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Chinese Chemical Letters 2023年第1期34卷 544-549页

作者： Fengjun Yin Hong Liu Chongqing Institute of Green and Intelligent Technology Chinese Academy of SciencesChongqing 400714China Key Laboratory of Reservoir Aquatic Environment Chinese Academy of SciencesChongqing 400714China China University of Chinese Academy of Sciences Beijing 100049China

Derivative-extremum analysis(DEA) of j-E curves is a newly proposed method of half wave potential(E1/2) and activation feature extraction from steady-state voltammetry. Here, the DEA is demonstrated to be valid in the full range of reversibility using numerical simulations with a derived universal electrode equation, providing a novel perspective of electrochemical kinetics in the reversibility domain. The results reveal that E1/2is a better choice of the reference potential instead of equilibrium potential(Eeq) in electrode equations, especially since Eeqis meaningless in an irreversible case. The equations referenced with standard potential, E1/2and Eeq, are summarized in three tables, and their applications in parameter determinations are specified. Finally, reversibility is proved to be a relative measure between kinetic slowness and mass transport of electroactive species, and the reversibility classifications are proposed according to the DEA feature in the reversibility domain. This work, based on the DEA principle, refines the electrode equation forms and generalizes their applicability in the full range of reversibility.

关键词： reversibility Electrochemical kinetics Half-wave potential Derivative-extremum analysis Parameter determinations

Revisiting the conversion reaction voltage and the reversibility of the CuF2 electrode in Li-ion batteries

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Nano Research 2017年第12期10卷 4232-4244页

作者： Joon Kyo Seo Hyung-Man Cho Katsunori Takahara Karena W. Chapman Olaf J. Borkiewicz Mahsa Sina Y. Shirley Meng Department of NanoEngineering University of California San Diego 9500 Gilman Drive La Jolla CA 92093 USA Materials Science and Engineering University of California San Diego 9500 Gilman Drive La Jolla CA 92093 USA X-ray Science Division Advanced Photon Source Argonne National Laboratory 9700 South Cass Avenue Argonne IL 60439 USA

Deviation between thermodynamic and experimental voltages is one of the key issues in Li-ion conversion-type electrode materials; the factor that affects this phenomenon has not been understood well in spite of its importance. In this work, we combine first principles calculations and electrochemical experiments with characterization tools to probe the conversion reaction voltage of transition metal difluorides MF2（M = Fe, Ni, and Cu）. We find that the conversion reaction voltage is heavily dependent on the size of the metal nanoparticles generated. The surface energy of metal nanoparticles appears to penalize the reaction energy, which results in a lower voltage compared to the thermodynamic voltage of a bulk-phase reaction. Furthermore, we develop a reversible CuF2 electrode coated with NiO. Electron energy loss spectroscopy （EELS） elemental maps demonstrate that the lithiation process mostly occurs in the area of high NiO content. This suggests that NiO can be considered a suitable artificial solid electrolyte interphase that prevents direct contact between Cu nanoparticles and the electrolyte. Thus, it alleviates Cu dissolution into the electrolyte and improves the reversibility of CuF2.

关键词： Li-ion battery conversion material reaction voltage nanoparticle reversibility coating

reversibility of diabetes mellitus: Narrative review of the evidence

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World Journal of Diabetes 2018年第7期9卷 127-131页

作者： Gary Yee Ang Health Services and Outcomes Research National Healthcare Group

The global disease burden of diabetes mellitus is high. It is well-established that prediabetes is reversible but it is unclear whether diabetes is reversible once it has been diagnosed. The objective of this narrative review is to review the evidence of reversibility of diabetes me-llitus and stimulate interest in prolonged remission as a treatment target. The current evidence for bariatric surgery is stronger than intensive medical management and the evidence is stronger for type 2 diabetes pa-tients compared with type 1 diabetes patients. It is also unclear whether non obese diabetes patients would benefit from such interventions and the duration of diabetes before diabetes become irreversible. Further research is needed in this area especially with regards to the subgroup of diabetes patient who will benefit from these interventions and the long term safety and efficacy remains unknown especially with intensive me-dical management.

