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Nanocavity enriched CuPd alloy with high selectivity for CO_(2. electroreduction toward C_(2.H_(4)

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Rare Metals 2024年第4期43卷 1513-1523页

作者： Ze-Yu Zhang Hai-Bin Wang Fei-Fei Zhang Jing-Wei Li Xin-Zhuo Hu Si-Wei Yan Yi-Ming Bai Xun Zhang Gu-Rong Shen Peng-Fei Yin Jing Yang Cun-Ku Dong Jing Mao Hui Liu Xi-Wen Du Institute of New-Energy materials School of Materials Science and EngineeringTianjin UniversityTianjin300350China

Electrocatalysis of CO_(2.reduction reaction is an effective way to convert CO_(2.into high value-added products,but the selectivity of Cu-based catalysts for C2.products needs to be improved due to the high energy barrier of C-C ***,a viable catalyst design strategy to decrease energy barrier of C-C coupling should be put ***,a nanocavity-enriched CuPd single atom alloy(CuPd SAA)catalyst is designed to promote CC coupling *** faradaic efficiency of CuPd SAA for ethylene and C_(2.)reaches 75.6%and 85.7%at-0.7 V versus reversible hydrogen electrode(RHE),*** on the results given by in situ characterization,the porous hollow structure dramatically increases the ratio of the linear-bond*CO,thus enhancing the faradaic efficiency for *** functional theory(DFT)calculation reveals that the Pd doping can regulate the electronic structure of neighboring Cu atoms to decrease the energy barrier of C-C coupling,further improving the faradaic *** work provides a new idea for designing catalyst with high selectivity for ethylene.

关键词： Adsorption configuration C-C coupling CO_(2. electrocatalysis Ethylene Single atom alloy

Mechanism research progress on transition metal compound electrode materials for supercapacitors

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Rare Metals 2024年第9期43卷 4076-4098页

作者： Zhi-Hui Xu Xue-Lei Li Qing-Wen Li Kai Lv Jing-Shun Liu Xiu-Kun Hang Aruuhan Bayaguud school of materials {2. and engineering Inner Mongolia University of Technology school of materials {2. and engineering Tianjin University of Technology College of Chemistry and Chemical engineering Inner Mongolia University

Supercapacitors(SCs) have remarkable energy storage capabilities and have garnered considerable interest due to their superior power densities and ultra-long cycling characteristics. However, their comparatively low energy density limits their extensive application in large-scale commercial applications. Electrode materials directly affect the performance of SCs. Thus, the development of cutting-edge electrode materials and modification of their morphological and structural properties are vital for advancing the performance of SCs. Transition metal compounds have a high specific capacity and good cycling durability, making them the most promising electrode active materials for high-energy density SCs. Nevertheless,their inadequate conductivity, unfavorable ion diffusion rates, substantial volume expansion and phase transitions during charging and discharging are obstacles to their stable and efficient integration into SCs. To address these challenges, this study provides a comprehensive summary of the current advancements in transition metal nanomaterials as electrode materials for SCs, an overview of the current research status, and the prevailing ***, this study highlights synthetic techniques and management strategies for electrode materials derived from transition metal compounds, targeting the resolution of the aforementioned challenges. Finally, a concise discussion is provided on the future directions of SC development, with an emphasis on the utilization of transition metal compound electrode materials.

关键词： Electrodes

Interface structure of α-Mg/14H-LPSO:First-principles prediction and experimental study

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Journal of Rare Earths 2024年第9期42卷 1792-1799,I0006页

作者： Yuan Shi Xiaohua Zhang Hongyan Yue Chao Li school of materials {2. and Chemical engineering Harbin University of Science and TechnologyHarbin150040China

The interfacial structure of the α-Mg/14H-LPSO phase in rare earth-including magnesium alloy was investigated via high-angle annular dark-field scanning transmission electron microscopy(HAADFSTEM) imaging and first-principles calculations of density-functional *** possible interfacial models were constructed according to the different terminations of the LPSO phase,and the corresponding interfacial energies were calculated,from which the four most stable structures(Terl-MgY-hollow,Ter2.Zn-hollow,Ter3-MgYII-hollow and Ter4-Mg-bridge) were *** interfacial phase diagrams related to the Y chemical potentials were obtained from the calculations,and the most stable interfacial structure was ***-MgY-hollow and Ter2.Zn-hollow have the lowest interfacial energies in the range of-0.7 eV 2. for the interface model of α-Mg and 14H-LPSO phase structure with Ter2.Zn-hollow termination.

