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Exciting lattice oxygen of nickel–iron bi-metal alkoxide for efficient electrochemical oxygen evolution reaction

Journal of Energy Chemistry 2024年第1期88卷 194-201,I0005页

作者： Saihang Zhang Senchuan Huang Fengzhan Sun Yinghui Li Li Ren Hao Xu Zhao Li Yifei Liu Wei Li Lina Chong Jianxin Zou national Engineering Research Center of Light Alloy Net Forming&State Key Laboratory of Metal Matrix Composites Center of Hydrogen ScienceSchool of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China Department of Chemistry Laboratory of Advanced MaterialsShanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsiChEM and State Key Laboratory of Molecular Engineering of PolymersCollege of Chemistry and MaterialsFudan UniversityShanghai 200433China

High efficiency,cost-effective and durable electrocatalysts are of pivotal importance in energy conversion and storage *** electro-oxidation of water to oxygen plays a crucial role in such energy conversion ***,we report a robust method for the synthesis of a bimetallic alkoxide for efficient oxygen evolution reaction(OER)for alkaline electrolysis,which yields current density of 10 mA cm^(-2)at an overpotential of 215 mV in 0.1 M KOH *** catalyst demonstrates an excellent durability for more than 540 h operation with negligible degradation in *** spectra revealed that the catalyst underwent structure reconstruction during OER,evolving into oxyhydroxide,which was the active site proceeding OER in alkaline ***-situ synchrotron X-ray absorption experiment combined with density functional theory calculation suggests a lattice oxygen involved electrocatalytic reaction mechanism for the in-situ generated nickel–iron bimetal-oxyhydroxide *** mechanism together with the synergy between nickel and iron are responsible for the enhanced catalytic activity and *** findings provide promising strategies for the rational design of nonnoble metal OER catalysts.

关键词： Oxygen evolution reaction Nickel-iron bi-metal alkoxide Lattice oxygen-mediated reaction mechanism Alkaline electrolysis Electrocatalysts

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The significance of resource recycling for coking wastewater treatment:based on environmental and economic life cycle assessment

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Green Chemical Engineering 2024年第1期5卷 50-59页

作者： Di Zhang He Zhao Wenfang Gao Yuxing Sheng Hongbin Cao Institute of Process Engineering Innovation Academy for Green ManufactureChinese Academy of SciencesBeijing100190China University of Chinese Academy of Sciences Beijing100049China Chemistry&Chemical Engineering Data Center Chinese Academy of SciencesBeijing100190China Tianjin Key Laboratory of Clean Energy and Pollutant Control School of Energy and Environmental EngineeringHebei University of TechnologyTianjin300401China

The sustainability of the coking industry is supported by reasonable production profit and environmental quality *** traditional measures substantially increased the related costs for enterprises to reach *** paper aims to develop a comprehensive cost combined environmental impact assessment method that is necessary for the analysis of wastewater treatment *** three coking wastewater treatment processes in China were *** showed that eutrophication dominantly contributed to the overall environmental *** effluent quality could significantly reduce the total environmental *** terms of an economic perspective,the price of raw materials was the main factor that affected the operating cost of comprehensive *** on subsystem analysis,the pretreatment stage accounted for the majority of environmental and cost burdens,respectively reaching 64%-78%and 64%-86%.Optimizing the pretreatment process by enhancing the efficiency of high concentration raw material recovery and substituting toxic raw materials for extractant could reduce the environmental impact and economic cost by 43.8%and 57%,respectively,which was an effective way to improve the potential performance of coking wastewater treatment plants(WWTPs).