关键词： Diabetes reversibility Remission Bariatric surgery Obesity

reversibility of quantum entanglement state

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Reversibility of quantum entanglement state

The Theory of Everything as the reversibility Theory

第十八届全国量子光学学术会议

作者：杜少将 Hai-Ran Feng Feng Han Lianwu Yang Yu-Jun Zheng 济宁学院 Department of Physics and Information Engineering Ji-ning University School of Physics Shandong University

Based on the theory of balance between information gain and reversibility to study the entanglement intensity of quantum state. Using the theory to study entanglement state, taking two-body entanglement state as an example, to analyse the trade-off relation and calculate entanglement intensity after weak measurement operation and proper reversible operation. The result indicate that entanglement intensity can practically reverse to its original state. This protocol can help us to get some information from quantum system and reverse the a destruct quantum entanglement system.

关键词： quantum entanglement state weak measurement Information gain reversibility Trade-off Relation

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Journal of Modern Physics 2015年第13期6卷 1820-1832页

作者： Ding-Yu Chung Utica MI USA

In the posited reversibility theory, 1) all physical laws and phenomena are permanently reversible, 2) all physical laws are derived from the reversible M-theory (extension of string theory) in the reversible multiverse, and 3) temporary irreversible entropy increase is allowed through reversibility breaking, symmetry breaking, and low entropy beginning. Dealing with all physical laws and phenomena, the reversibility theory is the theory of everything, including thermodynamic, cosmology, the composition (baryonic matter, dark matter, and dark energy) in the universe, the periodic table of all elementary particles, the galaxy evolution, superconductivity, and black hole. In the reversible M-theory, space-time dimension number oscillates between 11D (space-time dimension) and 10D and between 10D and 4D. The reversible M-theory includes 11D membrane, 10D string, and variable D particle. Space-time dimension number between 10 and 4 decreases with decreasing speed of light, decreasing vacuum energy, and increasing rest mass. In our dual universe of positive-negative energy universe, the reversible oscillation between 10D with and 4D in the negative energy universe without kinetic energy is the reversible cyclic fractionalization-condensation for the reversible cyclic expansion-contraction of the universe. Without kinetic energy, the individual particles have no individual momenta for entropy increase. The negative energy universe is the locally reversible universe for dark energy. In the positive energy universe where we live, the absorption of the interuniversal void forced the direct transformation from 10D to 4D as the inflation followed by the Big Bang, and created kinetic energy that provided individual momenta for individual particles to produce irreversible entropy increase, resulting in the reversibility breaking of the reversible oscillation. The positive energy universe is the locally irreversible universe. The dual universe as a whole is reversible guided by t

关键词： The Theory of Everything reversibility Theory Entropy Thermodynamic Cyclic Universe Multiverse Interuniversal Void M-Theory Cosmology String Theory

A Review of Rechargeable Zinc-Air Batteries:Recent Progress and Future Perspectives

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Nano-Micro Letters 2024年第7期16卷 358-401页

作者： Ghazanfar Nazir Adeela Rehman Jong-Hoon Lee Choong-Hee Kim Jagadis Gautam Kwang Heo Sajjad Hussain Muhammad Ikram Abeer AAlObaid Seul-Yi Lee Soo-Jin Park Department of Nanotechnology and Advanced Materials Engineering Hybrid Materials Research Center(HMC)Sejong UniversitySeoul 05006Republic of Korea Department of Chemical and Biomolecular Engineering Yonsei University50 Yonsei-RoSeodaemun-GuSeoul 03722Republic of Korea Department of Chemistry Inha UniversityIncheon 22212Republic of Korea Solar Cell Applications Research Lab Department of PhysicsGovernment College University LahoreLahore 54000 PunjabPakistan Department of Chemistry College of ScienceKing Saud UniversityP.O.Box 2455Riyadh 11451Saudi Arabia

