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Recent progress in COF-based electrode materials for rechargeable metal-ion batteries

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Nano Research 2023年第5期16卷 6753-6770页

作者： Shunhang Wei Jiwei Wang Yuzhao Li Zebo Fang Lei Wang Yuxi Xu Zhejiang Engineering Research Center of MEMS Shaoxing UniversityShaoxing 312000China School of Engineering Westlake UniversityHangzhou 310024China School of Mechatronics Engineering and Automation Foshan UniversityFoshan 528225China Department of Chemistry Binghamton UniversityBinghamtonNew York 13902USA China Electronics Corporation Beijing 100086China

Covalent organic frameworks(COFs)have emerged as promising electrode materials for rechargeable metal-ion batteries and have gained much attention in recent years due to their high specific surface area,inherent porosity,tunable molecular structure,robust framework,abundant active ***,compared with inorganic materials and small organic molecules,COFs have the advantages of multi-electron transfer,short pathways,high cycling *** great progress on COF-based electrodes has been made,the corresponding electrochemical performance is still far from satisfactory for practical *** this review,we first summarize the fundamental background of COFs,including the species of COFs(different active covalent bonds)and typical synthesis methods of ***,the key challenges and the latest research progress of COF-based cathodes and anodes for metal-ion batteries are reviewed,including Li-ion batteries,Na-ion batteries,K-ion batteries,Zn-ion batteries,et ***,the effective strategies to enhance electrochemical performance of COF-based electrodes are ***,this review also covers the typical superiorities of COFs used in energy devices,as well as providing some perspectives and outlooks in this *** hope this review can provide fundamental guidance for the development of COFbased electrodes for metal-ion batteries in the further research.

关键词： covalent organic frameworks metal-ion batteries electrochemical performance synthetic methods structure–property relationship

Electrolytic alloy-type anodes for metal-ion batteries

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Rare metals 2021年第2期40卷 329-352页

作者： Xian-Yang Li Jia-Kang Qu Hua-Yi Yin Key Laboratory for Ecological metallurgy of Multimetallic Mineral of Ministry of Education School of MetallurgyNortheastern UniversityShenyang110819China Key Laboratory of Data Analytics and Optimization for Smart Industry Ministry of EducationNortheastern UniversityShenyang110819China

Alloy-type metals/alloys hold the promise of increasing the energy density of metal-ion batteries(MIBs)because of their theoretical high gravimetrical *** and semimetal-analogs are typical alloy-type ***,the large-scale extraction of semimetals(Si,Ge)and semimetal-analogs(Sb,Bi,Sn)by traditional metallurgical routes highly relies on using reducing agents(e.g.,carbon,hydrogen,reactive metals),which consumes a large number of fossil fuels and produces greenhouse gas *** addition,the common metallurgical methods for extracting semimetals involve relatively high operating temperatures and therefore produce bulk metal ingots solidified from the liquid ***,the commonly used electrode materials in batteries are fine ***,directly producing semimetal powders would be more energy *** addition,semimetals are good candidates to host alkali/alkaline-earth ions through the alloying process because the electronegativity of semimetals is ***,preparing semimetal powders via an environment-sound manner is of great interest to provide sustainable anode materials for MIBs while reducing the ecological ***-cost and high-output capacity anode powder materials,as well as straightforward and environmental-benign synthetic methods,play key roles in enabling the energy conversion and storage technologies for real applications of *** technologies offer new strategies to extract semimetals using electrons as the reducing agent that comes from renewable ***,the morphologies and structures of the electrolytic products can be rationally tailored by tuning the electrode potentials,electrolytes,and operating *** this regard,using the one-step green electrochemical method to prepare high-capacity and cheaper alloy-type metalloids for MIB anodes can fulfill the requirements for developing *** review critically overviews recent developments and advances in the elect

关键词： Electrochemical extraction Alloy-type anodes metal-ion batteries Manufacture strategies Morphologies and structures

Covalent organic frameworks as electrode materials for rechargeable metal-ion batteries

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Interdisciplinary Materials 2023年第2期2卷 231-259页

作者： Manman Wu Zhen Zhou School of Chemical Engineering Zhengzhou UniversityZhengzhouHenanChina

