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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2011年第6期12卷 461-469页

作者： Dan-qing YU Yue LIU zhong-biao wu Department of Environmental Engineering Zhejiang University Hangzhou 310027 China Zhejiang Provincial Engineering Research Center of Industrial Boiler & Furnace Flue Gas Pollution Control Hangzhou 310027 China

Six transition metal oxides were added in ceria-modified titania using a sol-gel method for catalytic oxidation of *** MnOx based catalyst was found to be the most active one,with which toluene could be decomposed completely at 200 *** greatest Mn/Ti and molar ratio of the mobile oxygen to the total oxygen concentration,together with a large surface area and a low reduction peak-starting temperature,would result in its best activity in toluene oxidation.

关键词： Transition metal oxides CeO2/TiO2 Sol-gel method Catalytic oxidation Toluene

Mechanistic insight into the synergy between nickel single atoms and nanoparticles on N-doped carbon for electroreduction of CO2

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Journal of Energy Chemistry 2025年第1期100卷 327-336页

作者： Mingdong Sun Wenwen Guan Cailing Chen Chao wu Xiaoling Liu biao Meng Tao Chen Yu Han Jun Wang Shibo Xi Yu Zhou State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Advanced Membranes and Porous Materials Center Physical Sciences and Engineering Division King Abdullah University of Science and Technology Institute of Sustainability for Chemicals Energy and Environment A*STAR (Agency for Science Technology and Research) College of Materials Science and Engineering Sichuan University

The synergy of single atoms （SAs） and nanoparticles （NPs） has demonstrated great potential in promoting the electrocatalytic carbon dioxide reduction reaction （CO2RR）;however,the rationalization of the SAs/NPs proportion remains one challenge for the catalyst ***,a Ni2+-loaded porous poly（ionic liquids）(PIL) precursor synthesized through the free radical self-polymerization of the ionic liquid monomer,1-allyl-3-vinylimidazolium chloride,was pyrolyzed to prepare the Ni,N co-doped carbon materials,in which the proportion of Ni SAs and NPs could be facilely modulated by controlling the annealing *** catalyst Ni-NC-1000 with a moderate proportion of Ni SAs and NPs exhibited high efficiency in the electrocatalytic conversion of CO2into *** Ni K-edge X-ray absorption near-edge structure （XANES） spectra and theoretical calculations were conducted to gain insight into the synergy of Ni SAs and *** charge transfer from Ni NPs to the surrounding carbon layer and then to the Ni SAs resulted in the electron-enriched Ni SAs active *** the electroreduction of CO2,the coexistence of Ni SAs and NPs strengthened the CO2activation and the affinity towards the key intermediate of*COOH,lowering the free energy for the potential-determining*CO2→*COOH step,and therefore promoted the catalysis efficiency.

关键词： Single atom catalyst Synergy effect Carbon catalyst Electrocatalysis

Dynamic Regulation of Hydrogen Bonding Networks and Solvation Structures for Synergistic Solar‑Thermal Desalination of Seawater and Catalytic Degradation of Organic Pollutants

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Nano-Micro Letters 2025年第2期17卷 548-565页

作者： Ming‑Yuan Yu Jing wu Guang Yin Fan‑Zhen Jiao zhong‑Zhen Yu Jin Qu Beijing Key Laboratory of Advanced Functional Polymer Composites Beijing University of Chemical TechnologyBeijing 100029People’s Republic of China State Key Laboratory of Organic‑Inorganic Composites College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029People’s Republic of China

Although solar steam generation strategy is efficient in desalinating seawater,it is still challenging to achieve continuous solar-thermal desalination of seawater and catalytic degradation of organic ***,dynamic regulations of hydrogen bonding networks and solvation structures are realized by designing an asymmetric bilayer membrane consisting of a bacterial cellulose/carbon nanotube/Co_(2)(OH)_(2)CO_(3)nanorod top layer and a bacterial cellulose/Co_(2)(OH)_(2)CO_(3)nanorod(BCH)bottom ***,the hydrogen bonding networks inside the membrane can be tuned by the rich surface–OH groups of the bacterial cellulose and Co_(2)(OH)_(2)CO_(3)as well as the ions and radicals in situ generated during the catalysis ***,both SO_(4)^(2−)and HSO_(5)−can regulate the solvation structure of Na^(+)and be adsorbed more preferentially on the evaporation surface than Cl^(−),thus hindering the de-solvation of the solvated Na^(+)and subsequent nucleation/growth of ***,the heat generated by the solar-thermal energy conversion can accelerate the reaction kinetics and enhance the catalytic degradation *** work provides a flow-bed water purification system with an asymmetric solar-thermal and catalytic membrane for synergistic solar thermal desalination of seawater/brine and catalytic degradation of organic pollutants.

