Studies on preparation and thermal control behavior of hybrid fillers/binary-polymer composites with positive temperature coefficient characteristic

作     者：YU AiMei LI Qiang YU AiMei;LI Qiang

作者机构：MIIT Key Laboratory of Thermal Control of Electronic EquipmentSchool of Energy and Power EngineeringNanjing University of Science and TechnologyNanjing210094China 

出 版 物：《Science China(Technological Sciences)》 (中国科学（技术科学英文版）)

年 卷 期：2021年第64卷第7期

页      面：1447-1458页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：supported by the National Natural Science Foundation of China (Grant No. 51225602) 

主　　题：positive temperature coefficient room-temperature Curie point adaptive thermal control CPCs materials 

摘      要：Conductive polymer composites(CPCs) as the thermo-sensitive materials have attracted much attention in thermal control field due to their reliable self-regulating behaviors, high efficiency and mechanical flexibility. However, the development of these materials needs to manage the normal conflicting requirements, such as effective heating performance and good self-regulating capability. This paper presents a series of novel CPCs material having different amounts of hybrid fillers of multi-walled carbon nanotubes(CNTs) and carbon black(CB). The positive temperature coefficient intensity is enhanced to 105.2, and the roomtemperature resistivity is optimized to 320 ? cm. Besides, the Curie temperatures are regulated to room-temperature range by incorporating the low-melting-point blend matrix into the poly(ethylene-co-vinyl acetate)/CNTs/CB composite. The thermalcontrol experiment demonstrates that CPCs-heating elements can adjust the equilibrium temperature of controlled equipment near their Curie temperatures without any control methods. Compared with the ordinary resistor, the CPCs materials have the remarkable adaptive thermal control behavior. Furthermore, the temperature control capability is particularly prominent in the changing environment temperature. The CPCs as a safe and reliable adaptive heating element is potential to replace the conventional active thermal control means.