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Chinese Journal of Polymer Science 2021年第2期39卷 228-236,I0008页

作者： Long Chen Xiao Wu Xiao-Fang Zhang Jian-Ming Zhang Key Laboratory of Rubber-Plastics Ministry of Education/Shandong Provincial Key Laboratory of Rubber-plasticsQingdao University of Science&TechnologyQingdao 266042China

Developing an effective method for improving the reproducibility of positive temperature coefficient(PTC)effect is of great significance for large-scale application of polymer based PTC composites,owing to its contribution to the security and ***,we developed a carbon black(CB)/high density polyethylene(HDPE)/poly(vinylidene fluoride)(PVDF)composite with outstanding PTC reproducibility,by incorporating 1-octyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide([OMIm][NTf2])into the *** multiple repeated temperature cycles,the PTC performance of as-prepared material keeps almost unchanged and the varition of resistance at room temperature is less than 7%.Our studies revealed that[OMIm][NTf2]contributes to the improvement of PTC reproducibility in two ways:(i)it acts as an efficient plasticizer for refining the co-continuous phase morphology of HDPE/PVDE blends;(ii)it inhibits the crystallization of PVDF through the dilution effect,leading to more overlaps of the volume shrinkage process of HDPE and PVDF melt which results in the decrease of interface gap between HDPE and *** study demonstrated that ionic liquids as the multifunctional agents have great potential for improving the reproducibility in the application of the binary polymer based PTC composites.

关键词： Conductive polymer composites Reproducibility positive temperature coefficient Ionic liquid

Studies on preparation and thermal control behavior of hybrid fillers/binary-polymer composites with positive temperature coefficient characteristic

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Science China(Technological Sciences) 2021年第7期64卷 1447-1458页

作者： YU AiMei LI Qiang MIIT Key Laboratory of Thermal Control of Electronic Equipment School of Energy and Power EngineeringNanjing University of Science and TechnologyNanjing210094China

Conductive polymer composites(CPCs) as the thermo-sensitive materials have attracted much attention in thermal control field due to their reliable self-regulating behaviors, high efficiency and mechanical flexibility. However, the development of these materials needs to manage the normal conflicting requirements, such as effective heating performance and good self-regulating capability. This paper presents a series of novel CPCs material having different amounts of hybrid fillers of multi-walled carbon nanotubes(CNTs) and carbon black(CB). The positive temperature coefficient intensity is enhanced to 105.2, and the roomtemperature resistivity is optimized to 320 ? cm. Besides, the Curie temperatures are regulated to room-temperature range by incorporating the low-melting-point blend matrix into the poly(ethylene-co-vinyl acetate)/CNTs/CB composite. The thermalcontrol experiment demonstrates that CPCs-heating elements can adjust the equilibrium temperature of controlled equipment near their Curie temperatures without any control methods. Compared with the ordinary resistor, the CPCs materials have the remarkable adaptive thermal control behavior. Furthermore, the temperature control capability is particularly prominent in the changing environment temperature. The CPCs as a safe and reliable adaptive heating element is potential to replace the conventional active thermal control means.

关键词： positive temperature coefficient room-temperature Curie point adaptive thermal control CPCs materials

Preparation of Self-limiting Heating Cables with Excellent Processability, Mechanical Properties and PTC Effect via Thermal and Electrical Treatments

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Chinese Journal of Polymer Science 2024年第4期42卷 511-520页

作者： Tian-Hao Yang Tong Wu Qiang Fu State Key Laboratory of Polymer Materials Engineering College of Polymer Science and EngineeringSichuan UniversityChengdu610065China State Key Laboratory of Polymer Materials Engineering Polymer Research Institute of Sichuan UniversityChengdu610065China

Polymer/conductive filler composites have been widely used for the preparation of self-limiting heating cables with the positive temperature coefficient (PTC) effect. The control of conductive filler distribution and network in polymer matrix is the most critical for performance of PTC materials. In order to compensate for the destruction of the filler network structure caused by strong shearing during processing, an excessive conductive filler content is usually added into the polymer matrix, which in turn sacrifices its processability and mechanical properties. In this work, a facile post-treatment of the as-extruded cable, including thermal and electrical treatment to produce high-density polyethylene (HDPE)/carbon black (CB) cable with excellent PTC effect, is developed. It is found for the as-extruded sample, the strong shearing makes the CB particles disperse uniformly in HDPE matrix, and 25 wt% CB is needed for the formation of conductive paths. For the thermal-treated sample, a gradually aggregated CB filler structure is observed, which leads to the improvement of PTC effect and the notable reduction of CB content to 20 wt%. It is very interesting to see that for the sample with combined thermal and electrical treatment, CB particles are agglomerated and oriented along the electric field direction to create substantial conductive paths, which leads to a further decrease of CB content down to 15 wt%. In this way, self-limiting heating cables with excellent processability, mechanical properties and PTC effect have simultaneously been achieved.

