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First-principles Study of Point Defects in Stoichiometric and Non-stoichiometric Y_4Al_2O_9

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Journal of Materials Science & Technology 2013年第12期29卷 1161-1165页

作者： z.li B.liu J.M.Wang L.C.Sun J.Y.Wang Y.C.zhou z.J.Hu High-performance Ceramics Division Shenyang National Laboratory for Materials ScienceInstitute of Metal ResearchChinese Academy of Sciences Aerospace Research Institute of Materials and Processing Technology

By using the first-principles calculation, we studied the mechanisms of point defects in Y4AI209 （YAM）, a promising ternary oxide with excellent optical and thermal properties. It is found that the predominant native defect species is closely dependent on the chemical potentials of each constituent. In the case of O-rich condition, the oxygen interstitial has the very low defect formation energy, followed by the anti-site defects and AI vacancy; in the case of AI-rich condition, the oxygen vacancy yields the lowest defect formation energy, followed by the anti-site defects and AI interstitial. The present result shows that in all the possible chemical potential ranges, anti-site defects have relatively low defect formation energy and might exist in high concentration in YAM. Furthermore, AIy anti-site has relatively lower defect formation energy than the YAt anti- site throughout. The behaviors of defect complexes under non-stoichiometric condition, such as the AI203 or Y203 excess, are also investigated. The results provide helpful guide to optimize the experimental synthesizing of YAM.

关键词： Ternary Y-AI-O oxide Defect formation energy Chemical potential

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IMAGING REDOX STATE HETEROGENEITY WITHIN INDIVIDUAL EMBRYONIC STEM CELL COLONIES

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Journal of Innovative Optical Health Sciences 2011年第3期4卷 279-288页

作者： HE N.XU RUSSELL C.ADDIS DAVIDA F.GOINGS SHOKO NIOKA BRITTON CHANCE JOHN D.GEARHART liN z.li Molecular Imaging Laboratory Department of Radiology University of PennsylvaniaSchool of Medicine PhiladelphiaPA 19104USA Institute for Regenerative Medicine and Department of Cell and Developmental Biology University of Pennsylvania School of Medicine PhiladelphiaPA 19104USA Britton Chance Laboratory of Redox Imaging Johnson Research Foundation Department of Biochemistry and Biophysics University of Pennsylvania School of Medicine PhiladelphiaPA 19104USA Institute of Translational Medicine and Therapeutics University of Pennsylvania PhiladelphiaPA 19104USA

Redox state mediates embryonic stem cell(ESC)differentiation and thus offers an important complementary approach to understanding the pluripotency of stem *** redox ratio(NADH/(Fp t NADH)),where NADH is the reduced form of nicotinamide adenine dinucleotide and Fp is the oxidizedflavoproteins,has been established as a sensitive indicator of mitochondrial redox *** this paper,we report our redox imaging data on the mitochondrial redox state of mouse ESC(mESC)colonies and the implications *** low-temperature NADH/Fp redox scanner was employed to image mESC colonies grown on a feeder layer of gamma-irradiated mouse embryonicfibroblasts(MEFs)on glass cover *** result showed significant heterogeneity in the mitochondrial redox state within individual mESC colonies(size:~200-440μm),exhibiting a core with a more reduced state than the *** more reduced state positively correlates with the expression pattern of Oct4,a well-established marker of *** observation is thefirst to show the heterogeneity in the mitochondrial redox state within a mESC colony,suggesting that mitochondrial redox state should be further investigated as a potential new biomarker for the stemness of embryonic stem cells.

关键词： Redox imaging pluripotency NADH flavoproteins redox ratio

肺自由呼吸质子MRI检测COVID-19存活者动态通气功能异常

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国际医学放射学杂志 2022年第5期 617-618页

作者： C.Wang H.li S.Xiao z.li X.zhao J.Xie 吴美妮

摘要目的采用肺自由呼吸1H-MRI技术观察和定量评估新型冠状病毒肺炎（COVID-19）住院存活者的局部肺功能。方法前瞻性纳入12名健康志愿者和27例COVID-19

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INVESTIGATION INTO HOT DEFORMATION BEHAVIOR OF SPRAY FORMED SUPERALLOY GH742

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Acta Metallurgica Sinica(English Letters) 2004年第2期17卷 205-209页

