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Defect engineering in transition-metal(Fe,Co,andNi)-based electrocatalysts for water splitting

Carbon Energy 2024年第6期6卷 165-199页

作者： Kaili Wu Chaojie Lyu Jiarun Cheng Weifan Ding Jiwen Wu Qian Wang woon-ming lau Jinlong Zheng Beijing Advanced Innovation Center for Materials Genome Engineering University of Science and Technology BeijingBeijingChina School of Chemistry and Chemical Engineering Linyi UniversityLinyiChina Institute for Advanced Materials and Technology University of Science and Technology BeijingBeijingChina Shunde Innovation School University of Science and Technology BeijingFoshanChina

Electrocatalytic water splitting seems to be an efficient strategy to deal with increasingly serious environmental problems and energy crises but still suffers from the lack of stable and efficient *** practical electrocatalysts by introducing defect engineering,such as hybrid structure,surface vacancies,functional modification,and structural distortions,is proven to be a dependable solution for fabricating electrocatalysts with high catalytic activities,robust stability,and good *** review is an overview of some relevant reports about the effects of defect engineering on the electrocatalytic water splitting performance of *** detail,the types of defects,the preparation and characterization methods,and catalytic performances of electrocatalysts are presented,emphasizing the effects of the introduced defects on the electronic structures of electrocatalysts and the optimization of the intermediates'adsorption energy throughout the ***,the existing challenges and personal perspectives of possible strategies for enhancing the catalytic performances of electrocatalysts are *** in-depth understanding of the effects of defect engineering on the catalytic performance of electrocatalysts will light the way to design high-efficiency electrocatalysts for water splitting and other possible applications.

关键词： defect engineering electrocatalytic water splitting element doping interfacial engineering vacancy

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Multifunctional catalytic sites regulation of atomic-scale iridium on orthorhombic-CoSe_(2)for high efficiency dual-functional alkaline hydrogen evolution and organic degradation

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Journal of Energy Chemistry 2024年第5期92卷 271-281页

作者： Jingjing Huang Chenglin Zhong Yanjie Xia Jia Liu Guizhen Li Chao Yang Jiahong Wang Qian Wang Zhenbao Zhang Feng Yan Jianghua Wu Yu Deng Zhenjiang Zhou Xingchen He Paul K.Chu woon-ming lau Xue-Feng Yu College of Chemistry and Chemical Engineering Linyi UniversityLinyi 276005ShandongChina Shenzhen Engineering Center for the Fabrication of Two-Dimensional Atomic Crystals Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen 518055GuangdongChina National Laboratory of Solid State Microstructures Jiangsu Key Laboratory of Artificial Functional MaterialsCollege of Engineering and Applied Sciences and Collaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210093JiangsuChina College of Biosystems Engineering and Food Science Zhejiang UniversityHangzhou 310058ZhejiangChina Department of Physics Department of Materials Science and EngineeringDepartment of Biomedical EngineeringCity University of Hong KongTat Chee AvenueKowloonHong KongChina

The earth-abundant and high-performance catalysts are crucial for commercial implementation of hydrogen evolution reaction(HER).Herein,a multifunctional site strategy to construct excellent HER catalysts by incorporating iridium(Ir)ions on the atomic scale into orthorhombic-CoSe2(Ir-CoSe_(2))was *** hydrogen evolution activity in alkaline media such as a low overpotential of 48.7 mV at a current density of 10 mA cm^(-2)and better performance than commercial Pt/C catalysts at high current densities were found in the Ir-CoSe_(2) *** the experiments and theoretical calculations,it was revealed that Ir enabled CoSe_(2)to form multifunctional sites to synergistically catalyze alkaline HER by promoting the adsorption and dissociation of H_(2)O(Ir sites)and optimizing the binding energy for H^(*)on Co *** was noticeable that the electrolytic system comprising the Ir-CoSe_(2)electrode not only produced hydrogen efficiently via HER,but also degraded organic pollutants(Methylene blue).The cell voltage of the dual-function electrolytic system was 1.58 V at the benchmark current density of 50 mA cm^(-2),which was significantly lower than the conventional water splitting *** was indicated that this method was a novel strategy for designing advanced HER electrocatalysts by constructing multifunctional catalytic sites for hydrogen production and organic degradation.

