检索结果-南通市图书馆

Solid Bronsted acidity boosts adsorption reactivity of nano-adsorbent for water decontamination

Frontiers of Environmental Science & Engineering 2024年第7期18卷 23-34页

作者： Sikai Cheng Zhixian Li Kaisheng zhang Qingrui zhang Xiaolin zhang Bingcai Pan State Key Laboratory of Pollution Control and Resource Reuse School of the EnvironmentNanjing UniversityNanjing 210023China Environmental Materials and Pollution Control Laboratory Institute of Solid State PhysicsHFIPSChinese Academy of SciencesHefei 230031China State Key Laboratory of Metastable Materials Science and Technology Yanshan UniversityQinhuangdao 066004China Hebei Key Laboratory of Heavy Metal Deep-remediation in Water and Resource Reused Qinhuangdao 066004China Research Center for Environmental Nanotechnology(ReCENT) Nanjing UniversityNanjing 210023China

Despite the development of various Lewis acidic nano-adsorbents for fluoride removal through innersphere coordination,strong competition for hydroxyl ions still hinders efficient water *** addition,the critical issue of polysilicate scaling that results from the ubiquitous silicates must be *** tackle these issues,an alternative approach to enhancing adsorption reactivity by modifying nano-adsorbents with dual Lewis and Bronsted acidity is *** feasibility of this approach is demonstrated by growing zirconium phosphate(ZrP)inside a gel-type anion exchanger,N201,to produce nanocomposite ZrP@N201,in which the confined ZrP contained an otherwise metastable amorphous phase with Lewis acidic Zr^(4+) sites and Bronsted acidic monohydrogen phosphate groups(-O_(3)POH).Compared with the Lewis acidic nano-zirconium oxide analog(HZ0@N201),ZrP@N201 exhibited a greatly improved adsorption capacity(117.9 vs.52.3 mg/g-Zr)and mass transfer rate(3.56×10^(-6) vs.4.55×10^(-7) cm/s),while bulk ZrP produced a thermodynamically stableα-phase with Bronsted acidity that exhibited negligible adsorption capability toward *** enhanced defluoridation activity of ZrP@N201 is attributed to Bronsted acidity and the increased outer electron density of ZA+sites,as corroborated using XPS and solid-state NMR ***,Bronsted acidity strengthens the resistance of ZrP@N201 to silicate,allowing its full regeneration during cyclic *** tests demonstrated 3-10 times the amount of clean water from(waste)for ZrP@N201 as compared to both HZO@N201 and the widely used activated aluminum *** study highlights the potential of developing nano-adsorbents with dual acidities for various environmental remediation applications.

关键词： Nanocomposite Selective adsorption Fluoride removal Dual Lewis and Bronsted acidity Regeneration

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Flexible regulation engineering of titanium nitride nanofibrous membranes for efficient electromagnetic microwave absorption in wide temperature spectrum

引用

Nano Research 2024年第3期17卷 1666-1675页

作者： Cuiping Li Lu zhang Shuai zhang Qiqi Yu Dan Li Lei zhang Chunhong Gong Jingwei zhang Institute of Functional Polymer Composites College of Chemistry and Molecular SciencesHenan UniversityKaifeng 475004China National&Local Joint Engineering Research Center for Applied Technology of Hybrid Nanomaterials Henan UniversityKaifeng 475004China

Simultaneous development of well impedance matching and strong loss capability has become a mainstream method for achieving outstanding electromagnetic microwave absorption(EMWA)performances over wide temperature ***,it is difficult to pursue both due to the mutual restraint of relationship between impedance matching and loss capability about ***,we propose a flexible regulation engineering of titanium nitride(TiN)nanofibrous membranes(NMs,TNMs),which could be distributed uniformly in the polydimethylsiloxane(PDMS)matrix and contributed to the formation of abundant local conductive networks,generating the local conductive loss and enhancing the loss ability of ***,when the TNMs are used as functional units and dispersed in the matrix,the corresponding composites exhibit an outstanding anti-reflection effect on *** hoped,under the precondition of good impedance matching,local conductive loss and polarization loss together improve the loss capacity at room temperature,and polarization loss can compensate the local conductive loss to acquire effective dielectric response at elevated *** from the reasonably synergistic loss ability caused by flexible regulation engineering,the corresponding composites exhibit the perfect EMWA performances in a wide temperature range from 298 to 573 *** work not only elaborates the ponderable insights of independent membrane in the composition-structure-function connection,but also provides a feasible tactic for resolving coexistence of well impedance matching and strong loss capability issues in wide temperature spectrum.

