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Mechanical Behavior of Bamboo,and Its Biomimetic Composites and Structural Members:A Systematic Review

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Journal of Bionic Engineering 2024年第1期21卷 56-73页

作者： Shanyu Han Yuyuan He Hanzhou Ye Xueyong Ren Fuming Chen Kewei Liu Sheldon Q.Shi Ge Wang Institute of Biomaterials for Bamboo and Rattan Resources International Centre for Bamboo and RattanBeijing 100102China key Laboratory of national Forestry and Grassland Administration/Beijing for Bamboo&Rattan Science and Technology Beijing 100102China national Forestry and Grassland Engineering Technology Center for Wood Resources Recycling College of Materials Science and TechnologyBeijing Forestry UniversityBeijing 100083China International Bamboo and Rattan Organization Beijing 100102China School of Civil Engineering Tsinghua UniversityBeijing 100084China Mechanical Engineering Department University of North TexasDentonTX 762077102USA

Bamboo is a typical biological material widely growing in nature with excellent physical and mechanical *** is lightweight with high strength and *** naturally optimized bamboo structure,which has inspired global material scientists and engineers for decades,is significantly important for the bionic design of novel structural materials with ultra-light,ultra-strong,or ultra-tough and comprehensive *** literature on innovative composite materials and structural members inspired by bamboo are reviewed in this paper,and the research progress and prospects in this field are expounded in three ***,the structural characteristics of the bamboo wall layer along the thickness and height directions are described in terms of chemical composition,gradient structure,pore structure,and hollow structure with variable ***,this paper summarizes the research progress on new composite materials and structural components by applying bamboo’s structural features from the perspective of sustainability,designability,and ***,given the limitations of current research,the biomimetic scientific research on bamboo’s structural characteristics is prospected from the interpretation of bamboo structure,new bamboo-like materials,and structural design optimization perspectives,providing a reference for future research on biomimetic aspects of biomass.

关键词： Bamboo Structural characteristics-Bamboo-like material Physical and mechanical properties

A novel Effective Panicle Number per Plant 4 haplotype enhances grain yield by coordinating panicle number and grain number in rice

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The Crop Journal 2024年第1期12卷 202-212页

作者： Yun Wang Xiaoqian Wang Laiyuan Zhai Sundus Zafar Congcong Shen Shuangbing Zhu Kai Chen Yun Wang Jianlong Xu State key Laboratory of Crop Gene Resources and Breeding Institute of Crop SciencesChinese Academy of Agricultural SciencesBeijing 100081China State key Laboratory of Crop Biology College of AgronomyShandong Agricultural UniversityTai’an 271018ShandongChina Shenzhen Branch Guangdong Laboratory for Lingnan Modern AgricultureAgricultural Genomics Institute at ShenzhenChinese Academy of Agricultural SciencesShenzhen 518120GuangdongChina Rice research Institute Shenyang Agricultural UniversityShenyang 110866LiaoningChina national Nanfan research Institute(Sanya) Chinese Academy of Agricultural SciencesSanya 572024HainanChina

Increasing effective panicle number per plant(EPN)is one approach to increase yield potential in ***,molecular mechanisms underlying EPN remain *** this study,we integrated mapbased cloning and genome-wide association analysis to identify the EPN4 gene,which is allelic to NARROW LEAF1(NAL1).Overexpression lines containing the Teqing allele(TQ)of EPN4 had significantly increased ***-EPN4^(TQ) in japonica(geng)cultivar Lemont(LT)exhibited significantly improved EPN but decreased grain number and flag leaf size relative to *** analysis indicated that accessions with EPN4-1 had medium EPN,medium grain number,and medium grain weight,but had the highest grain yield among seven haplotypes,indicating that EPN4-1 is an elite haplotype of EPN4 for positive coordination of the three components of grain ***,accessions carrying the combination of EPN4-1 and haplotype GNP1-6 of GNP1 for grain number per panicle showed higher grain yield than those with other allele ***,pyramiding of EPN4-1 and GNP1-6 could be a preferred approach to obtain high yield potential in breeding.

关键词： Rice Effective panicle number per plant Grain number per panicle Haplotype Grain yield potential

Palladium-catalyzed vinylation of indoles with vinyl ethers via deoxygenative coupling

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Science china Chemistry 2024年第11期67卷 3785-3790页

作者： Bowen Wang Jianxiao Li Wanqing Wu Liangbin Huang Huanfeng Jiang key Laboratory of Functional Molecular Engineering of Guangdong Province School of Chemistry and Chemical EngineeringSouth China University of Technology

Indole is a promising heteroarene in many natural products and pharmaceuticals; therefore, various synthetic methods for indole functionalizations have arisen in recent years. Herein, we report a Pd-catalyzed deoxygenative coupling for the N-vinylation of indoles by employing vinyl ethers. The vinylated indoles could be readily prepared in good to excellent yields with N1-regioselectivity regardless of the electronic characteristics and substitution patterns of indole substrates. Some indole-based pharmaceutical molecules, such as gramine, evodiamine, rutaecarpine, and melatonine, are also successfully vinylated. Moreover, carbazoles and indazoles are shown to participate. Additionally, vinylated indole can readily transform into structurally interesting indole derivatives.

