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High-Voltage and fast-charging Lithium Cobalt Oxide Cathodes: From Key Challenges and Strategies to Future Perspectives

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Engineering 2024年第6期37卷 105-127页

作者： Gongrui Wang Zhihong Bi Anping Zhang Pratteek Das Hu Lin Zhong-Shuai Wu State Key Laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China Dalian National Laboratory for Clean Energy Chinese Academy of SciencesDalian 116023China

Lithium-ion batteries(LIBs)with the“double-high”characteristics of high energy density and high power density are in urgent demand for facilitating the development of advanced portable ***,the lithium ion(Li+)-storage performance of the most commercialized lithium cobalt oxide(LiCoO_(2),LCO)cathodes is still far from satisfactory in terms of high-voltage and fast-charging capabilities for reaching the double-high ***,we systematically summarize and discuss high-voltage and fast-charging LCO cathodes,covering in depth the key fundamental challenges,latest advancements in modification strategies,and future perspectives in this *** and elaborated discussions are first presented on key fundamental challenges related to structural degradation,interfacial instability,the inhomogeneity reactions,and sluggish interfacial *** provide an instructive summary of deep insights into promising modification strategies and underlying mechanisms,categorized into element doping(Li-site,cobalt-/oxygen-site,and multi-site doping)for improved Li+diffusivity and bulkstructure stability;surface coating(dielectrics,ionic/electronic conductors,and their combination)for surface stability and conductivity;nanosizing;combinations of these strategies;and other strategies(i.e.,optimization of the electrolyte,binder,tortuosity of electrodes,charging protocols,and prelithiation methods).Finally,forward-looking perspectives and promising directions are sketched out and insightfully elucidated,providing constructive suggestions and instructions for designing and realizing high-voltage and fast-charging LCO cathodes for next-generation double-high LIBs.

关键词： Lithium cobalt oxide High energy/power density fast-charging High-voltage Lithium-ion battery

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Macroporous Directed and Interconnected Carbon Architectures Endow Amorphous Silicon Nanodots as Low‑Strain and fast‑charging Anode for Lithium‑Ion Batteries

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Nano-Micro Letters 2024年第5期16卷 333-351页

作者： Zhenwei Li Meisheng Han Peilun Yu Junsheng Lin Jie Yu Guangdong Provincial Key Laboratory of Semiconductor Optoelectronic Materials and Intelligent Photonic Systems Shenzhen Engineering Lab for Supercapacitor MaterialsSchool of Material Science and EngineeringHarbin Institute of TechnologyShenzhenUniversity TownShenzhen 518055People’s Republic of China Songshan Lake Materials Laboratory Dongguan Dongguan 523808GuangdongPeople’s Republic of China Department of Mechanical and Energy Engineering Southern University of Science and TechnologyShenzhen 518055People’s Republic of China

Fabricating low-strain and fast-charging silicon-carbon composite anodes is highly desired but remains a huge challenge for lithium-ion ***,we report a unique silicon-carbon composite fabricated by uniformly dis-persing amorphous Si nanodots(SiNDs)in carbon nanospheres(SiNDs/C)that are welded on the wall of the macroporous carbon framework(MPCF)by vertical graphene(VG),labeled as MPCF@VG@SiNDs/*** high dispersity and amor-phous features of ultrasmall SiNDs(~0.7 nm),the flexible and directed electron/Li+transport channels of VG,and the MPCF impart the MPCF@VG@SiNDs/C more lithium storage sites,rapid Li+transport path,and unique low-strain property during Li+***,the MPCF@VG@SiNDs/C exhibits high cycle stability(1301.4 mAh g^(-1) at 1 A g^(-1) after 1000 cycles without apparent decay)and high rate capacity(910.3 mAh g^(-1),20 A g^(-1))in half cells based on industrial electrode *** assembled pouch full cell delivers a high energy density(1694.0 Wh L^(-1);602.8 Wh kg^(-1))and an excellent fast-charging capability(498.5 Wh kg^(-1),charging for 16.8 min at 3 C).This study opens new possibilities for preparing advanced silicon-carbon com-posite anodes for practical applications.

