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In situ and on-line monitoring of cadmium in soil pore water using an automatic sampling integrated electrochemical sensor

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Science China(Technological Sciences) 2024年第9期67卷 2894-2904页

作者： KUANG JiaJie WEN JunLin CAI XiXi ZHOU LiHua YUAN Yong Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control School of Environmental Science and EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China School of Biomedical and Pharmaceutical Sciences Guangdong University of TechnologyGuangzhou 510006China

Cadmium(Cd) contamination in soil pore water is the primary pathway for Cd uptake by food crops,such as rice(Oryza sativa L.),posing significant risks to both food safety and human *** study presents a novel soil pore water metal sensor(SPW-Msensor) for in situ and online monitoring of Cd in soil pore water(Cd_(pw)).The SPW-Msensor integrates an automated sampling device,comprising a Rhizon sampler and a reciprocating series pump with an independent dual plunger drive,along with a portable electrochemical sensor consisting of a screen-printed electrode,flow cell,and portable *** SPW-Msensor enables the detection of Cd within a linear range of 50 to 300 ppb while exhibiting high anti-interference ***,it demonstrates excellent repeatability(relative standard deviation values(RSDs)sensor and total Cd concentration(Cd_(total)) in the soil with an R^(2) value equal to *** acquired from the SPW-Msensor can be utilized for predicting Cd_(total)through partial least squares regression modeling,achieving model quality score(Q^(2)) of 0.69,adjusted R^(2) of 0.9345,and root mean square error(RMSE) of *** SPW-Msensor demonstrates real-time monitoring capabilities for assessing Cd levels in acidified *** SPW-Msensor offers an efficient approach for in-situ and continuous monitoring of Cd_(pw)that provides valuable insights applicable to environmental and agricultural domains.

关键词： cadmium pore water electrochemical sensor in-situ monitoring soil

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A nonenzymatic electrochemical sensor for the detection of hydrogen peroxide in vitro and in vivo fibrosis models

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Chinese Chemical Letters 2024年第3期35卷 394-398页

作者： Hongyao Liu Yan Yu Taixiong Xue Cailing Gan Yuting Xie Doudou Wang Peilin Li Zhiyong Qian Tinghong Ye Department of Gastroenterology and Hepatology Sichuan University-University of Oxford Huaxi Joint Centre for Gastrointestinal Cancer and Frontiers Science Center for Disease-Related Molecular NetworkState Key Laboratory of BiotherapyWest China HospitalSichuan UniversityChengdu 610041China Department of Biotherapy Cancer Center and State Key Laboratory of BiotherapyWest China HospitalSichuan UniversityChengdu 610041China

Fibrosis occurs due to the excessive deposition of extracellular matrix caused by cell *** various types of tissue injury,the dysregulation of the internal response can eventually lead to the destruction of organ structure and *** is increasing evidence that oxidative stress,which is characterized by excessive production of hydrogen peroxide(H_(2)O_(2)),is an important cause of ***,we synthesized a biosensitive and efficient electrochemical H_(2)O_(2)sensor based on PtNi nanoparticle-doped N-reduced graphene oxide(PtNi-N-rGO)to detect H_(2)O_(2)released from transforming growth factorβ1(TGFβ1)-induced *** addition,the sensor could easily detect changes in H_(2)O_(2)in the lung and bronchoalveolar lavage fluid(BALF)of mice with pulmonary ***,the sensor could also detect H_(2)O_(2)in activated hepatic stellate cells and the liver of carbon tetrachloride(CCl_(4))-induced liver ***,the alterations in H_(2)O_(2)detected by the sensor were consistent with nicotinamide adenine dinucleotide phosphate oxidase 4(NOX4)protein expression and the staining results of pathological *** together,these results highlight the use of H_(2)O_(2)sensors for the rapid detection of fibrosis and facilitate the rapid evaluation of antifibrotic drug candidates.

