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Asian Agricultural Research 2024年第5期16卷 29-32页

作者： Junxia LUO Qianqian ZHAO Lumei DUAN Yanzhen LI Huifang QIAO Zhipei DOU Jianbo ZHAO Zhengzhou Product Quality Inspection and Testing Center Zhengzhou 450006China Jiaozuo Product Quality Inspection and Testing Center Kaifeng 454000China Kaifeng Product Quality Inspection and Testing Center Kaifeng 454000China Zhengzhou Agricultural Technology Extension Center Zhengzhou 450002China

[Objectives]To fully understand the quality of commercial enzyme inhibition-colorimetric pesticide residue rapid detection kits,so that they can play a greater role in the detection and supervision of agricultural products.[Methods]The sensitivity of 28 kinds of pesticides was determined by using the commercially available enzyme inhibition colorimetric rapid detection kit with Hendu brand.[Results]There was a significant difference in the sensitivity of the kit to each pesticide,and the kit was more sensitive to dichlorvos among the 28 pesticides *** sensitivity to methyl isosalifos,dimethoate,isocarbophos,fenthion and phorate was poor,and the sensitivity to quinalphos was different between 3.0 and 2.5 mL.[Conclusions]The large difference of the sensitivity of the enzyme inhibition-colorimetric rapid detection kit for pesticide residues to different kits is a reason for the false positive and false negative test results of the kit,which needs to be considered by relevant personnel.

关键词： Enzyme inhibition-colorimetry Reagent kit pesticide Inhibition rate Sensitivity

Lower blood malondialdehyde is associated with past pesticide exposure:findings in Gulf War illness and healthy controls

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Military Medical Research 2022年第2期9卷 205-214页

作者： Beatrice Alexandra Golomb Sridevi Devaraj Alexis K.Messner Hayley Jean Koslik Jun Hee Han Barnabas Yik Department of Medicine School of MedicineUniversity of CaliforniaSan DiegoLa JollaCA 92093USA Department of Pathology and Immunology Baylor College of MedicineHoustonTX 77030USA Swedish Medical Center SeattleWA 98109USA Henry M.Jackson Foundation for the Advancement of Military Medicine San DiegoCA 92134USA Santa Clara Valley Medical Center San JoseCA 95128USA

Background: Malondialdehyde(MDA) is a candidate general marker of oxidative stress(OS). We sought to assess the relation of MDA to Gulf War illness(GWI) and to a variety of ***: This is an observational study involving subjects from Southern California recruited from October 2011 to May 2014. MDA was assessed in 81 participants(41 GWI-cases, 40 controls). General and Gulf-specific exposures were elicited. MDA case–control comparison was restricted to 40 matched pairs. The potential association between MDA and exposures was assessed using regression analyses. Gulf-specific exposures were incorporated into a case-specific ***: Plasma MDA was significantly lower in GWI-cases than controls. Composite pesticide and fuel-solvent exposures negatively predicted MDA in the total sample, as well as in the analyses that included either GWI-cases or controls only. Self-reported exposure to organophosphate(OP) nerve gas was a strong predictor for lower MDA level in veterans with ***: Past pesticide exposures predicted lower MDA in both veterans with GWI and in healthy controls.

关键词： Malondialdehyde Oxidative stress Free radical Gulf War veterans Gulf War illness pesticide

QSAR Models for Predicting Additive and Synergistic Toxicities of Binary pesticide Mixtures on Scenedesmus Obliquus

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Chinese Journal of Structural Chemistry 2022年第3期41卷 166-177,I0011页

作者：莫凌云袁柏康朱杰覃礼堂代俊峰 College of Environmental Science and Engineering Guilin University of TechnologyGuilin 541004China Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology Guilin University of TechnologyGuilinGuangxi 541004China Technical Innovation Center of Mine Geological Environmental Restoration Engineering in Southern Karst Area MNRNanning 530023China Guangxi Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area Guilin University of TechnologyGuilin 541004China

