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Agitation drying synthesis of porous carbon supported Li_(3)VO_4 as advanced anode material for lithium-ion batteries

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Rare Metals 2021年第12期40卷 3466-3476页

作者： wen-wen Gou Shuang zhou xin-xin Cao Yi-Lin Luo Xiang-Zhong Kong Jing Chen Xue-Fang Xie An-Qiang Pan School of Materials Science and Engineering Central South UniversityChangsha 410083China Institute of New Energy College of Mechanical EngineeringHunan Institute of Science and TechnologyYueyang 414006China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin 300071China School of Physics and Technology Xinjiang UniversityUrumqi 830046China

Li_(3)VO_4 has been considered as a promising insertion-type anode for lithium-ion batteries due to its high theoretical specific capacity and suitable operating voltage platform. However, this promising anode still suffers from poor electrical conductivity. To address this issue, herein, a porous carbon supported Li_(3)VO_4 composites(Li_(3)VO_4/C) via a facile agitation-drying method combined with subsequent calcination is reported, in which Ketjen black carbon with high porosity, easy dispersion and excellent conductivity can serve as one of carbon sources. The Li_(3)VO_4/C composite prepared at 700 ℃ with a carbon content of~10% exhibits the optimized structure. The void space of the composite accommodates the volume changes during the charge/discharge ***, the carbon shell serves as a conductive skeleton to provide bi-continuous Li ions and electrons pathways. Electrochemical results reveal that the composite delivers a high initial discharge capacity of 572 m Ahág^(-1) and maintains a capacity of 442.9 m Ahág^(-1) after 100 cycles at 100 m Aág^(-1). Even at a high current density of 2 Aág^(-1), a considerable capacity of 243.8 m Ahág^(-1) can still be obtained. This work provides a promising approach for the practical application of Li_(3)VO_4 as anode material for LIBs.

关键词： Lithium-ion battery Anode Li_(3)VO_4 Ketjen black carbon Electrochemical performance

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Novel Shaped Sweeping Jet for Improved Film Cooling and Anti-Deposition Performance

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Journal of Thermal Science 2024年第6期33卷 2089-2096页

作者： zhou wenwu WANG Kechen ZHANG Tianluan wen xin PENG Di LIU Yingzheng Key Lab of Education Ministry for Power Machinery and Engineering School of Mechanical EngineeringShanghai Jiao Tong UniversityShanghai 200240China Gas Turbine Research Institute Shanghai Jiao Tong UniversityShanghai 200240China

The present study proposed a shaped sweeping jet(SJ)that possesses the merits of both SJ and shaped hole,which demonstrates significantly improved cooling effectiveness and anti-deposition *** to a classical 777 shaped hole,the shaped SJ exhibits a maximum enhancement of 70%in cooling effectiveness and a maximum reduction of 28%in particle deposition height,*** to the periodic oscillation of coolant jet and higher streamwise jet momentum,the shaped SJ can provide much wider coolant coverage and therefore sweep the adhesive particle away from the *** study is the first attempt to reconcile the performance of film cooling and particle anti-deposition simultaneously,which offers a promising design concept for future engine cooling.

关键词： sweeping jet film cooling particle deposition pressure sensitive paint multi-perspective scanni

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Strengthening iron enrichment and dephosphorization of high-phosphorus oolitic hematite using high-temperature pretreatment

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International Journal of Minerals,Metallurgy and Materials 2020年第4期27卷 443-453页

作者： wen-tao zhou Yue-xin Han Yong-sheng Sun Yan-jun Li College of Resources and Civil Engineering Northeastern UniversityShenyang 110819China

The efficient development and utilization of high-phosphorus oolitic hematite is of great strategic significance for the sustainable supply of iron-ore resources in *** this paper,the mechanism of high-temperature pretreatment for enhancing the effect of iron enrichment and dephosphorization in the magnetization roasting–leaching process was studied by X-ray diffraction(XRD),vibration sample magnetometer(VSM),scanning electron microscopy and energy dispersive spectrometry(SEM–EDS).Compared with the process without high-temperature pretreatment,the iron grade of the magnetic separation concentrate after high-temperature pretreatment had increased by 0.98%,iron recovery rate had increased by 1.33%,and the phosphorus content in the leached residue had decreased by 0.12%.High-temperature pretreatment resulted in the dehydration and decomposition of hydroxyapatite,the dehydration of limonite and the thermal decomposition of siderite,which can produce pores and cracks and weaken the compactness of the ore,improve the magnetization characteristics of roasted ore,and strengthen the iron enrichment and dephosphorization during the magnetization roasting and leaching process.

