Recent progress in COF-based electrode materials for rechargeable metal-ion batteries

作     者：Shunhang Wei Jiwei Wang Yuzhao Li Zebo Fang Lei Wang Yuxi Xu Shunhang Wei;Jiwei Wang;Yuzhao Li;Zebo Fang;Lei Wang;Yuxi Xu

作者机构：Zhejiang Engineering Research Center of MEMSShaoxing UniversityShaoxing 312000China School of EngineeringWestlake UniversityHangzhou 310024China School of Mechatronics Engineering and AutomationFoshan UniversityFoshan 528225China Department of ChemistryBinghamton UniversityBinghamtonNew York 13902USA China Electronics CorporationBeijing 100086China 

出 版 物：《Nano Research》 (纳米研究（英文版）)

年 卷 期：2023年第16卷第5期

页      面：6753-6770页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China(No.51872186) Project funded by China Postdoctoral Science Foundation(No.2021M702316) Guangdong Basic and Applied Basic Research Foundation(No.2020A1515110999) 

主　　题：covalent organic frameworks metal-ion batteries electrochemical performance synthetic methods structure–property relationship 

摘      要：Covalent organic frameworks(COFs)have emerged as promising electrode materials for rechargeable metal-ion batteries and have gained much attention in recent years due to their high specific surface area,inherent porosity,tunable molecular structure,robust framework,abundant active ***,compared with inorganic materials and small organic molecules,COFs have the advantages of multi-electron transfer,short pathways,high cycling *** great progress on COF-based electrodes has been made,the corresponding electrochemical performance is still far from satisfactory for practical *** this review,we first summarize the fundamental background of COFs,including the species of COFs(different active covalent bonds)and typical synthesis methods of ***,the key challenges and the latest research progress of COF-based cathodes and anodes for metal-ion batteries are reviewed,including Li-ion batteries,Na-ion batteries,K-ion batteries,Zn-ion batteries,et ***,the effective strategies to enhance electrochemical performance of COF-based electrodes are ***,this review also covers the typical superiorities of COFs used in energy devices,as well as providing some perspectives and outlooks in this *** hope this review can provide fundamental guidance for the development of COFbased electrodes for metal-ion batteries in the further research.