关键词： indole vinylation regioselectivity N-vinyl indole palladium catalyst

Membrane-less MoO_(3-x)@TiO_(2)-bromine battery with excellent rate capability and cyclic stability

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Journal of Energy Chemistry 2024年第6期93卷 316-321,I0008页

作者： Wenjie Huang Hui Wang Bin Yuan Liuzhang Ouyang Lichun Yang Min Zhu School of Materials Science and Engineering Guangdong Provincial Key Laboratory of Advanced Energy Storage MaterialsSouth China University of TechnologyGuangzhou 510640GuangdongChina

Bromine has attracted significant attention as a cathode material for aqueous batteries due to its high reduction potential of 1.05 V(Br_(3)^(-)+2e~-■3Br~-),impressive theoretical specific capacity of 223 mA h g^(-1),and rapid reaction kinetics in the ***,searching for compatible anode materials to match with bromine has posed a challenge due to its highly corrosive *** this study,we developed oxygen-deficient MoO_(3) with TiO_(2) coating(referred to as MoO_(3-x)@TiO_(2))as an anode material to pair with a bromine cathode in static full *** oxygen deficiency contributes to enhanced electronic and protonic diffusion within the MoO_(3-x)lattice,while the TiO_(2) coating mitigates structural dissolution and proton trapping during *** MoO_(3-x)@TiO_(2) demonstrates fast charge storage kinetics and excellent resistance to bromine *** impressive compatibility between MoO_(3-x)@TiO_(2) and bromine enables the construction of membrane-less full batteries with exceptional rate capability and cyclic *** MoO_(3-x)@TiO_(2)-bromine battery achieves an energy density of70.8 W h kg^(-1)at a power density of 328.1 W kg^(-1),showcasing an impressive long-term cyclic life of 20,000 *** study provides valuable insights for the development of high-performance aqueous secondary batteries.

关键词： Molybdenum trioxide Oxygen deficiency TiO_(2)coating Compatibility Bromine-based battery

CD87-targeted BiTE and CAR-T cells potently inhibit invasive nonfunctional pituitary adenomas

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Science china(Life Sciences) 2024年第10期67卷 2169-2185页

作者： Yuan Ren Xinjie Bao Ming Feng Bing Xing Wei Lian Yong Yao Renzhi Wang Department of Neurosurgery Peking Union Medical College HospitalChinese Academy of Medical Sciences and Peking Union Medical CollegeBeijing 100730China

Recently,bispecific T-cell engagers(BiTEs)and chimeric antigen receptor-modified T cells(CAR-Ts)have been shown to have high therapeutic efficacy in hematological ***87 is highly expressed in solid tumors with an oncogenic *** assess their cytotoxic effects on invasive nonfunctioning pituitary adenomas(iNFPAs),we first examined CD87 expression and its effects on the metabolism of iNFPA *** generated CD87-specific BiTE and CAR/IL-12 T cells,and their cytotoxic effects on iNFPAs cells and in mouse models were ***87 had high expression in i NFPA tissue and cell samples but was undetected in noncancerous brain ***87×CD3 BiTE and CD87 CAR/IL-12 T-cells showed antigenic specificity and exerted satisfactory cytotoxic effects,decreasing tumor cell proliferation in vitro and reducing existing tumors in experimental ***,the above findings suggest that CD87 is a promising target for the immunotherapeutic management of iNFPAs using anti-CD87 BiTE and CD87-specific CAR/IL-12 T cells.

关键词： CD87 chimeric antigen receptor T cells invasive non-functional pituitary adenomas bispecific T cell engager Warburg effect

All-optical suppression on the impact of Sun outage in laser satellite communication systems by using a nonlinear semiconductor optical amplifier

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Chinese Optics Letters 2024年第2期22卷 76-80页

作者：李晓亮刘荣科范峰 School of Electronics and Information Engineering Beihang UniversityBeijing 100191China Beijing research Institute of Telemetry Beijing 100094China

We introduce an all-optical approach,optical parametric amplification(OPA)processor to suppress the impact of Sun outage in laser satellite communication systems,which is implemented by only one nonlinear semiconductor optical amplifier driven by both electrical and optical *** optimized OPA processor,with a current of 539 mA and a pump-to-signal ratio of 16 dB,could significantly improve the signal quality by 3.5 dB in experiments for the elevation angle of Sun radiation of 0 *** signal quality improvement is observed in the whole range of the elevation angle,confirming the effectiveness of the proposed OPA processor in the field of Sun radiation mitigation.

