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Catalyst–Support Interaction in Polyaniline‑Supported Ni_(3)Fe Oxide to Boost Oxygen Evolution Activities for Rechargeable zn‑Air Batteries

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Nano-Micro Letters 2025年第1期17卷 176-190页

作者： Xiaohong zou Qian Lu Mingcong Tang Jie Wu kouer zhang Wenzhi li Yunxia Hu Xiaomin Xu Xiao zhang zongping Shao liang An Department of Mechanical Engineering The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China Jiangsu key Laboratory of Atmospheric Environment Monitoring and Pollution Control Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and TechnologyNanjing University of Information Science and TechnologyNanjing 210044People’s Republic of China Department of Chemistry The Chinese University of Hong KongMa Lin BuildingShatinHong Kong SAR 999077People’s Republic of China WA School of Mines:Minerals Energy and Chemical Engineering(WASM‑MECE)Curtin UniversityPerthWA 6102Australia Research Institute for Advanced Manufacturing The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China Research Institute for Smart Energy The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China

Catalyst–support interaction plays a crucial role in improving the catalytic activity of oxygen evolution reaction(OER).Here we modulate the catalyst–support interaction in polyaniline-supported Ni_(3)Fe oxide(Ni_(3)Fe oxide/PANI)with a robust hetero-interface,which significantly improves oxygen evolution activities with an overpotential of 270 mV at 10 mA cm^(-2)and specific activity of 2.08 mA cm_(ECSA)^(-2)at overpotential of 300 mV,3.84-fold that of Ni_(3)Fe *** is revealed that the catalyst–support interaction between Ni_(3)Fe oxide and PANI support enhances the Ni–O covalency via the interfacial Ni–N bond,thus promoting the charge and mass transfer on Ni_(3)Fe *** the excellent activity and stability,rechargeable zn-air batteries with optimum Ni_(3)Fe oxide/PANI are assembled,delivering a low charge voltage of 1.95 V to cycle for 400 h at 10 mA cm^(-2).The regulation of the effect of catalyst–support interaction on catalytic activity provides new possibilities for the future design of highly efficient OER catalysts.

关键词： Catalyst-support interaction Supported catalysts Heterointerface Oxygen evolution reaction zn-air batteries

Designing Electronic Structures of Multiscale Helical Converters for Tailored Ultrabroad Electromagnetic Absorption

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Nano-Micro Letters 2025年第1期17卷 439-455页

作者： zhaobo Feng Chongbo liu Xin li Guangsheng Luo Naixin zhai Ruizhe Hu Jing lin Jinbin Peng Yuhui Peng Renchao Che key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle School of Environmental and Chemical EngineeringNanchang Hangkong UniversityNanchang 330063People’s Republic of China School of Physics and Materials Nanchang UniversityNanchang 330031People’s Republic of China key Laboratory of Nondestructive Testing Ministry of EducationNanchang Hangkong UniversityNanchang 330063People’s Republic of China Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative MaterialsAcademy for Engineering and TechnologyFudan UniversityShanghai 200438People’s Republic of China

Atomic-scale doping strategies and structure design play pivotal roles in tailoring the electronic structure and physicochemical property of electromagnetic wave absorption(EMWA)***,the relationship between configuration and electromagnetic(EM)loss mechanism has remained ***,drawing inspiration from the DNA transcription process,we report the successful synthesis of novel in situ Mn/N co-doped helical carbon nanotubes with ultrabroad EMWA *** calculation and EM simulation confirm that the orbital coupling and spin polarization of the Mn–N4–C configuration,along with cross polarization generated by the helical structure,endow the helical converters with enhanced EM *** a result,HMC-8 demonstrates outstanding EMWA performance,achieving a minimum reflection loss of−63.13 dB at an ultralow thickness of 1.29 *** precise tuning of the graphite domain size,HMC-7 achieves an effective absorption bandwidth(EAB)of 6.08 GHz at 2.02 mm ***,constructing macroscale gradient metamaterials enables an ultrabroadband EAB of 12.16 GHz at a thickness of only 5.00 mm,with the maximum radar cross section reduction value reaching 36.4 dB *** innovative approach not only advances the understanding of metal–nonmetal co-doping but also realizes broadband EMWA,thus contributing to the development of EMWA mechanisms and applications.

