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Preparation and Structure-Property Regulation Mechanism of Reversible Thermochromic Polydiacetylene

Chinese Journal of Polymer Science 2024年第8期42卷 1111-1121页

作者： Zhi-Qing ge Shuo Yan Zu-Xiong Pan Shan Lei Xuan-Zhi Mao Chu Zhao Mo-Zhen Wang xue-wu ge Key Laboratory of Precision and Intelligent Chemistry Department of Polymer Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China Marshall Laboratory of Biomedical Engineering International Cancer CenterLaboratory of Evolutionary Theranostics(LET)School of Biomedical EngineeringShenzhen University Medical SchoolShenzhen UniversityShenzhen 518055China Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China University of Chinese Academy of Sciences Beijing 100049China

The thermochromic mechanism and the structure-property regulation principle of reversible thermochromic polydiacetylene(PDA)materials have always been a challenging *** this work,a series of diacetylene monomers(m-PCDA)containing phenyl and amide or carboxyl groups were synthesized from 10,12-pentacosadiynoic acid(PCDA)through the esterification or amidation *** effects of the number and the distribution of the functional groups in m-PCDA molecules on their solid-state polymerization capability,and the thermochromic mechanism of their corresponding polymers(m-PDA)were investigated and discussed in *** results show that the m-PCDA monomers containing both benzene ring and groups that can form hydrogen bonding interactions have strong intermolecular interaction,and are easy to carry out the solid phase polymerization under 254-nm UV irradiation to obtain the corresponding new thermochromic m-PDA *** thermochromic behavior of m-PDA depends on its melting *** initial color-change temperature(blue to red)is determined by the onset melting tem perature,and the temperature range in which reversible color recovery can be achieved by repeat heating-cooling treatment is determined by its melting *** to the proposed thermochromic mechanism of PDA,various new PDA materials with precise thermochromic temperatu res and reversible thermochromic temperature ra nges can be designed and synthesized through the appropriate introduction of benzene ring and groups that can form hydrogen bonding interactions into the molecular structure of linear diacetylene *** work provides a perspective to the precise molecular structure design and the property regulation of the reversible thermochromic PDA materials.

关键词： Polydiacetylene Thermochromism Hydrogen bonding Chemical modification

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Coupling WO_(3-x) dots-encapsulated metal-organic frameworks and template-free branched polymerization for dual signal-amplified electrochemiluminescence biosensing

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Chinese Chemical Letters 2024年第4期35卷 469-474页

作者： Fei Yin Erli Yang xue ge Qian Sun Fan Mo Guoqiu wu Yanfei Shen Medical School Southeast UniversityNanjing 210009China Center of Clinical Laboratory Medicine Zhongda HospitalSoutheast UniversityNanjing 210009China Jiangsu Provincial Key Laboratory of Critical Care Medicine Southeast UniversityNanjing 210009China

Developing accurate and sensitive DNA methyltransferase(MTase) analysis methods is essential for early clinical diagnosis and development of antimicrobial drug targets. In this work, by coupling WO_(3-x) dotsencapsulated metal-organic frameworks(MOFs) as co-reactants and terminal deoxynucleotidyl transferase(Td T)-mediated template-free branched polymerization, a dual signal-amplified electrochemiluminescent(ECL) biosensor was constructed to detect DNA adenine methylation(Dam) MTase. The employment of WO_(3-x) dots-encapsulated MOFs(i.e., NH_(2)-UIO66@WO_(3-x) ) was not only beneficial for biomolecule conjugation because of the abundant amino groups but also led to a 7-fold enhanced ECL response due to the increased loading of WO_(3-x). Moreover, Td T-mediated template-free branched polymerization promoted the capture of ECL emitters on the electrode surface, achieving 20-fold enhanced signal amplification. The presented ECL biosensor demonstrated a low detection limit of 2.4 × 10^(-4)U/m L, and displayed high reliability for the detection of Dam MTase in both spiked human serum and E. coli cell samples, and for the screening of potential inhibitors. This study opens a new avenue for designing a dual signal amplificationbased ECL bioassay for Dam MTase and screening inhibitors in the fields of clinical diagnosis and drug development.

