检索结果-南通市图书馆

Corrosion behavior of Fe–Cr–Ni based alloys exposed to molten MgCl_(2)–KCl–NaCl salt with over-added Mg corrosion inhibitor

引用

Frontiers of Chemical Science and Engineering 2023年第10期17卷 1608-1619页

作者： Rui Yu Qing Gong Hao Shi Yan Chai Alexander Bonk Alfons Weisenburger Dihua Wang Georg Müller Thomas Bauer Wenjin Ding Institute for Pulsed Power and Microwave Technology Karlsruhe Institute of Technology(KIT)76344 Eggenstein-LeopoldshafenGermany School of Resources and Environmental Science Wuhan University(WHU)Wuhan 430072China Institute of Engineering Thermodynamics German Aerospace Center(DLR)70569 StuttgartGermany Institute of Engineering Thermodynamics German Aerospace Center(DLR)70569 CologneGermany

MgCl_(2)–NaCl–KCl salts mixture shows great potential as a high-temperature(>700°C)thermal energy storage material in next-generation concentrated solar power *** Mg into molten MgCl_(2)–NaCl–KCl salt as a corrosion inhibitor is one of the most effective and cost-effective methods to mitigate the molten salt corrosion of commercial Fe–Cr–Ni ***,it is found in this work that both stainless steel 310 and Incoloy 800H samples were severely corroded after 500 h immersion test at 700°C when the alloy samples directly contacted with the over-added Mg in the liquid *** corrosion attack is different from the classical impurity-driven corrosion in molten chloride salts found in previous *** analysis indicates that Ni preferentially leaches out of alloy matrix due to the tendency to form MgNi_(2)/Mg_(2)Ni *** Ni-depletion leads to the formation of a porous corrosion layer on both alloys,with the thickness around 204μm(stainless steel 310)and 1300μm(Incoloy 800H),*** results suggest that direct contact of liquid Mg with Ni-containing alloys should be avoided during using Mg as a corrosion inhibitor for MgCl_(2)–NaCl–KCl or other chlorides for high temperature heat storage and transfer.

关键词： concentrated solar power(CSP) Mg corrosion inhibitor Mg-Ni intermetallic salt purification thermal energy storage(TES)

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated solar power plants： A review

引用

Frontiers of Chemical Science and Engineering 2018年第3期12卷 564-576页

作者： Wenjin Ding Alexander Bonk Thomas Bauer Institute of Engineering Thermodynamics German Aerospace Center (DLR) 70569 Stuttgart Germany Institute of Engineering Thermodynamics German Aerospace Center (DLR) 51147 Cologne Germany

Recently, more and more attention is paid on applications of molten chlorides in concentrated solar power （CSP） plants as high-temperature thermal energy storage （TES） and heat transfer fluid （HTF） materials due to their high thermal stability limits and low prices, compared to the commercial TES/HTF materials in CSP- nitrate salt mixtures. A higher TES/HTF operating temperature leads to higher efficiency of thermal to electrical energy conversion of the power block in CSP, however causes additional challenges, particularly increased corrosiveness of metallic alloys used as contain- ers and structural materials. Thus, it is essential to study corrosion behaviors and mechanisms of metallic alloys in molten chlorides at operating temperatures （500-800℃） for realizing the commercial application of molten chlorides in CSE The results of studies on hot corrosion of metallic alloys in molten chlorides are reviewed to understand their corrosion behaviors and mechanisms under various conditions （e.g., temperature, atmosphere）. Emphasis has also been given on salt purification to reduce corrosive impurities in molten chlorides and development of electrochemical techniques to in-situ monitor corrosive impurities in molten chlorides, in order to efficiently control corrosion rates of metallic alloys in molten chlorides to meet the requirements of industrial applications.

关键词： corrosion mechanisms impurities metallic corrosion salt purification electrochemical techniques

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：