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Optimal mining sequence for coal faces under a bedding slope:insight from landslide prevention

Journal of Mountain Science 2024年第5期21卷 1775-1798页

作者： LI Qingmiao ZHAO Jianjun LI zhichao DENG Jie ZUO Jing LAI Qiyi State Key Laboratory of Geohazard Prevention and Geoenvironment Protection Chengdu University of TechnologyChengdu 610059China

Repetitive mining beneath bedding slopes is identified as a critical factor in geomorphic disturbances, especially landslides and surface subsidence. Prior research has largely concentrated on surface deformation in plains due to multi-seam coal mining and the instability of natural bedding slopes, yet the cumulative impact of different mining sequences on bedding slopes has been less explored. This study combines drone surveys and geological data to construct a comprehensive three-dimensional model of bedding slopes. Utilizing FLAC3D and PFC2D models, derived from laboratory experiments, it simulates stress, deformation, and failure dynamics of slopes under various mining sequences. Incorporating fractal dimension analysis, the research evaluates the stability of slopes in relation to different mining sequences. The findings reveal that mining in an upslope direction minimizes disruption to overlying strata. Initiating extraction from lower segments increases tensile-shear stress in coal pillar overburdens, resulting in greater creep deformation towards the downslope than when starting from upper segments, potentially leading to localized landslides and widespread creep deformation in mined-out areas. The downslope upward mining sequence exhibits the least fractal dimensions, indicating minimal disturbance to both strata and surface. While all five mining scenarios maintain good slope stability under normal conditions, recalibrated stability assessments based on fractal dimensions suggest that downslope upward mining offers the highest stability under rainfall, contrasting with the lower stability and potential instability risks of upslope downward mining. These insights are pivotal for mining operations and geological hazard mitigation in multi-seam coal exploitation on bedding slopes.

关键词： Bedding rock landslides Mining-induced deformation Bedding slope stability Underground mining sequences Fractal-based strength reduction method

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Developing Domestic Offshore Finance to Meet the Needs of the Real Economy

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China Forex 2024年第3期 44-47页

作者： GAO Hao DENG zhichao xu Lei Tsinghua University PBC School of Finance Shanghai Academy of Social Sciences

In recent years,there has been a gradual upsurge in the international use of RMB in China's real economy,leading to a growing potential demand for offshore RMB international settlement,deposits and loans,and other financial *** such a background,the development of domestic offshore finance with RMB as the main transaction currency is beneficial to meet these financial needs and promote the high-quality development of the real *** key to developing domestic offshore finance in China is to deeply understand the needs of the real economy,vigorously develop offshore RMB businesses and products,build an offshore RMB financial system,facilitate the global layout of China's real economy,and steadily advance the internationalization of RMB.

关键词： finance offshore loans

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Geometric and defects engineering collaboration for enhanced cascade enzymatic nanoreactors

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Nano Research 2024年第4期17卷 2451-2461页

作者： zhichao Yu Ruijin Zeng Hexiang Gong Yuan Gao Shuyun Chen Yunsen Wang Dianping Tang Key Laboratory for Analytical Science of Food Safety and Biology(MOE&Fujian Province) Department of ChemistryFuzhou UniversityFuzhou 350108China

Highly evolved multi-enzyme cascade catalytic reactions in organisms facilitate rapid transfer of substrates and efficient conversion of intermediates in the catalytic unit,thus rationalizing their efficient *** this study,pore-ordered mesoporous single-atom(Fe)nitrogen-doped carbon nanoreactors(Mp-Fe-CN)were designed,in which a reasonable pore size was designed as a natural enzyme trap coupled to a simulated enzyme center.A polarity-mediated strategy was developed to obtain atomically dispersed nanoporous substrates,with the finding that polarity-guided engineering of the nitrogen-ligand environment and vacancy cluster defects clearly affects nanoporous activity,accompanied by appreciable mesoporous pore size *** active center and distal N atom coordination of Fe-N_(4) affect the catalytic process of the nanozyme exposed by density functional theory(DFT),determining the contribution of hybridized orbitals to electron transfer and the decisive step.A cascade nanoreactor-based domain-limited sarcosine oxidase developed for non-invasive monitoring of sarcosine levels in urine for evaluation of potential prostate carcinogenesis as a proof of *** on the design of surface mesoporous channels of nanocatalytic units,a bridge was built for the interaction between nanozymes and natural enzymes to achieve cascade nanocatalysis of natural enzymatic products.