关键词： Metal-nonmetal co-doping 3d-2p orbital coupling Spin polarization Helical structure Broadband EM wave absorption

INFLUENCE OF HEAT TREATMENT ON OXIDATION PROPERTIES OF C/C COMPOSITES FABRICATED BY HIGH PRESSURE IMPREGNATION CARBONIzATION

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Acta Metallurgica Sinica(English Letters) 2004年第4期17卷 426-430页

作者： Q.Chen H.J.li A.J.li H.M.Han k.z.li School of Materials Science and Engineering Northwestern Polytechnical University Xi'an 710072 ChinaSchool of Materials Science and Engineering Northwestern Polytechnical University Xi'an 710072 ChinaSchool of Materials Science and Engineering Northwestern Polytechnical University Xi'an 710072 ChinaSchool of Materials Science and Engineering Northwestern Polytechnical University Xi'an 710072 ChinaSchool of Materials Science and Engineering Northwestern Polytechnical University Xi'an 710072 China

Felt base carbon/carbon composites fabricated by super-high pressure impregnation carbonization process (SPIC) were heat treated at high temperature 2773k. The oxidation properties of felt base carbon/carbon composites were investigated at different temperatures (773-1173k), and the microstructures of carbon/carbon composites were studied by SEM and X-ray diffraction. The experimental results showed that the inter-laminar distance of (002) plane (d002) deceased while the microcrystalline stack height (Lc) increased. The oxidation rate of felt base carbon/carbon composites was invari-able at certain temperatures. The oxidation mechanism of carbon/carbon composites changed remarkably at the oxidation temperature 973k. At the initial oxidation stage of carbon/carbon composites, carbon matrix was oxidized much more rapidly than carbon felt.

关键词： carbon/carbon composites high pressure impregnation carbonization high temperature heat treatment oxidation mi-crostructure

Decreased levels of phosphorylated synuclein in plasma are correlated with poststroke cognitive impairment

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Neural Regeneration Research 2025年第9期20卷 2598-2610页

作者： Yi Wang Yuning li Yakun Gu Wei Ma Yuying Guan Mengyuan Guo Qianqian Shao Xunming Ji Jia liu Department of Clinical Laboratory Beijing Bo’ai HospitalChina Rehabilitation Research CenterCapital Medical UniversityBeijingChina Beijing Institute of Brain Disorders Laboratory of Brain DisordersMinistry of Science and TechnologyCollaborative Innovation Center for Brain DisordersBeijing Advanced Innovation Center for Big Data-based Precision MedicineCapital Medical UniversityBeijingChina Department of Neurosurgery Xuanwu HospitalCapital Medical UniversityBeijingChina

Poststro ke cognitive impairment is a major secondary effect of ischemic stroke in many patients;however,few options are available for the early diagnosis and treatment of this *** aims of this study were to(1)determine the specific relationship between hypoxic andα-synuclein during the occur of poststroke cognitive impairment and(2)assess whether the serum phosphorylatedα-synuclein level can be used as a biomarker for poststro ke cognitive *** found that the phosphorylatedα-synuclein level was significantly increased and showed pathological aggregation around the cerebral infa rct area in a mouse model of ischemic *** addition,neuronalα-synuclein phosphorylation and aggregation were observed in the brain tissue of mice subjected to chronic hypoxia,suggesting that hypoxia is the underlying cause ofα-synuclein-mediated pathology in the brains of mice with ischemic *** phosphorylatedα-synuclein levels in patients with ischemic stroke were significantly lower than those in healt hy subjects,and were positively correlated with cognition levels in patients with ischemic ***,a decrease in serum high-density lipoprotein levels in stroke patie nts was significantly correlated with a decrease in phosphorylatedα-synuclein *** ischemic stroke mice did not show significant cognitive impairment or disrupted lipid metabolism 14 days after injury,some of them exhibited decreased cognitive function and reduced phosphorylatedα-synuclein *** together,our results suggest that serum phosphorylatedα-synuclein is a potential biomarker for poststroke cognitive impairment.

关键词： biomarker high-density lipoprotein ischemic stroke phosphorylatedα-synuclein poststroke cognitive impairment

An application of interacting shear flows theory: exact solution for unsteady oblique stagnation point flow

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Acta Mechanica Sinica 2006年第5期22卷 397-402页

作者： Guibo li Minguo Dai z. Gao College of Physical and Environmental Oceanography Ocean University of China Qingdao 266003 China LHD Institute of Mechanics Chinese Academy of Sciences Beijing 100080 China

An analytical solution of the governing equations of the interacting shear flows for unsteady oblique stagnation point flow is obtained. It has the same form as that of the exact solution obtained from the complete NS... 详细信息

关键词： Navier-Stokes equations Interacting shear flows Unsteady oblique stagnation point flow Exact solution

MECHANICAL PROPERTIES OF LONGITUDINAL SUBMERGED ARC WELDED STEEL PIPES USED FOR GAS PIPEliNE OF OFFSHORE OIL

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Acta Metallurgica Sinica(English Letters) 2008年第2期21卷 85-93页