关键词： Self-limiting heating cables positive temperature coefficient Thermal treatment Electrical treatment

Structure and electrical properties of (1-x)BaTiO_3+(x)La_(2/3)-Sr_(1/3)MnO_3 composites

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Acta Metallurgica Sinica(English Letters) 2011年第4期24卷 315-320页

作者： Zhengyou ZHOU Yu LEI School of Materials Science and Engineering Nanchang University Nanchang 330031 China College of Vocational Education East China Jiaotong University Nanchang 330031 China

Liquid-phase sintering method was used to prepare BaTiO3 powders and the struc- ture and electrical properties of （1-x）BaTiO3-]-（x）La2/3Srl/3Mn03 （LSMO） compos- ites were investigated. The results of X-ray diffraction showed that the prepared BaTiO3 powders were pure and fine, indicating that sintering temperature was effec- tively lowered when the NaC1 sintering aid was added. X-ray diffraction patterns of （1-x）BaTiO3＋（x）La2/3Srl/3Mn03 （LSMO） composites showed that LSMO and BaTiO3 phases were coexistent and no other phases were detected. The impedance spectra showed that the resistance of grain boundaries for LSMO-doped samples was suppressed. The resistivity-temperature measurements showed that room- temperature resistivity of the composites was lowered from insulator for pure BaTiO3 ceramic to 103 ~.m for the x----0.3 sample. The sample of x_〈0.2 showed the positive temperature coefficient （PTC） effect whereas the x=0.3 sample exhibited PTC effect at temperatures below 68 ~C and then negative temperature coefficient （NTC） effect at temperatures above 68 ~C. The related mechanism has been elucidated.

关键词： positive temperature coefficient Composite Impedance spectra Resistivity

A dual-gate and dielectric-inserted lateral trench insulated gate bipolar transistor on a silicon-on-insulator substrate

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Chinese Physics B 2013年第7期22卷 473-477页

作者：付强张波罗小蓉李肇基 State Key Laboratory of Electronic Thin Films and Integrated Devices University of Electronic Science and Technology of China

In this paper, a novel dual-gate and dielectric-inserted lateral trench insulated gate bipolar transistor （DGDI LTIGBT） structure, which features a double extended trench gate and a dielectric inserted in the drift region, is proposed and discussed. The device can not only decrease the specific on-resistance Ron,sp , but also simultaneously improve the temperature performance. Simulation results show that the proposed LTIGBT achieves an ultra-low on-state voltage drop of 1.31 V at 700 A·cm-2 with a small half-cell pitch of 10.5 μm, a specific on-resistance R on,sp of 187 mΩ·mm2, and a high breakdown voltage of 250 V. The on-state voltage drop of the DGDI LTIGBT is 18% less than that of the DI LTIGBT and 30.3% less than that of the conventional LTIGBT. The proposed LTIGBT exhibits a good positive temperature coefficient for safety paralleling to handling larger currents and enhances the short-circuit capability while maintaining a low self-heating effect. Furthermore, it also shows a better tradeoff between the specific on-resistance and the turnoff loss, although it has a longer turnoff delay time.

关键词： lateral trench insulated gate bipolar transistor specific on-resistance positive temperature coefficient turnoff characteristic

Conductive Behaviors of Carbon Nanofibers Reinforced Epoxy Composites

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Journal of Wuhan University of Technology(Materials Science) 2008年第1期23卷 139-142页

作者：梅启林 School of Materials Science and Engineering Wuhan University of Technology

By means of ultrasonic dispersion, carbon nanofibers reinforced epoxy resin composite was prepared in the lab, the electrical conductivity of composite with different carbon nanofibers loadings were studied, also the voltage-current relationship, resistance-temperature properties and mechano-electric effect were investigated. Results show that the resistivity of composite decreases in geometric progression with the increasing of carbon nanofibers, and the threshold ranges between 0.1 wt%-0.2 wt%. The voltage-current relationship is in good conformity with the Ohm＇s law, both positive temperature coefficient and negative temperature coefficient can be found at elevated temperature. In the course of stretching, the electrical resistance of the composites increases with the stress steadily and changes sharply near the breaking point, which is of importance for the safety monitor and structure health diagnosis.

关键词： carbon nanofibers positive temperature coefficient negative temperature coefficient, mechano-electric effect