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High-performance aqueous asymmetric supercapacitors based on the cathode of one-step electrodeposited cracked bark-shaped nickel manganese sulfides on activated carbon cloth

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Science China(Technological Sciences) 2022年第2期65卷 293-301页

作者： ADIL Emin XIE WenLu long Xiao WANG Xiao SONG XiaoQiang CHEN Yue FU YuJun LI JunShuai LI YaLi HE DeYan Key Laboratory of Special Function Materials&Structure Design of the Ministry of Education and School of Materials&EnergyLanzhou UniversityLanzhou 730000China

In this work,we report a high-performance self-standing supercapacitor electrode of mixed nickel manganese sulfides (NMSs)with a cracked-bark shape grown by one-step electrochemical deposition on activated carbon cloth (ACC).The electrode possesses outstanding electrochemical properties,including a high specific capacitance of up to 3142.8 F g^(-1)at 1.0 A g^(-1),the high-rate performance (~1206.8 F g^(-1)at 60.0 A g^(-1)),and cycle stability (~92.3%capacitance retention after 8000 cycles at8 A g^(-1)).An asymmetric supercapacitor assembled using NMSs on ACC as the cathode,activated carbon on carbon cloth as the anode and 1.0 mol L;KOH as the electrolyte delivers a high energy density of 111.2 W h kg^(-1)at 800.0 W kg^(-1)and the prominent cycling performance of~93.2%capacitance retention after 10000 cycles at 5 A g^(-1)with the Columbic efficiency of around 100%during these 10000 *** high performance and facile preparation indicate that the NMSs on ACC hold a huge potential as the electrode for supercapacitors.

关键词： aqueous asymmetric supercapacitors nickel manganese sulphides high specific capacitance high energy density long cycle stability

Micro-structured lepidocrocite-type H_(1.07)Ti_(1.73)O_(4)as anode for lithium-ion batteries with an ultrahigh rate and long-term cycling performance

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Rare Metals 2021年第6期40卷 1391-1401页

作者： Li-Juan Hou Rui-Chao Liu Hui-Yu Yuan De-Zhi Kong Wei-Xia Shen Jin-Hao Zang Juan Guo Shu-Ge Dai Ming-Lang Wang Ting-Ting Xu Xin-Jian Li Ye Wang Key Laboratory of Material Physics of Ministry of Education School of Physics and MicroelectronicsZhengzhou UniversityZhengzhou 450052China School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450052China Key Laboratory of Henan Province for High Temperature Functional Materials Zhengzhou 450000China Shandong Key Laboratory of Medical Physics and Image Processing&Shandong Provincial Engineering and Technical Center of Light Manipulations School of Physics and ElectronicsShandong Normal UniversityJinan 250358China

The lepidocrocite-type H_(1.07)Ti_(1.73)O_(4) microsized structures with a tap density of 0.88 g·cm^(-3) were prepared through the ion exchange method with K_(0.8)Li_(0.27)Ti_(1.73)O_(4) powder as the precursor,and they exhibited good rate performance and outstanding cycle stability as an anode material for lithium ion batteries(LIB).The ion exchange method provides favorable conditions for H_(1.07)Ti_(1.73)O_(4) as an anode electrode material for LIBs.X-ray photoelectron spectroscopy(XPS)result demonstrates the existence of defects in the nonstoichiometric H1.07Ti1.73O4,which have a beneficial effect on the LIB *** electrochemical performance test proves that the half-cell with microsized H_(1.07)Ti_(1.73)O_(4)as the anode electrode can maintain a specific capacity of 129.5 mAh·g^(-1) after 1100 cycles and 101 mAh·g^(-1)after 3000 long cycles at high current densities of 2.0 and 5.0 A·g^(-1),*** addition,the small volume change rate of 3.6%in H_(1.07)Ti_(1.73)O_(4)during Li ion insertion was confirmed by real-time in situ transmission electron microscopy(TEM).The LiFePO_(4)||H_(1.07)Ti_(1.73)O_(4)full battery exhibits a longterm cycling stability with a specific capacity of73.8 mAh·g^(-1) at a current density of 500 mA·g^(-1) after 200 cycles.

关键词： Lepidocrocite-type H_(1.07)Ti_(1.73)O_(4) Anode material of lithium ion batteries long cycle stability

A three-dimensional co-continuous network structure polymer electrolyte with efficient ion transport channels enabling ultralong-life all solid-state lithium metal batteries

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Journal of Energy Chemistry 2024年第7期94卷 635-645页

作者： Meng Wang Hu Zhang Yewen Li Ruiping Liu Huai Yang School of Chemical&Environmental Engineering China University of Mining and Technology(Beijing)Beijing 100083China Beijing Advanced Innovation Center for Materials Genome Engineering&School of Materials Science and Engineering Peking UniversityBeijing 100871China

Solid polymer electrolytes(SPEs)have emerged as one of the most promising candidates for the construction of solid-state lithium batteries due to their excellent flexibility,scalability,and interface compatibility with ***,a novel all-solid polymer electrolyte(PPLCE)was fabricated by the copolymer network of liquid crystalline monomers and poly(ethylene glycol)dimethacrylate(PEGDMA)acts as a structural frame,combined with poly(ethylene glycol)diglycidyl ether short chain interspersed serving as mobile ion transport *** preparaed PPLCEs exhibit excellent mechanical property and out-standing electrochemical performances,which is attributed to their unique three-dimensional cocontinuous structure,characterized by a cross-linked semi-interpenetrating network and an ionic liquid phase,resulting in a distinctive nanostructure with short-range order and long-range ***,the addition of PEGDMA is proved to be critical to the comprehensive performance of the PPLCEs,which effectively modulates the microscopic morphology of polymer networks and improves the mechanical properties as well as cycling stability of the solid *** used in a lithiumion symmetrical battery configuration,the 6 wt%-PPLCE exhibites super stability,sustaining operation for over 2000 h at 30 C,with minimal and consistent overpotential of 50 *** resulting Li|PPLCE|LFP solid-state battery demonstrates high discharge specific capacities of 160.9 and 120.1 mA h g^(-1)at current densities of 0.2 and 1 C,*** after more than 300 cycles at a current density of 0.2 C,it retaines an impressive 73.5%***,it displayes stable cycling for over 180 cycles at a high current density of *** super cycle stability may promote the application for ultralong-life all solid-state lithium metal batteries.

关键词： Solid-state electrolyte Lithium-metal batteries Liquid crystalline polymer Copolymer 3D co-continuous structure long cycle stability