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Rare Metals 2024年第9期43卷 4234-4242页

作者： Jia-Guo Deng Hao-Qin Feng Yu-Long Xu Si-Guang Guo Jian-Ping Li Kai-Fu Huo Ji-Jiang Fu Biao Gao Pual-K.Chu The State Key Laboratory of Refractories and Metallurgy and Institute of Advanced Materials and Nanotechnology Wuhan University of Science and Technology Wuhan National Laboratory for Optoelectronics (WNLO) School of Optical and Electronic InformationHuazhong University of Science and Technology department of Physics Department of Materials Science & Engineeringand Department of Biomedical EngineeringCity University of Hong Kong

Silicon （Si） has mild discharge potential and high theoretical capacity,making it a highly desirable material for lithium-ion batteries （LIBs）.Nevertheless,the excessive volume expansion,poor ion/electron conductiv ity and unstable solid electrolyte interface （SEI） hinde practical application to ***,the metallic antimony（Sb） stabilized porous Si （SiDSb） composite was prepared by magnesiothermic reduction of Sb2O3and Mg2Si and chemical etching to remove the by-product of *** highly conductive Sb nanodots embedded in the Si liga ments promote not only the formation of conductive and stable LiF-rich SEI,but also the electron/ion transpor ability of *** to the outstanding bulk/interface stability,excellent conductivity,as well as ideal porous structure,the SiDSb electrode demonstrates a capacity of820 mAh·g-1after undergoing 320 turns at 1000 mA·***,it exhibits a stable capacity of 675 m Ah·g-1when tested at a higher current density of 5000 m A·*** results reveal a viable solution to solve three problems at the same time,namely the poor conductivity,inferior SEI and excessive volume expansion of Si,boding well for the design of Si-based materials for high-energy LIBs.

关键词： Anodes Antimony Lithium-ion batteries Silicon Solid electrolyte interphase

Large-scale manufacturing of functional single-atom ink for convenient glucose sensing

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Nano Research 2024年第8期17卷 7256-7263页

作者： Muyu Yan Xiaofei Zhu Can Xiong Xiao Han Zhenggang Xue Yuen Wu department of Endocrinology Institute of Endocrine and Metabolic DiseasesThe First Affiliated Hospital of USTCDivision of Life Sciences and MedicineUniversity of Science and Technology of ChinaHefei 230001China Deep Space Exploration Laboratory University of Science and Technology of ChinaHefei 230026China NEST Laboratory Department of PhysicsDepartment of ChemistryCollege of ScienceShanghai UniversityShanghai 200444China Center of Advanced Nanocatalysis(CAN) Department of Applied ChemistryUniversity of Science and Technology of ChinaHefei 230026China

Printing techniques hold great potential in the manufacture of electronics such as sensors,micro-supercapacitors,and flexible ***,developing large-scale functional conductive inks with appropriate rheological properties and active components still remains a ***,through optimizing the formulations of ink,iron single sites supported N-doped carbon black(Fe_(1)-NC)inks can serve as both conductive electrodes and high-reactive catalysts to realize convenient glucose detection,which pronouncedly reduces the dosage of enzyme and simplifies the sensors *** detail,utilizing in-situ pyrolysis method,Fe_(1)-NC single-atom catalysts(SACs)are prepared in bulk(dekagram-level).The batched Fe_(1)-NC SACs materials can be uniformly mixed with modulated ink to realize the screen printing with high resolution and ***,the whole scalable preparation and ink-functional process can be extended to various metals(including Co,Ni,Cu,and Mn).The introduction of highly active Fe_(1)-NC sites reduces the amount of enzyme used in glucose detection by at least 50%,contributing to the cost reduction of *** strategy in harnessing the SACs onto the carbon inks thus provides a broad prospect for the low-cost and large-scale printing of sensitive sensing devices.

关键词： large-scale manufacturing single-atom inks screen printing glucose sensing low enzyme dosage

Correlation between hydration properties and electrochemical performances on Ln cation size effect in layered perovskite for protonic ceramic fuel cells

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Journal of Energy Chemistry 2024年第1期88卷 1-9,I0001页

作者： Inhyeok Cho Jiwon Yun Boseok Seong Junseok Kim Sun Hee Choi Ho-Il Ji Sihyuk Choi department of Mechanical Engineering Kumoh National Institute of TechnologyGumi 39177GyeongbukRepublic of Korea department of Aeronautics Mechanical and Electronic Convergence EngineeringKumoh National Institute of TechnologyGumi 39177GyeongbukRepublic of Korea Center for Energy Materials Research Korea Institute of Science and Technology(KIST)Seoul 02792Republic of Korea Center for Hydrogen and Fuel Cell Research Clean Technology Research DivisionKorea Institute of Science and Technology(KIST)Seoul 02792Republic of Korea department of Energy and Environmental Engineering University of Science and TechnologySeoul 02792Republic of Korea Nanomaterials science and Engineering Korea University of Science and Technology(UST)KIST CampusSeoul 02792Republic of Korea

