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Visible-light-mediated tungsten-catalyzed C-H amination of unactivated alkanes with nitroarenes

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Science China Chemistry 2022年第4期65卷 678-685页

作者： Qing Wang shengyang ni Xiaochen Wang Yi Wang Yi Pan State Key Laboratory of Coordination Chemistry Jiangsu Key Laboratory of Advanced Organic MaterialsSchool of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China

Alkylamines are important motifs in pharmaceutical and material *** existing reports of C-H amination are limited to ammonia,diazo and azide nitrogen *** work describes a rapid construction of C-N bonds from accessible nitroarene and alkane feedstock under decatungstate catalysis.A variety of C-H precursors including gaseous,linear,cyclic and benzylic hydrocarbons could adopt this protocol to afford the corresponding alkylamines in high efficiency.

关键词： amination photoredox light alkane nitrobenzene

Humic acid and metal ions accelerating the dechlorination of 4-chlorobiphenyl by nanoscale zero-valent iron

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Journal of Environmental Sciences 2011年第8期23卷 1286-1292页

作者： Yu Wang Dongmei Zhou Yujun Wang Xiangdong Zhu shengyang Jin State Key Laboratory of Soil and Sustainable Agriculture Institute of Soil Science Chinese Academy of Sciences Nanjing 210008 China. Graduate University of Chinese Academy of Sciences Beijing 100049 China

Transformation of polychlorinated biphenyls （PCBs） by zero-valent iron represents one of the latest innovative technologies for environmental remediation. The dechlorination of 4-chlorobiphenyl （4-C1BP） by nanoscale zero-valent iron （NZVI） in the presence of humic acid or metal ions was investigated. The results showed that the dechlorination of 4-C1BP by NZVI increased with decreased solution pH. When the initial pH value was 4.0, 5.5, 6.8, and 9.0, the *** efficiencies of 4-CIBP after 48 hr were 53.8%, 47.8%, 35.7%, and 35.6%, respectively. The presence of humic acid inhibited the reduction of 4-CIBP in the first 4 hi＇, and then significantly accelerated the dechlorination by reaching 86.3% in 48 hr. Divalent metal ions, Co2＋, Cu2＋, and ni2＋, were reduced and formed bimetals with NZVI, thereby enhanced the dechlorination of 4-CIBP. The dechlorination percentages of 4-CIBP in the presence of 0.1 mmol/L Co2~, Cuz~ and niz~ were 66.1%, 66.0% and 64.6% in 48 hr, and then increased to 67.9%, 71.3% and 73.5%, after 96 hr respectively. The dechlorination kinetics of 4-C1BP by the NZVI in all cases followed pseudo-first order model. The results provide a basis for better understanding of the dechlorination mechanisms of PCBs in real environment.

关键词： 4-chlorobiphenyl nanoscale zero-valent iron humic acid metal ions dechlorination

MICROSTRUCTURE AND CORROSION BEHAVIOR OF 70Cu-30ni WELDED PIPE

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中国有色金属学会会刊：英文版 1995年第2期5卷 88-92页

作者： Wang,Jihui Jiang, Xiaoxia Li,Shizhuo(Institute of Metal Research, Chinese Academy of Sciences,shengyang 110015) Chinese Acad of Sciences Shengyang China

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关键词： cupronickel alloy welding corrosion behavior

COLOR CHARACTERISTICS OF BINARY COPPER-BASE ALLOYS

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中国有色金属学会会刊：英文版 1993年第3期3卷 61-65页

作者： Li, Baomian Liu, Hongcheng Li, Anguo Shenyang Institute of Gold Technology, shengyang 110015, China

The effect of Al, Zn, Sn, Mn, Si and ni on the color characteristics of binary copper-base alloys has been researched systematically and quantitatively. The results show that all alloying elements decrease the red content of an alloy at different levels but have different effects on the yellow color. Al and Zn enhance the yellow content of an alloy, whereas Sn, Mn, Si and ni decrease the yellow content. When the alloys with different karat gold colors are imitated, Al and Zn are the most important color mixing elements and Sn, Mn, Si and ni can be used as auxiliary.

关键词： alloy color alloying elements red content yellow content binary copper-base alloys zinc aluminum

Collision-induced Rotational Energy Transfer in an Atom-Diatom System

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Chinese Journal of Chemical Physics 2008年第5期21卷 457-462页

作者： Yan-qing ni Jian Li Feng-cai Ma Department of Physics Liaoning University Shenyang 110036 China Department of Science Shenyang Institute of Aeronautical Engineering Shengyang 110036 China

As a further theoretical study of the collision-induced quantum interference on rotational energy transfer in an atom-diatom system, based on the first-Born approximation of time-dependent perturbation theory, taking into account the anisotropic Lennard-Jones interaction potential and the long-range interaction potential, the differential interference angles in singlet-triplet mixed states of CO A^1Π（v=9）-e3∑-（v=1） system in collision with He, Ne, Ar, and other partners were calculated theoretically. The relationships of differential interference angle versus impact parameters, including collision parameter b and velocity, are obtained.

