Advances and challenges of methanol-tolerant oxygen reduction reaction electrocatalysts for the direct methanol fuel cell

作     者：Muhammad Aizaz Ud Din Muhammad Idrees Sidra Jamil Syed Irfan Ghazanfar Nazir Muhammad Ahmad Mudassir Muhammad Shahrukh Saleem Saima Batool Nanpu Cheng Rahman Saidur Muhammad Aizaz Ud Din;Muhammad Idrees;Sidra Jamil;Syed Irfan;Ghazanfar Nazir;Muhammad Ahmad Mudassir;Muhammad Shahrukh Saleem;Saima Batool;Nanpu Cheng;Rahman Saidur

作者机构：School of Materials and EnergySouthwest UniversityChongqing 400715China Additive Manufacturing InstituteCollege of Mechatronics and Control EngineeringShenzhen UniversityShenzhen 518060GuangdongChina Chongqing Key Lab for Advanced Materials and Clean Energies of TechnologiesSchool of Materials and EnergySouthwest UniversityChongqing 400715China School of Materials Science and EngineeringDongguan University of TechnologyDongguan 523808GuangdongChina Department of Nanotechnology and Advanced Materials EngineeringSejong UniversitySeoul 05006Republic of Korea Department of ChemistryKhawaja Fareed University of Engineering and Information TechnologyRahim Yar Khan 64200Pakistan Laboratory for High Performance CeramicsEmpaSwiss Federal Laboratories for Materials Science and Technology8600 DübendorfSwitzerland Institute for Advanced StudyShenzhen UniversityShenzhen 518060GuangdongChina Research Centre for Nano-Materials and Energy TechnologySchool of Engineering and TechnologySunway UniversityBandar SunwayMalaysia Department of EngineeringLancaster UniversityLancasterUnited Kingdom 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2023年第77卷第2期

页      面：499-513,I0013页

核心收录：

学科分类：0808[工学-电气工程] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the National Natural Science Foundations of China(22150410340) the Chongqing Science&Technology Commission(catc2018jcyjax0582) 

主　　题：Oxygen reducing reaction Methanol tolerant electrocatalyst Portable power sources Direct methanol Fuel cell 

摘      要：Methanol cross-over effects from the anode to the cathode are important parameters for reducing catalytic performance in direct methanol fuel cells.A promising candidate catalyst for the cathode in direct methanol fuel cells must have excellent activity toward oxygen reduction reaction and resistance to methanol oxidation *** review focuses on the methanol tolerant noble metal-based electrocatalysts,including platinum and palladium-based alloys,noble metal–carbon based composites,transition metal-based catalysts,carbon-based metal catalysts,and metal-free *** understanding of the correlation between the activity and the synthesis method,electrolyte environment and stability issues are *** the transition metal-based catalyst,their activity,stability and methanol tolerance in direct methanol fuel cells and comparisons with those of platinum are particularly ***,strategies to enhance the methanol tolerance and hinder the generation of mixed potential in direct methanol fuel cells are also *** review provides a perspective for future developments for the scientist in selecting suitable methanol tolerate catalyst for oxygen reduction reaction and designing high-performance practical direct methanol fuel cells.