关键词： high-phosphorus oolitic hematite high-temperature pretreatment iron enrichment and dephosphorization magnetization roasting–leaching process phase transformation

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Modular assembly of Co4-thiacalix[4]arene units and Keggin-type SiW12O40 for visible-light photothermal conversion

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Tungsten 2025年第1期7卷 112-119页

作者： Jia-Hui Li Qing Zhao Dong-Ao Mao Kun zhou Bao-Kuan Chen Yan-Feng Bi School of Petrochemical Engineering Liaoning Petrochemical University

The construction of metal-organic coordination clusters（MCCs） using modular secondary building units is an important method for preparing functional *** this study,two new MCCs modularly assembled from Keggin-type {SiW12O40}H4TC4A=p-tert-Butylthiacalix[4]arene(SiW12) units and thiacalixarene-supported Co4-thiacalix[4]arene(Co4-TC4A polynuclear second-building units（PSBUs,H4TC4A=p-tert-Butylthiacalix[4]arene） are *** two MCCs,abbreviated as Co4-SiW12and Co8-SiW12,were structurally characterized by single-crystal X-ray *** Co4-SiW12is a supramolecular structure involving cation-anion interactions between Co4-TC4A PSBUs and ***8-SiW12features "barbell-like" shapes with two Co4-TC4A coordinatively linked to a Keggin-type SiW12unit on opposite via W-O_t-Co *** coordination of Co4-TC4A to SiW12in Co8-SiW12resulted in significantly improved photothermal conversion performances compared with Co4-SiW12and pure SiW12or ***-gap determination and photophysical analysis combined with density functional theory calculations indicated the binding mode between Co4-TC4A PSBUs and SiW12,which considerably influences the way of electron transport and the conversion ability of visible light to heat.

关键词： Modular construction Photothermal conversion Polyoxometalate Thiacalixarene

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Rational modulation of fluorophosphate cathode by anionic groups to reduce the polarization behavior for fast-charging sodium-ion batteries

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Journal of Energy Chemistry 2025年第1期100卷 509-521页

作者： xinyuan Wang Fan Zhang xingyu zhou Qian Wang Changyu Liu Yangyang Liu Hui Wang Xiaojie Liu Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education College of Chemistry & Materials Science Northwest University

Na3V2（PO4）2O2F （VP） is recognized as a promising cathode material for sodium-ion batteries due to its stable structural framework and high specific *** functional theory （DFT） and finite element simulations show that incorporating SO42-into VP decreases its band gap,lowers the migration energy barrier,and ensures a uniform Na+concentration gradient and stress distribution during charge and discharge ***,the average Na+diffusion coefficient of Na3V2（PO4）1.95（SO4）0.05O2F（VPS-1） is roughly double that of VP,leading to enhanced rate capability (80 C,75.5 mAh g-1) and cycling stability (111.0 mAh g-1capacity after 1000 cycles at 10 C current density) for ***-1 exhibits outstanding fast-charging capabilities,achieving an 80%state of charge in just 8.1 *** assembled VPS-1//SbSn/NPC full cell demonstrated stable cycling over 200 cycles at a high 5 C current,maintaining an average coulombic efficiency of 95.35%.

关键词： Anionic group modulation Polarization behavior Fast-charging Sodium-ion battery Fluorophosphate Cathode

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基于HS-SPME-GC-MS解析核桃雄花挥发性成分

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西南大学学报（自然科学版） 2025年第2期47卷 51-60页

作者：王纪辉胡伯凯周雯贵州省核桃研究所/贵州省核桃工程技术研究中心贵阳550005 贵州省公共资源交易中心贵阳550002

检测分析核桃雄花的香气组分种类、相对体积分数,探明核桃雄花的呈香成分及香气特征。以鲜核桃雄花为材料,采用顶空固相微萃取串联气质技术(HS-SPME-GC-MS)对核桃雄花中挥发性成分进行鉴定和定量分析。结果从核桃雄花中共鉴定出22种挥... 详细信息