关键词： Fibrosis H_(2)O_(2) electrochemical sensor NOX4 Nintedanib

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Fabrication of a novel electrochemical sensor based on MnFe_(2)O_(4)/graphene modified glassy carbon electrode for the sensitive detection of bisphenol A

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Journal of Central South University 2024年第6期31卷 1856-1869页

作者： GAO Si-lei TANG Jian-she XIANG Li LONG Jin-wei Department of Environmental and Energy Engineering Anhui Jianzhu UniversityHefei 230601China Anhui Provincial Key Laboratory of Environmental Pollution Control and Resource Reuse Hefei 230601China

Manganese ferrite(MnFe_(2)O_(4))has the advantages of simple preparation,high resistivity,and high crystal ***,we have developed an electrochemical sensor utilizing graphene and MnFe_(2)O_(4) nanocomposites modified glassy carbon electrode(GCE),which is very efficient and sensitive to detect bisphenol A(BPA).MnFe_(2)O_(4)/graphene(GR)was synthesized by immobilizing the MnFe_(2)O_(4) microspheres on the graphene nanosheets via a simple one-pot solvothermal *** morphology and structure of the MnFe_(2)O_(4)/GR nanocomposite have been characterized through scanning electron microscopy(SEM),Fourier transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD)and X-ray photoelectron spectroscopy(XPS).In addition,electrochemical properties of the modified materials are comparably explored by means of cyclic voltammetry(CV),electrochemical impedance spectroscopy(EIS)and differential pulse voltammetry(DPV).Under the optimal conditions,the proposed electrochemical sensor for the detection of BPA has a linear range of 0.8-400μmol/L and a detection limit of 0.0235μmol/L(S/N=3)with high sensitivity,good selectivity and high *** addition,the proposed sensor was used to measure the content of BPA in real water samples with a recovery rate of 97.94%-104.56%.At present,the synthesis of MnFe_(2)O_(4)/GR provides more opportunities for the electrochemical detection of BPA in practical applications.

关键词： MnFe_(2)O_(4) graphene electrochemical sensor bisphenol A

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electrochemical sensor for Sensitive Determination of Ga（III） Ion Based on β-Cyclodextrin Incorporated Multi-walled Carbon Nanotubes and Imprinted Sol-gel Composite Film

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Chinese Journal of Chemistry 2012年第2期30卷 377-385页

作者： Hu,Yufang Zhang,Zhaohui Zhang,Huabin Luo,Lijuan Zhang,Minglei Yang,Xiao Yao,Shouzhuo College of Chemistry and Chemical Engineering Jishou UniversityJishouHunan 416000China State Key Laboratory of Chemo/Biosensing and Chemometrics ChangshaHunan 410082China

A novel sensor for detection of trace gallium ion [Ga（III）] was created by stepwise modification of a gold electrode with fl-cyclodextrin （β-CD）/multi-walled carbon nanotubes （MWCNTs） and an ion imprinted polymer （IIP）. The sensor surface morphology was characterized by scanning electron microscopy. The electrochemical performance of the imprinted sensor was investigated by cyclic voltammetry, differential pulse voltammetry and chronoamperometry. The sensor displayed excellent selectivity towards the target Ga（III） ion. Meanwhile, the introduced MWCNTs displayed noticeable catalytic activity, and fl：CD demonstrated significant enrichment capacity. A linear calibration curve was obtained covering the concentration range from 5.0 × 10 8 to 1.0 × 10-4 moloL-1, with a detection limit of 7.6× 10 9 mol·L-1. The proposed sensor was successfully applied to detect Ga（III） in real urine samples.