pesticides released into the environment may pose potential risks to the ecological system and hu-man ***,existing toxicity data on pesticide mixtures still lack,especially regarding the toxic interac-tions of their *** study aimed to determine the toxic interactions of binary mixtures of pesticides on Scenedesmus Obliquus(***)and to build quantitative structure-activity relationship models(QASR)for predicting the mixture *** applying direct equipartition ray method to design binary mixtures of five pes-ticides(linuron,dimethoate,dichlorvos,trichlorfon and metribuzin),the toxicity of a single pesticide and its mix-ture was tested by microplate toxicity analysis on *** QASR models were built for combined toxicity of binary mixtures of pesticides at the half-maximal effective concentration(EC_(50)),30%maximal effective concen-tration(EC_(30))and 10%maximal effective concentration(EC_(10)).The results showed that the single toxicity follows:metribuzin>linuron>dichlorvos>trichlorfon>*** mixtures of linuron and trichlorfon,dichlorvos and metribuzin,dimethoate and metribuzin induced synergetic effects,while the remaining binary mixtures exhib-ited *** developed QSAR models were internally validated using the leave-one-out cross-validation(LOO),leave-many-out cross-validation(LMO),bootstrapping,and y-randomization test,and externally validated by the test *** three QSAR models satisfied well with the experimental values for all mixture toxicities,and presented high internally(R^(2)and Q^(2)>0.85)and externally(Q^(2)_(F1),Q^(2)_(F2),and Q^(2)_(F3)>0.80)predictive *** developed QSAR models could accurately predict the toxicity values of EC_(50),EC_(30)and EC_(10)and were superior to the concentration addition model's results(CA).Compared to the additive effect,the QSAR model could more ac-curately predict the binary mixture toxicities of pesticides with synergistic effects.

关键词： pesticide QSAR toxicity prediction binary mixture algae

Effect of Chinese steamed bun and bread processing on pesticide residues in wheat flour

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Food Production, Processing and Nutrition 2022年第1期4卷 136-143页

作者： Ying Liang Jinmiao Duan Qingchao Gao Yahui Li Zhiyong Zhang Key Laboratory of Food Quality and Safety of Jiangsu Province Institute of Food Safety and NutritionJiangsu Academy of Agricultural ScienceNanjing210014JiangsuChina School of Food and Biological Engineering Jiangsu UniversityZhenjiang212013JiangsuChina

The changes of five pesticides including imidacloprid, triadimefon, fenitrothion, chlorpyrifos-methyl, and chlorpyrifos in wheat flour during Chinese steamed bun and bread processing were systematically investigated. The pesticide residues were determined by high performance liquid chromatography coupled with diode array detector. Dough mixing step in both Chinese steamed bun and bread processing reduced the concentration of five pesticide residues significantly by 33 to 46%. It was mainly attributed to the increase of moisture content in mixed dough during this step. The reduction of pesticides in fermenting step varied from 2 to 22% in Chinese steamed bun and bread processing. Resting step in both Chinese steamed bun and bread processing has little effect on the pesticide residues with the reduction from 2 to 8%. The five pesticides have different behaviours in steaming step of Chinese steamed bun processing and in baking step of bread processing. During the steaming step, only the concentrations of triadimefon and imidacloprid residues in crust were increased by 52 and 1%, the others in crust and in crumb of Chinese steamed bun were decreased by 4 to 38%. After the baking step, the concentrations of triadimefon and imidacloprid residues in crust, and the triadimefon residue in crumb of bread were increased by 65, 83, and 14%, respectively, the others were all reduced. The processing factors (PFs) for triadimefon and imidacloprid in crust in the steaming and baking steps, for triadimefon in crumb in the baking steps were greater than 1, and the others were all less than 1. Overall, this study provides important references for monitoring pesticide residues in the processing of wheat flour products. The PFs obtained could be helpful for the risk assessment of pesticides in wheat flour products.

关键词： Wheat flour Chinese steamed bun Bread pesticide Processing factor

Electrocatalytic degradation of pesticide micropollutants in water by high energy pulse magnetron sputtered Pt/Ti anode

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Chinese Chemical Letters 2022年第12期33卷 5196-5199页

作者： Yuxin Zeng Siyao Zhang Lifeng Yin Yunrong Dai School of Environment Beijing Normal UniversityBeijing 100875China School of Water Resources and Environment China University of Geosciences(Beijing)Beijing 100083China

The increasing occurrence of pesticide micropollutants highlights the need for innovative water treatment technologies,particularly for small-community and household ***-oxidation is being widely studied in this area,unfortunately,safe,stable and efficient electrocatalytic anodes without released heavy metal ions are still highly *** this study,we fabricated a Pt/Ti anode by high energy pulse magnetron sputtering(HiPIMS-PtTi)which was used to decompose dichlorvos(DDVP)and azoxystrobin(AZX)in *** results show that the reaction rate constant(kENR)on HIPIMS was 35.7 min-1(DDVP)and 41.3 min-1(AZX),respectively,superior to electroplating Pt/Ti anode(EP-PtTi).The identification of radicals(^(·)OH,^(1)O_(2),^(·)O_(2)-)and micro-area analyses evidenced that Pt atoms were embedded into the TiO_(2) lattice on the surface of Ti plate by high-energy ions,which resulted in more adsorbed hydroxyls,and higher production of·OH under polarization ***,the electro-oxidation intermediates of DDVP and AZX were identified and the degradation pathways were speculated:(1)indirect oxidation dominated by·OH attack,and(2)direct electron transfer reaction of pesticides on the anode *** cooperated reactions achieve the complete degradation and highly efficient mineralization of DDVP and AZX.

