检索结果-南通市图书馆

Effect of ZnO,La_(2)O_(3),and YF_(3)on Crystallization and Rehological Behavior of Y_(2)O_(3)-Al_(2)O_(3)-SiO_(2)Glass

引用

Journal of Wuhan University of Technology(Materials Science) 2023年第4期38卷 753-758页

作者：王君 GAO Shengnan ZHENG Qingshuang ZHANG Xiaowei ZHANG Dongliang XIONG Dehua JIN Siqingaowa 王觅堂焦国豪 School of Materials and Chemistry University of Shanghai for Science and TechnologyShanghai200093China State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan430070China School of Materials and Metallurgy Inner Mongolia University of Science and TechnologyBaotou014010China Guangxi Academy of Sciences Nanning530000China

The effect of substitution La_(2)O_(3)and YF_(3)as network modifiers respectively for Y_(2)O_(3),and ZnO as intermediate oxide for Al_(2)O_(3)on crystallization and viscous behavior of Y_(2)O_(3)-Al_(2)O_(3)-SiO_(2)glass was studied.La_(2)O_(3)and YF_(3)substitution for Y_(2)O_(3)decreases the melting temperature of studied glass from 1402 to 1346 and 1379℃,and the activation energy of viscous flow decreases from 340 to 250 and 265 kJ/mol.Meanwhile,ZnO substitution for Al_(2)O_(3)decreases the melting temperature to 1379℃while increases the activation energy of viscous flow to 542 kJ/mol,due to their different role in glass structure.Substitution ZnO for Al_(2)O_(3)refines and homogenizes the crystals size and lowers crystallinity because the nucleation and crystal growth are depressed by higher activation energy of crystallization and change of crystallization mechanism from bulk crystallization to surface crystallization.Replacement of Y_(2)O_(3)by La_(2)O_(3)and YF_(3)respectively also decreases the crystallinity of Y_(2)O_(3)-Al_(2)O_(3)-SiO_(2)glass ceramic due to competitive and hindering effect on the rearranged atoms,structural units and groups required by precipitated two crystals.Besides,y-Y2Si2O7,precipitation of Y4.67(SiO4)3O,ZnAl_(2)O_(4),and Y3Si3O10F were observed respectively due to incorporation of La_(2)O_(3),ZnO,and YF_(3).

关键词： Y_(2)O_(3) aluminosilicate glass crystallization viscous activation energy

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Effects of MgO/Al_(2)O_(3)and CaO/SiO_(2)ratios on viscosity of high titaniumbearing blast furnace slag

引用

Journal of Iron and Steel Research(International) 2023年第3期30卷 456-464页

作者： Hua-bin Gao Jue Tang Man-sheng Chu Shu-yu Zhong Zheng-gen Liu School of Metallurgy Northeastern UniversityShenyang 110819LiaoningChina Liaoning Province Engineering Research Center for Technologies of Low-Carbon Steelmaking Northeastern UniversityShenyang 110819LiaoningChina State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang 110819LiaoningChina

The effects of MgO/Al_(2)O_(3)and CaO/SiO_(2)ratios on the viscosity,break-point temperature,and viscous activation energy of a high titanium-bearing slag were studied.The results showed that both the viscosity and the break-point temperature of the slag decreased with the MgO/Al_(2)O_(3)ratio increasing from 0.50 to 0.65,the viscous activation energy decreased gradually,and the thermal stability became better.In addition,with an increase in CaO/SiO_(2)ratio from 1.12 to 1.22,the main viscous units in the slag depolymerized and the viscosity of slag decreased.However,the break-point temperature of slag showed an increasing tendency.The viscous activation energy decreased gradually and the thermal stability became better.The basic phase in the experimental high titanium-bearing slag was pyroxene,and its amount increased with increasing the MgO/Al_(2)O_(3)ratio while decreased with increasing the CaO/SiO_(2)ratio.

关键词： High titanium-bearing slag Viscosity viscous activation energy Break-point temperature Phase composition

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：