Covalent organic frameworks(COFs),as a class of crystalline porous polymers,featuring designable structures,tunable frameworks,well-defined channels,and tailorable functionalities,have emerged as promising organic electrode materials for rechargeable metal-ion batteries in recent *** efforts have been devoted to improving the electrochemical performance of ***,although significant achievements have been made,the electrochemical behaviors of developed COFs are far away from the desirable performance for practical batteries owing to intrinsic problems,such as poor electronic conductivity,the trade-off relationship between capacity and redox potential,and unfavorable *** this review,the recent progress in the development of COFs for rechargeable metal-ion batteries is presented,including Li,Na,K,and Zn ion *** research strategies for improving the electrochemical performance of COFs are summarized in terms of the molecular-level design and the material-level ***,the major challenges and perspectives of COFs are also discussed in the aspect of large-scale production and electrochemical performance improvements.

关键词： covalent organic frameworks electrode materials material-level modification metal-ion batteries molecular-level design

Carbon materials for metal-ion batteries

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ChemPhysMater 2023年第4期2卷 267-281页

作者： Zhong Qiu Feng Cao Guoxiang Pan Chen Li Minghua Chen Yongqi Zhang Xinping He Yang Xia Xinhui Xia Wenkui Zhang College of Materials Science&Engineering Zhejiang University of TechnologyHangzhou 310014China Department of Engineering Technology Huzhou CollegeHuzhou 313000China Department of Materials Engineering Huzhou UniversityHuzhou 313000China Institute of Fundamental and Frontier Science University of Electronic Science and Technology of ChinaChengdu 611371China Key Laboratory of Engineering Dielectric and Applications(Ministry of Education) School of Electrical and Electronic EngineeringHarbin University of Science and TechnologyHarbin 150080China State Key Laboratory of Silicon Materials Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang ProvinceDepartment of Materials Science and EngineeringZhejiang UniversityHangzhou 310027China

metal-ion(Li-,Na-,Zn-,K-,Mg-,and Al-ion)batteries(MIBs)play an important role in realizing the goals of“emission peak and carbon neutralization”because of their green production techniques,lower pollution,high voltage,and large energy ***-based materials are indispensable for developing MIBs and are widely adopted as active or auxiliary materials in the anodes and *** example,carbon-based materials,includ-ing graphite,Si/C and hard carbon,have been used as anode materials for Li-and Na-ion *** can also be used as a conductive coating for cathodes,such as in LiFePO 4/C,to achieve better *** addition,as new high-valence MIBs(Zn-,Al-,and Mg-ion)have emerged,a growing number of novel carbon-based mate-rials have been utilized to construct high-performance ***,we discuss the recent development trends in advanced carbon-based materials for *** impact of the structure properties of advanced carbon-based materials on energy storage is addressed,and a perspective on their development is also proposed.

关键词： Carbon materials Electrochemical energy storage metal-ion batteries Lithium-ion batteries Sodium-ion batteries

Self-healing Ga-based liquid metal/alloy anodes for rechargeable batteries

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Nano Research 2024年第3期17卷 1366-1383页

作者： Meijia Song Zhonghua Zhang School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212000China Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials(Ministry of Education) School of Materials Science and EngineeringShandong UniversityJingshi Road 17923Jinan 250061China

With the rapid development of electronics,electric vehicles,and grid energy storage stations,higher requirements have been put forward for advanced secondary *** metal/alloy electrodes have been considered as a promising development direction to achieve excellent electrochemical performance in metal-ion batteries,due to their specific advantages including the excellent electrode kinetics and self-healing ability against microstructural electrode *** conventional liquid batteries,high temperatures are needed to keep electrode liquid and ensure the high conductivity of molten salt electrolytes,which also brings the corrosion and safety ***-based metal/alloys,which can be operated at or near room temperature,are potential candidates to circumvent the above *** this review,the properties and advantages of Ga-based metal/alloys are ***,Ga-based liquid metal/alloys as anodes in various metal-ion batteries are reviewed in terms of their self-healing ability,battery configurations,working mechanisms,and so ***,some views on the future development of Ga-based electrodes in batteries are provided.

