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International Journal of Minerals,Metallurgy and Materials 2024年第6期31卷 1456-1461页

作者： Anran Zhang Xinquan Zhou Ranran Gu Zhiguo Xia State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied TechniquesSchool of Materials Science and EngineeringSouth China University of TechnologyGuangzhou 510641China School of Physics and Optoelectronics South China University of TechnologyGuangzhou 510641China

Mn^(2+)doping has been adopted as an efficient approach to regulating the luminescence properties of halide perovskite nano-crystals(NCs).However,it is still difficult to understand the interplay of Mn^(2+)luminescence and the matrix self-trapped exciton(STE)emission therein.In this study,Mn^(2+)-doped CsCdCl_(3) NCs are prepared by hot injection,in which CsCdCl_(3) is selected because of its unique crystal structure suitable for STE emission.The blue emission at 441 nm of undoped CsCdCl_(3) NCs originates from the defect states in the NCs.Mn^(2+)doping promotes lattice distortion of CsCdCl_(3) and generates bright orange-red light emission at 656 nm.The en-ergy transfer from the STEs of CsCdCl_(3) to the excited levels of the Mn^(2+)ion is confirmed to be a significant factor in achieving efficient luminescence in CsCdCl_(3):Mn^(2+)NCs.This work highlights the crucial role of energy transfer from STEs to Mn^(2+)dopants in Mn^(2+)-doped halide NCs and lays the groundwork for modifying the luminescence of other metal halide perovskite NCs.

关键词： perovskite nanocrystals self-trapped excitons luminescence energy transfer

Interparticle energy transfer between NaNdF_(4) and NaYbF_(4) in self-assembled nanostructures

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Journal of Rare Earths 2024年第6期42卷 1029-1035,I0001页

作者： Xinyu Chen Haoze Yang Yuyang Gu Chenqing Wen Yishuo Sun Jiaming Ke Wei Feng Department of Chemistry and State Key Laboratory of Molecular Engineering of Polymers Fudan University Shanghai200433China

Forster resonance energy transfer(FRET)is a widely used spectroscopic technique.The development of donor-acceptor combinations is essential to advance this technique.To make the energy transfer efficiency independent of the external environment,we explored the potential of constructing donor—acceptor combinations with lanthanide ion-doped nanoparticles(LNPs),in which the 4f electrons of the lanthanide ions are shielded by the 5s and 6p electrons.Non-radiative energy transfer between LNPs was demonstrated in self-assembled nanostructures and core-shell structure of LNPs was used to control the distance between donor and acceptor in self-assembled nanostructures.The emission intensity ratio of donor and acceptor illustrates that the energy transfer efficiency decreases significantly with increasing distance and the effective energy transfer distance is 8.5 nm,showing the potential of using LNPs as donor-acceptor pairs in the construction of distance-dependent energy transfer system.

关键词： Lanthanide nanoparticles Self-assembly energy transfer Distance Epitaxialgrowth Rare earths

Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis

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Chinese Chemical Letters 2024年第4期35卷 409-413页

作者： Chaoqun Ma Yuebo Wang Ning Han Rongzhen Zhang Hui Liu Xiaofeng Sun Lingbao Xing School of Chemistry and Chemical Engineering Shandong University of TechnologyZibo 255000China Department of Materials Engineering KU LeuvenLeuven 3001Belgium

In this work, we designed and synthesized cationic carbon dots(CDs) with a size distribution of 1.6–3.7 nm, which exhibited dark blue fluorescence in the aqueous solution. Based on its excellent luminescence properties, we used it as an energy donor to construct a sequential artificial light-harvesting system(LHS) by employing the energy-matching dyes eosin Y disodium salt(EY) and sulforhodamine101(SR101), which could regulate the white light emission(Commission Internationale de l'Eclairage(CIE) coordinate:(0.30, 0.31)) with the energy transfer efficiency(ΦET) of 53.9% and 20.0%. Moreover, a single-step artificial LHS with white light emission(0.32, 0.28) can be constructed directly using CDs and dye solvent 43(SR) with ΦETand antenna effect(AE) of 48.8% and 6.5, respectively. More importantly,CDs-based artificial LHSs were firstly used in photocatalytic of α-bromoacetophenone, with a yield of90%. This work not only provides a new strategy for constructing CDs-based LHSs, but also opens up a new application for further applying the energy harvested in CDs-based LHSs to the field of the aqueous solution photocatalysis.