关键词： Life cycle assessment Environmental impact Economic evaluation Coking wastewater treatment Resource recycling Comprehensive benefits

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Detection of Increasingγ-Ray Emissions from 4FGL J1718.5+4237 with Fermi-LAT

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Research in Astronomy and Astrophysics 2024年第8期24卷 169-174页

作者： Jiao Zheng Pengfei Zhang Li Zhang Department of Astronomy School of Physics and AstronomyKey Laboratory of Astroparticle Physics of Yunnan ProvinceYunnan UniversityKunming 650091China School of Physics and Engineering Technology Xingyi Normal University for NationalitiesXingyi 562400China

We report a gradual brighteningγ-ray source,4FGL J1718.5+4237,in 0.1-500.0 GeV,which may be associated with a blazar NVSS J171822+423948 with a redshift of~*** analyzed 15.25 yr ofγ-ray data recorded by the Large Area Telescope on board the Fermi Gamma-ray Space Telescope and detected significantγ-ray emissions in the direction of the blazar with a test statistic(TS)of~*** on timing analysis using a 1 yr time bin,we have observed a gradual brightening inγ-ray emissions from the *** our analysis,we categorize them into two states:Quiet(TS~0)and Loud(TS~226)states,with the distinction occurring in 2016 August(MJD57602.69).From the Quiet state to the brightest period(the last data point),theγ-ray flux in 0.1-500.0 GeV increased by more than 12-fold from<0.2×10^(-8)photons cm^(-1)s^(-1)to 2.6×10^(-8)photons cm^(-1)s^(-1).Additionally,we studied the spectral properties in detail for the Loud state and the overall *** no significant variation was detected,both exhibited a spectral indexΓof~*** origin of the brighteningγ-ray emissions from the target is not yet *** long-term multi-wavelength observations and studies will provide insight into the astrophysical mechanisms of the target.

关键词： galaxies active-blazars individual(4FGL J1718.5+4237)

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A Possible γ-Ray Pulsation from PSR J1740-5340B in the Globular Cluster NGC 6397

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Research in Astronomy and Astrophysics 2024年第1期24卷 285-291页

作者： Jiao Zheng Pengfei Zhang Li Zhang Department of Astronomy School of Physics and AstronomyKey Laboratory of Astroparticle Physics of Yunnan ProvinceYunnan UniversityKunming 650091China

Recently, a new radio millisecond pulsar(MSP) J1740-5340B, hosted in the globular cluster(GC) NGC 6397,was reported with a 5.78 ms spin period in an eclipsing binary system with a 1.97 days orbital period. Based on a modified radio ephemeris updated by tool tempo2, we analyze the ~15 yr γ-ray data obtained from the Large Area Telescope on board the Fermi Gamma-ray Space Telescope and detect PSR J1740-5340B's γ-ray pulsation at a confidence level of ~4σ with a weighted H-test value of ~26. By performing a phase-resolved analysis, the γ-ray luminosity in on-pulse interval of PSR J1740-5340B is L_(γ)~ 3.8 × 10^(33) erg s^(-1) using NGC 6397's distance of 2.48 kpc. And γ-rays from the on-pulse part of PSR J1740-5340B contribute ~90% of the total observed γ-ray emissions from NGC 6397. No significant γ-ray pulsation of another MSP J1740-5340A in the GC is *** that the previous four cases of MSPs in GCs, more data in γ-ray, X-ray, and radio are encouraged to finally confirm the γ-ray emissions from MSP J1740-5340B, especially starving for a precise ephemeris.

关键词： gamma-rays:galaxies (stars:)pulsars:individual(PSR J1740-5340B) (Galaxy:)globular clusters:individual(NGC 6397)

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Higgs boson decays h→MZ in the TNMSSM

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Chinese Physics C 2024年第9期48卷 21-35页

作者： Huai-Cong Hu Zhao-Yang Zhang Ning-Yu Zhu Hai-Xiang Chen School of Physical Science and Technology Guangxi UniversityNanning 530004China

We study the SM-like Higgs boson decays h→MZ in the triplet extended NMSSM(TNMSSM),where M is a vector meson(ρ,ω,φ,J/ψ,Υ).Compared to the minimal supersymmetric standard model(MSSM),the TNMSSM includes two new SU(2) triplets with hypercharge ±1 and an SM gauge singlet,which are coupled to each *** indirect contributions to the h→MZ decays are produced from the effective hyZ vertex,and they are more important than the direct *** results of this work could encourage a detection on h→Zγ at the future high energy colliders for exploring new physics beyond the SM.