关键词： Electrocatalysis Magnetron sputtering pesticide Degradation mechanism Dichlorvos Azoxystrobin

Reprogramming of phytopathogen transcriptome by a non-bactericidal pesticide residue alleviates its virulence in rice

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Fundamental Research 2022年第2期2卷 198-207页

作者： Haruna Matsumoto Yuan Qian Xiaoyan Fan Sunlu Chen Yanxia Nie Kun Qiao Dandan Xiang Xinzhong Zhang Meng Li Bo Guo Peilin Shen Qiangwei Wang Yunlong Yu Tomislav Cemava Mengcen Wang State Key Laboratory of Rice Biology&Ministry of Agricultural and Rural Affairs Laboratory of Molecular Biology of Crop Pathogens and Insects Institute of Pesticide and Environmental ToxicologyZhejiang UniversityHangzhou 310058China Key Laboratory of Biology of Crop Pathogens and Insects of Zhejiang Province College of Agriculture and BiotechnologyZhejiang UniversityHangzhou 310058China Institute of Environmental Biotechnology Graz University of TechnologyPetersgasse 128010 GrazAustria Global Education Program for AgriScience Frontiers Graduate School of AgricultureHokkaido UniversitySapporo 0608589Japan State Key Laboratory of Crop Genetics and Germplasm Enhancement Nanjing Agricultural UniversityNanjing 210095China Ecology and Environmental Sciences Center South China Botanical GardenChinese Academy of SciencesGuangzhou 510650China Key laboratory of South Subtropical Fruit Biology and Genetic Resource Uilization(MOA) Instiute of Fruit Tree ResearchGuangdong Acadermy of Agricultural SciencesGuangzhou 510640China Tea Research Instiute Chinese Academy of Agriculural SciencesHangzhou 310008China Shanghai Intermnational Studies University Shanghai 200083China Xiaoshan Agricultural Comprehensive Development Zone&Management Committee Hangzhou 311200China

Bacteria equipped with virulence systems based on highly bioactive small molecules can circumvent their host's defense *** employing this strategy are currently threatening global rice *** the present study,variations in the virulence of the highly destructive Barkholderiaplantarii were observed in different rice-producing *** environment-linked variation was not attributable to any known host-related or external ***-occurrence analyses indicated a connection between reduced virulence and 5-Amino-l,3,4-thiadiazole-2-thiol(ATT),a non-bactericidal organic ***,which accumulates in rice plants during metabolization of specific agrochemicals,was found to reduce virulence factor secretion by *** up to 88.8%and inhibit pathogen virulence by hijacking an upstream signaling *** assessment of the newly discovered virulence inhibitor resulted in mechanistic insights into positive effects of ATT accumulation in plant *** of virulence alleviation were deciphered by integrating high-throughput data,gene knockout mutants,and molecular interaction ***,a histidine protein kinase in a two-component system that regulates virulence factor secretion,is likely the molecular target antagonized by *** findings provide novel insights into virulence modulation in an important plant-pathogen system that relies on the host's metabolic activity and subsequent signaling interference.

关键词： Phytopathogen Virulence factor Transcriptome reprogramming Agrochemical pesticide Rice

pesticide wastewater treatment using the combination of the microbial electrolysis desalination and chemical-production cell and Fenton process

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Frontiers of Environmental Science & Engineering 2020年第1期14卷 137-151页

作者： Songwei Lin Yaobin Lu Bo Ye Cuiping Zeng Guangli Liu Jieling Li Haiping Luo Renduo Zhang Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology School of Environmental Science and EngineeringSun Yat-sen UniversityGuangzhou 510006China

The combination of the microbial electrolysis desalination and chemical-production cell(MEDCC)and Fenton process for the pesticide wastewater treatment was investigate in this *** wastewater with several toxic pesticides,1633 mg/L COD,and 200 in chromaticity was used for the *** showed that desalination in the desalination chamber of MEDCC reached 78%.Organics with low molecular weights in the desalination chamber could be removed from the desalination chamber,resulting in 28%and 23%of the total COD in the acid-production and cathode chambers,*** desalination in the desalination chamber and organic transfer contributed to removal of pesticides(e.g.,triadimefon),which could not be removed with other methods,and of the organics with low molecular *** COD in the effluent of the MEDCC combined the Fenton process was much lower than that in the perixo-coagulaiton process(<150 vs.555 mg/L).The combined method consumed much less energy and acid for the pH adjustment than that the Fenton.