关键词： Carbon dots White light emission energy transfer Antenna effect Artificial light-harvesting system Photocatalysis

energy transfer Dynamics between Carbon Quantum Dots and Molybdenum Disulfide Revealed by Transient Absorption Spectroscopy

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化学物理学报(英文) 2023年第5期36卷 503-508,I0001页

作者： Ruixiang Wu Xin Liu Xiaoshuai Wang Jingjing Luo Bin Li Shengzhi Wang Xiangyang Miao Key Laboratory of Spectral Measurement and Analysis of Shanxi Province College of Physics and Information EngineeringShanxi Normal UniversityTaiyuan 030031China

Zero-dimensional environmentally friendly carbon quantum dots(CQDs)combined with two-di-mensional materials have a wide range of applications in optoelec-tronic devices.We combined steady-state and transient absorp-tion spectroscopies to study the energy transfer dynamics between CQDs and molybdenum disulfide(MoS_(2)).Transient absorption plots showed photoinduced absorption and stimulated emission features,which involved the intrinsic and defect states of CQDs.Adding MoS_(2)to CQDs solution,the lowest unoccupied molecular orbital of CQDs transferred energy to MoS_(2),which quenched the intrinsic emission at 390 nm.With addition of MoS_(2),CQD-MoS_(2)composites quenched defect emission at 490 nm and upward absorption,which originated from another energy transfer from the defect state.Two energy transfer paths between CQDs and MoS_(2)were efficiently manipulated by changing the concentration of MoS_(2),which laid a foundation for improving device performance.

关键词： energy transfer Transient absorption spectroscopy Carbon quantum dot Molybdenum disulfide

Efficient energy transfer in organic light-emitting transistor with tunable wavelength

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Nano Research 2022年第4期15卷 3647-3652页

作者： Ke Zhou Jian Tang Shaofan Fang Ke Jiang Fangxu Yang Deyang Ji Jing Xiang Jie Liu Huanli Dong(✉) Cheng Han Hanlin Hu Xiaotao Zhang Wenping Hu Yumeng Shi International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education Institute of Microscale OptoelectronicsShenzhen UniversityShenzhen 518060China Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of ChemistrySchool of SciencesTianjin UniversityTianjin 300072China Hoffman Institute of Advanced Materials Shenzhen PolytechnicShenzhen 518060China Beijing National Laboratory for Molecular Sciences Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China Joint School of National University of Singapore and Tianjin University International Campus of Tianjin UniversityBinhai New CityFuzhou 350207China

Key challenges in the development of organic light-emitting transistors(OLETs)are blocking both scientific research and practical applications of these devices,e.g.,the absence of high-mobility emissive organic semiconductor materials,low device efficiency,and color tunability.Here,we report a novel device configuration called the energy transfer organic light-emitting transistor(ET-OLET)that is intended to overcome these challenges.An organic fluorescent dye-doped polymethyl methacrylate(PMMA)layer is inserted below the conventional high-mobility organic semiconductor layer in a single-component OLET to separate the functions of the charge transport and light-emitting layers,thus making the challenge to essentially integrate the high mobility and emissive functions within a single organic semiconductor in a conventional OLET or multilayer OLET unnecessary.In this architecture,there is little change in mobility,but the external quantum efficiency(EQE)of the ET-OLET is more than six times that of the conventional OLET because of the efficient Förster resonance energy transfer,which avoids exciton-charge annihilation.In addition,the emission color can be tuned from blue to white to green-yellow using the sourcedrain and gate voltages.The proposed structure is promising for use with electrically pumped organic lasers.

关键词： color tunability energy transfer organic light-emitting transistor(OLET) Förster resonance energy transfer(FRET)

A single-phase full-color phosphor Sr_(2)Ca_(2)La(PO_(4))_(3)O:Eu^(2+),Tb^(3+),Mn^(2+):Photoluminescence and energy transfer

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Journal of Rare Earths 2022年第4期40卷 541-550,I0002页

作者： Ju Cheng Xintian Bian Zhangyin Zhai Maryam Sardar Jian Lu School of Physics and Electronic Electrical Engineering Huaiyin Normal UniversityHuai'an 223001China School of Science Nanjing University of Science and TechnologyNanjing 210094China

