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External-to-internal synergistic strategy to enable multi-scale stabilization of LiCoO_(2)at high-voltage

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Journal of Energy Chemistry 2023年第1期76卷 516-527,I0013页

作者： Shuaipeng hao Yunjiao Li Jiachao Yang shan Wang Zhouliang Tan xiaoming xi Zhenjiang He Panpan Zhang School of Metallurgy and Environment Central South UniversityChangsha 410083HunanChina Engineering Research Center of the Ministry of Education for Advanced Battery Materials Central South UniversityChangsha 410083HunanChina Changsha Research Institute of Mining and Metallurgy Changsha 410083HunanChina Office of Laboratory and Equipment Management Xinjiang UniversityUrumqi 830000XinjiangChina

High-voltage LiCoO_(2)(LCO)offers a prelude to breaking the bottleneck of the energy density of lithium-ion batteries,however,LiCoO_(2)is subject to serious structural and interfacial degradation above voltages>4.55 V(***/Li^(+)).Herein,an in-situ Li_(6.25)La_(3)Zr_(2)A_(l0.25)O_(12)(LLZAO)layer is constructed on the LCO surface to achieve operating voltage at 4.6 *** detailed characterizations(ex-situ XRD,ex-situ Raman,DFT,etc.)reveal that the LLZAO layer greatly enhances Li+conductivity attributed to the ionconducting layer on the surface/interface,and closely combines with LiCoO_(2)particle to ensure stable cathode/electrolyte interface,thus suppressing the highly reactive Co^(4+)and O^(-)triggered surface side reactions at ***,the introduction of La^(3+)/Zr^(4+)/Al^(3+)with a larger ionic radius(La^(3+)/Zr^(4+)are larger than Co^(3+))and weaker electronegativity(La/Zr/Al are weaker than Co)into Co^(3+)sites readjusts the electron cloud density between Co–O–Li,which reinforces the Co–O bond and widens the band-center gap of Co 3d and O 2p,thus restraining the detrimental phase transition(from H3 to H1-3 phase)and the formation of Co_(3)O_(4)spinel phase(attributed to lattice oxygen release),subsequently alleviating the particle cracking and structural collapse during repeated Li^(+)de/***,after 100 cycles at 3.0–4.6 V,LCO@1.0LLZAO exhibits a superior discharge capacity of 188.5 m A h g^(-1),with a capacity retention of 85.1%.The above research has brought about meaningful guidance for the evolution of cathode materials with high voltage.

关键词： LLZAO layer High-voltage LiCoO_(2) Irreversible phase transition Band-center gap Lattice oxygen release

Conductive Film with Flexible and Stretchable Capability for Sensor Application and Stealth Information Transmission

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Chinese Journal of Polymer Science 2021年第2期39卷 164-173,I0005页

作者： Yi-Fei shan Kun Yang Zhi-xi Li xiao-xiao Wang hao Li Yong-Yan Cui College of Chemical Engineering and Materials Science Tianjin University of Science and TechnologyTianjin 300457China Institute of Molecular Aggregation Science Tianjin UniversityTianjin 300072China

Flexible and wearable strain sensors for human-computer interaction,health monitoring,and soft robotics have drawn widespread attention to promising applications in the next generation of artificial intelligence ***,conventional semiconductor sensors are difficult to meet the requirements of flexibility and ***,we reported a kind of novel and simple sensor based on layer-by-layer(LBL)*** nanotubes(CNTs)layer provides high ductility and stability in the process of tension sensing,while silver layer provides low initial resistance and fast reflecting in the process of tension *** method ensures the uniformity of the conductive *** sensor has superior sheet resistance of 9.44Ω/sq.,high elongation at break of 104%.For sensing capability,the sensor has wide reflecting range of 60%,high gauge factor(GF)of 1000 up to 60%strain,fast reflecting time of 165 *** reliability and stability have also been *** is also worth mentioning that the entire process does not require any expensive equipments,complicated processes or harsh experimental *** above features provide an idea for large-scale application of flexible stretchable sensors.