作者： z.li G.Q.zhang z.H.zhang S.F.Tian National Key Lab.of High Temperature Structural Materials,Beijing Institute of Aeronautical Materials,Beijing 100095,China Lab. of High Temp. Structural Mat. Beijing Inst. of Aero. Mat. Beijing 100095 China

In order to evaluate the deformation characteristics of spray formed superalloy GH742and determine the appropriate forging procedure of the alloy on this basis, the influenceof deformation temperature and strain rate on the ductility of spray formed GH742was investigated by using the Gleeble-3500 thermal-mechanical testing machine. It isshown that the forgeability of spray formed GH742 is better than conventional GH742by ingot metallurgy because of refined grain structure and enhanced chemical homo-geneity of spray formed GH742. In the temperature range of 1020 to 1100℃, theductility of spray formed GH742 is dependent on the deformation temperature and isincreased linearly in proportion to the increment of deformation temperature, whichis more than 40% at 1020℃ and more than 60% at the temperature between 1100and 1140℃. Furthermore, the results indicate the flow stress is affected considerablyby the deformation temperature and strain rate. In the temperature range of 1020 to1140℃, the maximum flow stress of spray formed GH742 increases with the incrementof strain rate and decreases with the increment of the deformation temperature.

关键词： spray forming superalloy GH742 hot deformation physical simulation

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INTRODUCTION SPECIAL ISSUE IN MEMORY OF PROFESSOR BRITTON CHANCE

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Journal of Innovative Optical Health Sciences 2011年第3期4卷 I0001-I0003页

作者： lin z.li Shoko Nioka Molecular Imaging Lab Department of Radiology Britton Chance Lab of Redox Imaging Johnson Foundation Department of Biochemistry and Biophysics University of Pennsylvania

Britton Chance:One of the Most Outstanding Scientists in the World On June 3rd and 4th,2011,over 300 scientists and professionals from all over the world gathered at the Translational Research Center of the University of Pennsylvania to attend a memorial symposium on\Britton Chance:His life,Times and Legacy"and a\Molecular Spectroscopy/Imaging Workshop:from bench top to bedside"dedicated to Britton Chance as well.

关键词： Times Chance symposium

Quantitative redox imaging biomarkers for studying tissue metabolic state and its heterogeneity

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Journal of Innovative Optical Health Sciences 2014年第2期7卷 109-128页

作者： He N.Xu lin z.li Department of RadiologyBrtton Chance Laboratory of Redoa Imaging Johnson Research Foundation Departmentof Biochemistry and BiophysicsPerelman School of MedicineUniversity of Pennsyluania PhiladelphiaPAUSA

NAD+/NADH redox state has been implicated in many diseases such as cancer and diabetes aswell as in the regulation of embryonic development and aging,To fluorimetrically sssthemitochondrial redox state,*** and co-workers measured the fluorescence of NADH andoxidized flavoproteins(Fp)including favin-adenine-dinucleotide(FAD)and demonstrated theirratio(*** redox ratio)is a sensitive indicator of the mitochondrial redox states.,The Chanceredox sca mer was built to simult aneously measure NADH and Fp in tisue at submilimeter scalein 3D using the freeze-trap *** paper summarizes our recent research experience,development and new applications of the redox scanning technique in collaboration with *** beginning in *** initiated or actively involved in many of the projectsduring the last several years of his *** advanced the redox scanning technigue by measuringthe nominal concentrations(in reference to the frozen solution standards)of the endogenousfuorescent analy tes,i.e.,[NADH]and[rp]to quantify the redox ratios in various *** advancement has enabled us to identify an array of the redox indices as quantitativeimaging,biomarkers(including[NADH],[Fp],[Fp]/[NADH]+[Fp],[NADH]/[Fp],and theirstandard deviations)for studying some important biological questions on cancer and normaltsue *** found that the redox indices were asociated or changed with(NADH)tumorigenesis(cancer versus non-cancer of human breast tisue biopsies);(2)tumor metastaticpotential;(3)tumor glucose uptake;(4)tumor p53 stat us;(5)PI3K pathway activation in pre-malignant tissue;(6)therapeutic ffects on tumors;(7)embryonic stem cell diferentiation;(8)the heart under fasting,Together,our work demonstrated that the tisue redox indices obtainedfrom the redox scanning technique may provide usefil information about tisue met abolism and physiology status in normal and diseased *** Chance redox scanner and other redoximaging techniques may ha

