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Self-assembled S-scheme In_(2.77)S_(4)/K^(+)-doped g-C_(3)N_(4)photocatalyst with selective O_(2)reduction pathway for efficient h_(2)O_(2)production using water and air

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Chinese Journal of Catalysis 2024年第8期63卷 176-189页

作者： Qiqi Zhang hui Miao Jun Wang Tao sun Enzhou Liu School of Chemical Engineering/Xi’an Key Laboratory of Special Energy Materials Northwest UniversityXi’an 710127ShaanxiChina School of Physics Northwest UniversityXi’an 710127ShaanxiChina School of Electrical Engineering and Automation Wuhan UniversityWuhan 430072HubeiChina

The development of an efficient artificial h_(2)O_(2)photosynthesis system is a challenging work using h_(2)O and O_(2)as starting ***,3D In2.77S_(4)nanoflower precursor was in-situ deposited on K^(+)-doped g-C_(3)N_(4)(KCN)nanosheets using a solvothermal method,then In2.77S_(4)/KCN(IS/KCN)het-erojunction with an intimate interface was obtained after a calcination *** investigation shows that the photocatalytic h_(2)O_(2)production rate of 50IS/KCN can reach up to 1.36 mmol g^(-1)h^(-1)without any sacrificial reagents under visible light irradiation,which is 9.2 times and 4.1 times higher than that of KCN and In2.77S_(4),*** enhanced activity of the above composite can be mainly attributed to the S-scheme charge transfer route between KCN and In2.77S_(4)according to density functional theory calculations,electron paramagnetic resonance and free radical capture tests,leading to an expanded light response range and rapid charge separation at their interface,as well as preserving the active electrons and holes for h_(2)O_(2)***,the unique 3D nanostructure and surface hydrophobicity of IS/KCN facilitate the diffusion and transportation of O_(2)around the active centers,the energy barriers of O_(2)protonation and h_(2)O_(2)desorption steps are ef-fectively reduced over the *** addition,this system also exhibits excellent light harvesting ability and *** work provides a potential strategy to explore a sustainable h_(2)O_(2)photo-synthesis pathway through the design of heterojunctions with intimate interfaces and desired reac-tion thermodynamics and kinetics.

关键词： Photocatalysis h_(2)O_(2)production K^(+)-doped g-C3N4 In2.77S4 S-scheme heterojunction

Ru(II)-Catalyzed ortho C-h Allylation of N-Aryl-7-azaindoles with 2-Methylidene Cyclic Carbonate

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Chinese Journal of Chemistry 2024年第9期42卷 985-989页

作者： Jing Zhang Quan-Jian Luo han-Chi Wang Jin-heng Li Bo sun State Key Laboratory Base of Eco-Chemical Engineering College of Chemical EngineeringQingdao University of Science and Technology QingdaoShandong266042China State key Laboratory of Applied Organic Chemistry Lanzhou University LanzhouGansu 7300ooChina School of Chemistry and Chemical Engineering Henan Normal UniversityXinxiangHenan 453007China

A Ru(II)-catalyzed ortho allylation reaction of N-aryl-7-azaindole with readily available 2-methylidene cyclic carbonate has been *** reaction is an effective pathway for synthesizing 7-azaindole derivatives with a wide scope of substrates and high *** addition,the method can be extended to the allylation of other heterocyclic compounds and several cyclic carbonates,highlighting the practicality of this strategy for synthesis.

关键词： Ru(II) Allylation N-Aryl-7-azaindoles Cyclic carbonates heterocyclic compounds C-h activation

Ru(Ⅱ)-Catalyzed Selective C-h Alkynylation of Isoquinolones,Quinazolones and Phthalazinones with Bromoalkynes

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Chinese Journal of Chemistry 2024年第15期42卷 1686-1690页

作者： Quan-Jian Luo han-Chi Wang Jing Zhang Jin-heng Li Bo sun State Key Laboratory Base of Eco-Chemical Engineering College of Chemical EngineeringQingdao University of Science and TechnologyQingdaoShandong 266042China State Key Laboratory of Applied Organic Chemistry Lanzhou UniversityLanzhouGansu 730000China School of Chemistry and Chemical Engineering Henan Normal UniversityXinxiangHenan 453007China

A new,selective Ru(Ⅱ)-catalyzed alkynylation reaction of isoquinolones,quinazolones and phthalazinones with readily available bromoalkynes has been *** reaction enables the selective construction of a new C(sp^(2))-C(sp)bond through C-h activation and C-Br functionalization,and offers an effective and selective route to synthesizing highly valuable alkynylated isoquinolone,quinazolone and phthalazinonederivatives with a wide substrate scope and highselectivity.