关键词： Amorphous Si nanodots Low-strain fast-charging Lithium-ion batteries

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Revealing the key role of non-solvating diluents for fast-charging and low temperature Li-ion batteries

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Journal of Energy Chemistry 2024年第7期94卷 171-180页

作者： Yuping Zhang Siyin Li Junkai Shi Jiawei Lai Ziyue Zhuang Jingwen Liu Wenming Yang Liang Ma Yue-Peng Cai Jijian Xu Qifeng Zheng School of Chemistry Guangzhou Key Laboratory of Materials for Energy Conversion and StorageSouth China Normal UniversityGuangzhou 510006GuangdongChina Guangzhou Foreign Language School Guangzhou 511455GuangdongChina Department of Chemistry City University of Hong KongHong Kong 999077China

fast-charging and low temperature operation are of vital importance for the further development of lithium-ion batteries(LIBs),which is hindered by the utilization of conventional carbonate-based electrolytes due to their slow kinetics,narrow operating temperature and voltage ***,an acetonitrile(AN)-based localized high-concentration electrolyte(LHCE)is proposed to retain liquid state and high ionic conductivity at ultra-low temperatures while possessing high oxidation *** originally reveal the excellent thermal shielding effect of non-solvating diluent to prevent the aggregation of Li^(+) solvates as temperature drops,maintaining the merits of fast Li transport and facile desolvation as at room temperature,which bestows the graphite electrode with remarkable low temperature performance(264 mA h g^(-1) at-20 C).Remarkably,an extremely high capacity retention of 97%is achieved for high-voltage high-energy graphite||NCM batteries after 250 cycles at-20 C,and a high capacity of 110 mA h g^(-1)(71%of its room-temperature capacity)is retained at-30°*** study unveils the key role of the non-solvating diluents and provides instructive guidance in designing electrolytes towards fast-charging and low temperature LIBs.

关键词： Li-ion battery fast-charging Low temperature Non-solvating diluent Shielding effect

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Hybrid ion/electron interfacial regulation stabilizes the cobalt/oxygen redox of ultrahigh-voltage lithium cobalt oxide for fast-charging cyclability

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Science Bulletin 2024年第13期69卷 2071-2079页

作者： Zhihong Bi Anping Zhang Gongrui Wang Cong Dong Pratteek Das Xiaoyu Shi Zhong-Shuai Wu State Key Laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China University of Chinese Academy of Sciences Beijing 100049China Dalian National Laboratory of Clean Energy Chinese Academy of SciencesDalian 116023China

High-voltage and fast-charging LiCoO_(2)(LCO)is key to high-energy/power-density Li-ion ***,unstable surface structure and unfavorable electronic/ionic conductivity severely hinder its high-voltage fast-charging ***,we construct a Li/Na-B-Mg-Si-O-F-rich mixed ion/electron interface network on the 4.65 V LCO electrode to enhance its rate capability and long-term cycling ***,the resulting artificial hybrid conductive network enhances the reversible conversion of Co^(3+)/^(4+)/O_(2)/nredox by the interfacial ion–electron cooperation and suppresses interface side reactions,inducing an ultrathin yet compact cathode electrolyte ***,the derived near-surface Na+/Mg2+/Si^(4+)-pillared local intercalation structure greatly promotes the Li^(+)diffusion around the 4.55 V phase transition and stabilizes the cathode ***,excellent 3 C(1 C=274 mA g1)fast charging performance is demonstrated with 73.8%capacity retention over 1000 *** findings shed new insights to the fundamental mechanism of interfacial ion/electron synergy in stabilizing and enhancing fast-charging cathode materials.