PrBa_(0.5)Sr_(0.5)Co_(1.5)Fe_(0.5)O_(5+δ)(PrBSCF) has attracted much research interest as a potential triple ionic and electronic conductor(TIEC) electrode for protonic ceramic fuel cells(PCFCs). The chemical formula for Pr BSCF is AA'B_(2)O_(5+δ), with Pr(A-site) and Ba/Sr(A'-site) alternately stacked along the c-axis. Due to these structural features, the bulk oxygen ion diffusivity is significantly enhanced through the disorder-free channels in the PrO layer;thus, the A site cations(lanthanide ions) play a pivotal role in determining the overall electrochemical properties of layered perovskites. Consequently, previous research has predominantly focused on the electrical properties and oxygen bulk/surface kinetics of Ln cation effects,whereas the hydration properties for PCFC systems remain unidentified. Here, we thoroughly examined the proton uptake behavior and thermodynamic parameters for the hydration reaction to conclusively determine the changes in the electrochemical performances depending on LnBa_(0.5)Sr_(0.5)Co_(1.5)Fe_(0.5)O_(5+δ)(LnBSCF,Ln=Pr, Nd, and Gd) cathodes. At 500 ℃, the quantitative proton concentration of PrBSCF was 2.04 mol% and progressively decreased as the Ln cation size decreased. Similarly, the Gibbs free energy indicated that less energy was required for the formation of protonic defects in the order of Pr BSCF < Nd BSCF < Gd BSCF. To elucidate the close relationship between hydration properties and electrochemical performances in LnBSCF cathodes, PCFC single cell measurements and analysis of the distribution of relaxation time were further investigated.

关键词： Protonic ceramic fuel cell Cathode Triple ionic and electronic conductor Hydration property Proton uptake Gibbs free energy

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Segment routing for traffic engineering and effective recovery in low-earth orbit satellite constellations

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Digital Communications and Networks 2024年第3期10卷 706-715页

作者： Shengyu Zhang Xiaoqian Li Kwan Lawrence Yeung department of Electrical and Electronic Engineering The University of Hong KongHKSARChina National Key Laboratory of science and technology on Communications University of Electronic Science and Technology of ChinaChengduSichuan611731China

Low-Earth Orbit Satellite Constellations(LEO-SCs)provide global,high-speed,and low latency Internet access services,which bridges the digital divide in the remote *** inter-satellite links are not supported in initial deployment(*** Starlink),the communication between satellites is based on ground stations with radio frequency *** to the rapid movement of satellites,this hybrid topology of LEO-SCs and ground stations is time-varying,which imposes a major challenge to uninterrupted service provisioning and network *** this paper,we focus on solving two notable problems in such a ground station-assisted LEO-SC topology,i.e.,traffic engineering and fast reroute,to guarantee that the packets are forwarded in a balanced and uninterrupted ***,we employ segment routing to support the arbitrary path routing in *** solve the traffic engineering problem,we proposed two source routings with traffic splitting algorithms,Delay-Bounded Traffic Splitting(DBTS)and DBTS+,where DBTS equally splits a flow and DBTS+favors shorter ***-lation results show that DBTS+can achieve about 30%lower maximum satellite load at the cost of about 10%more *** guarantee the fast recovery of failures,two fast reroute mechanisms,Loop-Free Alternate(LFA)and LFA+,are studied,where LFA pre-computes an alternate next-hop as a backup while LFA+finds a 2-segment backup *** show that LFA+can increase the percentage of protection coverage by about 15%.

关键词： Fast reroute Low-earth orbit satellite constellation Segment routing Traffic engineering Traffic splitting

Tailoring high-refractive-index nanocomposites for manufacturing of ultraviolet metasurfaces

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Microsystems & Nanoengineering 2024年第2期10卷 303-310页

作者： Hyunjung Kang Dongkyo Oh Nara Jeon Joohoon Kim Hongyoon Kim Trevon Badloe Junsuk Rho department of Mechanical Engineering Pohang University of Science and Technology(POSTECH)PohangRepublic of Korea Graduate School of Artificial Intelligence Pohang University of Science and Technology(POSTECH)PohangRepublic of Korea department of Chemical Engineering Pohang University of Science and Technology(POSTECH)PohangRepublic of Korea department of Electrical Engineering Pohang University of Science and Technology(POSTECH)PohangRepublic of Korea POSCO-POSTECH-RIST Convergence Research Center for Flat Optics and Metaphotonics PohangRepublic of Korea National Institute of Nanomaterials technology(NINT) PohangRepublic of Korea