关键词： supersymmetry Higgs boson decay

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A review on the transformation of birnessite in the environment:Implication for the stabilization of heavy metals

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Journal of Environmental Sciences 2024年第5期139卷 496-515页

作者： Miao Shi Qingzhu Li Qingwei Wang Xuelei Yan Bensheng Li Linhai Feng Chao Wu Rongrong Qiu Hongkai Zhang Zhihui Yang Weichun Yang Qi Liao Liyuan Chai School of Metallurgy and Environment Central South UniversityChangsha 410083China national Engineering Research Centre for Control and Treatment ofHeavy Metal Pollution Central South UniversityChangsha 410083China Water Pollution Control Technology Key Lab of Hunan Province Changsha 410083China

Birnessite is ubiquitous in the natural environment where heavy metals are retained and easily *** surface properties and structure of birnessite change with the changes in external environmental conditions,which also affects the fate of heavy *** the effect and mechanism of the birnessite phase transition process on heavy metals is the key to taking effective measures to prevent and control heavy metal ***,the four transformation pathways of birnessite are summarized first in this ***,the relationship between transformation pathways and environmental conditions is *** relevant environmental conditions include abiotic(e.g.,co-existing ions,pH,oxygen pressure,temperature,electric field,light,aging,pressure)and biotic factors(e.g.,microorganisms,biomolecules).The phase transformation is achieved by the key intermediate of Mn(Ⅲ)through interlayer-condensation,folding,neutralizationdisproportionation,and dissolution-recrystallization *** AOS(average oxidation state)of Mn and interlayer spacing are closely correlated with the phase transformation of *** but not least,the mechanisms of heavy metals immobilization in the transformation process of birnessite are summed *** involve isomorphous substitution,redox,complexation,hydration/dehydration,*** transformation of birnessite and its implication on heavy metals will be helpful for understanding and predicting the behavior of heavy metals and the crucial phase of manganese oxides/hydroxides in natural and engineered environments.

关键词： Birnessite Transformation Heavy metals Pathways Mechanism

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Progress of gaseous arsenic removal from flue gas by adsorption:Experimental and theoretical calculations

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Journal of Environmental Sciences 2024年第2期136卷 470-485页

作者： Xuelei Yan Qingzhu Li Xiaowei Huang Bensheng Li Shengtu Li Qingwei Wang School of Metallurgy and Environment Central South UniversityChangsha 410083China national Engineering Research Centre for Control and Treatment of Heavy Metal Pollution Central South UniversityChangsha 410083China national Engineering Research Center for Rare Earth Materials General Research Institute for Non-Ferrous MetalsBeijing 100088China

Because of its high mobility and difficult capture,gaseous arsenic pollution control has become the focus of arsenic pollution *** mainly exists in the form of highly toxic As_(2)O_(3)in the flue ***,removing gaseous As_(2)O_(3)from flue gas is of great practical significance for arsenic pollution *** gaseous As_(2)O_(3)on the surface of adsorbents by physical or chemical adsorption is an effective way to reduce the content of arsenic in the flue gas and alleviate arsenic *** the past few decades,various adsorbents have been developed to capture gaseous As_(2)O_(3)in the flue gas,and their adsorption mechanisms have been studied in ***,it is necessary to review the strategies of arsenic removal from flue gas by adsorption,which can inspire further *** on summarizing the morphological distribution of gaseous As_(2)O_(3)in the flue gas,this review further summarizes the removal of gaseous As_(2)O_(3)by several adsorbents and the effect of temperature and the main components of the flue gas on arsenic *** addition,the mechanism of arsenic removal based on adsorption in the flue gas is discussed in depth through theoretical calculations,which is the particular focus of this ***,prospects based on the present research state of arsenic removal by adsorption are proposed to provide ideas for developing effective and stable adsorbents for arsenic removal from flue gas.