Zinc-air batteries(ZABs)are gaining attention as an ideal option for various applications requiring high-capacity batteries,such as portable electronics,electric vehicles,and renewable energy *** offer advantages such as low environmental impact,enhanced safety compared to Li-ion batteries,and cost-effectiveness due to the abundance of ***,early research faced challenges due to parasitic reactions at the zinc anode and slow oxygen redox *** advancements in restructuring the anode,utilizing alternative electrolytes,and developing bifunctional oxygen catalysts have significantly improved *** have achieved battery reversibility over thousands of cycles,introduced new electrolytes,and achieved energy efficiency records surpassing 70%.Despite these achievements,there are challenges related to lower power density,shorter lifespan,and air electrode corrosion leading to performance *** review paper discusses different battery configurations,and reaction mechanisms for electrically and mechanically rechargeable ZABs,and proposes remedies to enhance overall battery *** paper also explores recent advancements,applications,and the future prospects of electrically/mechanically rechargeable ZABs.

关键词： Zinc-air batteries Energy storage Affordability reversibility

Multiresponsive,easy-reversible,and dual-visual Pt(Ⅱ)salt nanostructures for advanced anti-counterfeiting application

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Nano Research 2024年第1期17卷 372-381页

作者： Zhen Su§ Depeng Li§ Lixin Zhang Si Tian Yuhong Su Xiaoyun Hu Duan Xiong Qingqing Guan Key Laboratory of Oil and Gas Fine Chemicals Ministry of Education College of Chemical EngineeringXinjiang UniversityUrumqi 830017China

Smart materials that integrate multi-stimuli response,full reversibility,and dual-visual read-out channel are highly desired for anticounterfeiting and information encryption ***,we developed a multiresponsive perchlorate terpyridyl Pt(Ⅱ)nano complex which could undergo fully reversible conversion between three forms stimulated by water or formaldehyde molecule due to the extent of Pt–Pt ***,a dual-visual channel,i.e.,the colorimetric channel changed from yellow to orange or red and the corresponding luminescent channel from orange to orange-red or red,has also been *** weak and equivalent strength of ion-dipole interaction and hydrogen bond that generated between formaldehyde/water and Pt(II)salt result in the easy-control reversibility between the three ***,by introducing different polymer matrices,1Cl·ClO_(4)@PMMA(1Cl·ClO_(4):[Pt(tpy)Cl]·ClO4,tpy:2,2':6',2''-terpyridine),PMMA:poly(methyl methacrylate))and 1Cl·ClO4@PVA(PVA:polyvinyl alcohol)are successfully constructed,which exhibit different reversible behaviors since the PMMA and PVA matrix exert different influences on the strength of *** smart Pt(II)salt nanostructures present great potential for high-security-level anticounterfeiting application.

关键词： Pt(II)complex multiresponse reversibility anticounterfeiting information encryption

Catalytic effects of V-and O-species derived from PrF_(3)/V_(2)C for efficient hydrogen storage in MgH_(2)

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Nano Research 2024年第8期17卷 7117-7125页

作者： Zhenluo Yuan Yuhang Wang Xiuxiu Zhang Shuyan Guan Xiaojiao Wang Liqiang Ji Qiuming Peng Shumin Han Yanping Fan Baozhong Liu College of Chemistry and Chemical Engineering Henan Polytechnic UniversityJiaozuo 454000China Henan Famous Diamond Co. Ltd.Mengzhou 454763China School of Chemical Engineering Zhengzhou UniversityZhengzhou 450001China Collaborative Innovation Center of Steel Technology University of Science and Technology BeijingBeijing 100083China State Key Laboratory of Metastable Materials Science and Technology Yanshan UniversityQinhuangdao 066004China

Magnesium hydride(MgH_(2))is considered as an ideal hydrogen storage material with excellent hydrogen capacity,but the slow kinetics impedes its ***,an efficient additive of V2C MXene-anchored PrF_(3) nanoparticles(PrF_(3)/V_(2)C)was synthesized,which presents excellent catalytic effect in improving the reversibility and stability of hydrogen storage in MgH_(2).The initial dehydrogenation temperature of the 5 wt.% PrF_(3)/V_(2)C-containing MgH_(2)(182℃) is 105℃ lower than that of pure MgH_(2),and 6.5 wt.%hydrogen is rapidly released from 5 wt.%PrF_(3)/V_(2)C-added MgH_(2)sample in 6 min at 240℃.In addition,5 wt.%PrF_(3)/V_(2)C-containing MgH_(2) sample possesses outstanding reversible hydrogen storage capability of 6.5 wt.% after 10 cycles of dehydrogenation and *** analysis shows that the introduction of Pr improves the stability of V-species(V^(0)and V^(2+))and O-species(lattice oxygen(OL)and vacancy oxygen(OV))formed during ball milling,promotes the interaction between V-species and O-species,and enhances their reversibility,which contributes to the significant improvement in re/dehydrogenation reversibility and cycling stability of MgH_(2).This study provides effective ideas and strategies for the purpose of designing and fabricating high-efficient catalysts for solid-state hydrogen storage materials.