关键词： Orthorhombic-CoSe_(2) Multifunctional sites design Hydrogen evolution reaction Synergistically catalyze Methylene blue oxidation

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Recent progress in cobalt-based compounds as high-performance anode materials for lithium ion batteries

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Rare Metals 2017年第5期36卷 307-320页

作者： Jian Wu woon-ming lau Dong-Sheng Geng Center for Green Innovation Beijing Key Laboratory for Magneto-Photoelectrical Composite and Interface ScienceSchool of Mathematics and PhysicsUniversity of Science and Technology BeijingBeijing 100083China

Despite carbonaceous materials are widely employed as commercial negative electrodes for lithium ion battery, an urge requirement for new electrode materials that meet the needs of high energy density, long cycle life, low cost and safety is still underway. A number of cobalt-based compounds（Co（OH）_2, Co_3O_4, CoN, CoS,CoP, NiCo_2O_4, etc.） have been developed over the past years as promising anode materials for lithium ion batteries（LIBs） due to their high theoretical capacity, rich redox reaction and adequate cyclability. The LIBs performances of the cobalt-based compounds have been significantly improved in recent years, and it is anticipated that these materials will become a tangible reality for practical applications in the near future. However, the different types of cobalt-based compounds will result in diverse electrochemical performance. This review briefly analyzes recent progress in this field, especially highlights the synthetic approaches and the prepared nanostructures of the diverse cobalt-based compounds and their corresponding performances in LIBs, including the storage capacity, rate capability, cycling stability and so on.

关键词： Lithium ion batteries Anode materials Cobalt Conversion reaction

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Recent Advances in Directed Assembly of Nanowires or Nanotubes

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Nano-Micro Letters 2012年第3期4卷 142-153页

作者： Mei Liu Zhizheng Wu woon ming lau Jun Yang School of Mechatronics Engineering and Automation Shanghai University State Key Laboratory of Transducer Technology Shanghai Institute of Microsystem and Information TechnologyChinese Academy of Sciences Green Energy and Green Manufacturing Technology R&D Center Department of Mechanical and Materials Engineering the University of West ern Ontario

Nanowires and nanotubes of diverse material compositions,properties and/or functions have been produced or fabricated through various bottom-up or top-down *** nanowires or nanotubes have also been utilized as potential building blocks for functional *** key for the integration of those nanowire or nanotube based devices is to assemble these one dimensional nanomaterials to specific locations using techniques that are highly controllable and *** such techniques should enable assembly of highly uniform nanowire/nanotube arrays with precise control of density,location,dimension or even material types of nanowires/*** assembly techniques are being developed that can quickly align and assemble large quantities of one type or multiple types of nanowires through parallel processes,including flow-assisted alignment,Langmuir-Blodgett assembly,bubble-blown technique,electric/magnetic-field directed assembly,contact/roll printing,knocking-down,etc..With these assembling techniques,applications of nanowire/nanotube based devices such as flexible electronics and sensors have been *** paper delivers an overall review of directed nanowire/nanotube assembling approaches and analyzes advantages and limitations of each *** future research directions have also been discussed.

关键词： Nanowire Nanotube Assembly Shear force Contact printing Dielectrophoresis Microfluidics Nanosystems Nanodevices

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Cu2O-templated fabrication of Ni(OH)2·0.75H2O hollow tubes for electrocatalytic oxygen evolution reaction

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Progress in Natural Science:Materials International 2022年第5期32卷 554-560页

作者： Yu Zhang Xueai Teng Zequn Ma Rongming Wang woon-ming lau Aixian Shan Beijing Advanced Innovation Center for Materials Genome Engineering & Center for Green Innovation School of Mathematics and Physics University of Science and Technology Beijing Beijing Advanced Innovation Center for Materials Genome Engineering Beijing Key Laboratory for Magneto-Photoelectrical Composite and Interface Science School of Mathematics and Physics University of Science and Technology Beijing Institute of Materials Science and Devices School of Materials Science and Engineering Suzhou University of Science and Technology Shunde Innovation School of University of Science and Technology Beijing

Cu2O is an ideal template material for the preparation of transition metal hydroxide/oxyhydroxides with oxygen evolution reaction(OER) enhanced catalytic performance. Here, inspired by Pearson’s principle, Cu2O wires were prepared and used as a sacrificial template to prepare Ni(OH)2·0.75H2O hollow tubes(Ni(OH)2HTs) with highly improved surface roughness. Benefiting from unique structural advantages, the Ni(OH)2HTs showed excellent catalytic activity, rapid kinetics and a long-term stability as the OER catalyst, where an overpotential of only 207mV was required to drive a current density of 10 mA cm-2, an ideal kinetics with a Tafel slope as 79.8 mV dec-1was calculated, and no obvious attenuation in chronoamperometry was discovered after operation for 24 h. This paper provides a novel template-assisted strategy to prepare high-performance transition metal-based OER catalysts possessing hollow and tubular structures.