关键词： Solar steam generation Seawater desalination Catalytic degradation Bacterial cellulose Cobalt hydroxycarbonate nanorods

Modification of FGD gypsum in hydrothermal mixed salt solution

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Journal of Environmental Sciences 2006年第1期18卷 170-175页

作者： wu Xiao-qin wu zhong-biao Department of Environmental Engineering Zhejiang University Hangzhou 310027 China Department of Chemical Engineering Wuhan University of Science and Technology Wuhan 430081 China

A novel utilization way of the sludge from wet calcium-based flue gas desulfurization （FGD） processes has been developed in this paper. This study focused on the conversion of the FGD gypsum into α-hemihydrate calcium sulfate by a hydrothermal salt solution method at atmospheric pressure. Experimental study has been carried out in a batch reactor. Qualitative and quantitative analyses were made by DSC/TG thermal analysis, SEM, XRD, metalloscope and chemical analysis. The experimental results showed that the modification of FGD gypsum was controlled by the dissolution and recrystallization mechanisms. With the introduction of FGD gypsum the salt solution was supersaturated, then crystal nucleus of α-hemihydrate calcium sulfate were produced in the solution. With the submicroscopic structure of FGD gypsum crystal changed, the crystal nucleus grew up into α-hemihydrate calcium sulfate crystals. Thus ,the modification of FGD gypsum was fulfilled.

关键词： FGD gypsum modification hydrothermal mixed salt solution atmospheric pressure

Recent progress on photoactive nonprecious transition-metal complexes

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Science China Chemistry 2025年第1期 46-95页

作者： zhong-Liang Gong Hong-Jie Zhang Yan Cheng Jianxun Liu Yuhan Ai Yaqin Li Zhihui Feng Qiong Zhang Shaolong Gong Yong Chen Chang-Jiang Yao Yuan-Yuan Zhu Liang-Jin Xu Yu-wu zhong CAS Key Laboratory of Photochemistry Institute of Chemistry Chinese Academy of Sciences State Key Laboratory of Structural Cemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences School of Chemistry and Chemical Engineering Anhui Key Laboratory of Advanced Catalytic Materials and Reaction EngineeringHefei University of Technology State Key Laboratory of Explosion Science and Safety Protection School of Mechatronical Engineering Beijing Institute of Technology College of Chemistry and Molecular Sciences Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Wuhan University School of Chemistry and Chemical Engineering Anhui University Key Laboratory of Photochemical Conversion and Optoelectronic Materials & CAS-HKU Joint Laboratory on New Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences

Photoactive complexes of nonprecious transition metals, mainly including those in the first-row and partially the second-row of the Periodic table of elements, have received increasing attention in view of their low cost and long-term sustainability. They are recognized as promising alternatives to noble transition metal complex congeners that have been extensively studied in optoelectronic devices, artificial photosynthesis, photocatalysis, biodiagnostics, and therapeutics, etc. This review is devoted to a comprehensive summary on the classical and recent advances on photoactive nonprecious transition metal complexes, including photoactive Zr, V, Cr, Mo, and W complexes, Mn complexes and hybrids, Fe, Co, Ni, and Cu complexes, and Zn and Cd complexes and hybrids. A particular focus is given on the molecular design, modulation of photophysical and photochemical properties, and applications of the representative and lately-developed nonprecious metal complexes. In addition, a perspective on the future development in this field is provided at the end of this review.