关键词： nonlinear optics Sun outage laser satellite communication

Light-controlled soft bio-microrobot

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Light(Science & Applications) 2024年第3期13卷 531-543页

作者： Jianyun Xiong Xing Li Ziyi He Yang Shi Ting Pan Guoshuai Zhu Dengyun Lu Hongbao Xin Guangdong Provincial key Laboratory of Nanophotonic Manipulation Institute of NanophotonicsJinan University511443 GuangzhouChina

Micro/nanorobots hold exciting prospects for biomedical and even clinical applications due to their small size and high ***,it is still a big challenge to maneuver micro/nanorobots into narrow spaces with high deformability and adaptability to perform complicated biomedical ***,we report a light-controlled soft bio-microrobots(called“Ebot”)based on Euglena gracilis that are capable of performing multiple tasks in narrow microenvironments including intestinal mucosa with high controllability,deformability and *** motion of the Ebot can be precisely navigated via light-controlled polygonal flagellum ***,the Ebot shows highly controlled deformability with different light illumination duration,which allows it to pass through narrow and curved microchannels with high *** these features,Ebots are able to execute multiple tasks,such as targeted drug delivery,selective removal of diseased cells in intestinal mucosa,as well as photodynamic *** light-controlled Ebot provides a new bio-microrobotic tool,with many new possibilities for biomedical task execution in narrow and complicated spaces where conventional tools are difficult to access due to the lack of deformability and bio-adaptability.

关键词： narrow illumination curved

Lithium Salt Combining Fluoroethylene Carbonate Initiates Methyl Methacrylate Polymerization Enabling Dendrite-Free Solid-State Lithium Metal Battery

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Energy & Environmental Materials 2024年第6期7卷 50-59页

作者： Xue Ye Jianneng Liang Baorong Du Yongliang Li Xiangzhong Ren Dazhuan Wu Xiaoping Ouyang Qianling Zhang Jianhong Liu Institute of Process Equipment College of Energy EngineeringZhejiang UniversityHangzhou310000 China Graphene Composite research Center College of Chemistry and Environmental EngineeringShenzhen UniversityShenzhen518061 China

This work demonstrates a novel polymerization-derived polymer electrolyte consisting of methyl methacrylate,lithium bis(trifluoromethanesulfonyl)imide and fluoroethylene *** polymerization of MMA was initiated by the amino compounds following an anionic catalytic *** plays both roles including the initiator and Li ion source in the polymer ***,lithium bis(trifluoromethanesulfonyl)imide has difficulty in initiating the polymerization reaction of methyl methacrylate monomer,a very high concentration of lithium bis(trifluoromethanesulfonyl)imide is needed for initiating the ***,the fluoroethylene carbonate additive can work as a supporter to facilitate the degree of dissociation of lithium bis(trifluoromethanesulfonyl)imide and increase its initiator capacity due to the high dielectric *** as-prepared poly-methyl methacrylate-based polymer electrolyte has a high ionic conductivity(1.19×10^(−3)S cm^(−1)),a wide electrochemical stability window(5 V vs Li^(+)/Li),and a high Li ion transference number(t_(Li^(+)))of 0.74 at room temperature(RT).Moreover,this polymerization-derived polymer electrolyte can effectively work as an artificial protective layer on Li metal anode,which enabled the Li symmetric cell to achieve a long-term cycling performance at 0.2 mAh cm^(−2)for 2800 *** LiFePO_(4)battery with polymerization-derived polymer electrolyte-modified Li metal anode shows a capacity retention of 91.17%after 800 cycles at 0.5 *** work provides a facile and accessible approach to manufacturing poly-methyl methacrylate-based polymerization-derived polymer electrolyte and shows great potential as an interphase in Li metal batteries.

关键词： in situ polymerization lithium anode polymer electrolyte solid-state lithium batteries

Acoustic characterization of hydrate formation and decomposition in clay-bearing sediments

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Petroleum Science 2024年第4期21卷 2830-2838页

作者： Yi-Jian Zhu Xiao-Mei Yang Xing Huang Hao Li Xiao-Hui Wang Yi-Fei Sun Peng Xiao Chang-Yu Sun Guang-Jin Chen State key Laboratory of Heavy Oil Processing College of Chemical Engineering and Environment China University of Petroleum

Understanding the acoustic characteristics of hydrates in various sediments is crucial for hydrate resource detection and safe and efficient exploitation, as hydrate occurrence patterns vary greatly in different sediments. In this work, sediments with different bentonite contents, water saturations, and types were prepared to investigate the characteristics of P-wave velocity(reflecting the magnitude of hydrate saturation in the sediment) and amplitude(reflecting the degree of hydrate-sediment cementation) during hydrate formation and depressurization. During hydrate formation, the P-wave velocity and amplitude have similar trends. As clay content increases, the P-wave velocity increase rates quickened. On the other hand, the increased rate of P-wave velocity slows down with the increase of water saturation in the clay-bearing sediments. Comparing various types of sediment shows that the water absorption and swelling of bentonite reduce the pore space, speeding up the cementation of the hydrate with the sediment and increasing P-wave velocity at a faster rate. Correspondence between P-wave velocity and hydrate saturation is strongly related to sediment type, clay content, and water *** rapidly decreasing amplitude in the early stage of hydrate depressurization indicates that hydrate in clay-bearing sediments is weakly cemented to the sediments, which is prone to stratigraphic *** findings of this study offer guidance for hydrate resource assessments in clay-bearing sediments as well as geologic risk estimations during hydrate mining.

关键词： gas hydrate bentonite illite P-wave velocity amplitude