关键词： ion imprinted electrochemical sensor multi-walled carbon nanotubes β-cyclodextrin Ga(III)-8- hydroxyquinoline complex

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2D-titanium carbide(MXene)based selective electrochemical sensor for simultaneous detection of ascorbic acid,dopamine and uric acid

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Journal of Materials Science & Technology 2021年第13期72卷 122-131页

作者： Nagaraj Murugan Rajendran Jerome Murugan Preethika Anandhakumar Sundaramurthy Ashok K.Sundramoorthy Department of Chemistry SRM Institute of Science and TechnologyKattankulathur603203Tamil NaduIndia SRM Research Institute SRM Institute of Science and TechnologyKattankulathur603203Tamil NaduIndia

Two-dimensional(2 D)titanium carbide(MXene)nanosheets exhibited excellent conductivity,flexibility,high volumetric capacity,hydrophilic surface,thermal stability,***,it has been exploited in various ***,we report synthesis of mixed phase 2 D MXene as a catalytic material for simultaneous detection of important biomolecules such as ascorbic acid(AA),dopamine(DA)and uric acid(UA).Crystalline structure,surface morphology and elemental composition of mixed phase titanium carbide(Ti-C-T_(x))MXene(T_(x)=-F,-OH,or-O)nanosheets were confirmed by X-ray diffraction(XRD),Raman spectroscopy,high-resolution transmission electron microscopy(HR-TEM),high-re solution scanning electron microscopy(HR-SEM)and Energy-dispersive X-ray spectroscopy(EDS)mapping ***,Ti-C-T_(x) modified glassy carbon electrode(GCE)was prepared and its electrochemical properties are studied by cyclic voltammetry(CV)and diffe rential pulse voltammetry(DPV).It was found that Ti-C-T_(x) modified GCE(Ti-C-T_(x)/GCE)showed excellent electrocatalytic activity and separated oxidation peaks of important biomolecules such as AA(at 0.01 V),DA(at 0.21 V)and UA(at 0.33 V).Also,Ti-C-T_(x)/GCE sensor is enabled their simultaneous detection in physiological pH from 100 to 1000μM for AA,0.5-50μM for DA and 0.5-4μM&100-1500μM for *** limit of detection’s(LOD)was estimated as 4.6μM,0.06μM and 0.075μM for AA,DA and UA,***,real sample analysis indicated that spiked AA,DA and UA can be determined accurately by Ti-C-T_(x)/GCE with the recovery ratio in the range between 100.5%-103%in human urine *** proposed Ti-C-T_(x) modified electrode exhibited good stability,selectivity and reproducibility as an electrochemical sensor for the detection of AA,DA and UA molecules.

关键词： Titanium carbide Dopamine Uric acid Ascorbic acid electrochemical sensor

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Titanium dioxide-graphene composite electrochemical sensor for detection of hexavalent chromium

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International Journal of Minerals,Metallurgy and Materials 2022年第3期29卷 529-535页

作者： Natpichan Pienutsa Krittamet Yannawibut Jetthana Phattharaphongmanee Oukrit Thonganantakul Sira Srinives Nanocomposite Engineering Laboratory(NanoCEN) Department of Chemical EngineeringFaculty of EngineeringMahidol University25/25 PuttamonthonNakhon Pathom73170Thailand

Hexavalent chromium(Cr(VI))compound is useful to various industries but is toxic and *** this research work,we fab-ricate an amperometric sensor for the determination of Cr(VI),using a titanium dioxide(TiO2)-reduced graphene oxide(rGO)composite as the sensing *** composite was synthesized following sol−gel chemistry,yielding TiO2 nanoparticles of~50 nm in size,immobilized on chemically exfoliated rGO *** composite was employed in a 3-electrode electrochemical cell and operated in an amperometric mode,exhibiting good responses to the 50 to 500 ppb Cr(VI).Our best result from pH 3 Mcilvane’s buffer medium reveals the sensitivity of 9.12×10−4 ppb−1 and a detection limit of 6 ppb with no signal interference from 200 ppm Ca(II),150 ppm Mg(II),and 50 ppb Pb(II).The excellent results of the TiO2-rGO sensor can be attributed to synergic effects between TiO2 and rGO,resulting from the presence of n-p heterojunctions and the formation of the TiO2 nanoparticles on rGO.