关键词： Ru(Ⅱ) Alkynylation Isoquinolones Bromoalkynes heterocyclic compounds C-h activation C-C coupling Synthetic methods

GCMC study hydrogen adsorption on MOFs with Ab initio force field

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GCMC study hydrogen adsorption on MOFs with Ab initio force ...

Isolation and role of fermentative bacterium Bacteroides sp.W7 in a microbial electrochamical assisted hydrogen production reactor

第九届全国氢能学术会议

作者： J.Fu,X.F.Li,L.F.Zhao,h.sun Shanghai Jiao Tong University,China

＜正＞MOFs are potential materials for hydrogen storage,but several key issues need to be solved before making this kind of materials *** order to help design new MOF materials, we developed an ab initio force *** thi...

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Isolation and role of fermentative bacterium Bacteroides sp....

BrrTCP4b interacts with BrrTTG1 to suppress the development of trichomes in Brassica rapa var. rapa

第九届全国氢能学术会议

作者： A.J.Wang,D.sun,L.h.Liu,h.Y.Cheng,N.Q.Ren,W.Z.Liu harbin Institute of Technology,China

＜正＞Till now,little information presents the remarkable bacteria that function in an microbial electrochamical assisted hydrogen production reactor（MEC）,especially,their characterization and motabolic behavior variation under such a power supply *** this study,a Gram-negative,short rod,polar flagellum,non-spore-forming dominant bacteria,strain W7, was isolated from a *** of physiological-biochemical characterization and 16S

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Plant Diversity 2024年第3期46卷 416-420页

作者： Cheng Li Li Zhang hefan Li Yuanwen Duan Xuemei Wen Yongping Yang Xudong sun The Germplasm Bank of Wild Species Yunnan Key Laboratory of Crop Wild Relatives OmicsInstitute of Tibetan Plateau Research at KunmingKunming Institute of BotanyChinese Academy of SciencesKunming 650201China University of Chinese Academy of Sciences BeijingChina Tibet Plateau Institute of Biology Lhasa 850001TibetChina

The number of trichomes significantly increased in CRISPR/Cas9-edited BrrTCP4b turnip(Brassica rapa ***)***,the underlying molecular mechanism remains to be *** this study,we performed the Y2h screen using BrrTCP4b as the bait,which unveiled an interaction between BrrTCP4b and BrrTTG1,a pivotal WD40-repeat protein transcription factor in the MYB-bhLh-WD40(MBW)*** physical interaction was further validated through bimolecular luciferase complementation and ***,it was found that the interaction between BrrTCP4b and BrrTTG1 could inhibit the activity of MBW complex,resulting in decreased expression of BrrGL2,a positive regulator of trichomes *** contrast,AtTCP4 is known to regulate trichomes development by interacting with AtGL3 in Arabidopsis ***,this study revealed that BrrTCP4b is involved in trichome development by interacting with BrrTTG1 in turnip,indicating a divergence from the mechanisms observed in model plant *** findings contribute to our understanding of the regulatory mechanisms governing trichome development in the non-model plants turnip.

关键词： TCP transcription factor MBW complex Trichome development Turnip

Anchoring heterometallic cluster on P-doped carbon nitride for efficient photocatalytic nitrogen fixation in water and air ambient

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Chinese Chemical Letters 2024年第4期35卷 176-180页

作者： Chao-Long Chen Rong Chen La-Sheng Long Lan-sun Zheng Xiang-Jian Kong Collaborative Innovation Center of Chemistry for Energy Materials State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of ChemistryCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China

Light-driven nitrogen fixation to produce ammonia is a green and economical technology of nitrogen reduction but is still quite challenging, especially in an air atmosphere without any sacrificial ***, we demonstrate efficient photocatalytic nitrogen fixation using water and air directly by loading lanthanide–transition metal(4f–3d) cluster NdCo_(3) on two-dimensional P-doped graphitic carbon nitrides(PCN) material surface. Benefiting from the increase in the number of nitrogen vacancies(NVs) and highly matched band gap structure and excellent hole trapping ability of clusters, the NdCo_(3)/PCN photocatalyst exhibits efficient nitrogen reduction activity with 371(in air) and 825 μmol h^(-1)g^(-1)(in pure nitrogen)without any sacrificial reagents. The introduction of potassium sulfate inhibits hydrogen production and promotes nitrogen reduction activation. This work suggests that anchoring precisely structured clusters on 2D materials may enhance photocatalytic nitrogen reduction under normal temperature and pressure.