关键词： flexible titanium nitride nanofibrous membranes local conductive loss dielectric loss electromagnetic microwave absorption wide temperature spectrum

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

A Bionic Starfish Adsorption Crawling Soft Robot

引用

Journal of Bionic Engineering 2024年第1期21卷 149-165页

作者： Xiangang Huang Chenghao zhang Wenqi Feng Xiangye zhang Deyuan zhang Yanqiang Liu Institute of Bionic and Micro-Nano Systems School of Mechanical Engineering and AutomationBeihang UniversityBeijing 100191China

A variety of soft wall-climbing robots have been developed that can move in certain *** of these soft robots can only move on conventional surfaces and lack adaptability to complex *** the adaptability of soft robots on complex surfaces is still a challenging *** this end,we study the layered structure of the starfish tube foot and the valve flap structure in the water vascular system,and use an ultrasonic stress detector to study the stiffness distribution of the arm *** by the motion of the starfish,we present a bionic soft wall-climbing robot,which is driven by two groups of pneumatic feet and achieves body bending through active adaptation *** design the structure of the foot to flex to provide driving force,and there are suction cups at the end of the foot to provide *** soft foot has a simple structure design,adapts to a variety of surfaces,and does not damage the surface of the *** stiffness layers achieve stiffness changes by the principle of line *** Central Pattern Generator theory is introduced to coordinately control the multiple feet of the *** experiments,we verify the adaptability of the soft robot to curved *** research may provide a reference for the design and development of crawling soft robots on complex surfaces.

关键词： Starfish Tube foot Biomimetic robot Soft robot Climbing robot

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Synthetic fungal melanin UV absorbers

引用

Science China Chemistry 2024年第9期67卷 3098-3110页

作者： Chao Wang Rong zhang Jianhua zhang Xueqian zhang Hengjie zhang Huan Cao Zhen Yang Yiwen Li College of Polymer Science and Engineering State Key Laboratory of Polymer Materials EngineeringSichuan UniversityChengdu 610065China Department of Radiology Huaxi MR Research CenterFunctional and Molecular Imaging Key Laboratory of Sichuan ProvinceNational Clinical Research Center for GeriatricsWest China HospitalSichuan UniversityChengdu 610041China

Agents with robust ultraviolet(UV)absorption capabilities play a vital role in safeguarding organisms and inorganic materials from UV ***,the synthetic procedures towards these UV absorbers are usually lengthy and complicated,accompanied by undesirable side reactions and the generation of toxic *** nature,allomelanin,a class of melanins variant found in melanized fungi near the Chernobyl nuclear power plant,plays crucial roles in the cell wall of melanized fungi,offering resistance to harsh external environments and promising UV resistance ***,allomelanin can be rapidly biosynthesized via the polymerization of 1,8-dihydroxynaphthalene in presence of enzymes in *** by this,we report here a green enzymatic polymerization strategy to efficiently and eco-friendly synthesize polydihydroxynaphthalene(PDHN)-based artificial allomelanin nanoparticles(NPs)with interesting *** calculations and experimental results demonstrated that the PDHN NPs exhibited excellent UVabsorption capacity,surpassing another widely used artificial melanin,polydopamine(PDA).Moreover,the light absorption mechanism of PDHN NPs was systematically elucidated for the first ***,the PDHN NPs were incorporated with polyvinyl alcohol(PVA)to create an anti-aging composite film with significantly enhanced UV shielding *** potential of these composite films in safeguarding plants from UV damage was meticulously ***,these PDHN NPs were first found to produce hydroxyl radicals(·OH)under UV irradiation,offering antibacterial properties that expand their potential applications.

关键词： melanin artificial allomelanin nanoparticles green synthesis UV absorption antibacterial

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

服装裁片自动抓取技术及其布局方法的研究进展

引用

纺织学报 2024年第6期45卷 227-234页

作者：王建萍沈津竹姚晓凤朱妍西张帆东华大学服装与艺术设计学院上海200051 东华大学现代服装设计与技术教育部重点实验室上海200051 东华大学上海市纺织智能制造与工程一带一路国际联合实验室上海200051 同济大学上海国际设计创新研究院上海200092 苏州柔触机器人科技有限公司江苏苏州215600

为促进服装裁片自动化运输的发展,推动服装加工端完成产业升级,即“机器代人”,实现服装智能制造,综述了目前国内外服装裁片智能抓取技术及其布局方法的研究现状。具体分析了空压吸附式抓取,静电式抓取,针刺式抓取,机械手抓取和软体手... 详细信息