检测分析核桃雄花的香气组分种类、相对体积分数,探明核桃雄花的呈香成分及香气特征。以鲜核桃雄花为材料,采用顶空固相微萃取串联气质技术(HS-SPME-GC-MS)对核桃雄花中挥发性成分进行鉴定和定量分析。结果从核桃雄花中共鉴定出22种挥发性成分,其中胡桃醌、二甲硫醚2种化合物占总体积分数的62.18%±2.93%、醇类占19.03%±1.91%、烯烃类占10.32%±1.84%、醛类、酮类及酯类化合物占比较低;核桃雄花香气主要由芳樟醇、反松香芹醇、2-甲基丙醛、2-甲基丁醛、3-甲基丁醛、壬醛、十六烷酸乙酯及烯烃类所贡献;主成分分析将22种挥发性化合物归为2类。综合显示:贵州产区核桃雄花香气主要由醇类、醛类和烯烃类成分所构成,种类最为丰富的烯烃类化合物贡献了突出的水果类气味。

关键词：核桃雄花挥发性成分顶空固相微萃取串联气质技术

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硫酸钙、β-TCP及生物活性玻璃治疗颌骨囊肿的疗效观察

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口腔颌面外科杂志 2016年第6期26卷 431-434页

作者：王珊珊程继光徐文华陈新周健安徽医科大学口腔医学院安徽医科大学附属口腔医院安徽省口腔疾病研究中心实验室安徽合肥230032

目的 :观察硫酸钙、β-TCP(β-磷酸三钙)及生物玻璃(倍骼生)在颌骨囊肿治疗中的疗效。方法 :颌骨囊肿病例45例,行囊肿刮除术后,随机分为4组,骨腔内填充不同物质。A组:硫酸钙组;B组:β-TCP组;C组:生物玻璃(倍骼生)组;D组:空白组。术后观... 详细信息

目的 :观察硫酸钙、β-TCP(β-磷酸三钙)及生物玻璃(倍骼生)在颌骨囊肿治疗中的疗效。方法 :颌骨囊肿病例45例,行囊肿刮除术后,随机分为4组,骨腔内填充不同物质。A组:硫酸钙组;B组:β-TCP组;C组:生物玻璃(倍骼生)组;D组:空白组。术后观察患者术区肿胀程度,且1、3、6、12个月后拍摄CBCT或全景片,观察术区骨愈合情况。结果:A组患者术后1周内术区肿胀明显;A、C组患者6个月后,术区与正常骨组织无明显区别;B组患者12个月后,新骨几乎充填整个骨腔;D组新骨形成明显较A、B、C组慢。结论:在新骨形成方面,A、B、C组分别与D组相比,差异均有统计学意义;硫酸钙会引起部分患者术区肿胀反应。

关键词：硫酸钙 β-TCP 倍骼生颌骨囊肿骨缺损修复

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Text-Image Feature Fine-Grained Learning for Joint Multimodal Aspect-Based Sentiment Analysis

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Computers, Materials & Continua 2025年第1期82卷 279-305页

作者： Tianzhi Zhang Gang zhou Shuang Zhang Shunhang Li Yepeng Sun Qiankun Pi Shuo Liu School of Data and Target Engineering Information Engineering UniversityZhengzhou450001China Information Engineering Department Liaoning Provincial College of CommunicationsShenyang110122China School of Computer and Artificial Intelligence Zhengzhou UniversityZhengzhou450000China

Joint Multimodal Aspect-based Sentiment Analysis(JMASA)is a significant task in the research of multimodal fine-grained sentiment analysis,which combines two subtasks:Multimodal Aspect Term Extraction(MATE)and Multimodal Aspect-oriented Sentiment Classification(MASC).Currently,most existing models for JMASA only perform text and image feature encoding from a basic level,but often neglect the in-depth analysis of unimodal intrinsic features,which may lead to the low accuracy of aspect term extraction and the poor ability of sentiment prediction due to the insufficient learning of intra-modal *** this problem,we propose a Text-Image Feature Fine-grained Learning(TIFFL)model for ***,we construct an enhanced adjacency matrix of word dependencies and adopt graph convolutional network to learn the syntactic structure features for text,which addresses the context interference problem of identifying different aspect ***,the adjective-noun pairs extracted from image are introduced to enable the semantic representation of visual features more intuitive,which addresses the ambiguous semantic extraction problem during image feature ***,the model performance of aspect term extraction and sentiment polarity prediction can be further optimized and *** on two Twitter benchmark datasets demonstrate that TIFFL achieves competitive results for JMASA,MATE and MASC,thus validating the effectiveness of our proposed methods.