关键词： Photocatalytic Nitrogen fixation 4f-3d Cluster Air atmosphere

Effects of high temperature and high relative humidity drying on moisture distribution,starch microstructure and cooking characteristics of extruded whole buckwheat noodles

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Journal of Future Foods 2024年第2期4卷 159-166页

作者： Linghan Meng Xuyang sun Yan Zhang Xiaozhi Tang Key Laboratory of Grains and Oils Quality Control and Processing College of Food Science and EngineeringCollaborative Innovation Center for Modern Grain Circulation and SafetyNanjing University of Finance and EconomicsNanjing 210023China hebei Key Laboratory of Food Safety Hebei Food Inspection and Research InstituteShijiazhuang 050091China

Drying is a key step in starch noodle *** effects of high temperature(60,70,80°C)and high relative humidity(65%,75%,85%)drying(hThD)on the moisture distribution,starch microstructure and cooking characteristics of extruded whole buckwheat noodles were *** to the conventional hot-air drying(ChAD)at 40°C,the increase in drying temperature(60–80°C)and the decrease in relative humidity(85%–65%)significantly improved drying efficiency of the extruded *** adjusting drying temperature and relative humidity,the rate of moisture migration in noodles and phase transition of starch could be appropriately *** optimum drying parameters(T70h75,70°C drying temperature and 75%relative humidity)showed smooth and dense network structure,resulting in the lowest cooking loss(6.61%),broken rate(0%),highest hardness(1695.17 g)and springiness(0.92).however,the total flavonoid content(TFC)and the total phenolic content(TPC)reduced by 6.81%–28.50%and 7.19%–53.23%in contrast to ChAD,and the color of buckwheat noodles became darker through *** findings showed the potential of hThD for increasing drying efficiency and improving buckwheat noodle *** appropriate drying parameters could maintain a balanced relationship between moisture migration in noodles and phase transition of starch,which resulted in better cooking quality for extruded whole buckwheat *** a study is valuable for regulating the process conditions of buckwheat-based foods and promoting its commercial utilization.

关键词： Extruded whole buckwheat noodle high temperature and high relative humidity drying Moisture distribution Starch microstructure Cooking characteristics

Tailored heterostructured Ni_(3)N-NiO nano-frameworks for boosting electrocatalytic oxygen evolution via surface-modulated plasma strategy

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Nano Research 2024年第9期17卷 7909-7917页

作者： Bo Ouyang haonan Qin Chao sun Yilin Deng Ang Li Jipeng Zhu Erjun Kan Rajdeep Singh Rawat MIIT Key Laboratory of Semiconductor Microstructure and Quantum Sensing School of ScienceNanjing University of Science&TechnologyNanjing 210094China The Laboratory of Road and Bridge Civil EngineeringSchool of ScienceNanjing University of Science&TechnologyNanjing 210094China Institute for Energy Research Jiangsu UniversityZhenjiang 212013China Natural Sciences and Science Education National Institute of EducationNanyang Technological University637616Singapore

The facile reconfiguration of phases plays a pivotal role in enhancing the electrocatalytic production of h2 through heterostructure *** chemical methods have been explored extensively for this purpose,plasma-based techniques offer a promising avenue for achieving heterostructured ***,the conventional plasma approach introduces complexities,leading to a multi-step fabrication process and challenges in precisely controlling partial surface structure modulation due to the intricate interaction *** our pursuit of heterostructures with optimized oxygen evolution reaction(OER)behavior,we have designed a facile auxiliary insulator-confined plasma system to directly attain a Ni_(3)N-NiO heterostructure(hNiNO).By meticulously controlling the surface heating process during plasma processing,such approach allows for the streamlined fabrication of hNiNO *** resulting nano-framework exhibits outstanding catalytic performance,as evidenced by its overpotential of 320 mV at a current density of 10 mA·cm^(-2),in an alkaline *** stands in stark contrast to the performance of NiO-covered Ni_(3)N fabricated using the conventional plasma method(sNiNO).Operando plasma diagnostics,coupled with numerical simulations,further substantiates the influence of surface heating due to auxiliary insulator confinement of the substrate on typical plasma parameters and the formation of the Ni_(3)N-NiO nanostructure,highlighting the pivotal role of controlled surface temperature in creating a high-performance heterostructured electrocatalyst.

关键词： structural modulation auxiliary insulator-confined plasma surface heating control heterostructure electrocatalytic O_(2) evolution