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Utilization of nano/micro-size iron recovered from the fine fraction of automobile shredder residue for phenol degradation in water

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Frontiers of Environmental Science & Engineering 2016年第4期10卷 53-59页

作者： Jiwan SINGH Yoon-young CHANG jae-Kyu YANG Seon-Hong KANG Janardhan Reddy KODURU Department of Environmental Engineering Kwangwoon University Seoul 139-701 Republic of Korea Division of General Education Kwangwoon University Seoul 139-701 Republic of Korea Graduate School of Environmental S~dies Kwangwoon university Seoul 139-701 Republic of Korea

The study investigates the magnetic separation of Fe from automobile shredder residue （ASR）（〈 0.25 mm） and its application for phenol degradation in water. The magnetically separated Fe was subjected to an ultrasonically assisted acid treatment, and the degradation of phenol in an aqueous solution using nano/micro-size Fe （n/m Fe） was investigated in an effort to evaluate the possibility of utilizing n/m Fe to remove phenol from wastewater. The prepared n/m Fe was analyzed by scanning electron microscopy （SEM） and Fourier transform infrared spectroscopy （FTIR）. The eflects of the dosages ot n/mFe, pH, concentration of phenol and amount of H2O2 on phenol removal were evaluated. The results confirm that the phenol degradation rate was improved with an increase in the dosages of n/mFe and H2O2; however, the rate is reduced when the phenol concentration is higher. The degradation of phenol by n/mFe followed the pseudo-first-order kinetics. The value of the reaction rate constant （k）was increased as the amounts of n/m Fe and H2O2 increased. Conversely, the value of k was reduced when the concentration of phenol was increased. The probable mechanism behind the degradation of phenol by n/m Fe is the oxidation of phenol through hydroxyl radicals which are produced during the reaction between H2O2 and n/m Fe.

关键词： Automobile shredder residue (ASR)Fe Phenol Scanning electron microscopy (SEM) andFourier transform infrared spectroscopy(FTIR)Mechanism

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Review on the characteristics of liver-pacifying medicinal in relation to the treatment of stroke: from scientific evidence to traditional medical theory

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Journal of Traditional Chinese Medicine 2018年第1期38卷 139-150页

作者： Kyungjin Lee Hyejin Joo Meixiang Sun Minwoo Kim Bumjung Kim Beom-Joon Lee jae-Heung Cho jae-young Jung jae-Woo Park youngmin Bu Department of Herbal Pharmacology College of Korean Medicine Kyung Hee University Department of Science in Korean medicine Graduate School Kyung Hee University Division of Allergy Immune and Respiratory System Department of Internal Medicine College of Korean Medicine Kyung Hee University Department of Korean Rehabilitation Medicine College of Korean Medicine Kyung Hee University Department of Internal Medicine College of Korean Medicine Kyung Hee University

OBJECTIVE： To analyze the characteristics of liver pacifying medicinal in the treatment of brain disease to provide scientific evidence in clinical usage on ***： MEDLINE/PubMed, Google Scholar, and China National Knowledge Infrastructure Database were used as the literature sources. The Scientific name, Latin pharmaceutical name, Chinese name of 7 kinds of liver pacifying medicinal including Gouteng （Ramulus Uncariae Rhynchophyllae cure Uncis）, Tianma （Rhizoma Gastrodiae）, Juemingzi （Semen Cassiae Obtusifoliae）, Quanxie （Scorpio）, Wugong （Scolopendra）, Jiangcan （Bombyx Batryticatus）, and Dilong （Pheretima Aspergillum） were used as the keywords to search the databases for relevant publications up to July 2016. Their major compounds were also used as the keywords. The papers were selected based on the pharmacological activities and mechanisms of action related to brain diseases and subsequently, were analyzed and reviewed. We first described the origin, efficacy, and clinical indications of selected medicines, then brain disease specific activities focusing on stroke after the description of the general pharmacological activities. RESULTS： On the basis of the literature of scientific studies and clinical use in traditional medicine, we found and discussed the characteristics of liver pacifying medicinal in stroke treatment. First, liver-pacifying medicinal, or their components, might pass through the blood-brain barrier and act directly on neurons or on the neural network to provide protective effects against brain disease. Second, although it could be used throughout the disease duration, treatment of stroke might be more effective from the subacute up to the convalescent phase than the acute ***： We can suggest that live pacifying medicinal has beneficial pharmacological activities directly or indirectly on neurons in brain disease and is useful for the treatment of stroke from subacute to convalescent phase.

