nanoparticles W_(x)Co_(y)C_(z) in the binder during the heat treatments of CT and *** the simultaneous combination of microstructure and nanoparticle-reinforced binder,a dramatically improved combination of hardness and wear resistance of the samples after TCT has been achieved.

关键词： Cryogenic treatment Tempering Coarsegrained cemented carbide Carbon content Nanoparticlereinforced binder

High-performance anisotropic SmCo-based magnet with novel microstructure

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Journal of Rare Earths 2024年第8期42卷 1539-1545,I0005页

作者： Yingchang Li Zicao Xing Nengjun Yu Zesong Ren Minxiang Pan Qiong Wu Hongliang Ge Minggang Zhu Wei Li College of materials and Chemistry China jiliang UniversityHangzhou 310018China Division of Functional materials research Central Iron and Steel Research InstituteBeijing 100081China

A novel micro structure of magnetically anisotropic Sm Co-based magnet with high-performance is *** magnet consists of SmCo_(7)-H(TbCu_(7)-hexagonal type),Sm_(2)Co_(17)-H(Th_(2)Ni_(17)-hexagonal type)and SmCo_(3)-R(SmCo_(3)-rhombohedral type)*** maximum magnetic energy product of the magnet is 231.69 kj/m^(3),and the intrinsic coercivity is 1005.47 kA/*** outstanding intrinsic coercivity temperature coefficient(β)of-0.125%/K between 298 and 773 K is obtained,which is very close to theβof commercial high-temperature Sm_(2)Co_(17)-based sintered *** initial magnetization curve indicates that the coercivity mechanism is controlled by a domain wall pinning *** SmCo_(3)-R lamellar phase may be a potential pinning center or self-pinning *** microstructure of the magnet is different from that of any previous SmCo-based *** findings provide a new idea for preparing high-performance SmCo-based permanent magnets.

关键词： Rare earths Permanent magnet Composite magnet Melt-spinning Microstructure