为促进服装裁片自动化运输的发展,推动服装加工端完成产业升级,即“机器代人”,实现服装智能制造,综述了目前国内外服装裁片智能抓取技术及其布局方法的研究现状。具体分析了空压吸附式抓取,静电式抓取,针刺式抓取,机械手抓取和软体手指抓取的原理和特点,阐述了各抓取方式所适用的面料范围,将其在面料表面的布局方式总结为3类:盲式布局抓取、单点布局抓取和多点协同抓取。研究认为软体手指抓取技术具有更广阔的应用前景,并展望了服装裁片智能抓取技术的未来发展趋势,指出提高抓取准确率,提高抓取头的重复定位精度,研发便捷、高效、经济的布局方式,以及研发结合机器视觉技术等人工智能技术的智能抓取方式为未来的重要研究方向。

关键词：自动抓取面料抓取布局规划软体手指服装智能制造

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

激光焊接焊缝显微组织磁光成像研究

引用

制造技术与机床 2020年第8期 17-21页

作者：王春草高向东张艳喜游德勇张南峰广东工业大学广东省焊接工程技术研究中心广东广州510006

针对焊缝显微组织对焊件质量影响问题,对激光焊接焊件不同区域的焊缝显微组织特征进行研究,对不同焊接试验参数下的焊缝成形差异进行分析,提出了一种焊缝显微组织磁光成像检测方法,采用低碳钢平板对接焊,试验共分为4组,将焊缝显微组织... 详细信息

针对焊缝显微组织对焊件质量影响问题,对激光焊接焊件不同区域的焊缝显微组织特征进行研究,对不同焊接试验参数下的焊缝成形差异进行分析,提出了一种焊缝显微组织磁光成像检测方法,采用低碳钢平板对接焊,试验共分为4组,将焊缝显微组织磁光图像与扫描电镜图像相结合,分析恒定磁场下不同区域焊接接头的显微组织磁光成像差异和焊缝的晶粒组成及特征。研究结果表明,在磁光图像中焊件焊缝可以分为熔合区、热影响区和母材区,且这3个区域的晶粒组成、大小及形态有明显的差异,恒定磁场下焊缝磁光图的颜色、亮度及灰度值反映了焊缝的成形质量。

关键词：激光焊接磁光成像焊接接头

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

西安市售水产品中甲醛本底值测定及来源分析

引用

农产品加工（下） 2018年第12期 53-55页

作者：邹力张炎茜严烨陕西省产品质量监督检验研究院陕西西安710000 陕西科技大学陕西西安710021 西安悟空检测科技有限公司陕西西安710000

为了解西安市售水产品甲醛本底值,为水产品管理提供依据,对西安市售鱼类、虾类、贝类、蟹类等100个水产样品甲醛本底含量进行测定。结果表明,52个样品检出了甲醛,甲醛含量为0.48～63.37 mg/kg,鱿鱼类样品中甲醛含量较高,其次为鱿鱼样品... 详细信息

为了解西安市售水产品甲醛本底值,为水产品管理提供依据,对西安市售鱼类、虾类、贝类、蟹类等100个水产样品甲醛本底含量进行测定。结果表明,52个样品检出了甲醛,甲醛含量为0.48～63.37 mg/kg,鱿鱼类样品中甲醛含量较高,其次为鱿鱼样品和虾类样品,贝类样品中甲醛含量最低,多数水产品中甲醛的本底含量处于低端水平。水产品中甲醛含量存在一定差异,究其原因,受种类、氧化三甲胺酶含量及加工过程影响较大。研究对于水产品安全风险评估、政府监管机构制定判定标准提供参考依据。

关键词：水产品甲醛本底值分析

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Multi-instance partial-label learning: towards exploiting dual inexact supervision

引用

Science China(Information Sciences) 2024年第3期67卷 48-61页

作者： Wei TANG Weijia zhang Min-Ling zhang School of Computer Science and Engineering Southeast University Key Laboratory of Computer Network and Information Integration (Southeast University) Ministry of Education School of Information and Physical Sciences The University of Newcastle

