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Thermo-and pH-sensitive Polymer with Pendant Spacer-linked Imidazole Cycles

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Chinese Journal of Polymer Science 2024年第4期42卷 437-445页

作者： Natalya v.Zakharova stanislav N.Zelinskiy Mariya S.Strelova Elena N.Danilovtseva vadim v.Annenkov Institute of Macromolecular Compounds of the Russian Academy of Sciences Saint Petersburg199004Russia Limnological Institute of Siberian Branch of the Russian Academy of Sciences Irkutsk664033Russia

By the reaction of poly(acryloyl chloride) with N-(3-aminopropyl)imidazole, poly(N-(3-(1H-imidazol-1-yl)propyl)acrylamide) was synthesized. The new polymer contains an imidazole ring removed from the main chain by a spacer of five bonds. The structure and purity, molecular weight, hydrodynamic and thermosensitive properties of the obtained sample were studied by1H-and13C-NMR, FTIR spectroscopy, acid-base titration, light scattering, turbidimetry and viscometry. The observed ability of the imidazole-containing polymer to form and destroy associates in water-salt solutions at pH 6.6-7.4 and temperatures of 29-48℃ indicates that these are promising candidates for designing complex biomedical systems. The new polymer is able to form complexes with oligo-DNA more actively than poly(1-vinylimidazole), which is of interest for gene delivery applications. The polymer cross-linked with epichlorohydrin gives micro-relief coatings on the plastic surface, and the modified surface is able to attach negatively charged objects. This thermo-and pH-sensitive polymer modification can be applied to create finely controlled surfaces for cell culturing.

关键词： Imidazole-containing polymer Thermolability pH-sensitivity The modified surface DNA immobilization

Current and further trajectories in designing functional materials for solid oxide electrochemical cells:A review of other reviews

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Journal of Energy Chemistry 2024年第7期94卷 302-331页

作者： stanislav Baratov Elena Filonova Anastasiya Ivanova Muhammad Bilal Hanif Muneeb Irshad Muhammad Zubair Khan Martin Motola Sajid Rauf Dmitry Medvedev Hydrogen Energy Laboratory Ural Federal University620002 EkaterinburgRussia Institute of Natural Sciences and Mathematics Ural Federal University620002 EkaterinburgRussia Department of Inorganic Chemistry Faculty of Natural SciencesComenius University BratislavaIlkovicova 6Mlynska Dolina84215 BratislavaSlovakia State Key Laboratory for Mechanical Behavior of Materials School of Materials Science and EngineeringXi'an Jiaotong UniversityXi'an 710049ShaanxiChina Department of Physics University of Engineering and TechnologyLahore 54890Pakistan Pak-Austria Fachhochschule:Institute of Applied Sciences and Technology Mang Haripur 22621Khyber PakhtunkhwaPakistan College of Mechatronics and Control Engineering Shenzhen UniversityShenzhen 518000GuangdongChina Laboratory of Electrochemical Devices Based on Solid Oxide Proton Electrolytes Institute of High Temperature Electrochemistry620066 EkaterinburgRussia

Complex oxides are an important class of materials with enormous potential for electrochemical *** on their composition and structure,such complex oxides can exhibit either a single conductivity(oxygen-ionic or protonic,or n-type,or p-type electronic)or a combination thereof gener-ating distinct dual-conducting or even triple-conducting *** properties enable their use as diverse functional materials for solid oxide fuel cells,solid oxide electrolysis cells,permeable membranes,and gas *** literature review shows that the field of solid oxide materials and related electro-chemical cells has a significant level of research engagement,with over 8,000 publications published since *** manual analysis of such a large volume of material is ***,by examining the review articles,it is possible to identify key patterns,recent achievements,prospects,and remaining *** perform such an analysis,the present article provides,for the first time,a comprehensive summary of previous review publications that have been published since 2020,with a special focus on solid oxide materials and electrochemical ***,this study provides an important reference for researchers specializing in the fields of solid state ionics,high-temperature electrochemistry,and energyconversiontechnologies.