关键词： Stroke Traditional medicine Calming liver wind Review

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Non-Invasive Measurements of Thickness of Superconductor Films by Using Two-Resonant-Mode Rutile Resonator

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Chinese Physics Letters 2010年第8期27卷 203-206页

作者： JUNG Ho Sang YANG Woo Il LEE jae Hun SOHN jae Min CHOO Kee Nam KIM Bong Goo LEE Sang young Department of Physics and Center for Wireless Transmission Technology Konkuk University Seoul 143-701 Korea Research Reactor Engineering Division Korea Atomic Energy Research Institute Daejeon 305-600 Korea

The film thickness should be known for extrazting the intrinsic surface resistance from the effective surface resistance as measured by using the dielectric resonator method. Thicknesses of 70 nm to 360 nm are measured for YBa2 Cu3 O7-δ films in a non-invasive way by using the two-resonant-mode dielectric resonator （TDR） method. A futile resonator with the respective resonant frequencies of 15.25-15.61 GHz and 15.10-15.37 GHz for the TE021 and the TE012 modes is used for this purpose. Differences between the values as measured by using the TDR technique and those measured by using a step profilometer appear to be less than 3%, which is smaller than the previous value of 5% as measured by using a 8. 6 GHz single-resonance mode futile resonator [Lee et al. J. Korean Phys. Soc. 54（2009）1619]. Merits of using the TDR method are discussed.

关键词： THICKNESS measurement SUPERCONDUCTORS THIN films RUTILE DIELECTRIC resonators PROFILOMETER ELECTRIC resistance SURFACES (Technology)

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Dipole-assisted carrier transport in bis(trifluoromethane) sulfonamide-treated O-ReS_(2) field-effect transistor

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Nano Research 2021年第7期14卷 2207-2214页

作者： jae young Park SangHyuk Yoo Byeongho Park Taekyeong Kim young Tea Chun Jong Min Kim Keonwook Kang Soo Hyun Lee Seong Chan Jun Department of Mechanical Engineering Yonsei UniversitySeoul 03722Republic of Korea Center for Biomicrosystem Brain Science InstituteKorea Institute of Science and TechnologySeoul 02792Republic of Korea Sensor System Research Center Korea Institute of Science and TechnologySeoul 02792Republic of Korea Department of Physics Hankuk University of Foreign StudiesYongin 17035Republic of Korea Division of Electronics and Electrical Information Engineering Korea Maritime and Ocean UniversityBusan 49112Republic of Korea Electrical Engineering Division Engineering Department University of CambridgeCambridgeCB3 OFAUK

We demonstrate the dipole-assisted carrier transport properties of bis(trifluoromethane)sulfonamide(TFSI)-treated O-ReS_(2) field-effect *** ReS_(2) was compared with defect-mediated ReS_(2) to confirm whether the presence of defects on the interface enhances the interaction between O-ReS_(2) and TFSI *** to the experiment,density functional theory(DFT)calculation was performed,and the result indicated that the charge transfer between TFSI and O-ReS_(2) is more sensitive to external electric fields than that between TFSI and pristine ReS_(2).After TFSI treatment,the drain current of O-ReS_(2) FET was significantly increased up to 1,113.4 times except in the range of−0.32–0.76 V owing to Schottky barrier modulation from dipole polarization of TFSI molecules,contrary to a significant degradation in device performance in pristine ReS_(2) ***,in the treated O-ReS_(2) device,the dipole direction was highly influenced by the voltage sweep direction,generating a significant area of hysteresis in I–V and transfer characteristics,which was further verified by the surface potential ***,the dipole state was enhanced according to the wavelength of the light source and *** results indicate that TFSI-treated ReS_(2) FET has large potential for use as next-generation memristor,memory,and photodetector.

关键词： Two-dimensional material ReS_(2) field-effect transistor TFSI superacid dipole

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The Spatial Effects of Antenna Configuration in a Large Area Inductively Coupled Plasma System for Flat Panel Displays

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Plasma Science and Technology 2014年第8期16卷 758-766页

作者： Seon-Geun OH young-Jun LEE jae-Hong JEON Jong-Hyeon SEO Hee-Hwan CHOE School of Electronics Telecommunication and Computer EngineeringKorea Aerospace University Department of Material Science and Engineering Korea Aerospace University

Spatial distributions of plasma parameters such as electron density, electron temperature and electric potential were investigated using a commercial simulation software （COMSOLTM） to predict the effects of antenna configuration in a large area inductively cou- pled plasma （ICP） system for flat panel displays. Nine planar antenna sets were evenly placed above a ceramic window. While the electron density was influenced by both the input current and gas pressure, the electron temperature and electric potential were dominantly affected by the gas pressure.