作者： z.z. Yang W. Tian Q.R. Ma Y.L. li J.k. li J.z. Gao H.B. zhang Y.H. Yang Tubular Goods Research Center of CNPC Xi＇an 710065 China Xiran Aerotechnical College Xi＇an 710077 China

Since the development of offshore oil and gas, increased submarine oil and gas pipelines were installed. All the early steel pipes of submarine pipelines depended on importing because of the strict requirements of comprehensive properties, such as, anti-corrosion, resistance to pressure and so on. To research and develop domes- tic steel pipes used for the submarine pipeline, the Longitudinal-seam Submerged Arc Welded （LSAW） pipes were made of steel plates cut from leveled hot rolled coils by both the JCOE and UOE （the forming process in which the plate like the letter “J”, “C”, “0” or “U” shape, then expansion） forming processes. Furthermore, the mechanical properties of the pipe base metal and weld metal were tested, and the results were in accordance with the corresponding pipe specification API SPEC 5L or DNV- OS-FI01, which showed that domestic LSAW pipes could be used for submarine oil and gas pipelines.

关键词： Mechanical properties Offshore oil and gas Longitudinal-seamsubmerged arc welded pipe (LSA W) Pipeline JCOE formingprocess UOE forming process

INVESTIGATION OF INFLUENCE OF HYDROGEN ATTACk ONFATIGUE PROPERTIES OF PRESSURE VESSEL STEELS

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Acta Metallurgica Sinica(English Letters) 1998年第2期11卷 141-149页

作者： J.L.li k.F.Wang J.li z.M.Yao W.ke Fushun Petroleum Inst Fushun China

Influence of hydrogen attack on mechanical and fatigue properties of 1020, 15CrMo and 2.25Cr-1Mo steels has been studied, which were exposed to gaseous hydrogen at pressure of 18MPa and 300-480℃ for up to 480h. The results of fatigue test showed that hydrogen attack (HA) resulted in an obvious change in fatigue properties of 1020 and 15CrMo steels, however, 2.25Cr-1Mo steel showed a lower susceptibility to hydrogen attack due to the addition of Cr and Mo. Fatigue crack behaviour for 1020 steel is attributed to hydrogen attack damage and the crack closure induced by the rough cracking surface, which lead to a valley on △kth～HA% plot. The change in the fatigue behaviour of 15CrMo steel is possibly caused by severe surface decarburization.

关键词： hydrogen attack pressure vessel steel threshold △k value crack closure

Diverse strategic approaches en route to Taxol total synthesis

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Chinese Chemical Letters 2022年第12期33卷 4957-4968页

作者： zexian li Jianfeng zheng Wei-Dong z.li Sichuan Engineering Research Center for Biomimetic Synthesis of Natural Drugs School of Life Science and EngineeringSouthwest Jiaotong UniversityChengdu 610031China

Taxol is one of the most famous diterpenoid natural products used in clinical cancer *** and its analogues are popular synthetic targets and have attracted worldwide attention over the past *** research efforts have already been made and ten groups have achieved the total synthesis of Taxol since *** mini-review summarized the recent highlights of divergent strategic approaches towards the chemical synthesis of Taxol's carbocyclic framework bearing a bridged eight-membered ring.

关键词： Taxol Total synthesis Biomimetic synthesis linear strategy Convergent strategy

EFFECTS OF TEST TEMPERATURE AND STRAIN RATE ON THE MECHANICAL PROPERTIES IN AN INTERCRITICALLYHEAT-TREATED BAINITE-TRANSFORMED STEEL

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Acta Metallurgica Sinica(English Letters) 2004年第6期17卷 840-848页

作者： z.li D.Wu TheStatekeyLaboratoryofRollingandAutomation NortheasternUniversityShenyang110004China／／InstituteofAeronauticalEngineeringShenyangl10034China TheStatekeyLaboratoryofRollingandAutomation NortheasternUniversityShenyang110004China

Larger amount of austenite could be retained in an intercritically heat-treated bainite- transformed steel. The elongation and the strength-ductility balance of the steel could be enhanced considerably due to strain-induced martensite transformation and transformation- induced plasticity (TRIP) of retained austenite. The effects of test temperature and strain rate on the mechanical properties and strain induced transformation behavior of retained austenite in the steel were investigated. Total elongation and strength-ductility balance of the specimen reached maximum when it strained at a strain rate of 2.8×10-4s-1 and at 350℃. The relation between test temperature and tensile properties showed the same tendency at three kinds of strain rates. Flow stress increased considerably with decreasing the strain rate.

关键词： strain rate mechanical property strain-induced transformation trans- formation-induced plasticity (TRIP)