关键词： photocatalyst electrochemical sensor hexavalent chromium graphene

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Rapid CO_(2)-laser scribing fabrication of an electrochemical sensor for the direct detection of Pb^(2+) and Cd^(2+)

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Nano Research 2023年第5期16卷 7671-7681页

作者： Guanglei Chu Yanyan Zhang Zhongrui Zhou Weixuan Zeng Dongfei Chen Siping Yu Jiemin Wang Yemin Guo Xia Sun Ming Li Hunan Agricultural Equipment Research Institute Hunan Academy of Agricultural SciencesChangsha 410125China School of Agriculture Engineering and Food Science Shandong University of TechnologyZibo 255049China School of Chemistry University of New South WalesSydneyNSW 2052Australia Hunan Rice Research Institute Hunan Academy of Agricultural SciencesChangsha 410125China Longping Branch College of BiologyHunan UniversityChangsha 410125China Department of Materials Science and Engineering National University of SingaporeNo.21 Lower Kent Ridge RoadSingapore 119077Singapore

Laser-induced graphene(LIG)is a highly promising preparation material for electrochemical sensors;however,its preparation speed and nanomaterial modification steps significantly limit its mass ***,this study proposed a new laser printing strategy that considerably improved the preparation speed of LIG with excellent electrochemical *** the optimal parameters(laser power of 1%,scribing spacing of 0.12 mm,scribing speed of 100 mm·s^(−1)),it took only 14.2 s to complete the preparation of the detection ***,we successfully detected Cd^(2+)and Pb^(2+)without any toxic reagents or electrode modification *** limits of detection of the sensor were 0.914 and 0.916μg·L^(−1)for Cd^(2+)and Pb^(2+),respectively,which are significantly lower than the required values for drinking-water quality,according to the World Health Organization *** study provides a novel approach for the rapid detection of heavy-metal ions.

关键词： laser-induced graphene electrochemical sensor rapid fabrication heavy-metal ions

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Preparation of Molecularly Imprinted electrochemical sensor for Detection of Vincristine Based on Reduced Graphene Oxide/Gold Nanoparticle Composite Film

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Chinese Journal of Chemistry 2016年第12期34卷 1268-1276页

作者： Yan Zhang Jing Zheng Mandong Guo College of Chemistry and Material Science Shanxi Normal University Linfen Shanxi 041004 China

An innovative molecularly imprinted electrochemical sensor was fabricated based on reduced graphene oxide （RGO） and gold nanocomposite （Au） for rapid detection of vincristine （VCR）. The RGO-Au composite membrane was obtained via direct one-step electrodeposition technique of graphene oxide （GO） and chloroauric acid （HAuCl4） on the surface of a glassy carbon electrode （GCE） by means of cyclic voltammetry （CV） in the potential range be- tween -1.5 and 0.6 V in phosphate buffer solution （PBS） of pH 9.18, which is capable of effectively utilizing its superior electrical conductivity, larger specific surface area due to its synergistic effect between RGO and Au. The molecularly imprinted polymers （MIPs） were synthesized on the RGO-Au modified glassy carbon electrode surface with VCR as the template molecular, methyl acrylic acid （MAA） as the functional monomer, and ethylene glycol maleic rosinate acrylate （EGMRA） as a cross-linker. The performance of the sensor was investigated by cyclic voltammetry （CV）, differential pulse voltammetry （DPV） and electrochemical impedance spectroscopy （EIS） in de- tail. Under the optimum conditions, the fabricated sensor exhibited a linear relationship between oxidation peak current and VCR concentration over the range of 5.0×10 8 5.0×10^-6 mol.L l with a correlation coefficient of 0.9952 and a detection limit （S/N=3） of 2.6×10 8 mol.L^-1. The results indicated that the imprinted polymer films exhibited an excellent selectivity for VCR. The imprinted sensor was successfully used to determine VCR in real samples with recoveries of 90%-- 120% by using the standard addition method.