关键词： Rotational energy transfer Collision-induced quantum interference Interference angle

Characteristics of “Guangyuan-Wangcang” trough during Late Middle Permian and its petroleum geological significance in northern Sichuan Basin, SW China

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Petroleum Exploration and Development 2021年第3期48卷 655-669页

作者： WANG Xingzhi LI Bo YANG Xiyan WEN Long XU Liang XIE shengyang DU Yao FENG Mingyou YANG Xuefei WANG Yaping PEI Senqi State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum UniversityChengdu 610500China School of Geoscience and Technology Southwest Petroleum UniversityChengdu 610500China Research Institute of Exploration and Development PetroChina Southwest Oil&Gasfield CompanyChengdu 610500China Exploration Division of PetroChina Southwest Oil&Gasfield Company Chengdu 610500China Northwest Sichuan Gas Mine of PetroChina Southwest Oil&Gasfield Company Jiangyou 621700China

Based on outcrop characteristics, combined with regional tectonic background, drilling and geophysical data, the sedimentary characteristics of the Middle Permian Maokou Formation in the northern Sichuan Basin was studied by means of macroscopic and microscopic observation, geochemical element test, total organic carbon content and vitrinite reflectance measurement. There is a set of deep-water sediments rich in organic matter in the Guangyuan-Wangcang area of northern Sichuan during the late depositional period of the Middle Permian Maokou Formation. The strata are distributed from northwest to southeast, with thickness of 10–30 m, mainly composed of siliceous rocks and siliceous mudstones, intercalated with gravity flow deposits. Siliceous rocks and siliceous mudstones are characterized by thin single layer, flat bedding and rich siliceous radiolarians, calthrop and brachiopod with small body and thin shell, belonging to the typical sedimentary characteristics of deep-water trough facies. The contents of Cu, Co, Mo, ni and the ratio of ni to Co in the geochemical tests all indicate that the siliceous rocks are products of deep-water reducing environment. The TOC value ranges from 3.21% to 8.19%, with an average of 5.53%, indicating that the siliceous rocks have good hydrocarbon generation ability. The south side of the trough is in platform margin facies with high energy, and the sediments are mainly thick massive micritic-calcsparite biogenic(clastic) limestone, which is conducive to the formation and evolution of the reservoir. During the late sedimentary period of the Maokou Formation, the northward subduction and extension of the oceanic crust at the northwestern margin of the Yangtze Plate provided the internal dynamic conditions for the formation of the "Guangyuan-Wangcang" trough. According to the location, sedimentary characteristics and formation dynamics of the trough, it is similar to the "Kaijiang-Liangping" trough during Late Permian proposed by previ

关键词： Sichuan Basin Guangyuan-Wangcang trough Middle Permian Maokou Formation deep-water deposition siliceous rock

Photo-induced self-formation of dual-cocatalysts on semiconductor surface

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Chinese Journal of Catalysis 2018年第11期39卷 1730-1735页

作者： Linchao Mu Qiao Zhang Xiaoping Tao Yue Zhao shengyang Wang Junyan Cui Fengtao Fan Can Li State Key Laboratory of Catalysis Dalian National Laboratory for Clean Energyand the Collaborative Innovation Center of Chemistry for Energy Materials(iChEM)Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina University of Chinese Academy of Sciences Beijing 100049China

Cocatalyst plays key roles in photogenerated charge separation and surface catalytic reactions in ***,it is not clear if the chemical states of cocatalysts changed or remains unchanged under photocatalytic reaction ***,taking NaTaO3 as an example,we systemically investigated the chemical states of nickel‐based cocatalysts during photocatalytic water splitting *** was found that photo‐induced self‐formation of ni and niO cocatalyst species take place on the surface of NaTaO3 *** self‐formation of dual‐cocatalysts not only occurs on 26‐facet NaTaO3,but also takes place on a more general 6‐facet *** work clarified that the chemical states of cocatalysts are changing and the redox dual‐cocatalysts are redistributed on the semiconductor surface owing to the reaction induced by photogenerated charges under the condition of photocatalytic reactions.

关键词： Photocatalysis Cocatalyst Chemical state Photogenerated charges Self‐formation