Visible-light-mediated tungsten-catalyzed C-H amination of unactivated alkanes with nitroarenes

作     者：Qing Wang Shengyang Ni Xiaochen Wang Yi Wang Yi Pan Qing Wang;Shengyang Ni;Xiaochen Wang;Yi Wang;Yi Pan

作者机构：State Key Laboratory of Coordination ChemistryJiangsu Key Laboratory of Advanced Organic MaterialsSchool of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2022年第65卷第4期

页      面：678-685页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(21772085,21971107,2201101) China Postdoctoral Science Foundation(2021T140309,2021M691511) 

主　　题：amination photoredox light alkane nitrobenzene 

摘      要：Alkylamines are important motifs in pharmaceutical and material *** existing reports of C-H amination are limited to ammonia,diazo and azide nitrogen *** work describes a rapid construction of C-N bonds from accessible nitroarene and alkane feedstock under decatungstate catalysis.A variety of C-H precursors including gaseous,linear,cyclic and benzylic hydrocarbons could adopt this protocol to afford the corresponding alkylamines in high efficiency.