关键词： Strain sensor Flexibility Silver films Carbon nanotubes Human motion monitoring

Boosting cationic and anionic redox activity of Li-rich layered oxide cathodes via Li/Ni disordered regulation

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Journal of Energy Chemistry 2025年第1期100卷 533-543页

作者： Zewen Liu Zhen Wu hao Wang Xudong Zhang Yuanzhen Chen Yongning Liu Shengwu Guo Shenghua Chen Yanli Nan Yan Liu State Key Laboratory for Mechanical Behavior of Materials Xi'an Jiaotong University School of Materials Science and Engineering Xi'an University of Architecture and Technology Hefei Advanced Computing Center Operation Management Corp Ltd Network Information Center Xi'an Jiaotong University

Lithium-rich layered oxides （LLOs） are increasingly recognized as promising cathode materials for nextgeneration high-energy-density lithium-ion batteries （LIBs）.However,they suffer from voltage decay and low initial Coulombic efficiency （ICE） due to severe structural degradation caused by irreversible O ***,we introduce a three-in-one strategy of increasing Ni and Mn content,along with Li/Ni disordering and TM–O covalency regulation to boost cationic and anionic redox activity simultaneously and thus enhance the electrochemical activity of *** target material,Li1.2Ni0.168Mn0.558Co0.074O2（L1）,exhibits an improved ICE of 87.2%and specific capacity of 293.2 mA h g-1and minimal voltage decay of less than 0.53 m V cycle-1over 300 cycles at 1C,compared to Li1.2Ni0.13Mn0.54Co0.13O2（Ls）(274.4 mA h g-1for initial capacity,73.8%for ICE and voltage decay of 0.84 mV/cycle over 300 cycles at 1C).Theoretical calculations reveal that the density of states （DOS） area near the Fermi energy level for L1 is larger than that of Ls,indicating higher anionic and cationic redox reactivity than ***,L1 exhibits increased O-vacancy formation energy due to higher Li/Ni disordering of 4.76%（quantified by X-ray diffraction Rietveld refinement） and enhanced TM–O covalency,making lattice O release more difficult and thus improving electrochemical *** increased Li/Ni disordering also leads to more Ni2+presence in the Li layer,which acts as a pillar during Li+de-embedding,improving structural *** research not only presents a viable approach to designing low-Co LLOs with enhanced capacity and ICE but also contributes significantly to the fundamental understanding of structural regulation in high-performance LIB cathodes.

关键词： Ice

疏棉状嗜热丝孢菌脂肪酶LipTL的酶学性质及脱胶应用研究

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食品与发酵工业 2025年第1期51卷 41-46页

作者：邵化单明明王琼波徐瑞敏陈曦魏涛郑州轻工业大学食品与生物工程学院河南郑州450001 漯河医学高等专科学校食品营养系河南漯河462002

酶法脱胶技术在油脂精炼行业应用潜力巨大,磷脂酶是酶法脱胶技术中的主要用酶,但因现有磷脂酶资源在底物选择性、温度稳定性方面难以满足工业脱胶工艺的要求,限制了磷脂酶在油脂精炼行业中的大规模应用。研究表明,来自疏棉状嗜热丝孢菌(... 详细信息

酶法脱胶技术在油脂精炼行业应用潜力巨大,磷脂酶是酶法脱胶技术中的主要用酶,但因现有磷脂酶资源在底物选择性、温度稳定性方面难以满足工业脱胶工艺的要求,限制了磷脂酶在油脂精炼行业中的大规模应用。研究表明,来自疏棉状嗜热丝孢菌(Thermomyces lanuginosus)的脂肪酶(LipTL)具有水解磷脂的功能。该研究利用大肠杆菌构建LipTL的基因工程菌,对LipTL进行异源表达,探究LipTL的酶学性质和油脂脱胶效果。序列比对显示,该酶与磷脂酶A1具有高度相似性;SDS-PAGE结果表明,LipTL分子质量约为30 kDa;LipTL的最适温度为55℃、最适pH值为9.0,在55℃条件下处理2 h仍能保持90%以上的相对活力。LipTL在脱胶反应6 h后,将大豆油和花生油的残磷量分别降至5.2、4.9 mg/kg,具有良好的脱胶效果。该研究结果证实该脂肪酶可用于油脂脱胶,不仅为酶法脱胶提供新的酶源,也为该酶的后续改造提供了研究基础。

关键词：疏棉状嗜热丝孢菌脂肪酶酶法脱胶同源建模酶学性质

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基于有限元仿真的后车门抗凹性能对比及优化

机械工程师 2025年第1期 110-113,118页

作者：蒋豪席向军成都盛名汽车科技有限公司成都611730

运用有限元仿真技术,使用3种压头类型对某乘用车后车门进行抗凹仿真分析,通过对比试验数据来判断哪种压头类型更贴近试验结果,并在此压头的模型上对后车门进行结构性优化以满足主机厂的车门抗凹强度目标值,其优化方式主要是对后车门外... 详细信息