Nanoimprint lithography(NIL)has been utilized to address the manufacturing challenges of high cost and low throughput for optical *** overcome the limitations inherent in conventional imprint resins characterized by a low refractive index(n),high-n nanocomposites have been introduced to directly serve as ***,comprehensive research on these nanocomposites is notably *** this study,we focus on the composition of high-n zirconium dioxide(ZrO_(2))nanoparticle(NP)concentration and solvents used to produce ultraviolet(UV)metaholograms and quantify the transfer fidelity by the measured conversion *** utilization of 80 wt%ZrO_(2)NPs in MIBK,MEK,and acetone results in conversion efficiencies of 62.3%,51.4%,and 61.5%,respectively,at a wavelength of 325 *** analysis of the solvent composition and NP concentration can further enhance the manufacturing capabilities of high-n nanocomposites in NIL,enabling potential practical use of optical metasurfaces.

关键词： ultraviolet refractive nanocomposites

Microstructure and magnetocaloric properties of melt-extracted SmGdDyCoAl high-entropy amorphous microwires

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Rare Metals 2024年第3期43卷 1234-1242页

作者： Shi-Jie Wei Hong-Xian Shen Lun-Yong Zhang Lin Luo Xin-Xing Tang Jian-Fei Sun Xiao-Qing Li School of Materials science and Engineering Harbin Institute of TechnologyHarbin150001China Applied Materials Physics Department of Materials Science and EngineeringKTH-Royal Institute of Technology10044StockholmSweden

This paper presents a systematic investigation of the microstructure and magnetocaloric properties of melt-extracted Sm_(20)Gd_(20)Dy_(20)Co_(20)Al_(20)high-entropy *** fabricated wires exhibited an amorphous structure,and the temperature interval of the undercooled liquid AT was 45 *** microwires underwent a second-order magnetic transition from a ferromagnetic to a paramagnetic state near the Curie temperature(T_(C)=52 K),The maximum magnetic entropy change(-ΔS_M^(max)),the relative cooling power and the refrigeration capacity reached 6.34 J·kg^(-1)·K^(-1).422.09 J·kg^(-1)and 332.94 J·kg^(-1),respectively,under a magnetic field change of 5 *** addition,the temperature-averaged entropy changes with two temperature lifts(3 and 10 K)were 6.32 and 6.27 J·kg^(-1)·K^(-1),*** good magnetocalorie performance highlights the significant potential for the Sm_(20)Gd_(20)Dy_(20)Co_(20)Al_(20)microwires to be used as magnetic refrigerant materials in low-temperature region *** work will serve as a valuable reference for future investigations on low-temperature high-entropy magnetocaloric materials.

关键词： Melt-extraction High-entropy amorphous microwires Magnetocaloric effect Magnetic refrigeration

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Extended context-based semantic communication system for text transmission

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Digital Communications and Networks 2024年第3期10卷 568-576页

作者： Yueling Liu Shengteng Jiang Yichi Zhang Kuo Cao Li Zhou Boon-Chong Seet Haitao Zhao Jibo Wei College of Electronic science and technology National University of Defense TechnologyChangsha410073China department of Electrical and Electronic Engineering Auckland University of TechnologyAucklandNew Zealand

Context information is significant for semantic extraction and recovery of messages in semantic ***,context information is not fully utilized in the existing semantic communication systems since re-lationships between sentences are often *** this paper,we propose an Extended Context-based Semantic Communication(ECSC)system for text transmission,in which context information within and between sentences is explored for semantic representation and *** the encoder,self-attention and segment-level relative attention are used to extract context information within and between sentences,*** addition,a gate mechanism is adopted at the encoder to incorporate the context information from different *** the decoder,Transformer-XL is introduced to obtain more semantic information from the historical communication processes for semantic *** results show the effectiveness of our proposed model in improving the semantic accuracy between transmitted and recovered messages under various channel conditions.

