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Advances and challenges of methanol-tolerant oxygen reduction reaction electrocatalysts for the direct methanol fuel cell

引用

Journal of Energy Chemistry 2023年第2期77卷 499-513,I0013页

作者： Muhammad Aizaz Ud Din Muhammad Idrees Sidra Jamil Syed Irfan Ghazanfar Nazir Muhammad Ahmad Mudassir Muhammad Shahrukh Saleem Saima Batool Nanpu Cheng Rahman Saidur School of Materials and Energy Southwest UniversityChongqing 400715China Additive Manufacturing Institute College of Mechatronics and Control EngineeringShenzhen UniversityShenzhen 518060GuangdongChina Chongqing Key Lab for Advanced Materials and Clean Energies of Technologies School of Materials and EnergySouthwest UniversityChongqing 400715China School of Materials Science and Engineering Dongguan University of TechnologyDongguan 523808GuangdongChina Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006Republic of Korea Department of Chemistry Khawaja Fareed University of Engineering and Information TechnologyRahim Yar Khan 64200Pakistan Laboratory for High Performance Ceramics EmpaSwiss Federal Laboratories for Materials Science and Technology8600 DübendorfSwitzerland Institute for Advanced Study Shenzhen UniversityShenzhen 518060GuangdongChina Research Centre for Nano-Materials and Energy Technology School of Engineering and TechnologySunway UniversityBandar SunwayMalaysia Department of Engineering Lancaster UniversityLancasterUnited Kingdom

methanol cross-over effects from the anode to the cathode are important parameters for reducing catalytic performance in direct methanol fuel cells.A promising candidate catalyst for the cathode in direct methanol fuel cells must have excellent activity toward oxygen reduction reaction and resistance to methanol oxidation *** review focuses on the methanol tolerant noble metal-based electrocatalysts,including platinum and palladium-based alloys,noble metal–carbon based composites,transition metal-based catalysts,carbon-based metal catalysts,and metal-free *** understanding of the correlation between the activity and the synthesis method,electrolyte environment and stability issues are *** the transition metal-based catalyst,their activity,stability and methanol tolerance in direct methanol fuel cells and comparisons with those of platinum are particularly ***,strategies to enhance the methanol tolerance and hinder the generation of mixed potential in direct methanol fuel cells are also *** review provides a perspective for future developments for the scientist in selecting suitable methanol tolerate catalyst for oxygen reduction reaction and designing high-performance practical direct methanol fuel cells.

关键词： Oxygen reducing reaction methanol tolerant electrocatalyst Portable power sources Direct methanol Fuel cell

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