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Dimensional Synthesis of a 3-DOF Parallel Manipulator with Full Circle Rotation

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Chinese Journal of Mechanical Engineering 2015年第4期28卷 830-840页

作者： NI Yanbing wu Nan zhong Xueyong ZHANG biao School of Mechanical Engineering Tianjin University FAW Jiefang Automotive Company LtdAxle Filiale

Parallel robots are widely used in the academic and industrial fields. In spite of the numerous achievements in the design and dimensional synthesis of the low-mobility parallel robots, few research efforts are directed towards the asymmetric 3-DOF parallel robots whose end-effector can realize 2 translational and 1 rotational（2T1R） motion. In order to develop a manipulator with the capability of full circle rotation to enlarge the workspace, a new 2T1 R parallel mechanism is proposed. The modeling approach and kinematic analysis of this proposed mechanism are investigated. Using the method of vector analysis, the inverse kinematic equations are established. This is followed by a vigorous proof that this mechanism attains an annular workspace through its circular rotation and 2 dimensional translations. Taking the first order perturbation of the kinematic equations, the error Jacobian matrix which represents the mapping relationship between the error sources of geometric parameters and the end-effector position errors is derived. With consideration of the constraint conditions of pressure angles and feasible workspace, the dimensional synthesis is conducted with a goal to minimize the global comprehensive performance index. The dimension parameters making the mechanism to have optimal error mapping and kinematic performance are obtained through the optimization algorithm. All these research achievements lay the foundation for the prototype building of such kind of parallel robots.

关键词： parallel manipulator kinematic analysis dimensional synthesis

Characterization of metal doped-titanium dioxide and behaviors on photocatalytic oxidation of nitrogen oxides

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Journal of Environmental Sciences 2007年第12期19卷 1505-1509页

作者： LIU Yue WANG Hai-qiang wu zhong-biao Department of Environmental Engineering Zhefiang University Hangzhou 310027 China.

A series of nanosized ion-doped TiO2 catalysts with different ion content （between 0.1 at.% and 1.0 at.%） have been prepared by wet impregnation method and investigated with respect to their behavior for UV photocatalytic oxidation of nitric oxide. The catalytic activity was correlated with structural, electronic and surface examinations of the catalysts using X-ray diffraction analysis （XRD）, ultraviolet-visible （UV-Vis） absorption spectroscopy, transmission electron microscopy （TEM）, energy disperse spectrometer （EDS） and high resolution-transmission electron microscopy （HR-TEM） techniques. An enhancement of the photocatalytic activity was observed for Zn2＋ doping catalyst ranged from 0.1 at.% to 1.0 at.% which was attributed to the lengthened lifetime of electrons and holes. The improvement in photocatalytic activity could be also observed with the low doping concentration of Cr^3＋（0.1 at.%）. However, the doping of Fe^3＋, Mo^6＋, Mn^2＋ and the high doping concentration of Cr^3＋ had no contribution to photocatalytic activity of nitric oxide.

关键词： NO photocatalytic oxidation ion doping doped

Exploring the nature of black hole and gravity with an imminent merging binary of supermassive black holes

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Science China(Physics,Mechanics & Astronomy) 2023年第3期66卷 76-87页

作者： Xingyu zhong Wen-biao Han Ziren Luo Yueliang wu Shanghai Astronomical Observatory Chinese Academy of SciencesShanghai 200030China Taiji Laboratory for Gravitational Wave Universe(Beijing/Hangzhou) University of Chinese Academy of SciencesBeijing 100049China Hangzhou Institute for Advanced Study University of Chinese Academy of SciencesHangzhou 310124China School of Astronomy and Space Science University of Chinese Academy of SciencesBeijing 100049China Institute of Mechanics Chinese Academy of SciencesBeijing 100190China Shanghai Frontiers Science Center for Gravitational Wave Detection Shanghai 200240China Institute of Theoretical Physics Chinese Academy of SciencesBeijing 100190China International Centre for Theoretical Physics Asia-Paciﬁc University of Chinese Academy of SciencesBeijing 100190China Key Laboratory of Gravitational Wave Precision Measurement of Zhejiang Province Hangzhou 310124China

A supermassive binary black-hole candidate SDSS J1430+2303 reported recently motivates us to investigate an imminent binary of supermassive black holes as potential gravitational wave source, and the radiated gravitational waves at the end of the merger are shown to be in the band of space-borne detectors. We provide a general analysis on the required detecting sensitivity needed for probing such type gravitational wave sources and make a full discussion by considering two typically designed configurations of space-borne antennas. If a source is so close, it is possible to be detected with Taiji pathfinder-plus which is proposed to be an extension for the planned Taiji pathfinder by just adding an additional satellite to the initial two satellites. The gravitational wave detection on such kind of source enables us to explore the properties of supermassive black holes and the nature of gravity.