A single-phase full-color emitting phosphor Sr_(2)Ca_(2)La(PO_(4))_(3)O:Eu^(2+),Tb^(3+),Mn^(2+) was synthesized by the high temperature solid-state method.The phase formation,luminescence properties,thermal stability,and energy transfer from Eu^(2+)to Tb^(3+) and Eu^(2+)to Mn^(2+) in Sr_(2)Ca_(2)La(PO_(4))_(3)O were investigated in details.Tunable emission color from blue to blueish green or orange can be observed under 365 nm near-ultraviolet excitation based on the energy transfer from Eu^(2+) to Tb^(3+)or Mn^(2+) ions by varying the ratio of Eu^(2+)/Tb^(3+)or Eu^(2+)/Mn^(2+) ions.White light was obtained with chromaticity coordinates of(0.3558,0.3500)in the Sr_(2)Ca_(2)La(PO_(4))_(3)O:0.04Eu^(2+),0.08Tb^(3+),0.40Mn^(2+) phosphor,suggesting their potential applications in white light emitting diodes.

关键词： Phosphors energy transfer Photoluminescence properties White light-emitting diodes Rare earths

Site occupation and energy transfer in full color emitting phosphor Ba2Ca(BO3)2:Ce3+(K+),Eu^(2+),Mn2+

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Journal of Rare Earths 2022年第11期40卷 1691-1698,I0002页

作者： Qingsong Hu Zaifa Pan Guijie Liang Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and ScienceXiangyang 441053China College of Chemical Engineering Zhejiang University of TechnologyHangzhou 310014China

White light-emitting diodes(WLEDs)fabricated by single-phase full color emitting phosphor are an emerging solution for health lighting.The crystallographic site occupation of activators in a proper host lattice is crucial for sophisticated design of such phosphor.Here,we report a high quality white lightemitting phosphor Ba_(2)Ca(BO_(3))_(2):Ce^(3+)(K^(+)),Eu^(2+),Mn^(2+)with spectral distribution covering whole visible region.Blue light emission originates from Ce3+ions occupying preferentially Ba^(2+)site by controlling synthesis conditions.Green and red lights are obtained from Eu^(2+)occupying Ba2+(and Ca)site and Mn2+occupying Casite,respectively.In this triple-doped phosphor,strong red emission with a low concentration of Mn2+is realized by the efficient energy transfer from Ce3+and Euto Mn.Furthermore,high quality white light is accomplished by properly tuning the relative doping amount of Ce^(3+)(K^(+))/Eu^(2+)/Mn^(2+)based on efficient simultaneous energy transfer.The results indicate that Ba_(2)Ca(BO_(3))_(2):Ce^(3+)(K^(+)),Eu^(2+),Mn^(2+)is a promising white light-emitting phosphor in WLEDs application.

关键词： Single-phase Full color phosphor Site preference occupation energy transfer Ba2Ca(BO3)2:Ce3+(K+) Eu^(2+) Mn2+ Rare earths

Improving acceptor efficacy rather than energy transfer efficiency:Dominant contribution of monomers of acceptors modified on upconversion nanoparticles

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Journal of Rare Earths 2022年第5期40卷 702-708,I0001页

作者： Jie Ren Yadan Ding Hancheng Zhu Zhipeng Li Xia Hong Huiying Zhao Hong Zhang Key Laboratory of UV-Emitting Materials and Technology(Northeast Normal University) Ministry of EducationChangchun 130024China Department of Basic Medicine Gerontology Department of First Bethune HospitalUniversity of JilinChangchun 130021China Van’t Hoff Institute for Molecular Sciences University of AmsterdamScience Park 9041098XHAmsterdamthe Netherlands

Upconversion nanosensitizers have been widely considered to have important applications in the treatment of major diseases such as tumors and the utilization of solar energy.Majority of the efforts so far have been focused on improving the efficiency of energy transfer(ET)between upconversion nanoparticles(UCNPs)and the anchored sensitizers with premise that high ET efficiency will lead to high acceptor efficacy.This premise is,however,proved by our current work to be invalid for commonly used load.Interaction between adjacent sensitizing molecules was found to be critical which undermines the amount of excited monomer sensitizers and thus fades the efficacy.Here NaYF_(4):Yb^(3+),Er^(3+)UCNPs and rose bengal(RB)photosensitizer molecules were used as the model energy donors and acceptors,respectively.Contrary to monotonous increase of the ET efficiency from UCNPs to RB species with increasing RB loading,acceptor efficacy characterized by the reactive oxygen species,as well as the RB fluorescence,exhibits bizarre dependence on the RB loading.The underlying mechanism was well studied by the steady-state and time-resolved spectroscopy of a series of samples.RB aggregates are believed to be responsible for the severe deviation between the ET efficiency and acceptor efficacy.The conclusion was validated by in vitro test where the photodynamic therapy with the most monomer RB in UCNPs-RB nanosensitizers kills 35.8%more cells than that with the highest RB loading.This understanding sheds light on construction of new ET based nanosystems for broad applications,such as medicine,solar energy utilization and optical storage.