关键词： Rare earths Magnesium alloy HAADF-STEM LPSO First-principles Interface

Grain refinement of 5A06 aluminum alloy welds caused by tungsten inert gas welding arc characteristics under Ar-He alternating gas supply conditions:a coupled method of water-cooled copper plate test/numerical simulation

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Journal of Iron and Steel Research International 2024年第3期31卷 767-777页

作者： Hong-bin Dai Jian Miao Jia-xin Lin school of materials {2. and engineering Harbin University of Science and TechnologyHarbin 150040HeilongjiangChina

The welding arc,as a carrier for the conversion of electrical energy to thermal energy,has a direct impact on the quality of welding by its properties and *** the tungsten inert gas(TIG)welding process under the condition of Ar-He alternating gas supply,the arc is alternately converted between Ar arc and He arc with an alternating gas supply cycle,which has obvious arc change *** FLUENT software was used to numerically simulate the characteristics of the TIG arc under the condition of alternating gas supply,and the arc temperature field,arc pressure,electric potential and current density distribution under the condition of alternating gas supply were *** with the real-time data of arc pressure measured by the water-cooled copper plate with holes,it is proved that the TIG arc has obvious dynamic characteristics under the condition of Ar-He alternating gas *** unique dynamic TIG arc acts on the 5A06 aluminum alloy weld,causing the molten pool to stir,resulting in uniform microstructure and grain refinement at the weld,and thereby improving the mechanical properties of the welded joint.

关键词： Alternating gas supply Grain refinement Numerical simulation Tungsten argon arc morphology Microstructure Mechanical property

MoS2.based anode materials for lithium-ion batteries:Developments and perspectives

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Particuology 2024年第4期87卷 240-270页

作者： Lianyu Zhao Yishan Wang Chuncheng Wei Xiaoxiao Huang Xueqian Zhang Guangwu Wena school of materials {2. and engineering Shandong University of TechnologyZibo255000China schoolof materials {2. and engineering Harbin Institute of TechnologyHarbin10001China

In recent years,significant progress has been achieved in the creation of innovative functional materials for energy storage and *** to their distinct physicochemical characteristics,ultrathin nanosheets composed of common layered transition metal sulfide materials(MoS2.have demonstrated promise as high-capacity anode materials for lithium-ion batteries(LIBs).Nevertheless,their practical application is severely limited by the tendency of monolayer nanosheets to restack due to strong van der Waals forces,dramatic volume changes during successive cycles,and low intrinsic *** research advances have shown that composite structures and nanowire morphologies with specific morphologies effectively overcome these *** paper reviews the recent research progress on molybdenum disulfide-based composites as anode materials for LIBs and discusses in detail the struc-tural characteristics of pure molybdenum disulfide and other composite forms of molybdenum *** addition,the phase engineering,defect engineering,and lithium storage mechanisms of molybdenum disulfide and the synthesis of molybdenum disulfide-based nanocomposites by different preparation methods are focused ***,we review the design(structure),recent developments,and challenges of novel anode materials and consider their electrochemical performance in Li-ion batteries.

关键词： Lithium-ion battery MoS_(2.-Based anode composites Synthesis methods Defect engineering Lithium storage mechanism

Precise construction of RuPt dual single-atomic sites to optimize oxygen electrocatalytic behaviors for high-performance Zn-air batteries

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Journal of Energy Chemistry 2024年第10期97卷 520-528页

作者： Xiaolin Hu Zhenkun Wu Chaohe Xu school of science Chongqing Key Laboratory of New Energy Storage Materials and Devices Chongqing University of Technology school of Chemistry and engineering Chongqing University College of materials science and {2. Chongqing University

The development of redox bifunctional electrocatalysts with high performance,low cost,and long lifetimes is essential for achieving clean energy *** study proposed an atom capture strategy for anchoring dual single atoms（DSAs） in a zinc-zeolitic imidazolate framework（Zn-ZIF）,followed by calcination under an N2.tmosphere to synthesize ruthenium-platinum DSAs supported on a nitrogendoped carbon substrate（RuPt DSAs-NC）.Theoretical calculations showed that the degree of Ru 5dxz-*O 2.xorbital hybridization was high when*O was adsorbed at the Ru site,indicating enhanced covalent hybridization of metal sites and oxygen ligands,which benefited the adsorption of intermediate *** presence of the RuPtN6active center optimized the absorption-desorption behavior of intermediates,improving the electrocatalytic performance of the oxygen reduction reaction（ORR） and the oxygen evolution reaction（DER）,RuPt DSAs-NC exhibited a 0.87 V high half-wave potential and a 2.8 mV low overpotential at 10 mA cm-2.n an alkaline ***,rechargeable zinc-air batteries（ZABs）achieved a peak power density of 171 MW *** RuPt DSAs-NC demonstrated long-term cycling for up to 500 h with superior round-trip *** study provided an effective structural design strategy to construct DSAs active sites for enhanced electrocata lytic performance.