关键词： Dual signal-amplified electrochemiluminescence WO_(3-x)dots MOFs Template-free branched polymerization DNA methyltransferase

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Synthesis and Optical Properties of ZnO Nanoparticles in Submicron PS Hollow Reactors

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Chinese Journal of Chemical Physics 2012年第6期25卷 719-724,I0004页

作者： xue-feng Huang Fei-fei Ju Mo-zhen Wang xue-wu ge CAS Key Laboratory of Soft Matter Chemisry Department of Polymer Science and EngineeringUniversity of Science and Technology of China Hefei 230026 China

ZnO nanoparticles 首先通过核心壳的二拍子的圆舞胀大过程在亚微米 PS 空 microspheres 被包含结构化的 PMMA/PS (PMMA：polymethyl methaorylate ) 在酸碱的答案的 microspheres，和 ZnO 先锋，即乙醇答案(CH3COO ) 2Zn 和 LiOH。传... 详细信息

ZnO nanoparticles 首先通过核心壳的二拍子的圆舞胀大过程在亚微米 PS 空 microspheres 被包含结构化的 PMMA/PS (PMMA：polymethyl methaorylate ) 在酸碱的答案的 microspheres，和 ZnO 先锋，即乙醇答案(CH3COO ) 2Zn 和 LiOH。传播电子显微镜， X 光检查衍射，和 thermogravimetric 分析结果证明乙醇答案的喂的顺序(CH3COO ) 在第二胀大的步的 2Zn 和 LiOH 在他们的水晶形式上在装载效率和 ZnO nanoparticles，而是很少的尺寸上有大影响。光致发光和 ZnO/PS microspheres 的紫外力的吸收行为证明 PS 壳罐头有效地避免熄灭效果的荧光。

关键词： ZnO纳米粒子亚微米空心电抗器 PS 光学性质聚甲基丙烯酸甲酯制备空心微球

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Curved anisotropic polaritons

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Frontiers of physics 2024年第3期19卷 217-224页

作者： Tao Hou Yixiao ge Shuwen xue Huanyang Chen Department of Physics and Institute of Electromagnetics and Acoustics Xiamen UniversityXiamen 361005China Jiujiang Research Institute of Xiamen University Jiujiang 332000China

The curved surface has emerged as new research platform for understanding and manipulating novel electromagnetic behaviors in complex media. In this paper, we explore the anisotropic polaritons on the spherical surface based on Maxwell’s fish-eye metric through stereographic projection. Additionally, this phenomenon can be extended to spindle surface by conformal mapping. Our calculations and simulations demonstrate the elliptic and hyperbolic polaritons, excited by an electric dipole on the sphere, will self-focus or focus on the poles on the sphere affected by anisotropic permittivity. Furthermore, we reveal the optical singularity nature of the curved hyperbolic polaritons from the perspective of transformation optics by obtaining the equivalent optical refractive index profiles and the particle potential energy. Based on natural anisotropic materials and metamaterials, the curved polaritons have potential applications in curved surface focusing and chaos regulation. This work not only bridges the transformation optics and anisotropic polaritons at curved surface, but also provides a new route to surface optical field manipulation.

关键词： anisotropic polaritons transformation optics curved surface

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Glaucoma drainage device implantation and cyclophotocoagulation in the management of refractory glaucoma after Descemet-stripping automated endothelial keratoplasty

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International Journal of Ophthalmology(English edition) 2024年第2期17卷 257-264页

作者： Min-Shu Wang xue-Chuan Dong Mi-Yun Zheng Xiang Fan ge-ge Xiao Jing Hong Ling-Ling wu Department of Ophthalmology Peking University Third HospitalBeijing 100191China Key Laboratory of Restoration of Damaged Ocular Nerve Beijing 100191China NIMO Ophthalmology Research Institute Beijing 100176China Department of Ophthalmology the First Hospital of PutianTeaching HospitalFujian Medical UniversityPutian 351100Fujian ProvinceChina

