检索结果-南通市图书馆

Engineering Thermoelectric Performance of α-GeTe by Ferroelectric Distortion

Energy & Environmental Materials 2024年第2期7卷 171-179页

作者： Yuting Fan Chenghao Xie Jun Li Xiangyu Meng Jinchang Sun Jinsong Wu Xinfeng Tang Gangjian Tan State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China International School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China

The rhombohedralα-GeTe can be approximated as a slightly distorted rock-salt structure along its[111]direction and possesses superb thermoelectric ***,the role of such a ferroelectric-like structural distortion on its transport properties remains ***,we performed a systematic study on the crystal structure and electronic band structure evolutions of Ge_(1-x)Sn_(x)Te alloys where the degree of ferroelectric distortion is continuously *** is revealed that the band gap is maximized while multiple valence bands are converged at x=0.6,where the ferroelectric distortion is the least but still *** undistorted,the band gap is considerably reduced,and the valence bands are largely separated ***,near the ferro-to-paraelectric phase transition Curie temperature,the lattice thermal conductivity reaches its minima because of significant lattice softening enabled by ferroelectric *** predict a peak ZT value of 2.6 at 673 K inα-GeTe by use of proper dopants which are powerful in suppressing the excess hole concentrations but meanwhile exert little influence on the ferroelectric distortion.

关键词： electronic band structures ferroelectric distortion lattice softening thermoelectric α-GeTe

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

巧妙的稀掺杂策略实现高性能GeTe热电材料

引用

Science Bulletin 2024年第8期69卷 1037-1049页

作者：钟锦璇杨晓玉吕途梁格格张胜楠张朝华敖伟琴刘福生南鹏飞葛炳辉胡利鹏 College of Materials Science and Engineering Shenzhen Key Laboratory of Special Functional MaterialsGuangdong Research Center for Interfacial Engineering of Functional MaterialsGuangdong Provincial Key Laboratory of Deep Earth Sciences and Geothermal Energy Exploitation and UtilizationInstitute of Deep Earth Sciences and Green EnergyShenzhen UniversityShenzhen 518060China Information Materials and Intelligent Sensing Laboratory of Anhui Province Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of EducationInstitutes of Physical Science and Information TechnologyAnhui UniversityHefei 230601China Superconducting Materials Research Center Northwest Institute for Nonferrous Metal ResearchXi’an 710016China

In thermoelectrics,doping is essential to augment the figure of *** strategy,predomina ntly heavy doping,aims to optimize carrier concentration and restrain lattice thermal ***,this tactic can severely hamper carrier transport due to pronounced point defect scattering,particularly in materials with inherently low carrier ***,dilute doping,although minimally affecting carrier mobility,frequently fails to optimize other vital thermoelectric ***,we present a more nuanced dilute doping strategy in GeTe,leveraging the multifaceted roles of small-size metal atoms.A mere 4%CuPbSbTe_(3)introduction into GeTe swiftly suppresses rhombohedral distortion and optimizes carrier concentration through the aid of Cu ***,the formation of multiscale microstructures,including zero-dimensional Cu interstitials,one-dimensional dislocations,two-dimensional planar defects,and three-dimensional nanoscale amorphous GeO_(2)and Cu_(2)GeTe_(3)precipitates,along with the ensuing lattice softening,contributes to an ultralow lattice thermal ***,dilute CuPbSbTe_(3)doping incurs only a marginal decrease in carrier *** trace Cd doping,employed to alleviate the bipolar effect and align the valence bands,yields an impressive figure-of-merit of 2.03 at 623 K in(Ge_(0.97)Cd_(0.03)Te)_(0.96)(CuPbSbTe_(3))_(0.04).This leads to a high energyconversion efficiency of 7.9%and a significant power density of 3.44 W cm^(-2)at a temperature difference of 500 *** results underscore the invaluable insights gained into the constructive role of nuanced dilute doping in the concurrent tuning of carrier and phonon transport in GeTe and other thermoelectric materials.

关键词： Thermoelectric GeTe Dilute doping Interstitial atoms lattice softening

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

The Mssbauer Effect of Y-Ba-Cu-Fe-O Superconductive Oxide

引用

Journal of Materials Science & Technology 1989年第6期5卷 434-436页

作者：夏思科马如璋曹国辉李正文冯永荣 University of Science and Technology Beijing China. To whom correspondence should be addressed University of Science and Technology Beijing China

We have studied the Mossbauer effect of YBa_2Cu_(2.88)Fe_(0.12)O_(7-x) superconductive oxide from 78 to 273K. Two minima of recoilless fraction and Debye temperature were found near 110K and 220K. It means that lattice softening happened near these two temperatures. We also observed minima of isomer shift near 110K and quadrupole splitting increase when temperature is lower than 110K. We suggest that lattice softening would lead to the displacement of oxygen atoms. This may be relative to superconductive transition.

关键词： Y-Ba-Cu-Fe-O superconductor Mossbauer effect lattice softening

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：