关键词： High-voltage fast-charging LiCoO_(2) Interfacial ion-electron cooperation Local intercalation

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Regulating the growth of lithium dendrite by coating an ultra-thin layer of gold on separator for improving the fast-charging ability of graphite anode

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Journal of Energy Chemistry 2022年第4期31卷 467-473页

作者： Shuaishuai Yan Xiaoxia Chen Pan Zhou Peican Wang Hangyu Zhou Weili Zhang Yingchun Xia Kai Liu The State Key Laboratory of Chemical Engineering Department of Chemical EngineeringTsinghua UniversityBeijing 100084China

With the ever-growing application of lithium-ion batteries(LIBs), their fast-charging technology has attracted great interests of scientists. However, growth of lithium dendrites during fast charge of the bat teries with high energy density may pose great threats to the operation and cause serious safety issues Herein, we prepared a functional separator with an ultra-thin(20 nm) layer of Au nanoparticles deposited by evaporation coating method which could regulate growth direction and morphology of the lithium dendrites, owing to nearly zero overpotential of lithium meal nucleation on lithiated Au. Once the Li den drites are about to form on the graphite anode during fast charging(or lithiation), they plate predomi nantly on the Au deposited separator rather than on the graphite. Such selective deposition does no compromise the electrochemical performance of batteries under normal cycling. More importantly, i enables the better cycling stability of batteries at fast charge condition. The Li/Graphite cells with Au nanoparticles coated separator could cycle stably with a high areal capacity retention of 90.5% over 95 cycles at the current density of 0.72 m A cm^(-2). The functional separator provides an effective strategy to adjust lithium plating position at fast charge to ensure high safety of batteries without a compromise on the energy density of LIBs.

关键词： fast-charging Functional separator Lithium-ion batteries Dendrites Safety

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Mechanoadaptive morphing gel electrolyte enables flexible and fast-charging Zn-ion batteries with outstanding dendrite suppression performance

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Nano Research 2022年第3期15卷 2030-2039页

作者： Faqing Cao Baohu Wu Tianyu Li Shengtong Sun Yucong Jiao Peiyi Wu State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Chemistry Chemical Engineering and Biotechnology&Center for Advanced Low-dimension MaterialsDonghua UniversityShanghai 201620China Jülich Centre for Neutron Science(JCNS)at Heinz Maier-Leibnitz Zentrum(MLZ)Forschungszentrum Jülich Lichtenbergstr.185748 GarchingGermany Division of Energy Storage Dalian National Laboratory for Clean EnergyDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China

The safe,flexible,and environment-friendly Zn-ion batteries have aroused great interests ***,flagrant Zn dendrite uncontrollably grows in liquid electrolytes due to insufficient surface protection,which severely impedes the future applications of Zn-ion batteries especially at high current *** electrolytes are emerging to tackle this issue,yet the required high modulus for inhibiting dendrite growth as well as concurrent poor interfacial contact with roughened Zn electrodes are not easily reconcilable to regulate the fragile Zn/Zn^(2+) *** we demonstrate,such a conflict may be defeated by using a mechanoadaptive cellulose nanofibril-based morphing gel electrolyte(MorphGE),which synergizes bulk compliance for optimizing interfacial contact as well as high modulus for suppressing dendrite ***,by anchoring desolvated Zn^(2+) on cellulose nanofibrils,the side reactions which induce dendrite formation are also significantly *** a result,the MorphGE-based symmetrical Zn-ion battery demonstrated outstanding stability for more than 100 h at the high current density of 10 mA·cm^(−2) and areal capacity of 10 mA·h·cm^(−2),and the corresponding Zn-ion battery delivered a prominent specific capacity of 100 mA·h·g^(−1) for more than 500 cycles at 20 *** present example of engineering the mechanoadaptivity of gel electrolytes will shed light on a new pathway for designing highly safe and flexible energy storage devices.

关键词： Zn-ion batteries dendrite growth interfacial adaptivity gel electrolytes fast-charging

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Kinetic Limits of Graphite Anode for fast‑charging Lithium‑Ion Batteries

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纳微快报:英文版 2023年第11期15卷 518-529页