运用有限元仿真技术,使用3种压头类型对某乘用车后车门进行抗凹仿真分析,通过对比试验数据来判断哪种压头类型更贴近试验结果,并在此压头的模型上对后车门进行结构性优化以满足主机厂的车门抗凹强度目标值,其优化方式主要是对后车门外板添加环氧补强胶片以及偏移外板内部防撞横梁位置,以提高车门抗凹能力。

关键词：有限元仿真技术抗凹仿真结构性优化目标值

An Intrinsic Model for the Polarization Position Angle Swing Observed in QSO 1150+812

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Chinese Journal of Astronomy and Astrophysics 2004年第1期4卷 37-50页

作者： shan-JieQian xi-ZhenZhang NationalAstronomicalObservatories ChineseAcademyofSciencesBeijing100012

The rapid polarization position angle swing of ~ 180° observed in QSO 1150+812 at 2cm by Kochenov and Gabuzda is quite a regular event. One interesting property of the event is that, during the time of the swing the polarized flux density remained almost constant. We suggest that such an event can be explained in terms of a relativistic thin shock propagating through a uniform helical magnetic field, giving rise to relativistic aberration effects as the transverse field component rotates. The model may also be applicable to other similar events in which variations in polarization are not accompanied by variations in total flux density.

关键词： radio continuum: galaxies polarization quasars: individual: QSO 1150+812

Theoretical Study of Haloacetonitrile Anions： CH2XCN^- （X=F, Cl）

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Chinese Journal of Chemical Physics 2008年第3期21卷 255-262页

作者： xin-wen Zhang Mei Li shan-xi Tian Hefei National Laboratory for Physical Sciences at Microscale University of Science and Technologyof China Hefei 230025 China Department of Chemical Physics University of Science and Technology of China Hefei 230026China

Haloacetonitrile anions CH2XCN- （X=F, Cl） were studied by HF-SCF, Becke3-LYP, and MP2 methods together with the Dunning＇s basis set aug-cc-PVTZ. The vertical electron attachments to the neutral are endothermic. The geometrically optimized CH2FCN^- is mainly a valence-bounded anion and CH2FCN→CH2CN＋F^- is a nonadiabatic dissociation. This theoretical study in good agreement with the experimental results shows that the Becke3-LYP method is reasonable in describing the electronic structures of anions and dissociative attachment dynamics, while significant differences between MP2 and Becke3-LYP results are shown for the dissociation potential curves of CH2ClCN→CH2CN＋Cl^-.

关键词： Haloacetonitrile Electron attachment Dissociation dynamics Electron correlation effect

A Note on Calculation of Threshold Resonance by the Method of Complex Scaling

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Chinese Physics Letters 1996年第4期13卷 241-244页

作者： Zhao Mei-shan xiE xi-shun The Janies Franck Institute The University of ChicagoChicagoIllinois 60637USA Department of Physics University of MinnesotaMinneapolisMinnesota 55455USA Department of Physics Southeastern UniversityNanjing210096

A new approach to threshold resonance calculation by the complex scaling method is *** to scattering over a model potential barrier is presented and compared to a direct quantum scattering calculation.

关键词： calculation. scaling quantum

A Weak∞-Functor in Morse Theory

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Acta Mathematica Sinica,English Series 2024年第11期40卷 2571-2614页

作者： shan Zhong SUN Chen xi WANG Department of Mathematics Capital Normal UniversityBeijing100048P.R.China Academy for Multidisciplinary Studies Capital Normal UniversityBeijing100048P.R.China

In the spirit of Morse homology initiated by Witten and Floer,we construct two∞-categories A and *** weak one A comes out of the Morse-Smale pairs and their higher homotopies,and the strict one B concerns the chain complexes of the Morse *** on the boundary structures of the compactified moduli space of gradient flow lines of Morse functions with parameters,we build up a weak∞-functor F:A→*** algebraic structures behind Morse homology are revealed with the perspective of defects in topological quantum field theory.

关键词： Morse function moduli space of gradient flow lines compactifications weak n/∞-category higher morphism homotopy