关键词： Tumor progresion mitochondria met astasis met astatic potential pre-malignancy NADH Fp FAD redox ratio

Anisotropic time-dependent behaviors of shale under direct shearing and associated empirical creep models

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第4期16卷 1262-1279页

作者： Yachen Xie Michael z.Hou Hejuan liu Cunbao li Shenzhen Key Laboratory of Deep Engineering Sciences and Green Energy Shenzhen UniversityShenzhen518060China Institute of Subsurface Energy Systems Clausthal University of TechnologyClausthal-Zellerfeld38678Germany State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan430071China

Understanding the anisotropic creep behaviors of shale under direct shearing is a challenging *** this context,we conducted shear-creep and steady-creep tests on shale with five bedding orientations (i.e.0°,30°,45°,60°,and 90°),under multiple levels of direct shearing for the first *** results show that the anisotropic creep of shale exhibits a significant stress-dependent *** a low shear stress,the creep compliance of shale increases linearly with the logarithm of time at all bedding orientations,and the increase depends on the bedding orientation and creep *** high shear stress conditions,the creep compliance of shale is minimal when the bedding orientation is 0°,and the steady-creep rate of shale increases significantly with increasing bedding orientations of 30°,45°,60°,and 90°.The stress-strain values corresponding to the inception of the accelerated creep stage show an increasing and then decreasing trend with the bedding orientation.A semilogarithmic model that could reflect the stress dependence of the steady-creep rate while considering the hardening and damage process is *** model minimizes the deviation of the calculated steady-state creep rate from the observed value and reveals the behavior of the bedding orientation's influence on the steady-creep *** applicability of the five classical empirical creep models is quantitatively *** shows that the logarithmic model can well explain the experimental creep strain and creep rate,and it can accurately predict long-term shear creep *** on an improved logarithmic model,the variations in creep parameters with shear stress and bedding orientations are *** abovementioned findings,a mathematical method for constructing an anisotropic shear creep model of shale is proposed,which can characterize the nonlinear dependence of the anisotropic shear creep behavior of shale on the bedding orientation.

关键词： Rock anisotropy Direct shear creep Creep compliance Steady-creep rate Empirical model Creep constitutive model

Dynamic immunohistochemical analysis for albumin and IgG in nephrons of acute hypertensive mouse kidneys by “in vivo cryotechnique”

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中国组织化学与细胞化学杂志 2004年第3期13卷 375-376页

作者： z.li N.Terada N.Ohno Y.Fujii T.Baba S.Ohno DepartmentofAnatomy InterdisciplinaryGraduateSchoolofMedicineandEngineeringUniversityofYamanashi1110ShimokatoTamahoYamanashi409-3898Japan

Applicability of large-ion lithophile and high field strength element basalt discrimination diagrams

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International Journal of Digital Earth 2018年第7期11卷 752-760页

作者： X.L.liu Q.zhang W.C.li F.C.Yang Y.zhao z.li S.T.Jiao J.R.Wang N.zhang S.S.Wang W.F.Chen z.J.Pan J.Yang X.L.Du Faculty of Land and Resource Engineering Kunming University of Science and TechnologyKunmingPeople’s Republic of China Institute of Geology and Geophysics Chinese Academy of SciencesBeijingPeople’s Republic of China Chengdu Geological Survey Center of China Geological Survey ChengduPeople’s Republic of China School of Earth Science Lanzhou UniversityLanzhouPeople’s Republic of China

Basalt discriminant diagrams have been used to identify the tectonic setting of basaltic magmatism since the 1970s and have played an important role in reconstructing paleotectonic ***,the significant increase in the availability of geochemical data has led to a reassessment of these diagrams,suggesting that some of the tectonic settings indicated by these diagrams are not ***,we use a database of global ocean island basalt(OIB),mid-ocean ridge basalt(MORB),and island arc basalt(IAB)geochemistry to propose a series of new tectonic discriminant diagrams based on the ratios of large-ion lithophile elements(liLEs)to high field strength elements(HFSEs).These new diagrams indicate that the liLE can be used to differentiate OIB,MORB,and IAB samples,meaning that liLE/HFSE ratios can discriminate between these basalts that form in different tectonic *** new diagrams can correctly assign samples to OIB,MORB,and IAB categories more than 85%of the time,with the discrimination between OIB and MORB having an accuracy of slightly less than 85%.

关键词： Basalt liLE HFSE discrimination diagram geochemistry