关键词： metal-ion batteries Ga-based liquid metal/alloy anodes self-healing capability room temperature

MoS_(2)/MoO_(2) nanosheets anchored on carbon cloth for high-performance magnesium-and sodium-ion storage

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Journal of Materials Science & Technology 2023年第12期143卷 43-53页

作者： Hui Wu Zhennan Xiong Yiyang Mao Huihui Zhang Yingying Hu Jun Shen Baofeng Wang Xuebin Yu Department of Materials Science Fudan UniversityShanghai 200433China Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power Shanghai University of Electric PowerShanghai 200090China

Developing new types of rechargeable metal-ion batteries beyond lithium-ions,including alkaline ion(such as Na+,K+)and multivalent ion(such as Mg 2+,Zn 2+,Ca 2+and Al 3+)batteries,is progressing quickly towards large-scale energy storage ***,the major obstacle to their large-scale applications has been a lack of appropriate electrode materials with reversible metal ions insertion/extraction be-havior,resulting in inferior electrochemical *** we develop a well-designed MoS_(2)/MoO_(2) hybrid nanosheets anchored on carbon cloth(MoS_(2)/MoO_(2)/CC)as electrode *** rational de-sign can effectively shorten ion diffusion distance,increase electric conductivity of the electrode,and buffer volume *** from the synergistic effect of structural and compositional features,the MoS_(2)/MoO_(2)/CC electrode exhibits high initial reversible capacities(326 mA h g^(−1) at 0.1 A g^(−1) in magnesium-ion storage;1270 mA h g^(−1) at 0.1 A g^(−1) in sodium-ion storage),excellent rate capacities(57 mA h g^(−1) at 10 A g^(−1) in magnesium-ion storage;335 mA h g^(−1) at 5 A g^(−1) in sodium-ion storage)and long-term cycling stability(105 mA h g^(−1) after 600 cycle at 1 A g^(−1) in magnesium-ion storage;208 mA h g^(−1) after 600 cycles at 5 A g^(−1) in sodium-ion storage).We expect that the multi-engineering strategy will provide some valuable insights for the development of other advanced electrode materials for high-performance metal-ion batteries.

关键词： metal-ion batteries MoS_(2)/MoO_(2)/CC Magnesium and sodium storage High reversibility

DFT‑Guided Design and Fabrication of Carbon‑Nitride‑Based Materials for Energy Storage Devices:A Review

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Nano-Micro Letters 2021年第1期13卷 245-288页

作者： David Adekoya Shangshu Qian Xingxing Gu William Wen Dongsheng Li Jianmin Ma Shanqing Zhang Centre for Clean Environment and Energy School of Environment and ScienceGriffith UniversityGold Coast CampusGold CoastQLD 4222Australia College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion MaterialsChina Three Gorges UniversityYichang 443002People’s Republic of China Key Laboratory of Materials Processing and Mold(Zhengzhou University) Ministry of EducationZhengzhouPeople’s Republic of China

Carbon nitrides(including CN,C2N,C3N,C3N4,C4N,and C5N)are a unique family of nitrogen-rich carbon materials with multiple beneficial properties in crystalline structures,morphologies,and electronic *** this review,we provide a comprehensive review on these materials properties,theoretical advantages,the synthesis and modification strategies of different carbon nitride-based materials(CNBMs)and their application in existing and emerging rechargeable battery systems,such as lithium-ion batteries,sodium and potassium-ion batteries,lithium sulfur batteries,lithium oxygen batteries,lithium metal batteries,zinc-ion batteries,and solid-state *** central theme of this review is to apply the theoretical and computational design to guide the experimental synthesis of CNBMs for energy storage,i.e.,facilitate the application of first-principle studies and density functional theory for electrode material design,synthesis,and characterization of different CNBMs for the aforementioned rechargeable *** last,we conclude with the challenges,and prospects of CNBMs,and propose future perspectives and strategies for further advancement of CNBMs for rechargeable batteries.

关键词： Carbon nitrides metal-ion batteries Density functional theory g-C3N4 Anode

2020 roadmap on two-dimensional materials for energy storage and conversion

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Chinese Chemical Letters 2019年第12期30卷 2053-2064页