关键词： Ni(OH) 2 hollow tube Cu 2 O wire Template One-dimensional hollow structure Oxygen evolution reaction

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Synthesis of FeOOH scaly hollow tubes based on Cu_(2)O wire templates toward high-efficiency oxygen evolution reaction

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Rare Metals 2023年第6期42卷 1836-1846页

作者： Yu Zhang Xue-Ai Teng Ze-Qun Ma Rong-ming Wang woon-ming lau Ai-Xian Shan Beijing Advanced Innovation Center for Materials Genome Engineering and Center for Green Innovation School of Mathematics and PhysicsUniversity of Science and Technology BeijingBeijing100083China Beijing Advanced Innovation Center for Materials Genome Engineering Beijing Key Laboratory for Magneto-Photoelectrical Composite and Interface ScienceSchool of Mathematics and PhysicsUniversity of Science and Technology BeijingBeijing100083China Shunde Innovation School of University of Science and Technology Beijing Foshan528000China Institute of Materials Science and Devices School of Materials Science and EngineeringSuzhou University of Science and TechnologySuzhou215009China

For catalytic materials,the characteristics of one-dimension and hollowness are the promotion factors for their full presentation of catalytic activity,and through a template-as sis ted method,both above superiorities can be fused ***,we proposed a novel strategy inspired by Pearson's principle with Cu_(2)O wires as templates,and prepared FeOOH hollow tubes,which covered by FeOOH *** applied as oxygen evolution reaction(OER)catalyst,the FeOOH scaly hollow tubes(FeOOH SHTs)showed outstanding catalytic activity with a low overpotential of 245 mV to drive a current density of10 mA·cm^(-2),excellent kinetics manifesting as a low Tafel slope of 46.9 mV·dec^(-1),and robust *** work provides a new synthesis strategy for an ideal OER catalyst,FeOOH,with high inherent activity and enhances the feasibility to broaden the design ideas of transition metalbased catalysts.

关键词： FeOOH scaly hollow tube(SHT) Cu_(2)O wire template One-dimensional(1D)hollow structure Oxygen evolution reaction(OER)

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Atomic-scaled surface engineering Ni-Pt nanoalloys towards enhanced catalytic efficiency for methanol oxidation reaction

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Nano Research 2020年第11期13卷 3088-3097页

作者： Aixian Shan Shuoyuan Huang Haofei Zhao Wengui Jiang Xueai Teng Yingchun Huang Chinping Chen Rongming Wang woon-ming lau Beijing Advanced Innovation Center for Materials Genome Engineering Center for Green InnovationBeijing Key Laboratory for Magneto-Photoelectrical Composite and Interface ScienceSchool of Mathematics and PhysicsUniversity of Science and Technology BeijingBeijing100083China Department of Physics Peking UniversityBeijing100871China Shunde Graduate School of University of Science and Technology Beijing Foshan528300China

Surface engineering is known as an effective strategy to enhance the catalytic properties of Pt-based ***,we report on surface engineering Ni-Pt nanoalloys with a facile method by varying the Ni doping concentration and oleylamine/oleicacid *** alloy-composition,exposed facet condition,and surface lattice strain are,thereby manipulated to optimize the catalytic efficiency of such nanoalloys for methanol oxidation reaction(MOR).Exemplary nanoalloys including Ni_(0.69)Pt_(0.31)truncated octahedrons,Ni_(0.45)Pt_(0.55)nanomultipods and Ni_(0.20)Pt_(0.80)nanoflowers are thoroughly characterized,with a commercial Pt/C catalyst as a common *** variations in MOR catalytic efficiency are significant:2.2 A/mgPt for Ni_(0.20)Pt_(0.80)nanoflowers,1.2 A/mgPt for Ni_(0.45)Pt_(0.55)nanomultipods,0.7 A/mgPt for Ni_(0.69)Pt_(0.31)truncated octahedrons,and 0.6 A/mgPt for the commercial Pt/C *** by density functional theory calculations,we correlate these observed catalysis-variations particularly to the intriguing presence of surface interplanar-strains,such as{111}facets with an interplanar-tensile-strain of 2.6%and{200}facets with an interplanar-tensile-strain of 3.5%,on the Ni_(0.20)Pt_(0.80)nanoflowers.

关键词： surface-strain high-index facets Ni-Pt alloy controllable synthesis electrocatalysis

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Substitute of Expensive Pt with Improved Electrocatalytic Performance and Higher Resistance to CO Poisoning for Methanol Oxidation: the Case of Synergistic Pt-Co_3O_4 Nanocomposite

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Nano-Micro Letters 2013年第4期5卷 296-302页

作者： Hongxiao Zhao Zhi Zheng Jing Li Huimin Jia Ka-wai Wong Yidong Zhang woon ming lau Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province Institute of Surface Micro and Nano Materials Xuchang University Chengdu Green Energy and Green Manufacturing R&D Center

In this paper, Pt-Co_3O_4 nanocomposite was synthesized by a sol gel process combined with electrodeposition method. Its electrocatalytic activity towards methanol oxidation was investigated at room temperature using cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and current density time curve. It is found that the resultant Pt-Co_3O_4 catalysts with minute amount of Pt exhibite attractive electrocatalytic activity for methanol oxidation reaction(MOR) but with a high resistance CO poisoning due to the synergistic effects from Pt and Co_3O_4. Together with the low manufacturing cost of Co_3O_4, the reported nanostructured Pt-Co_3O_4 catalyst is expected to be a promising electrode material for direct methanol fuel cells(DMFC).

