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The Role of Organic Matter During Metal Enrichment in permian Kupferschiefer of the Rudna Mine,Southwest poland

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Chinese Journal Of Geochemistry 2003年第1期22卷 1-10页

作者：孙玉壮 wilhelm püttmann Hebei Institute of Architectural Science and Technology Johann Wolfgang Goethe-Universitaet Frankfurt

The bulk composition of organic matter and saturated and aromatic hydrocarbons extracted from 16 samples collected from two Kupferschiefer profiles in the Rudna mine, Southwest poland has been analyzed to study the role of organic matter during base metal enrichment in the Kupferschiefer shale. The results indicated that the extract yields and saturated hydrocarbon yields decreased with increasing base metal contents. GC and GC/MS analyses indicated that n-alkanes and alkylated aromatic compounds were depleted and may have served as hydrogen donators for thermochemical sulfate reduction. The enrichment of base metals is closely connected with the destruction of hydrocarbons.

关键词：烃有机物铜页岩热化学作用硫酸盐贱金属波兰二叠纪欧洲

The Chloroplast Kinase Network： New Insights from Large-Scale phosphoproteome profiling

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Molecular plant 2009年第6期2卷 1141-1153页

作者： Sacha Baginsky wilhelm Gruissem Department of Biology ETH Zurich Universitatstrasse 2 8092 Zurich Switzerland

protein phosphorylation is one of the most important posttranslational modifications in eukaryotic cells and affects almost all basic cellular processes. The chloroplast as plant-specific cell organelle with important metabolic functions is integrated into the cellular signaling and phosphorylation network. Recent large-scale chloroplast phosphoproteome analyses in Arabidopsis have provided new information about phosphorylation targets and expanded the list of chloroplast metabolic and regulatory functions that are potentially controlled by protein phosphorylation. phosphorylated peptides identified from chloroplast proteins provide new insights into phosphorylation motifs, protein kinase activities, and substrate utilization. phosphorylation sites in protein kinases can reveal chloroplast phosphorylation cascades that may network different functions by integrating signaling chains. Our review provides a meta-analysis of currently available chloroplast phosphoproteome information and discusses biological insights from large-scale chloroplast phosphoprotein profiling as well as technological constraints of kinase network analysis.

关键词： photosynthesis protein phosphorylation/dephosphorylation proteomics signal transduction.

STRAIN-GRADIENT STRESS ANALYSIS IN SAINT-VENANT BENDING

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Acta Mechanica Sinica 1996年第3期12卷 225-242页

作者： Friedrich wilhelm Hecker Jerzy Tadeusz pindera Technische Universitat Braunschweig D-38106 Braunschweig Germany University of Waterloo Waterloo Ontario N2L 3G1 Canada

Light beam deflections caused by stress or strain gradients are inves- tigated analytically and experimentally in homogeneous beam specimens which are subjected to a particular case of flexure with shear. This study is a generalization of the prior an alytical-experimental examination of strain-gradient light deflections produced in stressed plates, which had concentrated on the simplest case where in- formation of interest is collected along a line of symmetry of the stress field. Main purpose of the present investigation is to document the efficacy of the strain-gradient method in analysis of the general case of stress state. The most interesting stress state is that in a beam subjected to the Saint-Venant bending, where the transversal and the longitudinal axes of the beam are in pure shear. The obtained results are compared with the predictions of the developed analytical models and with the pre- dictions of Filon's stress function. The procedures of evaluating the photoelastic and material coefficients using strain-gradient techniques were tested positively.

关键词： experimental stress analysis applied mechanics optical methods light propagation strain-gradient light bending testing mathematical models

Disparities of conjugating protective enzyme activities in the colon of patients with adenomas and carcinomas

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World Journal of Gastroenterology 2013年第36期19卷 6020-6025页

作者： Harald p Hoensch Hennie MJ Roelofs Lutz Edler wilhelm Kirch Wilbert HM peters Internal Medicine Marien Hospital Department of Gastroenterology Radboud University Nijmegen Medical Center Division of Biostatistics German Cancer Research Center Department of Clinical pharmacology Technical University of Dresden