关键词： gravitation wave SMBHBs Taiji pathfinder

PdSe_(2)/MoSe_(2) vertical heterojunction for self-powered photodetector with high performance

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Nano Research 2022年第3期15卷 2489-2496页

作者： Jiahong zhong biao wu Yassine MADOUNE Yunpeng Wang Zongwen Liu Yanping Liu School of Physics and Electronics Hunan Key Laboratory for Super-microstructure and Ultrafast ProcessCentral South UniversityChangsha 410083China State Key Laboratory of High-Performance Complex Manufacturing Central South UniversityChangsha 410083China School of Chemical and Biomolecular Engineering The University of SydneyNSW 2006Australia The University of Sydney Nano Institute The University of SydneyNSW 2006Australia Shenzhen Research Institute of Central South University A510aVirtual University BuildingSouthern DistrictHigh-tech Industrial ParkYuehai StreetNanshan DistrictShenzhen 518057China

Van der Waals’two-dimensional(2D)material heterostructure engineering offers an effective strategy for the design of multifunctional and high-performance optoelectronic ***,2D heterostructure photodetectors with a photoconductive effect tend to suffer from high driving source-drain voltages and significant dark noise ***,a self-powered photodetector with high performance was fabricated based on vertically stacked graphene/MoSe_(2)/PdSe_(2)/graphene heterojunctions through a dry transfer *** fabricated device displays current rectification characteristics in darkness(on/off ratio>10^(3))and superior photovoltaic behaviors under *** addition,benefitting from the strong built-in field,the Gr/PdSe_(2)/MoSe_(2)/Gr heterojunction photodetector is able to respond to a broad spectrum from visible to near-infrared(NIR)with a remarkable responsivity of 651 mA·W^(−1),a high specific detectivity of 5.29×10^(11) Jones and a fast response speed of 41.7/62.5μ***,an enhanced responsivity of 1.16 A·W^(−1) has been obtained by a reverse voltage(−1 V)and further evaluation on image recognition has also demonstrated the great application potential of the Gr/MoSe_(2)/PdSe_(2)/Gr heterojunction *** findings are expected to bring new opportunities for the development of highly sensitive,high-speed and energy-efficient photodetectors for comprehensive applications.

关键词： heterostructure MoSe_(2) PdSe_(2) self-powered photodetector high performance

Biodegradability of terephthalic acid in terylene artificial silk printing and dyeing wastewater

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Journal of Environmental Sciences 2003年第3期15卷 296-301页

作者： GUAN Bao-hong wu zhong-biao wu Zu-ceng XU Gen-liang TAN Tian-en Department of Environmental Engineering Zhejiang UniversityHangzhou 310027China.

As the characteristic pollutant, terephthalic acid(TA)was in charge of 40%—78% of the total COD of terylene artificial silk printing and dyeing wastewater(TPW-water). The studies on biodegradability of TA were conducted in a serial of activated sludge reactors with TPW-water. TA appeared to be readily biodegradable with removal efficiency over 96.5% under aerobic conditions, hardly biodegradable with removal efficiency below 10% under anoxic conditions and slowly biodegradable with a turnover between 31.4% and 56.0% under anaerobic conditions. TA also accounted for the majority of BOD in TPW-water. The process combined by anoxic, anaerobic and aerobic activated sludge reactor was suitable for TA degradation and TPW-water treatment. Further, the aerobic process was essentially much more effective than the anaerobic or anoxic one to degrade TA in TPW-water.

关键词： terephthalic acid biodegradability bio-treatment printing and dyeing wastewater terylene artificial silk