关键词： molecularly imprinted polymers electrochemical sensor reduced graphene oxide and gold nanocom-posites vincristine

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Nitrogen-doped carbon@TiO_(2) double-shelled hollow spheres as an electrochemical sensor for simultaneous determination of dopamine and paracetamol in human serum and saliva

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Journal of Pharmaceutical Analysis 2022年第3期12卷 436-445页

作者： Hui Yang Gongxun Cao Yongjun Huang Ye Lin Fengying Zheng Luxiu Lin Fengjiao Liu Shunxing Li College of Chemistry Chemical Engineering and EnvironmentMinnan Normal UniversityZhangzhouFujian363000China Fujian Provincial Key Laboratory of Pollution Monitoring and Control Minnan Normal UniversityZhangzhouFujian363000China Fujian Key Laboratory of Separation and Analysis Science and Technology ZhangzhouFujian363000China

As the most commonly used antipyretic and analgesic drug,paracetamol(PA)coexists with neurotransmitter dopamine(DA)in real biological *** simultaneous determination is extremely important for human health,but they also interfere with each *** order to improve the conductivity,adsorption affinity,sensitivity,and selectivity of TiO_(2)-based electrochemical sensor,N-doped carbon@-TiO_(2) double-shelled hollow sphere(HeC/N@TiO_(2))is designed and synthesized by simple alcoholic and hydrothermal method,using polystyrene sphere(PS)as a ***,TiO_(2) hollow spheres(H eTiO_(2))or N-doped carbon hollow spheres(HeC/N)are also prepared by the same ***/N@TiO_(2) has good conductivity,charge separation,and the highly enhanced and stable current responses for the detection of PA and *** detection limit and linear range are 50.0 nmol/L and 0.3-50 mmol/L for PA,40.0 nmol/L and 0.3e50 mmol/L for DA,respectively,which are better than those of carbon-based ***,this electrochemical sensor,with high selectivity,strong anti-interference,high reliability,and long time durability,can be used for the simultaneous detection of PA and DA in human blood serum and *** high electrochemical performance of HeC/N@TiO_(2) is attributed to the multifunctional combination of different layers,because of good conductivity,absorption and electrons transfer ability from in-situ N-doped carbon and electrocatalytic activity from TiO_(2).

关键词： electrochemical sensor Simultaneous determination Paracetamol Dopamine

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Cu(OH)_(2)/CMC one-dimensional composite-nanofiber-based electrochemical sensor for aspirin detection

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Nanotechnology and Precision Engineering 2023年第2期6卷 48-56页

作者： Meng Cui Xiaohui Wang Ziang Quan Bing Xu Di Gao Key Laboratory of Special Functional Materials in Colleges and Universities of Jilin Province Jilin Institute of Chemical TechnologyJilin 132022China Jilin Electric Power Plant National Energy GroupJilin 132022China

Copper-based nanomaterials have been widely used in catalysis,electrodes,and other applications due to their unique electron-transfer *** this work,an efficient electrochemical sensor based on an electrode modified with one-dimensional Cu(OH)_(2)/carboxymethyl cellulose(CMC)composite nanofibers was fabricated and investigated for the detection of *** electron microscopy was employed to examine the morphological characteristics of these composite *** voltammetry and electrochemical impedance spectroscopy were used to assess the electrochemical performance of a Cu(OH)_(2)/CMC composite nanofiber-modified *** findings indicate that the modified electrode has a very high sensitivity to *** observed enhanced performance could be a result of the high surface-to-volume ratio of the composite nanofibers and their superior electron-transport characteristics,which may hasten electron transfer between aspirin and the surfaces of the modified *** detection technique also demonstrated strong selectivity for *** findings imply that the technique can be applied as a highly effective and selective approach to aspirin measurement in biological science.

关键词： Sodium carboxymethyl cellulose Cu(OH)_(2)nanofiber electrochemical sensor Aspirin

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