Visible-light-mediated tungsten-catalyzed C-H amination of unactivated alkanes with nitroarenes
Visible-light-mediated tungsten-catalyzed C–H amination of unactivated alkanes with nitroarenes作者机构:State Key Laboratory of Coordination ChemistryJiangsu Key Laboratory of Advanced Organic MaterialsSchool of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China
出 版 物:《Science China Chemistry》 (中国科学(化学英文版))
年 卷 期:2022年第65卷第4期
页 面:678-685页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:supported by the National Natural Science Foundation of China(21772085,21971107,2201101) China Postdoctoral Science Foundation(2021T140309,2021M691511)
主 题:amination photoredox light alkane nitrobenzene
摘 要:Alkylamines are important motifs in pharmaceutical and material *** existing reports of C-H amination are limited to ammonia,diazo and azide nitrogen *** work describes a rapid construction of C-N bonds from accessible nitroarene and alkane feedstock under decatungstate catalysis.A variety of C-H precursors including gaseous,linear,cyclic and benzylic hydrocarbons could adopt this protocol to afford the corresponding alkylamines in high efficiency.