关键词： Multimodal sentiment analysis aspect-based sentiment analysis feature fine-grained learning graph convolutional network adjective-noun pairs

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Study on metal recovery process and kinetics of oxidative leaching from spent LiFePO_(4)Li-batteries

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Chinese Journal of Chemical Engineering 2024年第4期68卷 94-102页

作者： Xiaoming Zhang wen Xie Xiaolei zhou wenjie Zhang Jiawei wen xin Wang Guoyong Huang Shengming Xu College of New Energy and Materials China University of PetroleumBeijing 102249China State Key Laboratory of Heavy Oil Processing College of Chemical EngineeringChina University of PetroleumBeijing 102249China Beijing Spacecrafts Beijing 100094China Ganfeng Lithium Group Co. Ltd.Xinyu 338000China Institute of Nuclear and New Energy Technology Tsinghua UniversityBeijing 100084China Beijing Key Laboratory of Fine Ceramics Tsinghua UniversityBeijing 100084China

A green environmental protection and enhanced leaching process was proposed to recover all elements from spent lithium iron phosphate(LiFePO_(4)) lithium *** order to reduce the influence of Al impurity in the recovery process,NaOH was used to remove *** impurity removal,the spent LiFePO_(4) cathode material was used as raw material under the H_(2)SO_(4) system,and the pressure oxidation leaching process was adopted to achieve the preferential leaching of *** E-pH diagram of the Fe-P-Al-H_(2)O system can determine the stable region of each element in the recovery process of spent LiFePO_(4)*** the optimal conditions(500 r·min^(-1),15 h,363.15 K,0.4 MPa,the liquid-solid ratio was 4:1 ml·g^(-1)and the acid-material ratio was 0.29),the leaching rate of Li was 99.24%,Fe,Al,and Ti were 0.10%,2.07%,and 0.03%,*** Fe and P were precipitated and recovered as FePO_(4)·2H_(2)*** kinetic analysis shows that the process of high-pressure acid leaching of spent LiFePO_(4) materials depends on the surface chemical *** the life cycle assessment(LCA)of the spent LiFePO_(4) whole recovery process,eight midpoint impact categories were selected to assess the impact of recovery *** results can provide basic environmental information on production process for recycling industry.

关键词： Spent LiFePO_(4)Li-batteries Oxidative leaching Kinetic study Life cycle assessment

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Statistical characteristics and classification of ionospheric mid-latitude trough as revealed by the observations of DMSP-F18

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Earth and Planetary Physics 2025年第1期9卷 137-147页

作者： Yi Liu JiuHou Lei FuQing Huang Su zhou School of Earth and Space Sciences University of Science and Technology of ChinaHefei 230026China School of Science Guiyang UniversityGuiyang 550005China

Statistical characteristics and the classification of the topside ionospheric mid-latitude trough are systemically analyzed,using observations from the Defense Meteorological Satellite Program F18(DMSP-F18)*** data was obtained at an altitude of around 860 km in near polar orbit,throughout *** study identified the auroral boundary based on the in-situ electron density and electron spectrum,allowing us to precisely determine the location of the mid-latitude *** differs from most previous works,which only use Total Electron Content(TEC)or in-situ electron *** our study,the troughs exhibited a higher occurrence rate in local winter than in summer,and extended to lower latitudes with increasing geomagnetic *** was found that the ionospheric mid-latitude trough,which is associated with temperature changes or enhanced ion drift,exhibited distinct ***,the ionospheric mid-latitude troughs related to electron temperature(Te)peak were located more equatorward of auroral oval boundary in winter than in *** ionospheric mid-latitude troughs related to Te-maximum were less frequently observed at 60−70°S magnetic latitude and 90−240°E ***,the troughs related to ion temperature(Ti)maximums were observed at relatively higher latitudes,occurring more frequently in *** addition,the troughs related to ion velocity(Vi)maximums could be observed in all *** troughs with the maximum-Ti and maximum-Vi were located closer to the equatorward boundary of the auroral oval at the nightside,and in both *** implies that enhanced ion drift velocity contributes to increased collisional frictional heating and enhanced ion temperatures,resulting in a density depletion within the trough region.

关键词： topside ionosphere mid-latitude trough ionospheric main trough auroral oval boundary temperature maximum

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