关键词： plasma ICP antenna configuration simulation

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Sorption enhanced catalytic CF4 hydrolysis with a three-stage catalyst-adsorbent reactor

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Frontiers of Chemical Science and Engineering 2017年第4期11卷 537-544页

作者： jae-Yun Han Chang-Hyun Kim Boreum Lee Sung-Chan Nam Ho-young Jung Hankwon Lim Kwan-young Lee Shin-Kun Ryi . Advanced Materials and Devices Laboratory Korea Institute of Energy Research (KIER) Daejeon 34129 Korea.. Department of Advanced Materials and Chemical Engineering Catholic University of Daegu Gyeongbuk 38430 Korea.. Department of Environment and Energy Engineering Chonnam National University Gwangju 61186 Korea.. Department of Chemical and Biological Engineering Korea University Seoul 136-701 Korea

In this study, we developed a three-stage catalyst-adsorbent reactor for the catalytic hydrolysis of CF4. Each stage is composed of a catalyst bed followed by an adsorbent bed using Ca（OH）2 to remove HF. The three stages are connected in series to enhance the hydrolysis of CF4 and eliminate a scrubber to dissolve HF in water at the same time. With a 10 wt-% Ce/AlaO3 catalyst prepared by the incipient wetness method using boehmite and a granular calcium hydroxide as an adsorbent, the CF4 conversion in our proposed reactor was 7%-23% higher than that in a conventional single-bed catalytic reactor in the temperature range of 923-1023 K. In addition, experimental and numerical simulation （Aspen HYSYS） results showed a reasonable trend of increased CF4 conversion with the adsorbent added and these results can be used as a useful design guideline for our newly proposed multistage reactor system.

关键词： PFCs catalytic hydrolysis calcium hydro-xide sorption enhanced process simulation

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Some Radius Problems Related to a Certain Subclass of Analytic Functions

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Acta Mathematica Sinica,English Series 2014年第7期30卷 1133-1144页

作者： Oh Sang KWON young jae SIM Nak Eun CHO H.M.SRIVASTAVA Department of Mathematics Kyungsung University Department of Applied Mathematics Pukyung National University Department of Mathematics and Statistics University of Victoria

For real parameters αand β such that 0≤α 〈 1 〈β, we denote by S（α,β） the class of normalized analytic functions which satisfy the following two-sided inequality：where U denotes the open unit disk. We find a sufficient condition for functions to be in the class S（α,β） and solve several radius problems related to other well-known function classes.

关键词： Analytic functions univalent functions starlike functions functions of bounded real pos-itive real part radius problems

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Lactobacillus plantarum inhibits epithelial barrier dysfunction and interleukin-8 secretion induced by tumor necrosis factor-a

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World Journal of Gastroenterology 2007年第13期13卷 1962-1965页

作者： jae Sung Ko Hye Ran Yang Ju young Chang Jeong Kee Seo Department of Pediatrics Seoul National University College of Medicine Seoul 110-744 Korea

AIM： To determine whether Lactobacillus plantarum can modify the deleterious effects of tumor necrosis factor-α （TNF-α） on intestinal epithelial cells. METHODS： Caco-2 cells were incubated with TNF-α alone or in the presence of L. plantarum. Transepithelial electrical resistance was used to measure epithelial barrier function. Interleukin 8 （IL-8） secretion by intestinal epithelial cells was measured using an ELISA. Cellular lysate proteins were immunoblotted using the anti-extracellular regulated kinase （ERK）, anti-phospho- ERK and anti-IκB-α. RESULTS： A TNF-α-induced decrease in transepithelial electrical resistance was inhibited by L. plantarum. TNF- α-induced IL-8 secretion was reduced by L. plantarum. L. plantarum inhibited the activation of ERK and the degradation of IκB-α in TNF-a-treated Caco-2 cells. CONCLUSION： Induction of epithelial barrier dysfunction and IL-8 secretion by TNF-α is inhibited byL. plantarum. Probiotics may preserve epithelial barrier function and inhibit the inflammatory response by altering the signal transduction pathway.