Weakly supervised machine learning algorithms are able to learn from ambiguous samples or labels, e.g., multi-instance learning or partial-label learning. However, in some real-world tasks, each training sample is associated with not only multiple instances but also a candidate label set that contains one groundtruth label and some false positive labels. Specifically, at least one instance pertains to the ground-truth label while no instance belongs to the false positive labels. In this paper, we formalize such problems as multi-instance partial-label learning(MIPL). Existing multi-instance learning algorithms and partial-label learning algorithms are suboptimal for solving MIPL problems since the former fails to disambiguate a candidate label set, and the latter cannot handle a multi-instance bag. To address these issues, a tailored algorithm named MIPLGP, i.e., multi-instance partial-label learning with Gaussian processes, is *** first assigns each instance with a candidate label set in an augmented label space, then transforms the candidate label set into a logarithmic space to yield the disambiguated and continuous labels via an exclusive disambiguation strategy, and last induces a model based on the Gaussian processes. Experimental results on various datasets validate that MIPLGP is superior to well-established multi-instance learning and partial-label learning algorithms for solving MIPL problems.

关键词： machine learning multi-instance partial-label learning multi-instance learning partial-label learning Gaussian processes

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Effect of samarium doping on the activity and sulfur resistance of Ce/MnFeO_(x) catalyst for low-temperature selective catalytic reduction of NO_(x) by ammonia

引用

Chinese Journal of Chemical Engineering 2024年第7期71卷 272-282页

作者： Qiyao zhang Shuangshuang zhang Xu Hu Yongmin Huang Key Laboratory of Specially Functional Polymeric Materials and Related Technology School of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai 200237China

The self-made MnFeO_(x) catalysts doped with cerium and samarium were prepared by impregnation method for low-temperature selective catalytic reduction(SCR)by *** this work,the surface properties of the series of MnFe-based catalysts were *** results indicate Sm-modified catalyst have superior low-temperature SCR activity;NO_(x) conversion maintained at nearby to 100%at 90℃ to 240℃.In addition,The N_(2) selectivity of Sm doping remains above 80%in the range of 60℃ to 150℃.In SO_(2) poisoning test,the NO_(x) conversion can be remained>90%after 10 h of *** XPS,NH_(3)-TPD and H_(2)-TPR results show the catalyst with Sm doping enhances the acid sites and oxidation catalytic sites of mixed oxides serves for improving oxygen vacancies and transfer *** situ diffuse reflaxions infrared Fourier transformations spectroscopy(DRIFTS)results show that NO_(x) is more easily adsorbed on the surface after Sm doping,which provided favorable conditions for the NH_(3)-SCR reaction to *** reaction at the catalyst surface will follow the L-H reaction mechanism by transient reaction test.

关键词： SCR Sm doping Catalyst Sulfur resistance In situ DRIFTS Selectivity

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Microstructure evolution and strengthening mechanism of high -performance powder metallurgy TA15 titanium alloy by hot rolling

引用

International Journal of Minerals,Metallurgy and Materials 2024年第6期31卷 1426-1436页

作者： Ying Gao Ce zhang Jiazhen zhang Xin Lu Beijing Advanced Innovation Center for Materials Genome Engineering State Key Laboratory for Advanced Metals and MaterialsInstitute for Advanced Ma-terials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China National Engineering Research Center for Advanced Rolling Technology National Engineering Research Center for Flat Rolling EquipmentInstitute of Engin-eering TechnologyUniversity of Science and Technology BeijingBeijing 100083China

Hot deformation of sintered billets by powder metallurgy(PM)is an effective preparation technique for titanium alloys,which is more significant for high-alloying *** this study,Ti–6.5Al–2Zr–Mo–V(TA15)titanium alloy plates were prepared by cold press-ing sintering combined with high-temperature hot *** microstructure and mechanical properties under different process paramet-ers were *** microscope,electron backscatter diffraction,and others were applied to characterize the microstructure evolution and mechanical properties strengthening *** results showed that the chemical compositions were uniformly dif-fused without segregation during sintering,and the closing of the matrix craters was accelerated by increasing the sintering *** block was hot rolled at 1200℃ with an 80%reduction under only two passes without *** strength and elongation of the plate at 20–25℃ after solution and aging were 1247 MPa and 14.0%,respectively,which were increased by 24.5%and 40.0%,respect-ively,compared with the as-sintered alloy at 1300℃.The microstructure was significantly refined by continuous dynamic recrystalliza-tion,which was completed by the rotation and dislocation absorption of the substructure surrounded by low-angle grain *** hot rolling combined with heat treatment,the strength and plasticity of PM-TA15 were significantly improved,which resulted from the dense,uniform,and fine recrystallization structure and the synergistic effect of multiple slip systems.

关键词： elemental powder powder metallurgy titanium alloy hot rolling strength and plasticity

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：