关键词： SOFCs SOECs PCFCS Electrochemistry Energy conversion Hydrogen energy,Carbon neutrality

Artificial enhancement of sturgeon stock in freshwater reservoirs:A case study on sterlet Acipenser ruthenus of the Kama reservoir

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Aquaculture and Fisheries 2024年第2期9卷 287-294页

作者： Pavel B.Mikheev Semyon N.Kazarinov Alla G.Melnikova stanislav v.Ponosov Nikolai G.Petrenko Andrei I.Nikiforov Alexey Yu Puzik Olga N.Elchenkova Perm State National Research University Perm614990Russia Khabarovsk Branch of the Federal State Budget Scientific Institution“Russian Federal Research Institute of Fisheries and Oceanography”“KhabarovskNIRO” Khabarovsk680038Russia Perm Branch of the Federal State Budget Scientific Institution“Russian Federal Research Institute of Fisheries and Oceanography”“PermNIRO” Perm614991Russia Federal State Budget Scientific Institution“Russian Federal Research Institute of Fisheries and Oceanography”“vNIRO” Moscow117454Russia Moscow State Institute of International Relations(University)of the Ministry for Foreign Affairs of Russia“MGIMO” Moscow117454Russia Department of State Control Supervision and Protection of Aquatic Biological Resources for Perm KraiMiddle-Volga Regional Office of the Federal Fishery AgencyPerm614990Russia

The paper presents the results of the sterlet sturgeon Acipenser ruthenus reintroduction into the Kama Reservoir(Perm Krai,Russia)by sterlet fry from hatcheries into the reservoir since *** effectiveness of hatchery releases was evaluated by monitoring gillnet sampling *** results showed that the species was reported throughout entire Kama Reservoir,which contrasts with 1988-1994 data,when the species was registered only at the upper part of the reservoir near the Kama River *** highest number and biomass values of catch per unit effort(CPUE)of the sterlet were found in submerged river channels-the deepest habitats with flow conditions which are close to the ecological requirements of the *** distribution of the sterlet within the channel biotopes of the reservoir is defined by reduced *** biggest individuals and the widest size range of the sterlet were typical for the upper area of the reservoir and Chusovskoy Bay,which have the greatest *** smallest sizes were typical for fish from catches near the dam of the reservoir,which is consistent with the published data on the distribution of sterlet in reservoir *** presented results may indicate the artificial formation of the sterlet stock in the Kama Reservoir maintained by hatchery *** revealed distribution of the sterlet in the reservoir determines the direction of further research on natural reproduction and thus formation of an artificially formed ***,future studies are required to assess the possibility of hybridization of the sterlet of artificial origin with natural populations of the species,since the low genetic diversity of the sterlet released into the Kama Reservoir which can lead to irreversible loss of genetic individuality of the natural stocks of the species in the catchment of upper course of the Kama River.

关键词： Sterlet Acipenser ruthenus Kama reservoir Hatchery releases CPUE Artificial stock formation

Large-scale error-tolerant programmable interferometer fabricated by femtosecond laser writing

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Photonics Research 2024年第3期12卷 I0028-I0040页

作者： ILYA KONDRATYEv vERONIKA IvANOvA SUREN FLDZHYAN ARTEM ARGENCHIEv NIKITA KOSTYUCHENKO SERGEY ZHURAvITSKII NIKOLAY SKRYABIN IvAN DYAKONOv MIKHAIL SAYGIN stanislav STRAUPE ALEXANDER KORNEEv SERGEI KULIK Quantum Technology Centre and Faculty of Physics M.V.Lomonosov Moscow State UniversityMoscow 119991Russia Russian Quantum Center Moscow 121205Russia Laboratory of Quantum Engineering of Light South Ural State UniversityChelyabinsk 454080Russia

We introduce a programmable eight-port interferometer with the recently proposed error-tolerant architecture capable of performing a broad class of *** interferometer has been fabricated with femtosecond laser writing,and it is the largest programmable interferometer of this kind to *** have demonstrated its advantageous error tolerance by showing an operation in a broad wavelength range from 920 to 980 nm,which is particularly relevant for quantum photonics due to efficient photon sources existing in this wavelength *** work highlights the importance of developing novel architectures of programmable photonics for information processing.