关键词： semantic communication extended context Transformer-XL

Tailoring local structures of atomically dispersed copper sites for highly selective CO_(2) electroreduction

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Carbon Energy 2024年第4期6卷 79-90页

作者： Kyung‐Jong Noh Byoung Joon Park Ying Wang Yejung Choi Sang‐Hoon You Yong‐Tae Kim Kug‐Seung Lee Jeong Woo Han department of Chemical Engineering Pohang University of Science and Technology(POSTECH)PohangGyeongbukRepublic of Korea department of Materials science and Engineering Pohang University of Science and Technology(POSTECH)PohangGyeongbukRepublic of Korea Pohang Accelerator Laboratory(PAL) Beamline DivisionPohangGyeongbukRepublic of Korea

Atomically‐dispersed copper sites coordinated with nitrogen‐doped carbon(Cu–N–C)can provide novel possibilities to enable highly selective and active electrochemical CO_(2) reduction ***,the construction of optimal local electronic structures for nitrogen‐coordinated Cu sites(Cu–N_(4))on carbon remains ***,we synthesized the Cu–N–C catalysts with atomically‐dispersed edge‐hosted Cu–N_(4) sites(Cu–N_(4)C_(8))located in a micropore between two graphitic sheets via a facile method to control the concentration of metal ***‐hosted Cu–N_(4)C_(8) catalysts outperformed the previously reported M–N–C catalysts for CO_(2)‐to‐CO conversion,achieving a maximum CO Faradaic efficiency(FECO)of 96%,a CO current density of–8.97 mA cm^(–2) at–0.8 V versus reversible hydrogen electrode(RHE),and over FECO of 90%from–0.6 to–1.0 V versus *** studies revealed that the micropore of the graphitic layer in edge‐hosted Cu–N_(4)C_(8) sites causes the d‐orbital energy level of the Cu atom to shift upward,which in return decreases the occupancy of antibonding states in the*COOH *** research suggests new insights into tailoring the locally coordinated structure of the electrocatalyst at the atomic scale to achieve highly selective electrocatalytic reactions.

关键词： atomic local structure density functional theory electrochemical CO_(2)reduction metal nitrogen‐doped carbon single‐atom catalyst

Risk-Averse Two-Stage Distributionally Robust Economic Dispatch Model Under Uncertain Renewable Energy

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CSEE Journal of Power and Energy Systems 2024年第4期10卷 1514-1524页

作者： Ce Yang Weiqing Sun Jiannan Yang Dong Han department of Control science and Engineering University of Shanghai for Science and TechnologyShanghai 200093China department of Electrical Engineering University of Shanghai for Science and TechnologyShanghai 200093China School of Economics and Business Administration Chongqing UniversityChongqing 400044China

With the participation of large quantities of renewable energy in power system operations,their volatility and intermittence increases the difficulties and challenges of power system economic *** the uncertainty of renewable energy generation,based on the distributionally robust optimization method,a two-stage economic dispatch model is proposed to minimize the total operation *** this paper,it is assumed that the fluctuating of renewable power generation follows the unknown probability distribution that is restricted in an ambiguity set,which is established by utilizing the first-order moment information of available historical ***,the theory of conditional value-at-risk is introduced to transform the model into a tractable model,which we call robust counterpart *** on the stochastic dual dynamic programming method,an improved iterative algorithm is proposed to solve the robust counterpart ***,the convergence optimum can be obtained by the improved iterative algorithm,which performs a forward pass and backward pass repeatedly in each iterative ***,by comparing with other methods,the results on the modified IEEE 6-bus,118-bus,and 300-bus system show the effectiveness and advantages of the proposed model and method.

关键词： Energy and reserve co-dispatch distributionally robust conditional value-at-risk stochastic dual dynamic programming

Structure,electronic,and nonlinear optical properties of superalkaline M_(3)O(M=Li,Na)doped cyclo[18]carbon

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Chinese Physics B 2024年第2期33卷 311-317页

作者：刘晓东卢其亮罗其全 School of Physics and Material science Anhui UniversityHefei 230601China Institute of Physical science and Information technology Anhui UniversityHefei 230601China department of Chemical Physics University of Science and Technology of ChinaHefei 230026China

Cyclo[18]carbon has received considerable attention thanks to its novel geometric configuration and special electronic *** have low ionization *** a superalkali in cyclo[18]carbon is an effective method to improve the optical properties of the system because considerable electron transfer *** this paper,the geometry,bonding properties,electronic structure,absorption spectrum,and nonlinear optical(NLO)properties of superalkaline M_(3)O(M=Li,Na)-doped cyclo[18]carbon were studied by using density functional theory.M_(3)O and the C_(18) rings are not *** C_(18) ring still exhibits alternating long and short *** charge transfer between M_(3)O and C_(18) forms stable[M_(3)O]+[C_(18)]-ionic complexes.C_(18)M_(3)O(M=Li,Na)shows striking optical nonlinearity,i.e.,their first-and second-order hyperpolarizability(βvec andγ||)increase considerably atλ=1907 nm and 1460 nm.

关键词： superalkaline doped cyclocarbon structure and electronic properties nonlinear optical properties density functional theory(DFT)

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