关键词： Lactobacillus plantarum Tumor necrosisfactor-α Epithelial barrier Interleukin-8 ERK IκB-α

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Accuracy of an administrative database for pancreatic cancer by international classification of disease 10th codes: A retrospective large-cohort study

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World Journal of Gastroenterology 2019年第37期25卷 5619-5629页

作者： young-jae Hwang Seon Mee Park Soomin Ahn Jong-Chan Lee young Soo Park Nayoung Kim Departments of Internal Medicine Seoul National University Bundang HospitalSeoungnam 13620South Korea Department of Internal Medicine Chungbuk National University College of Medicine and Medical Research InstituteCheongju 28644South Korea Departments of Pathology Seoul National University Bundang HospitalSeoungnam 13620South Korea Department of Internal Medicine and Institute of Liver Research and Tumor Microenvironment Global Core Research Center Seoul National University College of MedicineSeoul 08826South Korea

BACKGROUND Korean National Health Insurance(NHI)claims database provides ***,studies regarding accuracy of administrative database for pancreatic cancer(PC)have not been *** aimed to identify accuracy of NHI database regarding PC classified by international classification of disease(ICD)-10 *** To identify the accuracy and usefulness of administrative database in PC and the accurate ICD codes for PC with *** Study and control groups were collected from 2003 to 2016 at Seoul National University Bundang *** of PC were identified in NHI database by international classification of diseases,10th revision edition(ICD-10 codes)supported with V codes.V code is issued by medical doctors for covering 95%of medical cost by Korean *** to pathologic reports,definite or possible diagnoses were defined using medical records,images,and *** A total of 1846 cases with PC and controls were *** PC,only 410(22.2%)cases were identified as specific cancer sites including head in 234(12.7%)cases,tail in 104(5.6%)cases and body in 72(3.9%)*** PC,910(49.3%)cases were diagnosed by definite *** of these were adenocarcinoma(98.0%).The rates of definite diagnosis of PC were highest in head(70.1%)followed by body(47.2%)and tail(43.3%).False-positive cases were pancreatic cystic neoplasm and metastasis to the *** terms of the overall diagnosis of PC,sensitivity,specificity,positive predictive value,and negative predictive value were 99.95%,98.72%,98.70%,and 99.95%,*** accuracy was similar both in terms of diagnostic criteria and tumor *** Korean NHI claims database collected according to ICD-10 code with V code for PC showed good accuracy.

关键词： Korean national health insurance Accuracy Pancreatic cancer International classification of disease Sensitivity Specificity

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Controlling a lithium surface with an alkyl halide nucleophile exchange

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Journal of Energy Chemistry 2021年第11期30卷 617-626,I0015页

作者： Jung-Hun Lee Thuy Hoai Linh Vuong Soo Min Hwang jae-Hun Kim young-Jun Kim SKKU Advanced Institute of Nanotechnology(SAINT) Sungkyunkwan UniversitySuwon 16419Republic of Korea Department of Nano Engineering Sungkyunkwan UniversitySuwon 16419Republic of Korea School of Materials Science and Engineering Kookmin UniversitySeoul 02707Republic of Korea

Despite its high theoretical energy density, lithium metal faces huge challenges in its implementation as an anode for Li secondary batteries because of its uncontrollable dendritic growth and large volume change during plating/stripping processes. These geometric changes cause degradation in a cell’s cycle life and performance and can lead to short-circuits and explosions. Here, we report a new approach to producing a LiF-rich phase on the lithium anode surface by employing a “bi-phase” separator. We fabricated it by coating polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) onto a cellulose separator. The coverage of coating was adjusted by varying its concentration in the coating solution. The combination of cellulose and PVDF-HFP produced a LiF-rich solid-electrolyte interphase layer on the Li metal surface via an alkyl halide nucleophile exchange in contact with the bi-phase separator during plating. Symmetric cell tests show that the bi-phase separator extends the cycle life by more than 300 h, with overpotentials of less than 100 mV under plating/stripping at 2 mA cm^(−2) for a capacity of 2 mAh cm^(−2). The formation mechanism of the LiF-rich phase is suggested from spectroscopic analyses.

关键词： Li metal anode PVDF-HFP Cellulose LiF Phase inversion

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