关键词： nanozyme single-atom catalyst bioreactor cascade catalysis non-Invasive sensing

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Bio-inspired Design and Inverse Kinematics Solution of an Omnidirectional Humanoid Robotic Arm with Geometric and Load Capacity Constraints

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Journal of Bionic Engineering 2024年第2期21卷 778-802页

作者： zhichao Zhu Zirong Luo Yiming Zhu Tao Jiang Minghai Xia Shanjun Chen Boyu Jin College of Intelligence Science and Technology National University of Defense TechnologyChangshaChina

Inspired by the driving muscles of the human arm,a 4-Degree of Freedom(DOF)concentrated driving humanoid robotic arm is proposed based on a spatial double parallel four-bar *** four-bar mechanism design reduces the inertia of the elbow-driving unit and the torque by 76.65%and 57.81%,*** the human pose regulation strategy that the human arm picks up a heavy object by adjusting its posture naturally without complicated control,the robotic arm features an integrated position-level closed-form inverse solution method considering both geometric and load capacity *** method consists of a geometric constraint model incorporating the arm angle(φ)and the Global Configuration(GC)to avoid joint limits and singularities,and a load capacity model to constrain the feasible domain of the arm ***,trajectory tracking simulations and experiments are conducted to validate the feasibility of the proposed inverse solution *** simulated maximum output torque,maximum output power and total energy consumption of the robotic arm are reduced by up to 2.0%,13.3%,and 33.3%,*** experimental results demonstrate that the robotic arm can bear heavy loads in a human-like posture,effectively reducing the maximum output torque and energy consumption of the robotic arm by 1.83%and 5.03%,respectively,while avoiding joints beyond geometric and load capacity *** proposed design provides a high payload–weight ratio and an efficient pose control solution for robotic arms,which can potentially broaden the application spectrum of humanoid robots.

关键词： Humanoid robotic arm Bio-inspired design Inverse kinematics solution Load capacity constraint Geometric constraint

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Access to Axially Chiral Aryl Aldehydes via Carbene-Catalyzed Nitrile Formation and Desymmetrization Reaction

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Research 2024年第3期2024卷 715-721页

作者： Yuanlin Cai Ya Lv Liangzhen Shu zhichao Jin Yonggui Robin Chi Tingting Li National Key Laboratory of Green Pesticide Key Laboratory of Green Pesticide and Agricultural BioengineeringMinistry of EducationGuizhou UniversityGuiyang 550025China School of Chemistry Chemical Engineeringand BiotechnologyNanyang Technological UniversitySingapore 637371Singapore.

An approach utilizing N-heterocyclic carbene for nitrile formation and desymmetrization reaction is developed. The process involves kinetic resolution, with the axially chiral aryl monoaldehydes obtained in moderate yields with excellent optical purities. These axially chiral aryl monoaldehydes can be conveniently transformed into functionalized molecules, showing great potential as catalysts in organic chemistry.

关键词： chemistry. aldehydes chiral

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Overweight,Obesity and Female Sex are Risk Factors for Gallbladder Cancer:a Systemic Review and Meta-analysis

Overweight,Obesity and Female Sex are Risk Factors for Gallb...

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第十九届中国科协年会——分10微创外科高峰论坛

作者： Dipak Kumar Thapa zhichao xu Lin WANG YaLing ZHAO ZhiMin GENG Department of Hepatobiliary Surgery First Affiliated Hospital of Xi’an Jiaotong University Department of Epidemiology and Biostatistics School of Public HealthXi'an Jiaotong UniversityHealth Science Center

AIM:Being overweight or obese is a leading risk factor for several cancers,however,the association between excess weight and the risk of gallbladder cancer(GBC)remains *** objective of this study was to determine the relative risk of GBC with regard to excess weight and female ***:We performed a meta-analysis of 12 studies searched from Pub Med and EMBASE databases,published up to December *** outcome of interest was GBC incidence or morbidity;The exposure of interest was overweight and/or obesity defined by body mass index(BMI).Statistical analysis were performed by using Review Manager 5.0(Rev Man 5.0) software.P < 0.05 was considered ***:People with BMI ≥ 25(i.e.,kg/m

关键词： Gallbladder cancer Overweight Obesity Body mass index(BMI)

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A near-zero quiescent power breeze wake-up anemometer based on a rolling-bearing triboelectric nanogenerator

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Microsystems & Nanoengineering 2024年第2期10卷 241-249页

作者： Xianpeng Fu zhichao Jiang Jie Cao Zefang Dong Guoxu Liu Meiling Zhu Chi Zhang CAS Center for Excellence in Nanoscience Beijing Key Laboratory of Micro-nano Energy and SensorBeijing Institute of Nanoenergy and NanosystemsChinese Academy of SciencesBeijing101400China School of Nanoscience and Engineering University of Chinese Academy of SciencesBeijing100049China Center on Nanoenergy Research Guangxi Colleges and Universities Key Laboratory of Blue Energy and Systems IntegrationSchool of Physical Science&TechnologyGuangxi UniversityNanning530004China Institute of Intelligent Flexible Mechatronics Jiangsu UniversityZhenjiang212013China College of Engineering Mathematics and Physical ScienceUniversity of ExeterExeterEX44QFUK