关键词： interferometer laser femtosecond

Assessment of the thermal effect of large industrial buildings on permafrost foundation soils in Yakutsk

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Research in Cold and Arid Regions 2023年第6期15卷 262-267页

作者： Rudolf v.Zhang stanislav I.Zabolotnik Pavel S.Zabolotnik Melnikov Permafrost Institute SB RAS Yakutsk 677010Russia

The results of monitoring studies of the ground thermal state beneath the Yakutsk Combined Heat and Power Plant buildings are presented in order to determine their structural stability and the possibility of further troublefree operation of the entire complex of the *** main causes for the formation of water-bearing taliks under and adjacent to the buildings are presented,and the factors influencing the existing geocryological situation are *** continuing stable state of the buildings demonstrates the possibility of using two construction principles on permafrost at one site,including preserving permafrost and accommodating permafrost thawing.

关键词： Yakutsk Combined Heat and Power Plant Permafrost Talik Ground temperature

Comprehensive semen examination in patients with pancreatic-sufficient and pancreatic-insufficient cystic fibrosis

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Asian Journal of Andrology 2023年第5期25卷 591-597页

作者： Anna O Sedova Maria I Shtaut Elizaveta E Bragina Tatyana M Sorokina Galina v Shmarina Marina v Andreeva Lyubov E Kurilo stanislav A Krasovskiy Aleksander v Polyakov vyacheslav B Chernykh Research Centre for Medical Genetics Russia Moscow 115522

We examined a cohort of 93 cystic fibrosis(CF)male patients who were pancreatic-sufficient(PS-CF;n=40)or pancreatic-insufficient(PI-CF;n=53).Complex semen examination was performed,including standard semen analysis,quantitative karyological analysis(QKA)of immature germ cells(IGCs),transmission electronic microscopy(TEM),biochemical analysis,and sperm DNA fragmentation by terminal deoxynucleotidyl transferase-mediated dUTP nickend labeling(TUNEL)*** was diagnosed in 83(89.2%)*** other 10(10.8%)patients were found to be nonazoospermic and showed various spermatological diagnoses(asthenozoospermia,n=2;asthenoteratozoospermia,n=3;oligoasthenozoospermia,n=1;oligoasthenoteratozoospermia,n=3;and normozoospermia,n=1)with no specific morphological *** was detected in 89.2%azoospermic and 30.0%nonazoospermic *** seminal pH(vealed in 2.4%azoospermic and 40.0%nonazoospermic semen *** signs of partial meiotic arrest at prophase I were found in 4 of 6 nonazoospermic patients examined by QKA of *** content of fructose and citrate was low in oligospermic and normal in nonoligospermic semen *** increased percentage(>30%)of spermatozoa with noncondensed(“immature”)chromatin was revealed in 2 of 6 nonazoospermic semen samples analyzed by TEM.

关键词： congenital bilateral agenesia/aplasia of vas deferens cystic fibrosis cystic fibrosis transmembrane conductance regulator gene semen spermatozoa

Effects of Morphological Integrity of Secondary Feather on Their Drag Reduction in Pigeons

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Journal of Bionic Engineering 2022年第5期19卷 1422-1438页

作者： Qian Li Huan Shen Qingfei Han Aihong Ji Zhendong Dai stanislav N.Gorb Institute of Bio-Inspired Structure and Surface Engineering College of Mechanical and Electrical EngineeringNanjing University of Aeronautics and Astronautics29 Yudao StreetNanjing 210016China Department of Functional Morphology and Biomechanics Kiel UniversityAm Botanischen Garten 924118 KielGermany