关键词： Atom capture Dual single atoms catalysts Oxygen evolution reaction Oxygen reduction reaction Rechargeable Zn-air batteries

Microstructure and magnetocaloric properties of melt-extracted SmGdDyCoAl high-entropy amorphous microwires

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Rare Metals 2024年第3期43卷 1234-1242页

作者： Shi-Jie Wei Hong-Xian Shen Lun-Yong Zhang Lin Luo Xin-Xing Tang Jian-Fei Sun Xiao-Qing Li school of materials {2. and engineering Harbin Institute of TechnologyHarbin150001China Applied materials Physics Department of Materials Science and EngineeringKTH-Royal Institute of Technology10044StockholmSweden

This paper presents a systematic investigation of the microstructure and magnetocaloric properties of melt-extracted Sm_(2.)Gd_(2.)Dy_(2.)Co_(2.)Al_(2.)high-entropy *** fabricated wires exhibited an amorphous structure,and the temperature interval of the undercooled liquid AT was 45 *** microwires underwent a second-order magnetic transition from a ferromagnetic to a paramagnetic state near the Curie temperature(T_(C)=52.K),The maximum magnetic entropy change(-ΔS_M^(max)),the relative cooling power and the refrigeration capacity reached 6.34 J·kg^(-1)·K^(-1).42..09 J·kg^(-1)and 332.94 J·kg^(-1),respectively,under a magnetic field change of 5 *** addition,the temperature-averaged entropy changes with two temperature lifts(3 and 10 K)were 6.32.and 6.2. J·kg^(-1)·K^(-1),*** good magnetocalorie performance highlights the significant potential for the Sm_(2.)Gd_(2.)Dy_(2.)Co_(2.)Al_(2.)microwires to be used as magnetic refrigerant materials in low-temperature region *** work will serve as a valuable reference for future investigations on low-temperature high-entropy magnetocaloric materials.

关键词： Melt-extraction High-entropy amorphous microwires Magnetocaloric effect Magnetic refrigeration

Effect of VEGF/GREDVY Modified Surface on Vascular Cells Behavior

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Journal of Wuhan University of Technology(materials science) 2024年第1期39卷 244-254页

作者：魏来 TAN Jianying LI Li WANG Huanran LIU Sainan ZENG Zheng LIU Tao WANG Jian 陈俊英 WENG Yajun school of materials {2. and engineering Southwest Jiaotong UniversityChengdu 610031 China

We synthesized B-He/B-GREDVY and immobilized them on avidin-coated *** examine the immobilization of molecules in the material, the following experiments were performed:fluorescein isothiocyanate(FITC) fluorescence staining, water contact angle and atomic force microscopy(AFM) measurements. Besides, the biological evaluation experiments were also performed, such as platelets adhesion and activation, the culturing of smooth muscle cells(SMC) and endothelial cells(EC). These experimental results show that the modified surfaces could prevent the hyperproliferation of SMC, and promote the proliferation and migration of EC and EPC. Furthermore, the adding of VEGF improved the EC adhesion in a dynamic environment. Generally, it is expected that the modified surfaces could be used to accelerate the formation of the newly endothelial layer for the construction of platforms for coronary artery stent therapy.

关键词： biotin-GREDVY VEGF anticoagulation endothelial cells endothelial progenitor cells

Atomic interface regulation of rare-marth metal single atom catalysts for energy conversion

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Nano Research 2024年第5期17卷 3493-3515页

作者： Ziheng Zhan Zhiyi Sun Zihao Wei Yaqiong Li Wenxing Chen Shenghua Li Siping Pang school of materials {2. and engineering Beijing Institute of TechnologyBeijing 100081China

Efficient photocatalysis and electrocatalysis in energy conversion have been important strategies to alleviate energy crises and environmental *** recent years,with the rapid development of emerging catalysts,significant progress has been made in photocatalysis for converting solar energy into chemical energy and electrocatalysis for converting electrical energy into chemical ***,their selectivity and efficiency of the products are *** earth(RE)can achieve atomic level fine regulation of catalysts and play an crucial role in optimizing catalyst performance by their unique electronic and orbital ***,there is a lack of systematic review on the atomic interface regulation mechanism of RE and their role in energy conversion *** atom catalysts(SACs)provide clear active sites and 100%atomic utilization,which is conducive to exploring the regulatory mechanisms of ***,this review mainly takes atomic level doped RE as an example to review and discuss the atomic interface regulation role of RE elements in energy ***,a brief introduction was given to the synthesis strategies that can effectively exert the atomic interface regulation effect of RE,with a focus on the atomic interface regulation mechanism of ***,the regulatory mechanisms of RE atoms have been systematically summarized in various energy conversion ***,the challenges faced by RE in energy conversion,as well as future research directions and prospects,were pointed out.

关键词： rare earth elements interface regulation effect single-atom catalyst energy conversion