关键词： pesticide wastewater COD removal Microbial electrolysis desalination and chemical-production cell Energy consumption Fenton oxidation

pesticide-induced photoluminescence quenching of ultra-small Eu3+-activated phosphate and vanadate nanoparticles

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Journal of Materials Science & Technology 2020年第3期38卷 197-204页

作者： Jovana Perisa Zeljka Antic Chong-Geng Ma Jelena Papan Dragana Jovanovic Miroslav D.Dramicanin Vinca Institute of Nuclear Sciences University of BelgradeP.O.Box 52211001 BelgradeSerbia College of Sciences Chongqing University of Posts and TelecommunicationsChongqing 400065China

The aim of this research was to investigate the luminescent behavior of ultra-small Eu3+-activated phosphate and vanadate nanoparticles in the presence of *** have an average diameter of approximately 2 nm with a narrow size *** monazite crystal structure of phosphate-based particles(space group P121/n1)and single tetragonal zircon-type structure of vanadate-based particles(space group of I41/amd)have been confirmed using X-ray diffraction *** synthesized Eu3+-activated colloidal nanoparticles show sharp emission peaks in the red spectral *** measurements revealed emission quenching upon addition of millimolar concentrations of following pesticides:4-Chloro-2-methyl-phenoxyacetic acid(MCPA),2,4-Dichlorophenoxyacetic acid(2,4-D)and N-(phosphonomethyl)glycine(Glyphosate).In both phosphate and vanadate-based colloidal nanoparticles luminescence quenching is more evident in the presence of 2,4-D pesticide with the lowest limit of detection(0.7μM)obtained for phosphate-based nanoparticles.

关键词： Phosphate/vanadate based colloidal nanoparticles Eu3+ Emission quenching pesticide

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pesticide pollution

Journal of Environmental Sciences 1991年第3期3卷 31-47页

作者： Shen Baocheng (Bozen Sun) and Shen QiResearch Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100083,ChinaResearch Center for Science of Sciences,City Commission of Science and Technology,Beijing,China

This is the first half of a review article, which deals with merits and demerits in many aspects of using pesticides, particularly in China for years. The second half published elsewhere continues to discuss about Treatment of pesticide Wastewater, Special Mention of BHC and DDT, a Case Study of Metropolitan Beijing, and Regula-tions, Standards promulgated lately. This is a review of its kind in English for a time, complete and comprehensive, that a glimpse of it will let you understand the past, present and future of the pesticide pollution situation and measures taken in this country.

关键词： pesticide pollution environment.

Photoelectrocatalytic degradation of high COD dipterex pesticide by using TiO_2 /Ni photo electrode

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Journal of Environmental Sciences 2012年第6期24卷 1149-1156页

作者： Tao Fang Chao Yang Lixia Liao The State Key Lab of Urban Water Resource and Environment National Engineering Research Center of Urban Water Resource&The Academy of Fundamental and Interdisciplinary ScienceHarbin Institute of TechnologyHarbin 150080China College of Science Northeast Forestry UniversityHarbin 150040China

A TiO2 thin film electrode deposited on porous nickel net （TiO2/Ni） was prepared by the sol-gel method, and the surface morphology, crystal structure features and the grain size were characterized by Field emission scan electron microscopy （FESEM） and X-ray diffraction （XRD）. The photoelectrocatalytic system was set up using a UV high-pressure mercury lamp as the light source, TiO2 coated on foamed nickel as photo anode, Pt sheet as counter electrode and the pesticide dipterex in synthetic wastewater. Various factors that influence the photoelectrocatalytic decomposition of dipterex pesticide have been studied, such as degradation time, the type of electrolyte, current density, original pH value and different degradation methods. The prepared catalysts were employed to photoelectrocatalytically degrade the pesticide dipterex under UV irradiation, comparing the results with photocatalytic degradation and electrochemical oxidation. The results indicated that under the optimal conditions of 0.02 mol/L NaC1 as the supporting electrolyte, current density = 2.5 mA/cm^2, pH 6.0 and dipterex pesticide 40 mg/L, and reaction time 2 hr, dipterex chemical oxygen demand （COD） removal rate and organophosphorous conversion of up to 82.6% and 83.5% were achieved, respectively. The method of photoelectrocatalytic degradation is more efficient than photocatalysis and electrochemical oxidation. The possible roles of the electrolytes on the reactions and probable mechanisms were also discussed.

关键词： photoelectrocatalysis COD removal TiO2 dipterex pesticide