AIM:To investigate the metabolic enzymatic capacity of the colon mucosa to detoxify noxious carcinogenic ***:We investigated the activity of 2 conjugating enzymes-the microsomal uridine glucuronosyltransferase(UGT)and the cytosomal glutathione S-transferase(GST)in the uninvolved mucosa of the colon transversum and sigmoideum in patients with adenomatous polyps and colorectal *** were taken from the mucosa during colonoscopies which were done for clinical(diagnostic)*** storage,the biopsy material was homogenized and after differential centrifugation the enzyme assays were performed with 4-nitrophenol(UGT)and 1-chloro 2,4-dinitrobenzene(GST)as ***:About 48 patients were included of which28 had adenomas and 20 had colorectal carcinomas confirmed by *** activities were expressed as nmol/mg per minute protein for the GST and as pmol/mg per minute protein for the *** of variance(F-test)indicated that both enzymes were more widely distributed in adenoma than in cancer *** means±SD were smaller for cancer patients:GST for adenomas 268±152 vs 241±69 for carcinomas and UGT for adenomas 197±200 vs 150±86 for ***:Compared to patients with adenomatous colon polyps those with colorectal carcinoma exhibited a lower capacity of detoxifying enzyme metabolism and their activities clustered over a smaller range.

关键词： Glutathione S-transferase UDp-glucuronosyltransferase Detoxification Colon adenoma Colon carcinoma

Layer-like FAU-type zeolites:A comparative view on different preparation routes

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Frontiers of Chemical Science and Engineering 2020年第2期14卷 127-142页

作者： Bastian Reiprich Tobias Weissenberger wilhelm Schwieger Alexandra Inayat Institute of Chemical Reaction Engineering Friedrich-Alexander University Erlangen-NumbergErlangen 91058Germany

The creation of intergrown layer-like zeolite crystals is one route to form hierarchical ***-type(FAU-type)zeolites are among the industrially most important zeolites and the implementation of hierarchical porosity is a promising way to optimise their catalytic and adsorptive *** a short general survey into routes for the preparation of hierarchical pore systems in FAU,we will review the currently existing strategies for the synthesis of FAU with layer-like *** strategies are mainly based on the presence of morphology modifying agents in the synthesis ***,a very recent approach is the synthesis of layer-like FAU-type zeolite crystals assembled in an intergrown manner in the absence of such additives,just by finely adjusting the crystallization *** additive-free preparation route for layer-like FAU,which appears very attractive from an ecological as well as economic point of view,is highlighted in this ***,a comparison,including powder X-ray diffraction,scanning and transmission electron microscopy,nitrogen physisorption and elemental analysis,between conventional FAU and three layer-like FAU obtained by different synthesis routes was carried out to show the structural,morphological and textural differences and similarities of these materials.

关键词： FAU hierarchical zeolite layer-like morphology

FerryBox: Using Automated Water Measurement Systems to Monitor Water Quality: perspectives for the Yangtze River and Three Gorges Dam

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Journal of Earth Science 2010年第6期21卷 861-869页

作者： Carsten Frank Friedhelm Schroeder wilhelm petersen Helmholtz-Zentrum Geesthacht GmbH Institute for Coastal Research

The building of the Three Gorges Dam （Hubei （湖北） province, China） has transformed a region with an economy based on sustainable agriculture for millennia into an entirely different environment within an exceptionally short time. This disrupts the natural biogeochemieal cycles of carbon, nutrients, and metals and possibly will affect the whole catchment including downstream ecosystems, such as wetlands, estuaries, deltas, and adjacent sea areas. Starting from changes that have already been documented, this article concentrates on the possible use of a ＂FerryBox＂, which is an automated water quality measurement system on board a ship or on shore, to monitor the short and long term development of the quality of the river water in the backwater area and downstream of the dam. While there are already research programmes running to monitor the water quality of the river and the backwater area, these programs are limited to ship campaigns with sampling and laboratory analysis. The spatial and temporal resolution of such measurements is not sufficient for an overall assessment of the water quality and for prognoses in the context of anthropogenic and climate change. Therefore, a concept of applying regular automated observations by a FerryBox is presented. It is shown that such systems are very well suited to give feedback for the assessment of measures to improve the water quality.

关键词： Three Gorges Dam Yangtze River eutrophication FerryBox.