关键词： hydrogen storage materials MgH_(2) dehydrogenation reversibility cyclic stability

Synergy effect of regulated Li-plating and functional solid electrolyte interphase on graphite anodes

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Nano Research 2024年第9期17卷 8077-8085页

作者： Panpan Wang Baojia Xia Jianling Li State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China Shanghai Institute of Microsystem and Information Technology Chinese Academy of SciencesShanghai 201800China

The growth of Li dendrites poses potential safety hazard to lithium-ion batteries(LIBs),and eliminating Li dendrites thoroughly stills face tough difficulties ***,regulating Li-plating is a critical optimization-direction to address the ***,a“graphite-Li hybrid”anode with high reversibility is realized under the constant-capacity lithiation(CCL).Within CCL,the uniform distribution of Li-plating on the graphite surface is successfully *** evolution in different states of solid electrolyte interphase(SEI)is investigated in detail to study the interaction between the potentials and impedance during the process of Liintercalation and *** the potential below 0 V and the state of charge(SOC)of 110%relative to the theoretical capacity,the F-rich SEI with high stability is constructed to hinder the emergency of Li dendrites and maintain the intact structure of graphite anode under long *** cell presents more than 100%Coulombic efficiency(CE)with the 900 cycles,demonstrating the reversible Li-plating and the utilization of *** the CCL half-cell provides a good cycling performance and specific capacity of 900 cycles at 0.5 C,it is attributed to the synergy effect of stable inorganic-rich SEI and regulated active Li-plating.

关键词： "graphite-Li hybrid"anode Li-plating reversibility solid electrolyte interphase(SEI)

Antifertility effects of quinestrol in male lesser bandicoot rat, Bandicota bengalensis, and potential in managing rodent population under field conditions

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Integrative Zoology 2024年第1期19卷 108-126页

作者： Ajooni SIDHU Neena SINGLA Department of Zoology Punjab Agricultural UniversityLudhianaPunjabIndia

Integrating fertility control techniques using steroid hormones after lethal control can help reduce post control rebuildup of rodent *** current study is thefirst to assess the antifertility effects of quinestrol in male lesser bandicoot rat,Bandicota bengalensis which is the predominant rodent pest species in Southeast *** in different groups were fed bait containing 0.00%,0.01%,0.02%,and 0.03%quinestrol for 10 days in laboratory and evaluated immediately,and 15,30,and 60 days after treatment discontinuation for effect on reproduction and other antifertility *** of 0.03%quinestrol treatment for 15 days was also observed in managing rodent populations in groundnut *** resulted in average consumption of 19.53±1.80,67.63±5.50,and 246.67±1.78 mg/kg bwt active ingredient by three treated groups of rats,*** reproduction was observed in female rats mated with male rats treated with 0.03%quinestrol,even 30 days after cessation of ***-mortem examination showed a significant(Preversibility after 60 days.A significant(P<0.0001)effect of quinestrol on the histomorphology of testis and cauda epididymis was observed,suggesting its effect on *** cell association and cell count in seminiferous tubules did not fully recover within 60 days of stopping *** of the effects of quinestrol treatment in groundnutfields showed greater reductions in rodent activity infields treated with 2%zinc phosphide followed by 0.03%quinestrol treatment as compared tofields treated with 2%zinc phosphide *** concludes that quinestrol has the potential to reduce fecundity and post control rebuildup of *** populations,but long-term studies

关键词： antifertility Bandicota bengalensis field evaluation quinestrol reversibility