关键词： Pt-Co3O4 nanocomposite MOR Electrocatalytic activity

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Strain-regulated sensing properties of α-Fe_(2)O_(3) nano-cylinders with atomic carbon layers for ethanol detection

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Journal of Materials Science & Technology 2021年第9期68卷 132-139页

作者： Huajing Xiong Jianan Fu Jinyao Li Rashad Ali Hong Wang Yifan Liu Hua Su Yuanxun Li woon-ming lau Nasir Mahmood Chunhong Mu Xian Jian School of Materials and Energy University of Electronic Science and Technology of ChinaChengdu 611731China Institute of Chemistry National Institute of Measurement and Testing Technology of ChinaChengdu 610021China School of Electronic Science and Engineering University of Electronic Science and Technology of ChinaChengdu 611731China Jiangxi Guo Chuang Industrial Park Development Co. LtdGanzhou 341000China Institute of Fundamental and Frontier Science University of Electronic Science and Technology of ChinaChengdu 610054China School of Engineering RMIT University124 La Trobe Street3001 MelbourneVictoriaAustralia National Engineering Research Center of Electromagnetic Radiation Control Materials State Key Laboratory of Electronic Thin Films and Integrated DevicesUniversity of Electronic Science and Technology of ChinaChengdu 611731China

The sensitivity of ethanol sensor is of paramount importance in a variety of areas,including chemical production with ethanol,alcohol testing for driving safety,***,α-Fe_(2)O_(3) nano-cylinders with atomic carbon layers are synthesized,for the first time,through in-situ catalytic chemical vapor deposition combined with hydrothermal techniques for the detection of *** reported α-Fe_(2)O_(3)@C nano-cylinders with double surficial strain effects deliver an ethanol detection sensitivity of 8 times as compared with α-Fe_(2)O_(3) nano-cylinders,10 times higher as compared with its detection sensitivity to ammonia,para-xylene,methanol and *** sensor also exhibits over-14-day operation stability and the minimum detection limit of 10 *** our best knowledge,the performances surpass those of previously reported α-Fe_(2)O_(3).Such attractive performances are attributed to the enhanced charge transfer in α-Fe_(2)O_(3) owing to the double surficial strain effects of α-Fe_(2)O_(3)@C nano-cylinders and the efficient adsorption of ethanol with atomic carbon layers.

关键词： Gas sensor Nano-cylinder Hybrid microstructure Sensitivity Carbon coating

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Asymmetric MXene/monolayer transition metal dichalcogenide heterostructures for functional applications

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npj Computational Materials 2019年第1期5卷 1024-1031页

作者： Baihai Li Haoran Guo Yunrui Wang Wenxu Zhang Qiuju Zhang Liang Chen Xiaoli Fan Wanli Zhang Yanrong Li woon-ming lau State Key Laboratory of Electronic Thin Films and Integrated Devices University of Electronic Science and Technology of China611731 ChengduSichuanChina School of Materials and Energy University of Electronic Science and Technology of China611731 ChengduSichuanChina Ningbo Institute of Industrial Technology Chinese Academy of Sciences315201 NingboZhejiangChina School of Material Science and Engineering Northwestern Polytechnical University710072 Xi’anShanxiChina School of Mechatronics Engineering University of Electronic Science and Technology of China611731 ChengduSichuanChina Center for Green Innovation School of Mathematics and PhysicsUniversity of Science and Technology Beijing100083 BeijingChina

A versatile two-dimensional(2D)molecular bilayer heterostructure of asymmetric MXene/monolayer transition metal dichalcogenide(aMXene/mTMDC)with a high interfacial built-in electric field is here simulated,where aMXene is an aMXene with the top or bottom electronegative atom plane of MXene *** asymmetric structural design of aMXene leads to a high dipole moment perpendicular to the 2D molecular *** the unpassivated metal atoms in the aMXene are unstable and electropositive,coupling them to the electronegative chalcogenide atoms in an aMXene/mTMDC bilayer resolves this *** dipole field tunable by the specific composition of aMXene/mTMDC is leveraged to engineer unusual band structures,band alignments,and charge redistribution/injection in the *** simulated design of several aMXene/mTMDC bilayers for possible use in spintronics,microelectronics/optoelectronics,and catalysis/photocatalysis are shown.

关键词： monolayer transition dipole

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