Tunable Emission and Energy Transfer of the Novel KY_(1-x)(MoO_(4))_(2-y)(WO_(4))y:xLn^(3+)(Ln^(3+)=Dy^(3+),Eu^(3+),and Tm^(3+))Single-phase White Luminescence Phosphor for White LEDs

作     者：ZHU Hai HE Bin HUANG Weigang 

作者机构：Department of OncologyThe Third People's Hospital of ChengduAfiliated Hospital of Southwest Jiaotong University&The Second Affiliated Hospital of ChengduChongqing Medical UniversityChengdu 610031China Medical Research CenterThe Third People's Hospital of ChengduAfiliated Hospital of Southwest Jiaotong University&The Second Afiliated Hospital of ChengduChongqing Medical UniversityChengdu 610031China National Engineering Research Center for BiomaterialsCollege of Biomedical MaterialsSichuan UniversityChengdu 610064China College of Materials Science and EngineeringSichuan UniversityChengd 610064China 

出 版 物：《Journal of Wuhan University of Technology(Materials Science)》 (武汉理工大学学报（材料科学英文版）)

年 卷 期：2023年第38卷第6期

页      面：1278-1286页

核心收录：

学科分类：08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

主　　题：rare earth phosphors white LEDs energy transfer sol-gel method 

摘      要：The phosphors of KY_(1-x)(MoO_(4))_(2-y)(WO_(4))y:xLn^(3+)(Ln^(3+)=Tm^(3+),Dy^(3+),Eu^(3+))were synthesized by using a sol-gel ***,the crystal structure,luminescence properties,energy transfer,and white emission of the prepared materials were *** molar ratio of the anion group on the photoluminescence(PL)emission and excitation intensity were investigated,revealing that the optimum intensity could be obtained by using=3:*** optimal Dy^(3+) doping concentration of KY(MoO_(4))1.5(WO4)0.5was *** addition,the color-tunable emissions of Dy^(3+)/Eu^(3+)-codoped KY(MoO_(4))1.5(WO4)0.5phosphors were observed because of the effective energy transfer(ET)from Dy^(3+)to Eu^(3+)***,by doping appropriate concentrations of Tm^(3+),Dy^(3+),and Eu^(3+)and different concentrations of(WO_(4))^(2-),white light emitting phosphors KY_(0.92)(WO_(4))2:0.01Tm^(3+),0.06Dy^(3+),0.01Eu^(3+)with excellent color-rending properties were *** chromaticity coordinate was calculated as(x=0.3238,y=0.3173),closing to the artificial daylight(D65,x=0.313,y=0.329)illuminant,and which indicates the potential application of near ultraviolet White light-emitting diodes(WLEDs).