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A new method for the derivation of the closed nets in the ph...

A new method for the derivation of the closed nets in the phase diagram space of *** absent phase substitution method

作     者:J.HU~(1,2),H.YIN~2 AND Z.DUAN~(1,3) 1 The Key Laboratory of Mineral Resources,Institute of Geology and Geophysics,Chinese Academy of Sciences,Beijing 100029,China 2 College of Material and Biological Engineering Chengdu University of Technology,Chengdu 610059,China 3 Department of Chemistry,0340,University of California,San Diego,La Jolla,CA 92129,USA 

会议名称:《中国科学院地质与地球物理研究所2004学术年会》

会议日期:2004年

学科分类:081801[工学-矿产普查与勘探] 08[工学] 0818[工学-地质资源与地质工程] 

基  金:supported by Zhenhao Duan’s  Hundred Scientists Project’funds awarded by the Chinese Academy of Sciences and his Outstanding Young Scientist Fund(#40225008)awarded by National Science Foundation of China 

关 键 词:closed net invariant point multisystem phase diagram the absent phase substitution method 

摘      要:A new convenient combinatorial method is developed here to derive the invariant points in multisystem closed nets - the absent phase substitution(APS) *** substantially simplifies the derivation of the closed nets in multisystems with many components and *** the multisystems whose total phase number(N)≤twice the number of the absent phases(m) in an invariant assemblage,the method can yield regular closed nets with or without globally absent phases;for other multisystems,the method can yield the regular closed nets with globally absent *** examples,the APS method was used to predict:(1) the regular closed nets of unary to quinary n + 4-phase multisystems,unary 6-phase multisystem and ternary 8-phase multisystem;(2) the basic properties of the regular closed nets of the quaternary and quinary multisystems with n + 4 and n + 5 *** multisystems were chosen to demonstrate how to select a realistic closed net from the numerous possible closed nets of a complex multisystem,and how to derive a realistic partially closed-net,closed-net-diagram and the related realistic *** of our APS method for the derivation of complicated closed nets with other methods indicate that this method is much simpler and more efficient.

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