Flight feathers of birds interact with the air flow during *** the observed low drag and high lift values at wind speeds from 9.0 to 19.8 m/s can be achieved due to the feather aerodynamics remains *** the present paper,we tested and compared morphological changes,drag reduction and flow visualization results of intact,damaged,and artificial feathers at different wind speeds in a wind *** the analysis of the drag force and resultant force angle,we proved that the integrity of feathers,whose barbs are usually closely interconnected,played an important role in the drag,which potentially triggers excellent drag reduction *** wind tunnel tests indicated that intact secondary feathers had a surprisingly high maximum drag reduction property at v?=?9 m/s compared with the feathers,where the integrity of barbs was *** hook cascades facilitated elasticity under pressure and suitable permeability in an intact feather,when the hooks were *** was indicated that the suitable permeability of intact feathers would prevent flow separation and reduce drag force at low wind speed;at high wind speed,elasticity under pressure and suitable permeability in an intact feather would facilitate strong squeezing effect,helping feathers withstand larger aerodynamic forces to which they might be subjected during *** was revealed that the intact secondary feather is a compromise between strong lift generation and drag reduction,which has a great significance for the bird’s flight.

关键词： Morphological integrity Secondary feather Drag reduction Wind tunnel Smoke visualization Bioinspiration

Euthanasia:National and International Experience(Based on the European Court of Human Rights Practice Materials)

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Journal of Forensic Science and Medicine 2023年第1期9卷 33-37页

作者： Olena O.Orlova Tetiana M.Alforova Tetiana M.Lezhnieva stanislav v.Chernopiatov Oleh v.Kyrychenko Department of General Legal Disciplines Faculty of LawDnipropetrovsk State University of Internal AffairsDniproUkraine Department of Law Faculty of Law and PsychologyDnipro Humanitarian UniversityDniproUkraine

Purpose:The relevance of the study is that today,there is no unanimous position on the right to euthanasia *** European Court of Human Rights(ECtHR),in making its decision,relies on the national legislation of the respective state,as there is no single decision on the right to euthanasia in the European ***,the aim of the article is to comprehensively study the phenomenon of euthanasia,elaborate the decisions of the ECtHR on euthanasia and related rights,and develop recommendations on the possibility of legalizing euthanasia in Ukraine and prospects for the right to die ***:The leading method of research of this issue is comparative and law,which allows to comprehensively consider the right to euthanasia and its positive and negative components and helps to establish trends in the implementation of the outlined ***:The article analyzes the current state of international and domestic legislation of some states on the use of euthanasia,reveals the meaning of the term“euthanasia,”provides a classification of euthanasia,analyzes the decisions of the ECtHR,and presents examples of national legislation of states within which euthanasia is legalized,the peculiarities of euthanasia recognition in the world are analyzed,as well as the research on the possibility of euthanasia legalization in Ukraine is ***:The materials of the article have practical value for all those interested in euthanasia and the realization of the right to die,as well as for practicing lawyers and judicial authorities.

关键词： Medical assistance in dying rules of end‑of‑life care the right to die the right to life treatment refusal

The role of mRNA splicing in prostate cancer

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Asian Journal of Andrology 2014年第4期16卷 515-521页

作者： Anna v Lapuk stanislav v volik Yuzhuo Wang Colin C Collins vancouver Prostate CentreUniversity of British Columbia Vancouver BC Canada. Department of Experimental Therapeutics BC Cancer AgencyUniversity of British Columbia Vancouver BC Canada. Department of Urologic Sciences University of British Columbia Vancouver BC Canada.

Alternative splicing （AS） is a crucial step in gene expression. It is subject to intricate regulation, and its deregulation in cancer can lead to a wide array of neoplastic phenotypes. A large body of evidence implicates splice isoforms in most if not all hallmarks of cancer, including growth, apoptosis, invasion and metastasis, angiogenesis, and metabolism. AS has important clinical implications since it can be manipulated therapeutically to treat cancer and represents a mechanism of resistance to therapy. In prostate cancer （PCa） AS also plays a prominent role and this review will summarize the current knowledge of alternatively spliced genes with important functional consequences. We will highlight accumulating evidence on AS of the components of the two critical pathways in PCa： androgen receptor （AR） and phosphoinositide 3-kinase （PI3K）. These observations together with data on dysregulation of splice factors in PCa suggest that AR and PI3K pathways may be interconnected with previously unappreciated splicing regulatory networks. In addition, we will discuss several lines of evidence implicating splicing regulation in the development of the castration resistance.

关键词： alternative splicing prostate cancer androgen receptor PI3K pathway CRPC neuroendocrine transdifferentiation REST repressor complex