关键词： Gaseous arsenic Flue gas Adsorption Theoretical calculation Mechanism

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Two-Dimensional Metallophthalocyanine Nanomaterials for Electrocatalytic Energy Conversion

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Energy & Environmental Materials 2024年第4期7卷 364-385页

作者： Xinqi Wang Shaohui Sun Jiahao Yao Hao Wan Renzhi Ma Wei Ma School of Chemical Engineering and Zhongyuan Critical Metals Laboratory Zhengzhou University Research Center for Materials Nanoarchitectonics (MANA) National Institute for Materials Science (NIMS)

Crowing energy demand drives the rapid development of clean and reliable energy *** the past years,the exploration of novel materials with considerable efficiency and durability has drawn attention in the area of elec... 详细信息

关键词： conjugated nanostructure electrocatalysis 2D metallophthalocyanines

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Effect of drying-wetting cycles on pore characteristics and mechanical properties of enzyme-induced carbonate precipitation-reinforced sea sand

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第1期16卷 291-302页

作者： Ming Huang Kai Xu Zijian Liu Chaoshui Xu Mingjuan Cui College of Civil Engineering Fuzhou UniversityFuzhou350108China Xiamen Rail Transit Construction and Development Group Co. Ltd.Xiamen361000China School of Civil Environment and Mining EngineeringThe University of AdelaideAdelaide5005Australia

Enzyme-induced carbonate precipitation(EICP)is an emanating,eco-friendly and potentially sound technique that has presented promise in various geotechnical ***,the durability and microscopic characteristics of EICP-treated specimens against the impact of drying-wetting(D-W)cycles is under-explored *** study investigates the evolution of mechanical behavior and pore charac-teristics of EICP-treated sea sand subjected to D-W *** uniaxial compressive strength(UCS)tests,synchrotron radiation micro-computed tomography(micro-CT),and three-dimensional(3D)recon-struction of CT images were performed to study the multiscale evolution characteristics of EICP-reinforced sea sand under the effect of D-W *** potential correlations between microstructure characteristics and macro-mechanical property deterioration were investigated using gray relational analysis(GRA).Results showed that the UCS of EICP-treated specimens decreases by 63.7% after 15 D-W *** proportion of mesopores gradually decreases whereas the proportion of macropores in-creases due to the exfoliated calcium carbonate with increasing number of D-W *** micro-structure in EICP-reinforced sea sand was gradually disintegrated,resulting in increasing pore size and development of pore shape from ellipsoidal to columnar and *** gray relational degree suggested that the weight loss rate and UCS deterioration were attributed to the development of branched pores with a size of 100-1000 m m under the action of D-W ***,the results in this study provide a useful guidancee for the long-term stability and evolution characteristics of EICP-reinforced sea sand under D-W weathering conditions.

关键词： Enzyme-induced carbonate precipitation(EICP) Plant-based urease Drying-wetting(D-W)cycles Microstructure

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Supramolecular polymer network constructed by a functionalized polyimidazolium salt derived from metal-carbene template approach

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Science China Chemistry 2024年第4期67卷 1224-1228页

作者： Ming-Ming Gan Zi-En Zhang Yi-Fan Zhang Heng Zhang Li-Ying Sun Ying-Feng Han Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Xi’an Key Laboratory of Functional Supramolecular Structure and MaterialsCollege of Chemistry and Materials ScienceNorthwest UniversityXi’an 710127China

In this study,we present a supramolecular templating approach for constructing polyimidazolium salt containing crown ether and cyclobutane *** strategy involves the formation of metal-carbene templates,photochemical cycloaddition,and subsequent demetallation of metal *** by the host-guest chemistry between crown ether units and ammonium salts,we successfully fabricated a supramolecular polymer SPN1,which features imidazolium receptors and cyclobutane *** obtained SPN1 demonstrates outstanding reversible stimulus-response,antibacterial behavior and conductivity.

关键词： metal-carbene template crown ether polyimidazolium salt host-guest chemistry

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