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A new method for the derivation of the closed nets in the phase diagram space of *** absent phase substitution method

A new method for the derivation of the closed nets in the ph...

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中国科学院地质与地球物理研究所2004学术年会

作者： J.HU~(1,2),H.YIN~2 AND Z.DUAN~(1,3) 1 The Key Laboratory of Mineral Resources,Institute of Geology and Geophysics,Chinese Academy of Sciences,Beijing 100029,China 2 College of Material and Biological Engineering Chengdu University of Technology,Chengdu 610059,China 3 Department of Chemistry,0340,University of California,San Diego,La Jolla,CA 92129,USA

A new convenient combinatorial method is developed here to derive the invariant points in multisystem closed nets - the absent phase substitution(APS) *** substantially simplifies the derivation of the closed nets in multisystems with many components and *** the multisystems whose total phase number(N)≤twice the number of the absent phases(m) in an invariant assemblage,the method can yield regular closed nets with or without globally absent phases;for other multisystems,the method can yield the regular closed nets with globally absent *** examples,the APS method was used to predict:(1) the regular closed nets of unary to quinary n + 4-phase multisystems,unary 6-phase multisystem and ternary 8-phase multisystem;(2) the basic properties of the regular closed nets of the quaternary and quinary multisystems with n + 4 and n + 5 *** multisystems were chosen to demonstrate how to select a realistic closed net from the numerous possible closed nets of a complex multisystem,and how to derive a realistic partially closed-net,closed-net-diagram and the related realistic *** of our APS method for the derivation of complicated closed nets with other methods indicate that this method is much simpler and more efficient.

关键词： closed net invariant point multisystem phase diagram the absent phase substitution method

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