AIM:To compare the surgical outcomes of glaucoma drainage device implantation(GDI)and trans-scleral neodymium:YAG cyclophotocoagulation(CPC)in the management of refractory glaucoma after Descemetstripping automated endothelial keratoplasty(DSAEK).METHODS:This retrospective study on observational case series enrolled 29 patients who underwent DSAEK and posterior anti-glaucoma surgery(15 with GDI and 14 with CPC).The main outcome measures were intraocular pressure(IOP),glaucoma surgery success rate(defined as IOP of 6–21 mm Hg without additional anti-glaucoma operation),number of glaucoma medications,endothelial graft status,and best-corrected visual acuity(BCVA).RESULTS:The mean follow-up time was 34.1 and 21.0mo for DSAEK or glaucoma surgeries,both for the GDI and CPC *** groups showed significant IOP reduction after glaucoma *** GDI group presented a significantly higher success rate in IOP control than the CPC group(60%vs 21.4%,P=0.03).Both procedures significantly decreased the number of glaucoma medications(P=0.03).Forty percent and 57%of cases in the GDI and the CPC group,respectively,experienced endothelial graft failure during follow-up(P=0.36).Significantly worse BCVA after surgery was observed in the CPC group but not in the GDI ***:Both GDI and CPC significantly decrease IOP in eyes with glaucoma after *** is preferable to CPC in refractory glaucoma cases after DSAEK,as it manifests a significantly higher success rate for IOP control,similar endothelial graft failure rate,and relatively preserves BCVA than CPC.

关键词： glaucoma drainage device implantation cyclophotocoagulation refractory glaucoma Descemetstripping automated endothelial keratoplasty

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Mechanical property of cylindrical sandwich shell with gradient core of entangled wire mesh

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Defence Technology（防务技术） 2024年第1期31卷 510-522页

作者： Xin xue Chao Zheng Fu-qiang Lai xue-qian wu Institute of Metal-rubber&Vibration Noise School of Mechanical Engineering and AutomationFuzhou UniversityFuzhou350116China Fujian Metallurgical Industry Design Institute Fuzhou350116China

To explore the wide-frequency damping and vibration-attenuation performances in the application of aerospace components,the cylindrical sandwich shell structure with a gradient core of entangled wire mesh was proposed in this ***,the gradient cores of entangled wire mesh in the axial and radial directions were prepared by using an in-house Numerical Control weaving machine,and the metallurgical connection between skin sheets and the gradient core was performed using vacuum ***,to investigate the mechanical properties of cylindrical sandwich shells with axial or radial gradient cores,quasi-static and dynamic mechanical experiments were carried *** primary evaluations of mechanical properties include secant stiffness,natural frequency,Specific Energy Absorption(SEA),vibration acceleration level,and so *** results suggest that the vibration-attenuation performance of the sandwich shell is remarkable when the high-density core layer is at the end of the shell or abuts the inner *** axial gradient material has almost no influence on the vibration frequencies of the shell,whereas the vibration frequencies increase dramatically when the high-density core layer approaches the ***,compared to the conventional sandwich shells,the proposed functional grading cylindrical sandwich shell exhibits more potential in mass reduction,stiffness designing,and energy dissipation.

关键词： Entangled wire mesh Gradient cylindrical sandwich shell Vacuum brazing Secant stiffness Damping

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Some Convergence Properties for Weighted Sums of Martingale Difference Random Vectors

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Acta Mathematica Sinica,English Series 2024年第4期40卷 1127-1142页

作者： Yi wu xue Jun WANG School of Big Data and Artificial Intelligence Chizhou UniversityChizhou 247000P.R.China School of Big Data and Statistics Anhui UniversityHefei 230601P.R.China

Let{X_(ni),F_(ni);1≤i≤n,n≥1}be an array of R^(d)martingale difference random vectors and{A_(ni),1≤i≤n,n≥1}be an array of m×d matrices of real *** this paper,the Marcinkiewicz-Zygmund type weak law of large numbers for maximal weighted sums of martingale difference random vectors is obtained with not necessarily finite p-th(1gence and strong law of large numbers are established under some mild *** application to multivariate simple linear regression model is also provided.