作者： Baolin Xu Shihan Qi Mengmeng Jin Xiaoyi Cai Linfei Lai Zhouting Sun Xiaogang Han Zifeng Lin Hui Shao Peng Peng Zhonghua Xiang Johan E.ten Elshof Rou Tan Chen Liu Zhaoxi Zhang Xiaochuan Duan Jianmin Ma School of Physics and Electronics Hunan UniversityChangsha 410082China Key Laboratory of Flexible Electronics&Institute of Advanced Materials(IAM) Jiangsu National Synergistic Innovation Center for Advanced Materials(SICAM)Nanjing Tech UniversityNanjing 210009China School of Physical and Mathematical Sciences Nanyang Technological UniversitySingapore 637371Singapore State Key Lab of Electrical Insulation and Power Equipment Xi'an Jiaotong UniversityXi'an 710049China College of Materials Science and Engineering Sichuan UniversityChengdu 610065China UniversitéPaul Sabatier Laboratoire CIRIMAT UMR CNRS 5085Toulouse 31062France Réseau sur le Stockage Electrochimique de l’Energie(RS2E) CNRS 3459AmiensFrance State Key Laboratory of Organic–Inorganic Composites Beijing University of Chemical TechnologyBeijing 100029China University of Twente AE Enschede 7500the Netherlands Pen-Tung Sah Institute of Micro-Nano Science and Technology Xiamen UniversityXiamen 361005China Key Laboratory of Materials Processing and Mold(Zhengzhou University) Ministry of EducationZhengzhou UniversityZhengzhou 450002China

Energy storage and conversion have attained significant intere st owing to its important applications that reduce CO2 emission through employing green *** promising technologies are included metalair batteries,metal-sulfur batteries,metal-ion batteries,electrochemical capacitors,***,metal elements are involved with lithium,sodium,and *** these devices,electrode materials are of importance to obtain high ***-dimensional(2 D) materials are a large kind of layered structured materials with promising future as energy storage materials,which include graphene,black phosporu s,MXenes,covalent organic frameworks(COFs),2 D oxides,2 D chalcogenides,and *** progress has been achieved to go ahead for 2 D materials in energy storage and *** researchers will join in this research *** the background,it has motivated us to contribute with a roadmap on ’two-dimensional materials for energy storage and conversion.

关键词： Graphene Black phosphorus MXenes Covalent organic frameworks Oxides Chalcogenides metal-air batteries metal-sulfur batteries metal-ion batteries Electrochemical capacitors

2020 roadmap on pore materials for energy and environmental applications

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Chinese Chemical Letters 2019年第12期30卷 2110-2122页

作者： Zengxi Wei Bing Ding Hui Dou Jorge Gascon Xiang-Jian Kong Yujie Xiong Bin Cai Ruiyang Zhang Ying Zhou Mingce Long Jie Miao Yuhai Dou Ding Yuan Jianmin Ma School of Physics and Electronics Hunan UniversityChangsha 410082China Jiangsu Key Laboratory of Electrochemical Energy-Storage Technologies College of Materials Science and TechnologyNanjing University of Aeronautics and AstronauticsNanjing 210016China King Abdullah University of Science and Technology KAUST Catalysis Center(KCC)Advanced Catalytic MaterialsThuwal 23955Saudi Arabia State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of ChemistryCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China Hefei National Laboratory for Physical Sciences at the Microscale and School of Chemistry and Materials ScienceUniversity of Science and Technology of ChinaHefei 230026China Physical Science Division Pacific Northwest National LaboratoryRichlandWA 99352United States State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum UniversityChengdu 610500China The Center of New Energy Materials and Technology School of Materials Science and EngineeringSouthwest Petroleum UniversityChengdu 610500China School of Environmental Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China Centre for Clean Environment and Energy Gold Coast CampusGriffith UniversityGold Coast 4222Australia Key Laboratory of Materials Processing and Mold(Zhengzhou University) Ministry of EducationZhengzhou UniversityZhengzhou 450002China

Porous materials have attracted great attention in energy and environment applications,such as metal organic frameworks(MOFs),metal aerogels,carbon aerogels,porous metal *** materials could be also hybridized with other materials into functional composites with superior *** high specific area of porous materials offer them the advantage as hosts to conduct catalytic and electrochemical *** one hand,catalytic reactions include photocatalytic,p ho toe lectrocatalytic and electrocatalytic reactions over some *** the other hand,they can be used as electrodes in various batteries,such as alkaline metal ion batteries and electrochemical *** far,both catalysis and batteries are extremely attractive *** are also many obstacles to overcome in the exploration of these porous *** research related to porous materials for energy and environment applications is at extremely active stage,and this has motivated us to contribute with a roadmap on ’porous materials for energy and environment applications’.

关键词： metal organic frameworks Zeolitic imidazolate frameworks Covalent organic frameworks Aerogels Photocatalysis Photoelectrocatalysis Electrocatalysis metal-ion batteries Electrochemical capacitors