Wind sensors have always played an irreplaceable role in environmental information monitoring and are expected to operate with lower power consumption to extend service ***,we propose a breeze wake-up anemometer(B-WA)based on a rolling-bearing triboelectric nanogenerator(RB-TENG)with extremely low static *** B-WA consists of two RB-TENGs,a self-waking-up module(SWM),a signal processing module(SPM),and a wireless transmission *** two RB-TENGs are employed for system activation and wind-speed *** the ambient wind-speed exceeds 2 m/s,the wake TENG(W-TENG)and the SWM can wake up the system within 0.96 *** the same time,the SPM starts to calculate the signal frequency from the measured TENG(M-TENG)to monitor the wind speed with a sensitivity of 9.45 Hz/(m/s).After the wind stops,the SWM can switch off the B-WA within 0.52 s to decrease the system energy *** quiescent on-duty mode,the operating power of the B-WA is less than 30 nW,which can greatly extend the service lifetime of the *** integrating triboelectric devices and rolling bearings,this work has realized an ultralow quiescent power and self-waked-up wireless wind-speed monitoring system,which has foreseeable applications in remote weather monitoring,IoT nodes,and so on.

关键词： generator power service

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Synergistic effects of peroxydisulfate on UV/O_(3) process for tetracycline degradation:Mechanism and pathways

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Chinese Chemical Letters 2024年第10期35卷 408-413页

作者： Fengrui Yang Debing Wang Xinying Zhang Jie Zhang zhichao Wu Qiaoying Wang State Key Laboratory of Pollution Control and Resource Reuse Shanghai Institute of Pollution Control and Ecological SecuritySchool of Environmental Science and EngineeringTongji UniversityShanghai 200092China Fujian Provincial Engineering Research Center of Rural Waste Recycling Technology College of Environment&Safety EngineeringFuzhou University.Fuzhou 350108China

Tetracycline(TC)as a typical emerging pollutant is becoming a serious threat to the environment and human health.A combined advanced oxidation technology of UV/Ozone(O_(3))/peroxydisulfate(PDS)process was developed to explore an efficient and economic treatment process of TC in ***,the reactive sites and transformation pathways of TC were explored and the toxicity of the intermediates was quantified with a quantitative structure-activity relationship(QSAR)*** degradation performance of TC was substantially enhanced in UV/O_(3)/PDS process with a kobsof 0.0949 min-1,which was 2.3 times higher than UV/O_(3)and 3.2 times than sole *** results demonstrated that there was a superior synergistic effect of PDS on UV/O_(3)processes for the degradation of *** paramagnetic resonance(EPR)analysis and quenching experiments show that·OH,SO_(4)·-,O_(2)·-and1O_(2)all contributed to TC degradation in the UV/O_(3)/PDS process and exhibited a synergistic effect,which inhibited the generation of harmful *** addition,the UV/O_(3)/PDS system can effectively degrade TC in a wide range of substrate concentrations and pH,and also showed excellent adaptability to various concentrations of anions(Cl-and HCO_(3)-).This study proves the feasibility of UV/O_(3)/PDS process for treating TC contaminated wastewater with complicated water matrix.

关键词： UV/ozonation/peroxydisulfate Synergistic effect Tetracycline Degradation Wastewater

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Performance of rotating jet bed——A new Higee

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化工进展 2011年第S2期30卷 254-257页

作者： LI Yuming,WANG ying,LI Xiaohua,xu zhichao,JI Jianbing (Zhejiang Province Key Laboratory of Biofuel,College of Chemical Engineering and Materials Science, Zhejiang University of Technology,Hangzhou 310014,Zhejiang,China)

The rotating jet bed(RJB) has been developed by Zhejiang University of Technology,as a noveler type of gas-liquid mass-transfer unit than rotating zigzag bed(RZB).The rotor of RJB is composed of perforated concentric baffles fixed to a rotating *** top of the baffles is in the grooves of the stationary disc,preventing short cut of the *** of total reflux distillation with RZB and two types of RJB were carried out with ethanol-water systems at atmospheric *** two types of RJB are with rotor of mesh baffles and of shutter baffles,*** results showed that the number of theoretical plates per meter of RJB,lower than that of RZB,increased with increasing rotational speed,and increased firstly and then decreased with increasing gas superficial *** maximum number of theoretical plates per meter is 40.7 for RJB with rotor of mesh baffles and 40.0 for RJB with rotor of shutter *** specific pressure drop of RJB was far less than that of *** gas phase film volumetric mass-transfer coefficients of RJB with rotor of mess baffles and shutter baffles were correlated with the Reynolds number,Grashof number and Schmidt *** calculated value agreed well with the experimental value,and the average deviation was less than 15%.

关键词： distillation rotating jet bed mass-transfer specific pressure drop

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A method for determining the complex refractive index dispersion of absorbing materials without thickness information

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Optoelectronics Letters 2024年第11期20卷 676-680页

作者： DENG zhichao MEI Jianchun WANG Jin YE Qing TIAN Jianguo Key Laboratory of Weak-Light Nonlinear Photonics Ministry of Education School of Physics and TEDA Applied Physics Nankai University

The complex refractive index dispersion(CRID) of absorbing materials is very important in many fields, especially in printing industry and medical research. However, due to their strong absorbing, CRID determination i... 详细信息

关键词： A

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