关键词： Martingale difference random vectors weighted sums Marcinkiewicz–Zygmund type weak law of large numbers complete convergence strong law of large numbers multivariate simple linear regression model

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Attack-Resilient Distributed Cooperative Control of Virtually Coupled High-Speed Trains via Topology Reconfiguration

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IEEE/CAA Journal of Automatica Sinica 2024年第4期11卷 1066-1068页

作者： Shunyuan Xiao Xiaohua ge Qing wu the Institute of Advanced Technology Nanjing University of Posts and TelecommunicationsNanjing 210023China the School of Science Computing and Engineering TechnologiesSwinburne University of TechnologyMelbourne VIC 3122Australia the School of Engineering and Technology Central Queensland UniversityRockhampton QLD 4701Australia

Dear Editor,This letter addresses the resilient distributed cooperative control problem of a virtually coupled train convoy under stochastic disturbances and cyber *** main purpose is to achieve distributed coordinati... 详细信息

关键词： prescribed Speed trains

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In-situ Enhanced Toughening of Poly（ethylene terephthalate）/elastomer Blends via Gamma-Ray Radiation at Presence of Trimethylolpropane Triacrylate

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Chinese Journal of Chemical Physics 2016年第6期29卷 703-709,I0001,I0002页

作者： Li-zhao Xie Le-chen Chen Mo-zhen Wang Qi-chao wu Xiao Zhou xue-wu ge CASKeyLaboratoryofSoftMatterChemistry DepartmentofPolymerScienceandEngineeringUniversityofScienceandTechnologyofChinaHefei230026China GuangdongTiananNewMaterialCo. Ltd.Foshan528000China

Gamma 光线放射总是是在聚合物混合修改界面的性质的一个方便、有效的方法。在这个工作， trimethylolpropane triacrylate (TMPTA ) 的小数量被合并到(乙烯 terephthalate )( 宠物) poly， /random terpolymer 弹性体(ST2000 ) 由融化... 详细信息

Gamma 光线放射总是是在聚合物混合修改界面的性质的一个方便、有效的方法。在这个工作， trimethylolpropane triacrylate (TMPTA ) 的小数量被合并到(乙烯 terephthalate )( 宠物) poly， /random terpolymer 弹性体(ST2000 ) 由融化混合相配。TMPTA 的存在将在相配的高温度导致宠物和 ST2000 分子的链的 crosslinking，导致在影响力量的改进但是在张力的力量的损失。当 PET/ST2000 混合被 gamma 光线放射照耀时，综合机械性质能在高吸收的剂量显著地被提高。在 100 kGy 的剂量的照耀的样品甚至 couldnt 在影响测试负担下面被打破，并且同时，将近不有张力的力量的损失。基于混合的断裂影响的表面形态学的分析，在高吸收的剂量的 gamma 光线放射能在 situ 推进，这能被结束由支持 TMPTA 和聚合物链的 crosslinking 反应提高界面的粘附。作为结果， PET/ST2000 混合的坚韧和力量能戏剧性地被改进。这个工作向一个面部、实际的方法提供到聚合物混合的制造高坚韧和力量。

关键词：三羟甲基丙烷三丙烯酸酯对苯二甲酸乙二醇酯聚合物共混物共聚物弹性体 γ射线辐射增强增韧 TMPTA 原位

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Synthesis and morphology control of raspberry-like poly(ethylene terephthalate)/polyacrylonitrile microspheres

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Chinese Chemical Letters 2016年第2期27卷 195-199页

作者： Yong-Fei Xu Mo-Zhen Wang Qi-Chao wu Xiao Zhou xue-wu ge CAS Key Laboratory of Soft Matter Chemistry Department of Polymer Science and Engineering University of Science and Technology of China School of Materials and Chemical Engineering Anhui Jianzhu University Guangdong Tianan New Material Co. Ltd.

The fabrication of raspberry-like poly（ethylene terephthalate）/polyacrylonitrile（PET/PAN） microspheres by g-ray radiation-induced polymerization of acrylonitrile on micron-sized PET microspheres were first reported in this work. A PET emulsion was firstly prepared by dispersing a PET solution with 1,1,2,2-tetrachloroethane/phenol mixture as the solvent into an aqueous solution of sodium dodecyl ***, PET microspheres were formed by precipitating the PET emulsion droplets from ethanol. The influence of the PET solvent and the weight ratio of ethanol to PET emulsion on the morphology of the PET microspheres had been investigated. After the surface of the prepared PET microspheres was grafted with poly（acrylic acid）, the grafting polymerization of AN also had been successfully initiated by g-ray radiation to form PAN microspheres with a size of about 100 nm on the PET microspheres. This work provides a new method to fabricate micron-sized PET microspheres, and further expands the functionalization of PET and its application fields.

关键词： PET emulsion Emulsion precipitation PET microsphere Raspberry-like microsphere PET/PAN composite microspheres

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