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Carbene-catalyzed enantioselective seleno-Michael addition as access to antimicrobial active Se-containing heterocycles

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Science China Chemistry 2024年第7期67卷 2199-2205页

作者： Hongyan Long Sha Zhao Chunyan Jian Xiuli Wu Fengfei Lu Minghong Liao Fengrui Che Xingxing Wu Yonggui Robin Chi State Key Laboratory of Green Pesticide Key Laboratory of Green Pesticide and Agricultural BioengineeringMinistry of EducationGuizhou UniversityGuiyang 550025China School of Chemistry Chemical Engineeringand BiotechnologyNanyang Technological UniversitySingapore 637371Singapore

Organoseleniums exhibit a diverse set of biological activities that are pivotal for drug discovery and are widely explored in synthetic chemistry and material *** many transformations have been developed for non-enantioselective C–Se bond formations,the catalyst-controlled stereoselective preparation of chiral organoseleniums continues to be of considerable *** particular,there are limited studies on the enantioselective seleno-Michael addition reactions to access chiral selenium functional ***,we disclose a carbene-catalyzed highly enantioselective nucleophilic C–Se bond construction through formal[3+3]annulations between selenocarboxamides and bromoenals,affording seleno-thiazinone products with good yields and excellent *** choice of a weak inorganic base was pivotal to suppressing the unproductive racemization and decomposition of the selenium ***,the catalytically generated chiral selenium-containing heterocyclic products feature remarkable antimicrobial activities that could serve as promising lead scaffolds for further agrochemical development.

关键词： seleno-Michael addition organocatalysis N-heterocyclic carbene seleno-heterocycles antimicrobial activity

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1SWASP J034439.97+030425.5:a short-period eclipsing binary system with a close-in stellar companion

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Research in Astronomy and Astrophysics 2020年第4期20卷 31-38页

作者： Bin Zhang Sheng-Bang Qian Jing-Jing Wang Qi-Jun Zhi Ai-Jun Dong Wei Xie Li-Ying Zhu Lin-Qiao Jiang School of Physics and Electronic Science Guizhou Normal UniversityGuiyang 550001China guizhou Provincial Key Laboratory of Radio Astronomy and Data Processing Guizhou Normal UniversityGuiyang 550001China Yunnan Observatories Chinese Academy of SciencesKunming 650216China Key Laboratory of the Structure and Evolution of Celestial Objects Chinese Academy of SciencesKunming 650216China university of Chinese Academy of Sciences Beijing 100049China Center for Astronomical Mega-Science Chinese Academy of SciencesBeijing 100101China China university of Petroleum-Beijing at Karamay Karamay 834000China School of Physics and Electronic Engineering Sichuan University of Science and EngineeringZigong 643000China

First multi-wavelength photometric light curves(LCs)of the short-period eclipsing binary(EB)1 SWASP J034439.97+030425.5(hereafter J0344)are presented and analyzed by using the 2013 version of the Wilson-Devinney(W-D)*** explain the asymmetric LCs of J0344,a cool star-spot on the less massive component was *** photometric solutions suggest that J0344 is a W-subtype shallow contact EB with a contact degree of f=4.9%±3.0%and a mass ratio of q=2.456±***,an obvious third light was detected in our *** calculated the average luminosity contribution of the third light to the total light,and that value reaches up to 49.78%.Based on the O-C method,the variations of the orbital period were studied for the first *** O-C diagram reveals a secular decrease superimposed on a cyclic *** orbital period decreases at a rate of d P/dt=-6.07×10-7 d yr-1,which can be explained by the mass transfer from the more massive component to the less massive ***,its O-C diagram also shows a cyclic oscillation with an amplitude of 0.0030 d and a period about 7.08 yr,which can be explained by the presence of a third body with a minimum mass of M3 min=0.15±0.02 M⊙.The third component may play an important role in the formation and evolution of J0344 by drawing angular momentum from the central system.

关键词： stars:binaries:close stars:binaries:eclipsing stars:individual(1SWASP J034439.97+030425.5)

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一类强耦合的奇异摄动对流扩散方程组的移动网格方法（英文）

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应用数学 2018年第3期31卷 653-660页

作者：毛志刘利斌铜仁学院数学与统计系贵州铜仁554300 广西师范学院数学与统计科学学院广西南宁530023 广西高校数据科学重点实验室广西南宁530023

本文研究一类强耦合的奇异摄动对流扩散方程组的移动网格方法.首先,利用迎风有限差分格式对方程组进行离散.然后,推出数值解的后验误差估计,并以此设计出相应的自适应网格生成算法.同时,证明数值解具有一阶一致收敛性.最后,数值实验验... 详细信息

本文研究一类强耦合的奇异摄动对流扩散方程组的移动网格方法.首先,利用迎风有限差分格式对方程组进行离散.然后,推出数值解的后验误差估计,并以此设计出相应的自适应网格生成算法.同时,证明数值解具有一阶一致收敛性.最后,数值实验验证了本文移动网格方法的一致收敛性.

关键词：一致收敛奇异摄动强耦合迎风有限差分格式

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