作者： Suting Weng Gaojing Yang Simeng Zhang Xiaozhi Liu Xiao Zhang Zepeng Liu Mengyan Cao Mehmet Nurullah Ateş Yejing Li Liquan Chen Zhaoxiang Wang Xuefeng Wang Beijing National Laboratory for Condensed Matter Physics Institute of PhysicsChinese Academy of SciencesBeijing 100190People’s Republic of China School of Physical Sciences University of Chinese Academy of SciencesBeijing 100049People’s Republic of China College of Materials Science and Opto‑Electronic Technology University of Chinese Academy of SciencesBeijing 100049People’s Republic of China Department of Chemistry Boğazici UniversityBebekIstanbul 34342Türkiye Tianmu Lake Institute of Advanced Energy Storage Technologies Co.Ltd. Liyang 213300People’s Republic of China

fast-charging lithium-ion batteries are highly required,especially in reducing the mileage anxiety of the widespread electric *** of the biggest bottlenecks lies in the sluggish kinetics of the Li^(+)intercalation into the graphite anode;slow intercalation will lead to lithium metal plating,severe side reactions,and safety *** premise to solve these problems is to fully understand the reaction pathways and rate-determining steps of graphite during fast Li^(+)***,we compare the Li^(+)diffusion through the graphite particle,interface,and electrode,uncover the structure of the lithiated graphite at high current densities,and correlate them with the reaction kinetics and electrochemical *** is found that the rate-determining steps are highly dependent on the particle size,interphase property,and electrode *** Li^(+)diffusion leads to high polarization,incomplete intercalation,and the coexistence of several staging *** Li^(+)diffusion and electrode transportation are the main rate-determining steps if the particle size is less than 10μ*** former is highly dependent on the electrolyte chemistry and can be enhanced by constructing a fluorinated *** findings enrich the understanding of the graphite structural evolution during rapid Li^(+)intercalation,decipher the bottleneck for the sluggish reaction kinetics,and provide strategic guidelines to boost the fast-charging performance of graphite anode.

关键词： fast-charging Graphite anode Cryogenic transmission electron microscopy(cryo-TEM) High-rate kinetics

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Porous Co_(2)VO_(4) Nanodisk as a High-Energy and fast-charging Anode for Lithium-Ion Batteries

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Nano-Micro Letters 2022年第1期14卷 107-120页

作者： Jinghui Ren Zhenyu Wang Peng Xu Cong Wang Fei Gao Decheng Zhao Shupei Liu Han Yang Di Wang Chunming Niu Yusong Zhu Yutong Wu Xiang Liu Zhoulu Wang Yi Zhang School of Energy Science and Engineering Nanjing Tech UniversityNanjing 211816People’s Republic of China Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power EquipmentSchool of Electrical EngineeringXi’an Jiaotong UniversityXi’an 710054People’s Republic of China Department of Computational Materials Design Max-Planck-Insitut Für Eisenforschung GmbHMax-Planck-Straße 140237 DüsseldorfGermany

High-energy–density lithium-ion batteries(LIBs)that can be safely fast-charged are desirable for electric ***,sub-optimal lithiation potential and low capacity of commonly used LIBs anode cause safety issues and low energy *** we hypothesize that a cobalt vanadate oxide,Co_(2)VO_(4),can be attractive anode material for fast-charging LIBs due to its high capacity(~1000 mAh g^(−1))and safe lithiation potential(~0.65 V ***^(+)/Li).The Li+diffusion coefficient of Co2VO4 is evaluated by theoretical calculation to be as high as 3.15×10^(-10) cm^(2) s^(−1),proving Co_(2)VO_(4) a promising anode in fast-charging LIBs.A hexagonal porous Co2VO4 nanodisk(PCVO ND)structure is designed accordingly,featuring a high specific surface area of 74.57 m^(2) g^(−1) and numerous pores with a pore size of 14 *** unique structure succeeds in enhancing Li^(+) and electron transfer,leading to superior fast-charging performance than current commercial *** a result,the PCVO ND shows a high initial reversible capacity of 911.0 mAh g^(−1) at 0.4 C,excellent fast-charging capacity(344.3 mAh g^(−1) at 10 C for 1000 cycles),outstanding long-term cycling stability(only 0.024% capacity loss per cycle at 10 C for 1000 cycles),confirming the commercial feasibility of PCVO ND in fast-charging LIBs.