Loss of Aβ-nerve endings associated with the Merkel cell-neurite complex in the lesional oral mucosa epithelium of lichen planus and hyperkeratosis

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International Journal of Oral Science 2016年第1期8卷 32-38页

作者： Daniela Calderon Carrion Yiiksel Korkmaz Britta Cho Marion Kopp wilhelm Bloch Klaus Addicks wilhelm Niedermeier Department of prosthetic Dentistry Dental SchoolUniversity of CologneCologneGermany Center for Biochemistry Institute for Experimental Dental Research and Oral Musculoskeletal BiologyMedical FacultyUniversity of CologneCologneGermany Department of Anatomy University of CologneCologneGermany Department of Molecular and Cellular Sport Medicine German Sport UniversityCologneGermany

The Merkel cell-neurite complex initiates the perception of touch and mediates Ap slowly adapting type I responses. Lichen planus is a chronic inflammatory autoimmune disease with T-cell-mediated inflammation, whereas hyperkeratosis is characterized with or without epithelial dysplasia in the oral mucosa. To determine the effects of lichen planus and hyperkeratosis on the Merkel cell-neurite complex, healthy oral mucosal epithelium and lesional oral mucosal epithelium of lichen planus and hyperkeratosis patients were stained by immunohistochemistry （the avidin-biotin-peroxidase complex and double immunofluorescence methods）using pan cytokeratin, cytokeratin 20 （K20, a Merkel cell marker）, and neurofilament 200 （NF200, a myelinated Aβ- and Aδ-nerve fibre marker） antibodies. N F200-immunoreactive （ir） nerve fibres in healthy tissues and in the lesional oral mucosa epithelium of lichen planus and hyperkeratosis were counted and statistically analysed. In the healthy oral mucosa, K20-positive Merkel cells with and without close association to the intraepithelial NF200-ir nerve fibres were detected. In the lesional oral mucosa of lichen planus and hyperkeratosis patients, extremely rare NF200-ir nerve fibres were detected only in the lamina propria. Compared with healthy tissues, lichen planus and hyperkeratosis tissues had significantly decreased numbers of NF200-ir nerve fibres in the oral mucosal epithelium. Lichen planus and hyperkeratosis were associated with the absence of Aβ-nerve endings in the oral mucosal epithelium. Thus, we conclude that mechanosensation mediated by the Merkel cell-neurite complex in the oral mucosal epithelium is impaired in lichen planus and hvperkeratosis.

关键词： Aβ-nerve fibres hyperkeratosis lichen planus mechanosensation Merkel cell-neurite complex

Introduction to the problems of Relativistic and Absolute Space, Time, and Motion

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Journal of Systems Engineering and Electronics 1995年第4期6卷 1-24页

作者： H.E.wilhelm GuestEditoroftheCJSE&E

Author(s) wilhelm, H. E. CJ SE & E

关键词： STR Time and Motion Introduction to the problems of Relativistic and Absolute Space GTR IFS

Strategies and challenges to increase the precision in feeding zinc to monogastric livestock

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Animal Nutrition 2017年第2期3卷 103-108页

作者： Daniel Brugger wilhelm M.Windisch TUM School of Life Sciences Weihenstephan Technical University of Munich

practical diets for monogastric livestock must be supplemented with zinc(Zn) due to their high contents of antagonistic substances like phytates. Current feeding recommendations include quite generous safety margins because of uncertainties regarding the gross Zn requirements under varying rearing ***, the use of pharmacological Zn doses to stabilise animal performance and wellbeing is widespread. Taken together, modern diets for pigs and poultry contain considerably more Zn than necessary to meet animal requirements, which is associated with concerns related to the environment as well as animal and consumer safety. Therefore, European authorities most recently reduced the allowed upper limits for Zn in complete feed. To maintain animal productivity and wellbeing while reducing the Zn load in complete feed, all measures that stabilize feed Zn bioavailability must be applied. Most importantly, reliable information on the gross Zn requirement under practical conditions must be provided, considering the bioavailability of native or supplemented feed Zn, antagonisms with dietary factors as well as the physiological status of the animal.

关键词： Zinc Requirement Recommendation pharmacological pig poultry