关键词： Upconversion nanoparticle energy transfer Monomer Aggregate Reactive oxygen species Rare earths

Tunable Emission and energy transfer of the Novel KY_(1-x)(MoO_(4))_(2-y)(WO_(4))y:xLn^(3+)(Ln^(3+)=Dy^(3+),Eu^(3+),and Tm^(3+))Single-phase White Luminescence Phosphor for White LEDs

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Journal of Wuhan University of Technology(Materials Science) 2023年第6期38卷 1278-1286页

作者： ZHU Hai HE Bin HUANG Weigang Department of Oncology The Third People's Hospital of ChengduAfiliated Hospital of Southwest Jiaotong University&The Second Affiliated Hospital of ChengduChongqing Medical UniversityChengdu 610031China Medical Research Center The Third People's Hospital of ChengduAfiliated Hospital of Southwest Jiaotong University&The Second Afiliated Hospital of ChengduChongqing Medical UniversityChengdu 610031China National Engineering Research Center for Biomaterials College of Biomedical MaterialsSichuan UniversityChengdu 610064China College of Materials Science and Engineering Sichuan UniversityChengd 610064China

The phosphors of KY_(1-x)(MoO_(4))_(2-y)(WO_(4))y:xLn^(3+)(Ln^(3+)=Tm^(3+),Dy^(3+),Eu^(3+))were synthesized by using a sol-gel method.Then,the crystal structure,luminescence properties,energy transfer,and white emission of the prepared materials were researched.The molar ratio of the anion group on the photoluminescence(PL)emission and excitation intensity were investigated,revealing that the optimum intensity could be obtained by using=3:1.The optimal Dy^(3+) doping concentration of KY(MoO_(4))1.5(WO4)0.5was obtained.In addition,the color-tunable emissions of Dy^(3+)/Eu^(3+)-codoped KY(MoO_(4))1.5(WO4)0.5phosphors were observed because of the effective energy transfer(ET)from Dy^(3+)to Eu^(3+)ions.Finally,by doping appropriate concentrations of Tm^(3+),Dy^(3+),and Eu^(3+)and different concentrations of(WO_(4))^(2-),white light emitting phosphors KY_(0.92)(WO_(4))2:0.01Tm^(3+),0.06Dy^(3+),0.01Eu^(3+)with excellent color-rending properties were obtained.The chromaticity coordinate was calculated as(x=0.3238,y=0.3173),closing to the artificial daylight(D65,x=0.313,y=0.329)illuminant,and which indicates the potential application of near ultraviolet White light-emitting diodes(WLEDs).

关键词： rare earth phosphors white LEDs energy transfer sol-gel method

A stimuli responsive lanthanide-based hydrogel possessing tunable luminescence by efficient energy transfer pathways

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Journal of Rare Earths 2022年第5期40卷 696-701,I0001页

作者： Yuan Wang Jinglei Chen Yuan Shang Peng Li Huanrong Li Tianjin Key Laboratory of Chemical Process Safety School of Chemical Engineering and TechnologyNational-Local Joint Engineering Laboratory for Energy Conservation in Chemical Process Integration and Resources UtilizationHebei University of TechnologyTianjin 300130China

energy transfer as an important component in light-harvesting antenna systems can mimic effectively natural photosynthesis processes,showing great potential in optoelectronic devices.Herein,we report a responsive polymeric hydrogel based on the combination of excited state intramolecular proton transfer(ESIPT) molecule(Salicylic acid,Sal) and terbium(Ⅲ)(Tb^(3+)),as enabled by external stimuli to construct artificial light-harvesting antenna systems.Benefiting from unique photophysical properties of Sal,the synthesized hydrogel displays a temperature-dependent reversible opaque?transparent states transition,accompanied with an interesting photoluminescence behavior.Moreover,by further incorporating europium(Ⅲ)(Eu^(3+)) into the hydrogel,we demonstrate well-defined cascades of energy transfer that provides a tunable optical output from the collection of lanthanides by the excitation of a common sensitizer(Sal) upon base vapor stimulation.Efficient energy transfer efficiency from Tb^(3+) to Eu^(3+),as high as 97.8%,was also obtained as established by the time-resolved fluorescence spectroscopy analysis.

关键词： energy transfer Lanthanides Stimuli-responsive hydrogel Luminescence Rare earths