关键词： Lithium-ion batteries Anode fast-charging High-energy Cobalt vanadate oxide

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Mechanically flexible V_(3)S_(4)@carbon composite fiber as a high-capacity and fast-charging anode for sodium-ion capacitors

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稀有金属:英文版 2023年第8期42卷 2633-2642页

作者： Zhi-Fei Mao Xiao-Jun Shi Tao-Qiu Zhang Peng-Ju Liang Rui Wang Jun Jin Bei-Bei He Yan-Sheng Gong Qiang Wang Xi-Li Tong Huan-Wen Wang Faculty of Material Science and Chemistry China University of GeosciencesWuhan 430074China Engineering Laboratory of Chemical Resources Utilization in South Xinjiang of XPCC Department of Chemistry and Chemical EngineeringCollege of LifeTarim UniversityAlar 843300China State Key Laboratory of Coal Conversion Institute of Coal ChemistryChinese Academy of SciencesTaiyuan 030001China

Hybrid Na-ion capacitors(NICs)have received considerable interests owing to their low-cost,high-safety,and rapidly charging energy-storage *** NICs are composed of a capacitor-type cathode and a battery-type *** major challenge for NICs is to search for suitable electrode materials to overcome the sluggish diffusion of Na^(+)in the ***,ultrafine vanadium sulfide is encapsulated in carbon fiber(V_(3)S_(4)@CNF)as a self-supported electrode by electrospinning and in situ *** carbon cladding and one-dimensional(ID)nanofiber network-like structure could alleviate the volume expansion of V_(3)S_(4)during Na^(+)de-/intercalation ***,the V_(3)S_(4)@CNF anode exhibited a pseudocapacitive sodium storage in terms of large Na^(+)-storage capacity(476 mAh·g^(-1)at 0.1A·g^(-1)),high-rate capability(290 mAh·g^(-1)at 20.0 A·g^(-1))and excellent cycling stability(95%capacity retention for1500 cycles at 2.0 A·g^(-1))in Na *** employing V_(3)S_(4)@CNF as the anode and the activated carbon(AC)cathode,the as-assembled NICs could deliver a high energy density of 110 Wh·kg^(-1)at a power density of200 W·kg^(-1).Even at a high power of 10,000 W·kg^(-1),the specific energy is still up to 42 Wh·kg^(-1).

关键词： Electrospinning Na-ion capacitor(NIC) Nanofibers Vanadium sulfide fast-charging

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SiO-Sn_(2)Fe@C composites with uniformly distributed Sn_(2)Fe nanoparticles as fast-charging anodes for lithium-ion batteries

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eScience 2023年第1期3卷 62-70页

作者： Hanyin Zhang Renzong Hu Sirui Feng Zhiqun Lin Min Zhu School of Materials Science and Engineering Guangdong Provincial Key Laboratory of Advanced Energy Storage MaterialsSouth China University of TechnologyGuangzhou 510640China School of Materials Science and Engineering Georgia Institute of TechnologyAtlantaGA30332USA

SiO-based materials represent a promising class of anodes for lithium-ion batteries(LIBs),with a high theoretical capacity and appropriate and safe Li-insertion ***,SiO experiences a large volume change during the electrochemical reaction,low Li diffusivity,and low electron conductivity,resulting in degradation and low rate capability for ***,we report on the rapid crafting of SiO–Sn_(2)Fe@C composites via a one-step plasma milling process,leading to an alloy of Sn and Fe and in turn refining SiO and Sn_(2)Fe into nanoparticles that are well dispersed in a nanosized,few-layer graphene *** Sn and Fe nanoparticles generated during the first Li-insertion process form a stable network to improve Li diffusivity and electron *** an anode mate-rial,the SiO–Sn_(2)Fe@C composite manifests high reversible capacities,superior cycling stability,and excellent rate *** capacity retention is found to be as high as 95%and 84%at the 100th and 300th cycles under 0.3 *** rate capability testing at 3,6,and 11 C,the capacity retentions are 71%,60%,and 50%,*** study highlights that this simple,one-step plasma milling strategy can further improve SiO-based anode materials for high-performance LIBs.

关键词： SiO based Sn_(2)Fe Lithium-ion batteries Anodes fast-charging

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